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At least 469 records · Page 26

Nitrogenase Inspired Peptide-Functionalized Catalyst for Efficient, Emission-Free Ammonia Production

Ammonia production is one of the most important industrial processes in the world, as the major component of fertilizer to sustain higher food production. It is also one of the most energy intensive and carbon intensive chemical processes worldwide, primarily due to the steam methane reforming step to produce hydrogen for the reaction. Currently, ammonia is produced via the Haber Bosch process, which requires high temperature and pressure, and has low equilibrium efficiency. Due to these reaction conditions, the process is most economical at extremely large scale (100,000s of tons per day). In order to enable more distributed production scales which better match with renewable energy input and sustainable reactant sources, alternative methods of ammonia synthesis are needed, which scale more effectively and economically. One such approach is electrochemical synthesis based on ion exchange membrane cells. Peptide templating to form catalyst nanoparticles of controlled size, combined with peptide surface adsorbtion to model the nitrogenase active site, was used to develop novel catalyst materials and deposit them on electrodes.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Direct Carbon Fuel Cell System Utilizing Solid Carbonaceous Fuels

This 1-year project has achieved most of its objective and successfully demonstrated the viability of the fluidized bed direct carbon fuel cell (FB-DCFC) approach under development by Direct Carbon technologies, LLC, that utilizes solid carbonaceous fuels for power generation. This unique electrochemical technology offers high conversion efficiencies, produces proportionately less CO{sub 2} in capture-ready form, and does not consume or require water for gasification. FB-DCFC employs a specialized solid oxide fuel cell (SOFC) arrangement coupled to a Boudouard gasifier where the solid fuel particles are fluidized and reacted by the anode recycle gas CO{sub 2}. The resulting CO is electrochemically oxidized at the anode. Anode supported SOFC structures employed a porous Ni cermet anode layer, a dense yttria stabilized zirconia membrane, and a mixed conducting porous perovskite cathode film. Several kinds of untreated solid fuels (carbon and coal) were tested in bench scale FBDCFC prototypes for electrochemical performance and stability testing. Single cells of tubular geometry with active areas up to 24 cm{sup 2} were fabricated. The cells achieved high power densities up to 450 mW/cm{sup 2} at 850 C using a low sulfur Alaska coal char. This represents the highest power density reported in the open literature for coal based DCFC. Similarly, power densities up to 175 mW/cm{sup 2} at 850 C were demonstrated with carbon. Electrical conversion efficiencies for coal char were experimentally determined to be 48%. Long-term stability of cell performance was measured under galvanostatic conditions for 375 hours in CO with no degradation whatsoever, indicating that carbon deposition (or coking) does not pose any problems. Similar cell stability results were obtained in coal char tested for 24 hours under galvanostatic conditions with no sign of sulfur poisoning. Moreover, a 50-cell planar stack targeted for 1 kW output was fabricated and tested in 95% CO (balance CO{sub 2}) that simulates the composition of the coal syngas. At 800 C, the stack achieved a power density of 1176 W, which represents the largest power level demonstrated for CO in the literature. Although the FB-DCFC performance results obtained in this project were definitely encouraging and promising for practical applications, DCFC approaches pose significant technical challenges that are specific to the particular DCFC scheme employed. Long term impact of coal contaminants, particularly sulfur, on the stability of cell components and cell performance is a critically important issue. Effective current collection in large area cells is another challenge. Lack of kinetic information on the Boudouard reactivity of wide ranging solid fuels, including various coals and biomass, necessitates empirical determination of such reaction parameters that will slow down development efforts. Scale up issues will also pose challenges during development of practical FB-DCFC prototypes for testing and validation. To overcome some of the more fundamental problems, initiation of federal support for DCFC is critically important for advancing and developing this exciting and promising technology for third generation electricity generation from coal, biomass and other solid fuels including waste.

01 COAL, LIGNITE, AND PEAT↗

Nanocomposite Magnetic Technology for High Frequency MW Scale Power Conversion

The purpose of this project was to demonstrate the use of advanced magnetic materials in a medium voltage DC-DC converter for photovoltaic applications. The lead, alloy development team met project development milestones targeting a low loss material (<20 W/kg at 10kHzT), alloy resistivity (>150μΩcm amorphous phase resistivity), evaluation of the operational lifetime of the material (continuous operation above 155C), and the performance metric (power ratio >100) for a new class of Co-rich alloys with tunable permeability. Material manufacturability was demonstrated in continuously casting over 5 kg batches of 1’’ width, 18μm thickness (less than 80-120% deviation), amorphous ribbon, and processing including field and strain annealing as well as rolling both Fe and Co based alloys to less the 15μm was achieved. Parallel technology to markets efforts found that while a more compact and more efficient converter, which reduces the balance of plant cost, would enjoy a $0.10/W premium over current technology. Due to uncertainty in future energy policy and barriers to market entry the technology to market analyses recommended partnering with an existing manufacturer. The industrial and transportation electric motor market was also identified as one standing to benefit from this material technology and key personnel within this market were identified. With the assistance of Dynapower the converter prototype was tested to 300 VDC (18 kVA) before the resonant capacitors failed. The prototype incorporated several subsystems including the passive and active components at the engineering scale and exposed at least one weak point in the prototype. Independent testing on the core materials predicts that the core would have met the operating specifications, but this component was not tested at nominal power. Based on this prediction and the demonstrated construction of the prototype core, we recommend that the core material is designated TRL 5. The CMU team is currently working with Eaton to identify opportunities further test cores in inductive components.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Modeling golden eagle‐vehicle collisions to design mitigation strategies

ABSTRACT The incidental take of golden eagles ( Aquila chrysaetos ) as a result of wind energy development requires some form of compensatory mitigation. Although several options have been proposed, only one has been formerly accepted and implemented, and the lack of options can limit the permit process for wind facilities. We developed a model to estimate numbers of golden eagles that die when struck by vehicles when eagles scavenge road kill to evaluate removal of road‐killed carcasses as an additional mitigation option. Our model estimates vehicle collision rates as a function of eagle densities, road traffic volume, and animal carcass abundance at the scale of a Wyoming, USA, county during fall‐winter, and quantifies the effects of different mitigation strategies, including estimates of uncertainty. We evaluated the plausibility of our model estimates by predicting mortality rates for each county in Wyoming and comparing overall state mortality to current estimates of mortality using derived estimates from expert judgment. We also developed a context‐dependent analysis of potential mitigation credits controlling for carcass number, traffic volume, and background carcass removals. We found that mitigation credit should be highest in areas with greatest number of carcasses. Collision mitigation is a potentially useful addition to the mitigation toolbox for wind energy development or other activities that need to offset predicted golden eagle mortality and satisfy incidental take permit requirements. © 2018 The Authors. Journal of Wildlife Management Published by Wiley Periodicals, Inc.

Lonsdorf, Eric↗

Issues and Recommendations Arising from the Idaho National Laboratory Remote-Handled Low-Level Waste Disposal Facility Composite Analysis - 13374

Development of the composite analysis (CA) for the Idaho National Laboratory's (INLs) proposed remote-handled (RH) low-level waste (LLW) disposal facility has underscored the importance of consistency between analyses conducted for site-specific performance assessments (PAs) for LLW disposal facilities, sites regulated by the Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) [1], and residual decontamination and decommissioning (D and D) inventories. Consistency is difficult to achieve because: 1) different legacy sources and compliance time-periods were deemed important for each of the sites evaluated at INL (e.g., 100 years for CERCLA regulated facilities vs. 1,000 years for LLW disposal facilities regulated under U.S. Department of Energy (DOE) Order 435.1 [2]); 2) fate and transport assumptions, parameters, and models have evolved through time at the INL including the use of screening-level parameters vs. site-specific values; and 3) evaluation objectives for the various CERCLA sites were inconsistent with those relevant to either the PA or CA including the assessment of risk rather than effective dose. The proposed single site-wide CA approach would provide needed consistency, allowing ready incorporation of new information and/or facilities in addition to being cost effective in terms of preparation of CAs and review by the DOE. A single site-wide CA would include a central database of all existing INL sources, including those from currently operating LLW facilities, D and D activities, and those from the sites evaluated under CERCLA. The framework presented for the INL RH-LLW disposal facility allows for development of a single CA encompassing air and groundwater impacts. For groundwater impacts, a site-wide MODFLOW/MT3D-MS model was used to develop unit-response functions for all potential sources providing responses for a grid of receptors. Convolution and superposition of the response functions are used to compute groundwater concentrations. A similar approach could be applied for the air pathway where air emissions are stored in a central database and air concentrations for unit releases could be scaled to actual releases. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Soft X-ray measurements of transport and MHD activity in the core and edge NSTX plasma (Final Technical Report)

A comprehensive suite of innovative diagnostic instrumentation and techniques has been developed by the Johns Hopkins collaboration for measurements of transport and MHD activity in the core and edge of the National Spherical Torus Experiment (NSTX) at the Princeton Plasma Physics Laboratory (PPPL). These include ultrafast multi-energy poloidal soft X-ray arrays, high spatial resolution multi-energy tangential soft X-ray arrays, high spectral resolution transmission grating imaging VUV spectrometers and ultrafast bolometric arrays, which measure over a broad range of spatial, spectral, and temporal scales the emission from ohmic, RF, and beam driven NSTX plasmas. The instrumentation was designed to fulfill the specific measurement needs of the Spherical Torus (ST) magnetic fusion concept and is accompanied by a comprehensive set of numerical tools for data analysis and modeling, aimed at determining as many as possible plasma parameters and at extracting as much as possible physics information from NSTX experiments. The Johns Hopkins diagnostics have been and continue to be instrumental for essentially all the NSTX experiments. In addition, our own research and experiments using these diagnostics has led over the years to fundamental conclusions for the ST fusion physics, such as the establishment of near neoclassical impurity transport in the NSTX core and edge plasma, and the critical role of the Global Alfven Eigenmode (GAE) MHD activity for the ST core electron thermal transport. The Johns Hopkins Diagnostics continue to be operational on the upgraded NSTX-U and will provide key plasma information in its upcoming high field, current and power experimental campaigns. The present report summarizes the main technical characteristics and measurement capabilities of the diagnostic instrumentation and methods developed within our research and describes a key physics result achieved during this research. Success in our research was made possible also by the excellent support and cooperation of the NSTX research team and of PPPL researchers, who are warmly acknowledged here.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Numerical Simulation of a High Mach Number Jet Flow

The recent efforts to develop accurate numerical schemes for transition and turbulent flows are motivated, among other factors, by the need for accurate prediction of flow noise. The success of developing high speed civil transport plane (HSCT) is contingent upon our understanding and suppression of the jet exhaust noise. The radiated sound can be directly obtained by solving the full (time-dependent) compressible Navier-Stokes equations. However, this requires computational storage that is beyond currently available machines. This difficulty can be overcome by limiting the solution domain to the near field where the jet is nonlinear and then use acoustic analogy (e.g., Lighthill) to relate the far-field noise to the near-field sources. The later requires obtaining the time-dependent flow field. The other difficulty in aeroacoustics computations is that at high Reynolds numbers the turbulent flow has a large range of scales. Direct numerical simulations (DNS) cannot obtain all the scales of motion at high Reynolds number of technological interest. However, it is believed that the large scale structure is more efficient than the small-scale structure in radiating noise. Thus, one can model the small scales and calculate the acoustically active scales. The large scale structure in the noise-producing initial region of the jet can be viewed as a wavelike nature, the net radiated sound is the net cancellation after integration over space. As such, aeroacoustics computations are highly sensitive to errors in computing the sound sources. It is therefore essential to use a high-order numerical scheme to predict the flow field. The present paper presents the first step in a ongoing effort to predict jet noise. The emphasis here is in accurate prediction of the unsteady flow field. We solve the full time-dependent Navier-Stokes equations by a high order finite difference method. Time accurate spatial simulations of both plane and axisymmetric jet are presented. Jet Mach numbers of 1.5 and 2.1 are considered. Reynolds number in the simulations was about a million. Our numerical model is based on the 2-4 scheme by Gottlieb & Turkel. Bayliss et al. applied the 2-4 scheme in boundary layer computations. This scheme was also used by Ragab and Sheen to study the nonlinear development of supersonic instability waves in a mixing layer. In this study, we present two dimensional direct simulation results for both plane and axisymmetric jets. These results are compared with linear theory predictions. These computations were made for near nozzle exit region and velocity in spanwise/azimuthal direction was assumed to be zero.

Hayder, M. Ehtesham↗

A Methodology to Evaluate Ecological Resources and Risk Using Two Case Studies at the Department of Energy’s Hanford Site

An assessment of the potential risks to ecological resources from remediation activities or other perturbations should involve a quantitative evaluation of resources on the remediation site and in the surrounding environment. We developed a risk methodology to rapidly evaluate potential impact on ecological resources for the U.S. Department of Energy’s Hanford Site in southcentral Washington State. We describe the application of the risk evaluation for two case studies to illustrate its applicability. The ecological assessment involves examining previous sources of information for the site, defining different resource levels from 0 to 5. We also developed a risk rating scale from nondiscernable to very high. Field assessment is the critical step to determine resource levels or to determine if current conditions are the same as previously evaluated. We provide a rapid assessment method for current ecological conditions that can be compared to previous site-specific data, or that can be used to assess resource value on other sites where ecological information is not generally available. The method is applicable to other Department of Energy’s sites, where its development may involve a range of state regulators, resource trustees, Tribes and other stakeholders. Achieving consistency across Department of Energy’s sites for valuation of ecological resources on remediation sites will assure Congress and the public that funds and personnel are being deployed appropriately.

54 ENVIRONMENTAL SCIENCES↗

A Self-Consistent Model of the Interacting Ring Current Ions and Electromagnetic Ion Cyclotron Waves, Initial Results: Waves and Precipitating Fluxes

Initial results from a newly developed model of the interacting ring current ions and ion cyclotron waves are presented. The model is based on the system of two kinetic equations: one equation describes the ring current ion dynamics, and another equation describes wave evolution. The system gives a self-consistent description of the ring current ions and ion cyclotron waves in a quasilinear approach. These equations for the ion phase space distribution function and for the wave power spectral density were solved on aglobal magnetospheric scale undernonsteady state conditions during the 2-5 May 1998 storm. The structure and dynamics of the ring current proton precipitating flux regions and the ion cyclotron wave-active zones during extreme geomagnetic disturbances on 4 May 1998 are presented and discussed in detail.

Khazanov, G. V.↗

Quantifying Uncertainties in Nighttime Light Retrievals From Suomi-NPP and NOAA-20 VIIRS Day/Night Band Data

Satellite observations of nighttime lights (NTL) from Suomi-NPP and NOAA-20 VIIRS Day/Night Band data have been widely used to estimate human activities. Long-term changes such as urban development and abrupt short-term changes such as power outages have been monitored from temporal NTL acquired by satellites. While high temporal NTL variation has been found across NTL data of varying temporal scale (e.g., daily, monthly, and annual composites), the sources of measurement error and uncertainty are poorly understood. This paper quantifies the sources of VIIRS-derived NTL uncertainty due to view-illumination geometry, surface Bidirectional Reflectance Distribution Function (BRDF)/albedo, and the effects of snow cover, lunar irradiance, aerosol loading, cloud mask, vegetation, geometry, and ephemeral artifacts (e.g., the Aurora Borealis). Based on this current assessment of NASA Black Marble retrievals (VNP46, Collection V001), we found that angular and atmospheric effects dominate retrieval uncertainty. Errors introduced by upstream data inputs (e.g., a coarser nighttime snow cover flag and misclassification errors in the existing VIIRS nighttime cloud mask) were also found to impact retrieval quality. Despite these challenges, a consistent daily NTL time series record can be routinely generated from top-of-atmosphere VNP46 radiances. Key recommendations include: (1) the use of lunar-BRDF adjusted and atmospherically corrected NTL (i.e., as identified as high-quality retrievals in the VNP46 QA fields), (2) development and improvement to the VIIRS snow cover and cloud masks algorithms to accurately reflect NTL retrieval conditions, (3) characterizing seasonal variations in NTL due to vegetation and snow, (4) reducing geometric effects due to the spatial mismatch of gridded pixel and observation footprint, (5) employing angularly-consistent NTL observations from multiple VIIRS instruments (i.e., Suomi-NPP and NOAA-20) to reduce pixel-based uncertainties and address persistent data gaps, and (6) being mindful of surface-reflected radiance from aurora events at mid-to-high latitudes.

Zhuosen Wang↗

Distributed Sensor Coordination for Advanced Energy Systems

The ability to collect key system level information is critical to the safe, efficient and reliable operation of advanced energy systems. With recent advances in sensor development, it is now possible to push some level of decision making directly to computationally sophisticated sensors, rather than wait for data to arrive to a massive centralized location before a decision is made. This type of approach relies on networked sensors (called “agents” from here on) to actively collect and process data, and provide key control decisions to significantly improve both the quality/relevance of the collected data and the associating decision making. The technological bottlenecks for such sensor networks stem from a lack of mathematics and algorithms to manage the systems, rather than difficulties associated with building and deploying them. Indeed, traditional sensor coordination strategies do not provide adequate solutions for this problem. Passive data collection methods (e.g., large sensor webs) can scale to large systems, but are generally not suited to highly dynamic environments, such as advanced energy systems, where crucial decisions may need to be reached quickly and locally. Approaches based on local decisions on the other hand cannot guarantee that each agent performing its task (maximize an agent objective) will lead to good network wide solution (maximize a network objective) without invoking cumbersome coordination routines. There is currently a lack of algorithms that will enable self-organization and blend the efficiency of local decision making with the system level guarantees of global decision making, particularly when the systems operate in dynamic and stochastic environments. In this work we addressed this critical gap and provided a comprehensive solution to the problem of sensor coordination to ensure the safe, reliable, and robust operation of advanced energy systems. The differentiating aspect of the proposed work is in shifting the focus towards “what to observe” rather than “how to observe” in large sensor networks, allowing the agents to actively determine both the structure of the network and the relevance of the information they are seeking to collect. In addition to providing an implicit coordination mechanism, this approach allows the system to be reconfigured in response to changing needs (e.g., sudden external events requiring new responses) or changing sensor network characteristics (e.g., sudden changes to plant condition). Outcome Summary: All milestones associated with this project have been completed. In particular, private sensor objective functions were developed which are aligned with the global objective function, sensor effectiveness has been improved by using “sensor teams,” system efficiency has been improved by 30% using difference evaluation functions, we have demonstrated system reconfigurability for 20% changes in system conditions, we have demonstrated extreme scalability of our proposed algorithm, we have demonstrated that sensor networks can overcome disruptions of up to 20% in network conditions, and have demonstrated system reconfigurability to 20% changes in system conditions in hardware-based simulations. This final report summarizes how each of these milestones was achieved, and gives insight into future research possibilities past the work which has been completed. The following publications support these milestones [6, 8, 9, 10, 16, 18, 19].

97 MATHEMATICS AND COMPUTING↗

Reversible Redox Chemistry of Azo Compounds for Sodium-Ion Batteries

Sustainable sodium-ion batteries (SSIBs) using renewable organic electrodes are promising alternatives to lithium-ion batteries for the large-scale renewable energy storage. However, the lack of high-performance anode material impedes the development of SSIBs. Herein, we report a new type of organic anode material based on azo group for SSIBs. Azobenzene-4,4'-dicarboxylic acid sodium salt is used as a model to investigate the electrochemical behaviors and reaction mechanism of azo compound. It exhibits a reversible capacity of 170 mAhg -1 at 0.2C. When current density is increased to 20C, the reversible capacities of 98 mAhg -1 can be retained for 2000 cycles, demonstrating excellent cycling stability and high rate capability. The detailed characterizations reveal that azo group acts as an electrochemical active site to reversibly bond with Na + . The reversible redox chemistry between azo compound and Na ions offer opportunities for developing longcycle-life and high-rate SSIBs.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Acetate as a Platform for Carbon-Negative Production of Renewable Fuels and Chemicals (Final Technical Report)

This project was an industrial-academic collaboration between experts at the University of Wisconsin-Madison, the University of Kentucky, and LanzaTech, a world leader in the use of gas fermentation to sustainably produce fuels and chemicals. The project developed technologies to create an integrated process for converting carbon dioxide and renewable hydrogen into molecules that can be blended with liquid transportation fuels or used in an array of chemical applications. The project was motivated by the Program Objectives of eliminating carbon dioxide release in the production of chemicals by integrating the unique and efficient capabilities of two microorganisms into a single process. The first microbe, an acetogen, produces acetate from carbon dioxide and hydrogen while the second microbe upgrades acetate from acetogen fermentation permeates to higher-value chemical products. The carbon dioxide released in the upgrading process is recycled internally to produce more acetate. As such, the process can be designed to operate with zero carbon dioxide release and net positive carbon dioxide capture. The process has the potential to provide an alternative paradigm to the current bioeconomy – one in which acetate is the primary energy carrier instead of sugars. Our process by-passes photosynthesis and the barriers created by biomass as primary chemical feedstock. As such, the process can be scaled to meet existing sources of carbon dioxide emissions and located anywhere renewable hydrogen can be provided. Our work developed microorganisms with optimized metabolism for producing acetate and other microorganisms with improved conversion of acetate to dodecanol and dodecyl-acetate. We developed synthetic biology tools for a promising non-model bacterium that could enhance metabolic engineering efforts to convert acetate to chemical products. We conducted protein engineering studies to improve the activity of key enzymes involved in our metabolic pathways. We conducted a full technoeconomic analysis that set technical targets for each strain to meet economic goals. We identified key technical barriers in our process and proposed strategies to overcome them.

09 BIOMASS FUELS↗

The emergence of multi-user expert systems

There exists a set of problems for which the single user workstation is not a viable solution. In some cases, it may be necessary for the system to support numerous experts working on different aspects of a single logical activity concurrently. In others, the activity may extend over a prolonged period of time during which different experts will work on different phases of the project to produce a single integrated result. Another possibility is that the results produced by the expert system must be continuously available to some group other than that actively exercising the expert system. These are the types of applications which require multiuser expert systems. The nature of NASA tends to produce expert system domains which are inherently multiuser. It is these domains that this new class of expert systems has first been encountered. As expert systems move into the main stream of large scale engineering projects, these encounters will become more frequent. A need for expert system building tools which can accommodate the unique properties of these multiuser domains as they emerge is a problem which needs to be addressed as the current set of tools migrate to time sharing environments, and as new tools are developed.

Freeman, Michael S.↗

Advanced Software Development Workstation Project

The Advanced Software Development Workstation Project, funded by Johnson Space Center, is investigating knowledge-based techniques for software reuse in NASA software development projects. Two prototypes have been demonstrated and a third is now in development. The approach is to build a foundation that provides passive reuse support, add a layer that uses domain-independent programming knowledge, add a layer that supports the acquisition of domain-specific programming knowledge to provide active support, and enhance maintainability and modifiability through an object-oriented approach. The development of new application software would use specification-by-reformulation, based on a cognitive theory of retrieval from very long-term memory in humans, and using an Ada code library and an object base. Current tasks include enhancements to the knowledge representation of Ada packages and abstract data types, extensions to support Ada package instantiation knowledge acquisition, integration with Ada compilers and relational databases, enhancements to the graphical user interface, and demonstration of the system with a NASA contractor-developed trajectory simulation package. Future work will focus on investigating issues involving scale-up and integration.

Lee, Daniel↗

Recycle of Am-241 obtained from long term stored plutonium for use in radioisotope power systems - 15035

Pu-238 has been used as a power source for spacecraft since the early days of space exploration. It has proven to be an effective source of power where the use of solar generated power is impractical. Its application for use in spacecraft power systems was developed by the USA and Russia who have spent many $ 100s of millions on its development and production. However, the original facilities for the production of Pu-238 are no longer in use and existing worldwide stockpiles have reduced to levels sufficient for only one or two further missions. Production of Pu-238 requires considerable facilities including a nuclear reactor and reprocessing plants that are very expensive to build and operate. The European Space Agency (ESA) has assessed the options for post-launch power generation in future European space missions and has made the decision to pursue the use of Am-241 as an alternative isotope to power future European Radioisotope Power Systems (RPS). What makes Am-241 attractive for the European market is its 100% isotopically pure production from the decay of Pu-241 in separated civil plutonium stockpiles. Historically, Europe has relied on collaborations with the USA or Russia to access these nuclear power sources. During 2009, the European Space Agency (ESA) funded a project to examine the cost and practicality of establishing a European source of material suitable for Radioisotope Power Systems (RPS). The study concluded that a small number of radioisotopes could be used in RPSs. On further review two leading candidates, Am-241 and Pu-238, were selected for further study. Whilst Pu-238 was recognized as the isotope of choice for use in RPSs, the costs of setting up a European based production facility was prohibitively expensive. Although Am-241 has a number of limitations compared to Pu-238, the much reduced production costs make Am-241 an attractive option for European based production of RPSs. Despite its lower power density of ∼ 0.11 Wth/g, Am-241 is viewed as a potential alternative to Pu-238 because of its availability within the nuclear fuel cycle. During the reprocessing of spent nuclear fuel plutonium is separated as a chemically pure PuO{sub 2} product, containing around 3-11% w/w of the Pu-241 isotope, and placed into storage. During storage the Pu-241 isotope beta decays to Am-241 with a half-life of 14.4 years. {sub 94}{sup 241}Pu → (β 14.4 y) {sub 95}{sup 241}Am. This process has resulted in many 100 kgs of americium growing into the civil plutonium stockpile in the UK; material that is of value in generating heat sources and is able to be recycled. The key benefit of Am-241 as a potential European RPS source isotope is the availability of feed material along with the facilities to process it. It is expected that aged civil PuO{sub 2} will contain 25-50 g Am-241 per kg PuO{sub 2} depending on the source. A conceptual flowsheet using facilities for separating americium from plutonium is expected to produce on average 8.4 kg Am/year. ESA are now following their published road-map of studies to develop flight ready RTGs and RHUs. This has included the development and testing of the flowsheet to be used for production of Am-241. The project has focused on underpinning the conceptual flowsheet, using aged plutonium in NNL's PuMA laboratory. This has underpinned the design of a plant to produce a steady supply of Am-241. The scope of the overall project is 'store to store' - the starting point is aged plutonium currently housed in existing Sellafield stores and the end point is the storage of separated plutonium and americium powders on the Sellafield site. The full scale process is planned to be housed within the NNL's Central Laboratory in an existing facility designed for plutonium active operations. (authors)

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Bench-Scale Development of Promoted High-Capacity Structured Sorbents (Final Technical Report)

The project objective was to develop high-capacity structured sorbent capable of achieving low CO 2 removal from air. The sorbent framework consists of an amine-functionalized onto hydrophobic polymer backbone with an added promoter. The functionalized amine provides high CO 2 capacity and adsorption rates and the polymer backbone to reduce water uptake. For the sorbent development, multiple functionalized amines and promoters were assessed to select a candidate that achieved high CO 2 capacity, high adsorption rate, and high stability. A sorbent-coated filter design was selected as the structured sorbent, which provides high sorbent loading capacity and contains an electrically conductive nonwoven filter substrate that can be Joule-heated to provide efficient utilization of available electricity for sorbent regeneration. A commercial partner operated a pilot filter manufacturing line to produce the filter panels coated with the developed sorbent. A 1 kg CO 2 /day bench unit was designed and fabricated to test the structured filter sorbent. The key achievements from the structured sorbent development activity were demonstrating that existing filter industrial-scale processes can be used for manufacturing Susteon’s structured sorbent and completing a proof-of-concept demonstration of the commercially manufactured structured sorbent filters for CO 2 capture from air with direct, Joule-heated regeneration. A techno-economic assessment with sensitivity analysis was conducted on a 100,000 TPY facility with 85% operating capacity. Through sorbent optimization and process design improvements, it is estimated that the cost of capture was reduced from $\$$349/tCO 2 to $\$$241/tCO 2 . The TEA projects further reductions to $165/tCO 2 through enhancements in CO 2 adsorption rate and sorbent capacity and reducing manufacturing and scale up risks. A life cycle analysis was conducted on the same 100,000 TPY facility and confirmed that the facility’s electricity demand drives its greenhouse gas impact. It was determined that electricity supplied through the current grid mix would result in net-positive CO 2 emissions and that achieving net-negative emissions is only possible by powering the system with renewable electricity or fossil fuel sources equipped with carbon capture and sequestration.

36 MATERIALS SCIENCE↗

Thermal System Verification and Model Validation for NASA's Cryogenic Passively Cooled James Webb Space Telescope

A thorough and unique thermal verification and model validation plan has been developed for NASA s James Webb Space Telescope. The JWST observatory consists of a large deployed aperture optical telescope passively cooled to below 50 Kelvin along with a suite of several instruments passively and actively cooled to below 37 Kelvin and 7 Kelvin, respectively. Passive cooling to these extremely low temperatures is made feasible by the use of a large deployed high efficiency sunshield and an orbit location at the L2 Lagrange point. Another enabling feature is the scale or size of the observatory that allows for large radiator sizes that are compatible with the expected power dissipation of the instruments and large format Mercury Cadmium Telluride (HgCdTe) detector arrays. This passive cooling concept is simple, reliable, and mission enabling when compared to the alternatives of mechanical coolers and stored cryogens. However, these same large scale observatory features, which make passive cooling viable, also prevent the typical flight configuration fully-deployed thermal balance test that is the keystone to most space missions thermal verification plan. JWST is simply too large in its deployed configuration to be properly thermal balance tested in the facilities that currently exist. This reality, when combined with a mission thermal concept with little to no flight heritage, has necessitated the need for a unique and alternative approach to thermal system verification and model validation. This paper describes the thermal verification and model validation plan that has been developed for JWST. The plan relies on judicious use of cryogenic and thermal design margin, a completely independent thermal modeling cross check utilizing different analysis teams and software packages, and finally, a comprehensive set of thermal tests that occur at different levels of JWST assembly. After a brief description of the JWST mission and thermal architecture, a detailed description of the three aspects of the thermal verification and model validation plan is presented.

Cleveland, Paul E.↗