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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 469 records · Page 26

Airship construction

Forty-four years ago the first successful metal airship was completed and delivered to the United States Navy, the ZMC-2. Between those years and the present, very little effort or serious consideration has been given to the manufacture, design, construction, or economic impact of airships. It is important to retain and exploit the small but continually diminishing pool of airship talent that will expedite the success of the United States in what is now a pioneering venture. The relative simplicity of airship construction, utilizing the tremendous technical advances of the last 44 years, leads to the conclusion that this form of transportation holds great promise for reducing costs of military missions and improving the international competitive position of the United States in commercial applications.

Roda, J.↗

Numerical aperture limits on efficient ball lens coupling of laser diodes to single-mode fibers with defocus to balance spherical aberration

The potential capabilities and limitations of single ball lenses for coupling laser diode radiation to single-mode optical fibers have been analyzed; parameters important to optical communications were specifically considered. These parameters included coupling efficiency, effective numerical apertures, lens radius, lens refractive index, wavelength, magnification in imaging the laser diode on the fiber, and defocus to counterbalance spherical aberration of the lens. Limiting numerical apertures in object and image space were determined under the constraint that the lens perform to the Rayleigh criterion of 0.25-wavelength (Strehl ratio = 0.80). The spherical aberration-defocus balance to provide an optical path difference of 0.25 wavelength units was shown to define a constant coupling efficiency (i.e., 0.56). The relative numerical aperture capabilities of the ball lens were determined for a set of wavelengths and associated fiber-core diameters of particular interest for single-mode fiber-optic communication. The results support general continuing efforts in the optical fiber communications industry to improve coupling links within such systems with emphasis on manufacturing simplicity, system packaging flexibility, relaxation of assembly alignment tolerances, cost reduction of opto-electronic components and long term reliability and stability.

Wilson, R. Gale↗

Infrared Measurement

A Jet Propulsion Laboratory Technical Support Package (TSP) describing a technique for processing data from an infrared radiometer assisted a manufacturer of laminates for printed circuit boards. To reduce emissions and lower the cost of producing prepreg (a continuous glass cloth, or web, impregnated with epoxy resin and partially cured by applying heat), Norplex Oak switched to infrared treating towers. The TSP confirmed the company's computer prediction of heat flux patterns, provided information that allowed the company to modify infrared treaters for consistency, and furnished a basis for development of optimal heater placements. The treaters are now successfully operating at increased speeds with improved product consistency.

Source record↗

Process Optimization of Bismaleimide (BMI) Resin Infused Carbon Fiber Composite

Engineers today are presented with the opportunity to design and build the next generation of space vehicles out of the lightest, strongest, and most durable materials available. Composites offer excellent structural characteristics and outstanding reliability in many forms that will be utilized in future aerospace applications including the Commercial Crew and Cargo Program and the Orion space capsule. NASA's Composites for Exploration (CoEx) project researches the various methods of manufacturing composite materials of different fiber characteristics while using proven infusion methods of different resin compositions. Development and testing on these different material combinations will provide engineers the opportunity to produce optimal material compounds for multidisciplinary applications. Through the CoEx project, engineers pursue the opportunity to research and develop repair patch procedures for damaged spacecraft. Working in conjunction with Raptor Resins Inc., NASA engineers are utilizing high flow liquid infusion molding practices to manufacture high-temperature composite parts comprised of intermediate modulus 7 (IM7) carbon fiber material. IM7 is a continuous, high-tensile strength composite with outstanding structural qualities such as high shear strength, tensile strength and modulus as well as excellent corrosion, creep, and fatigue resistance. IM7 carbon fiber, combined with existing thermoset and thermoplastic resin systems, can provide improvements in material strength reinforcement and deformation-resistant properties for high-temperature applications. Void analysis of the different layups of the IM7 material discovered the largest total void composition within the [ +45 , 90 , 90 , -45 ] composite panel. Tensile and compressional testing proved the highest mechanical strength was found in the [0 4] layup. This paper further investigates the infusion procedure of a low-cost/high-performance BMI resin into an IM7 carbon fiber material and the optical, chemical, and mechanical analyses performed.

Ehrlich, Joshua W.↗

Quantitative NDE of Composite Structures at NASA

The use of composite materials continues to increase in the aerospace community due to the potential benefits of reduced weight, increased strength, and manufacturability. Ongoing work at NASA involves the use of the large-scale composite structures for spacecraft (payload shrouds, cryotanks, crew modules, etc). NASA is also working to enable the use and certification of composites in aircraft structures through the Advanced Composites Project (ACP). The rapid, in situ characterization of a wide range of the composite materials and structures has become a critical concern for the industry. In many applications it is necessary to monitor changes in these materials over a long time. The quantitative characterization of composite defects such as fiber waviness, reduced bond strength, delamination damage, and microcracking are of particular interest. The research approaches of NASA's Nondestructive Evaluation Sciences Branch include investigation of conventional, guided wave, and phase sensitive ultrasonic methods, infrared thermography and x-ray computed tomography techniques. The use of simulation tools for optimizing and developing these methods is also an active area of research. This paper will focus on current research activities related to large area NDE for rapidly characterizing aerospace composites.

Cramer, K. Elliott↗

Research Developments in Nondestructive Evaluation and Structural Health Monitoring for the Sustainment of Composite Aerospace Structures at NASA

The use of composite materials continues to increase in the aerospace community due to the potential benefits of reduced weight, increased strength, and manufacturability. Ongoing work at NASA involves the use of the large-scale composite structures for spacecraft (payload shrouds, cryotanks, crew modules, etc). NASA is also working to enable both the use and sustainment of composites in commercial aircraft structures. One key to the sustainment of these large composite structures is the rapid, in-situ characterization of a wide range of potential defects that may occur during the vehicle's life. Additionally, in many applications it is necessary to monitor changes in these materials over their lifetime. Quantitative characterization through Nondestructive Evaluation (NDE) of defects such as reduced bond strength, microcracking, and delamination damage due to impact, are of particular interest. This paper will present an overview of NASA's applications of NDE technologies being developed for the characterization and sustainment of advanced aerospace composites. The approaches presented include investigation of conventional, guided wave, and phase sensitive ultrasonic methods and infrared thermography techniques for NDE. Finally, the use of simulation tools for optimizing and validating these techniques will also be discussed.

Cramer, K. Elliott↗

Current and Future Needs and Research for Composite Materials NDE

The use of composite materials continues to increase in the aerospace community due to the potential benefits of reduced weight, increased strength, and manufacturability. The ability to characterize damage in carbon fiber reinforced polymer composite components is required to facilitate damage progression models capable of yielding accurate remaining life predictions. As these composite structures become larger and more complex, nondestructive evaluation (NDE) techniques capable of quantifying and fully characterizing the material state are needed to enable damage progression models capable of yielding accurate remaining life predictions. This paper will present an overview of current NDE research activities for quantitative characterization of aerospace composites as well as a discussion of future directions in NDE research.

Cramer, K. Elliott↗

Future Exponential Economic Growth in Space

The human population and economy are now limited by the land area, materials and energy available on Earth. As explained by Malthus, human effort can increase this population limit only gradually and linearly at any fixed level of technology. The unexpected exponential increase in population since Malthus time is due to the even greater exponential increase in agricultural and industrial productivity due to modern technology. Current opinion is divided between the limiters who see fast approaching unavoidable limits to growth and growthers who expect continuing innovation and expansion. Given the minimum energy and food needed to support each human, the population of Earth is necessarily bounded. The past human exponential expansions were based on the invention of agriculture and industry. Continued expansion could occur with future colonization of the solar system. The initial occupation of near-Earth space would probably be for immediate military and economic gains rather than to escape the limits to growth on Earth. Space habitats could exploit solar system energy, materials, and living space, first in the Earth-moon system and later throughout the solar system. Space habitats would be supported by robotic power stations, mining, manufacturing, and transportation. These could travel to the stars with the addition of propulsion and nuclear power. Human expansion into the galaxy would allow continuing exponential growth and could establish a vast interconnected galactic civilization.

Jones, Harry W.↗

Three-dimensional printed porous silicone matrix using leachable porogen

The silicone-based ink for additive manufacturing includes a siloxane macromer, and a porogen mixture comprising a water-soluble porogen and a surfactant. The product of additive manufacturing with a silicone-based ink includes a three-dimensional printed structure including a plurality of continuous filaments arranged in a predefined pattern and a plurality of inter-filament pores defined by the predefined pattern of the continuous filaments. In addition, each continuous filament of the three-dimensional printed structure includes a silicone matrix having an open cell structure with a plurality of intra-filament pores, and the intra-filament pores form continuous channels through the silicone matrix.

36 MATERIALS SCIENCE↗

THE IMPACT OF VISCOSITY ON MATERIAL TRANSITIONS IN LARGE FORMAT ADDITIVE MANUFACTURING OF POLYMER COMPOSITES

The need to produce complex geometries incompatible with traditional manufacturing techniques has fueled rapid growth in Large-Format Additive Manufacturing (LFAM). Printing of polymer composite materials have generated significant interest, but the production of Multi-Material (MM) structures with location-based material properties continues to be a challenge. Extrusion-based techniques have utilized multiple deposition heads to successfully print MM structures with both stiff and flexible regions, but these techniques often result in discrete material boundaries that concentrate stress and act as failure points. To avoid discrete interfaces, a novel dual-hopper configuration was developed for the Big Area Additive Manufacturing (BAAM) system that creates a blended material region within the structure. The ability to blend and freely switch between stiff polymer composites and flexible polymers enables printing of robust MM structures with site-specific properties. This study characterizes the influence of viscosity on a blended material transition between carbon fiber-filled acrylonitrile butadiene styrene (CF-ABS) and unfilled thermoplastic polyurethane (TPU), which have significantly different viscoelastic behaviors

Brackett, James↗

Multicomponent Nanoparticle Synthesis for Advanced Manufactured Melt Wire Development

Additive manufacturing (AM) based direct-write technologies have emerged as a predominant enabler for the fabrication of advanced passive sensors in-pile applications. This work continues previous efforts with the modification and optimization of synthesis methods for multi-component nanoparticle systems used to support the development, fabrication and testing of AM sensors for peak temperature detection. For this report, bismuth, bismuth/platinum, tin, tin/silver, tin/zinc, indium, and indium/silver bi-metallic nanoparticles were synthesized using the wet chemical methods. The nanoparticles were then characterized with x-ray fluorescence to evaluate the elemental composition and differential scanning to determine the melting point and mass loss of the samples. Results continue to show that bi-metallic nanoparticles are a viable pathway for the fabrication of high-resolution AM melt wires.

36 MATERIALS SCIENCE↗

3D Woven Mid-Density Carbon Phenolic (3MDCP) Thermal Protection System Development

3-Dimensionally Woven, Mid-Density, Carbon Phenolic (3MDCP) Thermal Protection System (TPS) material is derived from the dual layer 3D woven Heatshield for Extreme Entry Environment Technology (HEEET) material. The baseline 3MDCP design is a single piece thermal protection system that avoids the manufacturing and certification challenges associated with a tiled configuration. 3MDCP is targeted for very aggressive entry environments such as high-speed sample return missions to Earth and missions to Saturn, Venus and the ice giants. A 3MDCP heatshield begins as a flat woven preform that is formed to a given heatshield shape and then infused with phenolic resin. NASA Ames, in collaboration with TEAM Inc. (weaving) and Fiber Materials Inc. (both Spirit AeroSystems Companies) have been developing and demonstrating the manufacturing processes to fabricate a 3MDCP heatshield at a diameter of 1.25 meters. The process of forming the flat woven preform into the final heatshield shape, a sphere-cone geometry, involves local movement of the yarns in the weave. This results in a single piece heatshield with continuous fibers, albeit with property variations between different regions on the heatshield. This presentation will provide a high-level status of 3MDCP development. This will include an overview of the manufacturing processes, with an emphasis on the impact of forming on fiber orientation, material properties and performance. The presentation will layout the plan for testing to assess the impact of forming on properties and review preliminary data comparing properties of flat to formed materials.

Thermal Protection System↗

Scale-up of Next Generation Nano-Enhanced Composite Materials for Longer Lasting Consumer Goods

The objective for this project was to create an industrial-scale manufacturing operation for Vertically Aligned Carbon Nanotube Forests (VACNTs), which make up N12 Technologies’ (N12) NanoStitch® product, a prepreg additive that makes advanced composites tougher, lighter, and more durable. This was achieved using University of Dayton Research Institute’s (UDRI) 60-inch Nano Adaptive Hybrid Fabric (NAHF-X) reactor system. N12 had a unique and effective nanomaterial-based product that they were manufacturing on small-scale 1-inch wide substrate machines in Boston, MA. UDRI had a large-scale 60-inch wide nanomaterial growth reactor available for scaling up 2nd party products in Dayton, OH. Thanks to the successful cooperation between both parties, this project resulted in the world’s first industrial-scale continuous VACNT film pilot plant in Dayton, OH with an increase in VACNT supply production rate of >10X. This scale up enabled market validation via testing programs and pilot manufacturing operations with a number of customers.

36 MATERIALS SCIENCE↗

Sodium Carbazolide and Derivatives as Solid‐State Electrolytes for Sodium‐Ion Batteries

Abstract Replacing widely used organic liquid electrolytes with solid‐state electrolytes (SSEs) could effectively solve the safety issues in sodium‐ion batteries. Efforts on seeking novel solid‐state electrolytes have been continued for decades. However, issues about SSEs still exist, such as low ionic conductivity at ambient temperature, difficulty in manufacturing, low electrochemical stability, poor compatibility with electrodes, etc. Here, sodium carbazolide (Na‐CZ) and its THF‐coordinated derivatives are rationally fabricated as Na + conductors, and two of their crystal structures are successfully solved. Among these materials, THF‐coordinated complexes exhibit fast Na + conductivities, i.e., 1.20×10 −4 S cm −1 and 1.95×10 −3 S cm −1 at 90 °C for Na‐CZ‐1THF and Na‐CZ‐2THF, respectively, which are among the top Na + conductors under the same condition. Furthermore, stable Na plating/stripping is observed even over 400 h cycling, showing outstanding interfacial stability and compatibility against Na electrode. More advantages such as ease of synthesis, low‐cost, and cold pressing for molding can be obtained. In situ NMR results revealed that the evaporation of THF may play an essential role in the Na + migration, where the movement of THF creates defects/vacancies and facilitates the migration of Na + .

Yu, Yang↗

Sodium Carbazolide and Derivatives as Solid‐State Electrolytes for Sodium‐Ion Batteries

Abstract Replacing widely used organic liquid electrolytes with solid‐state electrolytes (SSEs) could effectively solve the safety issues in sodium‐ion batteries. Efforts on seeking novel solid‐state electrolytes have been continued for decades. However, issues about SSEs still exist, such as low ionic conductivity at ambient temperature, difficulty in manufacturing, low electrochemical stability, poor compatibility with electrodes, etc. Here, sodium carbazolide (Na‐CZ) and its THF‐coordinated derivatives are rationally fabricated as Na + conductors, and two of their crystal structures are successfully solved. Among these materials, THF‐coordinated complexes exhibit fast Na + conductivities, i.e., 1.20×10 −4 S cm −1 and 1.95×10 −3 S cm −1 at 90 °C for Na‐CZ‐1THF and Na‐CZ‐2THF, respectively, which are among the top Na + conductors under the same condition. Furthermore, stable Na plating/stripping is observed even over 400 h cycling, showing outstanding interfacial stability and compatibility against Na electrode. More advantages such as ease of synthesis, low‐cost, and cold pressing for molding can be obtained. In situ NMR results revealed that the evaporation of THF may play an essential role in the Na + migration, where the movement of THF creates defects/vacancies and facilitates the migration of Na + .

Yu, Yang↗

Wind Energy Supply Chain Deep Dive Assessment

The Wind Energy Supply Chain Deep Dive Assessment finds that the U.S. wind supply chain is nascent for offshore wind and mature for land-based wind, but U.S. competitiveness is declining in key wind turbine components. Continued decarbonization of the U.S. grid and economy with domestically supplied wind technology will require innovation to increase U.S. manufacturing competitiveness; investment in logistics and infrastructure, such as offshore wind ports and vessels; and policies to provide a strong and stable demand signal to support accelerated investment in the wind supply chain.

17 WIND ENERGY↗

Advanced Serpentine Heat Exchangers to Minimize Number of Joints and Leakage in HVAC&R Systems

Refrigerant leakage has a significant impact on heating, ventilation, air conditioning and refrigeration (HVAC&R) industries in terms of both greenhouse gas (GHG) emissions and lost efficiency of the systems themselves. One of the major causes of refrigerant leakage is braze joints within a vapor compression system. The brazing process is often inconsistent and almost always imperfect. As a result, braze joints are left vulnerable to leaks and can be weaker than non-brazed tubing. Conventional tube-fin heat exchangers are manufactured using one brazed joint per tube. An alternative to the conventional approach is the use of a single continuous serpentine tube. An Advanced Serpentine Heat Exchanger was developed to provide a heat transfer solution that meets or exceeds performance while also significantly reducing the number of joints and, consequently, the potential for refrigerant leakage. The developed serpentine heat exchanger not only delivers on performance, but is also cost competitive with conventional heat exchangers on the market.

30 DIRECT ENERGY CONVERSION↗

Characterization of Carbon Foam Products Made from Coal at Atmospheric Pressure

Carbon foam products are currently manufactured on a commercial scale utilizing a high-pressure autoclave in batch mode. In an effort to increase manufacturing speed and reduce cost, carbon foam products (both panels and aggregates) were produced at atmospheric pressure in a continuous belt kiln. Here, the microstructure, properties, and performance of these materials were characterized and assessed in various applications. Lightweight aggregate was explored for use as a proppant, as well as it use in concrete and asphalt. The thermal conductivity, water permeability, and fire resistance of panels were evaluated, and its performance with respect to screw pullout was compared against conventional building materials. Some interesting performance aspects and potential for future work was revealed. This work was supported by a cooperative agreement with the Department of Energy – National Energy Technology Laboratory (DE-FOA-0002185, Area of Interest 4: Coal-Derived Carbon Foam Produced via a Continuous Process, award number DE-FE-0031992).

01 COAL, LIGNITE, AND PEAT↗