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At least 469 records · Page 26

Investigation to develop a method to apply diffusion barrier to high strength fibers

A radio frequency powered ion plating process was used to apply the diffusion barriers of aluminum oxide, yttrium oxide, hafnium oxide and titanium carbide to a substrate tungsten fiber. Each of the coatings was examined as to its effect on both room temperature strength and tensile strength of the base tungsten fiber. The coated fibers were then overcoated with a nickel alloy to become single cell diffusion couples. These diffusion couples were exposed to 1093 C for 24 hours, cycled between room temperature and 1093 C, and given a thermal anneal for 100 hours at 1200 C. Tensile testing and metallographic examinations determined that the hafnium oxide coating produced the best high temperature diffusion barrier for tungsten of the four coatings.

Veltri, R. D.↗

Study of diffusion coefficients of glasses under zero-G

Diffusion studies of the glass forming ion are examined in zero-g environments and diffusion data obtained from these experiments are unique because of earth based experimental problems. The choice of system for diffusion studies is discussed along with the lab processing. The space processing is described consisting of a heating cycle designed to maximize time exposed to the diffusion temperature without exposing the low viscosity melt to gravitational forces.

Kinser, D. L.↗

Effect of wall suction on performance of a short annular diffuser at inlet Mach numbers up to 0.5

A short annular diffuser equipped with wall bleed (suction)capability was evaluated at inlet Mach numbers of 0.186 to 0.5. The diffuser had an area ratio of 4.0 and a length-to-inlet height ratio of 1.6. Test results show that the exit velocity profiles, typical of annular jet flow without suction, could be considerably flattened by application of wall suction. This improved performance was also reflected in diffuser effectiveness (static-pressure recovery) and total-pressure loss results. At the inlet Mach number of 0.5 diffuser static-pressure recovery is equal to or better than at lower inlet Mach numbers for comparable suction rates.

Juhasz, A. J.↗

Diffuse interstellar band formation in dense clouds

Data are presented which show that the strengths of the diffuse interstellar bands at 4430, 5780, and 5797 A tend to be deficient with respect to color excess in the lines of sight to stars lying behind dense interstellar clouds. In addition, diffuse-band data for ten stars in the well-studied rho Ophiuchi cloud complex are presented, and systematic variations of band strengths with optical depth are discussed. It is found that the band strength per grain in the line of sight apparently decreases with increasing grain size, taking the ratio of total-to-selective absorption and the wavelength of maximum polarization as indicators of the latter. It is concluded that diffuse-band formation probably takes place most efficiently in the outer regions of interstellar clouds. This may be consistent with a diffuse-band origin in small grains which are coated by mantles in cloud interiors; or in some molecule or molecules which are most abundant in the outer portions of interstellar clouds.

Snow, T. P., Jr.↗

Chemical potential effects on neutrino diffusion in supernovae

The validity of imposing a zero chemical potential for neutrinos in hydrodynamic calculations of collapsing supernovae is investigated in the diffusion approximation of neutrino transport. A coupled system of equations is solved for neutrino and energy diffusion fluxes as well as lepton diffusion in a collapsing supernovae ambient medium, and the results indicate a substantial growth in the neutrino chemical potential for densities greater than 10 to the 12th power gm/cu cm. The rate of energy transport is shown to be significantly affected by increases in Fermi integrals and chemical-potential gradients accompanied by decreases in temperature, and the extent of neutrino particle/antiparticle reactions is found also to affect energy diffusion rates. It is concluded that the photon-like behavior usually assumed for neutrinos may be incorrect and that an extension of the Sn transport approximation to include lepton characteristics is necessary for a definitive answer to the question of neutrino transport in supernovae.

Mazurek, T. J.↗

Calculated diffusion coefficients and the growth rate of olivine in a basalt magma

Concentration gradients in glass adjacent to skeletal olivines in a basalt have been examined by electron probe. The glass is depleted in Mg, Fe, and Cr and enriched in Si, Al, Na, and Ca relative to that far from olivine. Ionic diffusion coefficients for the glass compositions are calculated from temperature, ionic radius and melt viscosity, using the Stokes-Einstein relation. At 1170 C, the diffusion coefficient of Mg(2+) ions in the basalt is 4.5 billionths sq cm per sec. Comparison with measured diffusion coefficients in a mugearite suggests this value may be 16 times too small. The concentration gradient data and the diffusion coefficients are used to calculate instantaneous olivine growth rates. Growth necessarily preceded emplacement such that the composition of the crystals plus the enclosing glass need not be that of a melt. The computed olivine growth rates are compatible with the rate of crystallization deduced for the Skaegaard intrusion.

Donaldson, C. H.↗

A preliminary study of the effects of vortex diffusers (winglets) on wing flutter

Some experimental flutter results are presented for a simple, flat-plate wing model and for the same wing model equipped with two different upper surface vortex diffusers over the Mach number range from about 0.70 to 0.95. Both vortex diffusers had the same planform, but one weighed about 0.3 percent of the basic wing weight, whereas the other weighed about 1.8 percent of the wing weight. The addition of the lighter vortex diffuser reduced the flutter dynamic pressure by about 3 percent; the heavier vortex diffuser reduced the flutter dynamic pressure by about 12 percent. The experimental flutter results are compared at a Mach number of 0.80 with analytical flutter results obtained by using doublet lattice and lifting surface (Kernel function) unsteady aerodynamic theories.

Doggett, R. V., Jr.↗

NASA/MSFC multilayer diffusion models and computer programs, version 5

The transport and diffusion models and algorithms developed for use by NASA in predicting concentrations and dosages downwind from normal and abnormal launches of rocket vehicles are described along with the associated computer programs for use in performing the calculations. Topics discussed include: the mathematical specifications and procedures used in the Preprocessor Program to calculate rocket exhaust cloud rise, cloud dimensions, and other input parameters to the transport and diffusion models; the revised mathematical specifications for the Multilayer Diffusion Models; users' instructions for implementing the Preprocessor and Multilayer Diffusion Models Programs; and worked example problems illustrating the use of the models and computer programs.

Dumbauld, R. K.↗

Diffusion effects on the line intensities of He I and He II in the solar transition region

A heuristic treatment of diffusion in the solar chromosphere-corona transition region is developed. It is shown that diffusion becomes increasingly important with steeper temperature gradients, in active and quiet regions relative to coronal holes, and with increasing excitation potential. Numerical calculations are made for the resonance lines of He I and He II and show that diffusion can enhance these lines. Thus the helium lines may appear relatively weak in coronal holes due to a weakening of the enhancement mechanism. Most transition region lines will be less affected by diffusion than He I or He II.

Shine, R.↗

The effect of gas diffusion on the flow coefficient for a ventilated cavity

The results of an experimental investigation into the effect of gas diffusion on the volume flow-rate of gas needed to sustain a ventilated cavity are presented. Gas diffusion was found to have a significant effect on the ventilated flow rate required to sustain a cavity of a given size. An analysis for the gas diffusion effect was conducted based on a mathematical model of diffusion proposed by Brennen. The results compare favorably with experimental data. Also, an empirical scaling relationship is proposed for ventilated cavity flows.

Billet, M. L.↗

The absorption of trapped particles by the inner satellites of Jupiter and the radial diffusion coefficient of particle transport

The process of trapped particle absorption by the inner Jovian satellites is considered in detail taking into account both the particle and satellite motions in a magnetic dipole field which is displaced from the center of the planet and tilted with respect to the planetary rotation axis. An expression is derived for computing the sweeping time at a given satellite, defined as the time required for the satellite to sweep up a given fraction of the trapped particles within its sweeping region. By making use of the sweeping time and the radial diffusion equation of particle transport approximate expressions for the diffusion coefficient are derived. Measurements obtained by Pioneer 10 are then used to obtain estimates of the diffusion coefficient at the orbits of Io and Europa. We find that the diffusion coefficient is a function of energy and magnetic latitude for electrons in the energy range 0.7-14 MeV.

Mogro-Campero, A.↗

Reaction diffusion in the nickel-chromium-aluminum and cobalt-chromium-aluminum systems

The effects of MCrAl coating-substrate interdiffusion on oxidation life and the general mutliphase, multicomponent diffusion problem were examined. Semi-infinite diffusion couples that had sources representing coatings and sinks representing gas turbine alloys were annealed at 1,000, 1,095, 1,150, or 1,205 C for as long as 500 hours. The source and sink aluminum and chromium contents and the base metal (cobalt or nickel) determined the parabolic diffusion rate constants of the couples and predicted finite coating lives. The beta source strength concept provided a method (1) for correlating beta recession rate constants with composition; (2) for determining reliable average total, diffusion, and constitutional activation energies; and (3) for calculating interdiffusion coefficients.

Levine, S. R.↗

Performance of high-area-ratio annular dump diffuser using suction-stabilized-vortex flow control

A short annular dump diffuser having a geometry conductive to formation of suction stabilized toroidal vortices in the region of abrupt area change was tested. The overall diffuser area ratio was 4.0 and the length to inlet height ratio was 2.0. Performance data were obtained at near ambient temperature and pressure for inlet Mach numbers of 0.18 and 0.30 with suction rates ranging from 0 to 18 percent of total inlet mass flowrate. Results show that the exit velocity profile could be readily biased toward either wall by adjustment of inner and outer wall suction rates. Symmetric exit velocity profiles were inherently unstable with a tendency to revert to a hub or tip bias. Diffuser effectiveness was increased from about 38 percent without suction to over 85 percent at a total suction rate of 10 to 12 percent. At the same time diffuser total pressure loss was reduced from 3.1 percent to 1.1 percent at an inlet Mach number of 0.3.

Juhasz, A. J.↗

Measurement of insulation integrity of IUE camera tube facsimiles by partial discharges method and diffusion of gases through various silicone rubbers

Several dummy tubes imitating the IUE Camera System design were encapsulated with Solithane 2, Conathane EN-11, Green and Black Hysols and SMRD 432. Various flaws were purposefully placed in some of these. Partial discharge testing in vacuum under direct voltage conditions was carried once a week for 12 weeks, 15 kv dc being applied during normal working hours for 40 hours duration per week. None of the units showed much damage during this time judging by the P.D. energy histograms. A more complete mathematical presentation is given on diffusion and permeation than previously. Measurements of diffusion constants for various silicone rubbers are carried out by the Time-Lag method and compared to other determinations in the literature. Calculations of the time required for diffusion through a thick wall are demonstrated in the long time approximation and for dimensions pertaining to void and wall sizes of a delamination problem in the LANDSAT-C vidicon tubes. An actual delaminated LANDSAT-C tube and some facsimiles are immersed in vacuum for long periods and tested for catastrophic breakdown due to diffusion of gas, by application of high voltage.

Bever, R. S.↗

Variations in eddy diffusion and associated transport processes

Variation in the eddy diffusion coefficient constitutes a momentum source. This variation near the turbopause affects both the composition and the wind and temperature fields of the thermosphere. Two types of calculations are carried out, for horizontal winds considered self-consistently in a three-dimensional dynamic model and horizontal winds artificially suppressed to simulate a one-dimensional model. Momentum transfer associated with variations in eddy diffusion coefficients represents the source function in the analysis presented. It is shown that for long-term variations in the thermosphere, the compositional dependence on variations in eddy diffusion coefficients can be entirely different in one and three dimensional models with horizontal winds included. Horizontal winds can greatly reduce the effects of eddy diffusion in general and the ratio between He and O amplitudes in particular.

Mayr, H. G.↗

An investigation of impurity redistribution in diffused layer on /n+/-p silicon solar cells parameters

Recent calculations by Wang et al. (1974) have shown that the short-circuit current for silicon solar cells is sensitive to the impurity distribution in the diffused and base region. In the present work, these theoretical results were verified by experimentally investigating the impurity profile and sheet resistance of the diffused layers of (n+)-p silicon solar cells fabricated by normal diffusion processes and at subsequently various drive-in times. Impurity profiles of the n+ diffused layer, measured by differential Hall and resistivity technique, resemble the erfc distribution. The junction depth is larger as drive-in time increases. Measured short-circuit current is in agreement with calculated ones. Open-circuit voltage is independent of drive-in times, and its calculated values are consistent with capacitance-voltage measurements.

Wang, E. Y.↗

Consequences of using nonlinear particle trajectories to compute spatial diffusion coefficients

In a study of cosmic ray propagation in interstellar and interplanetary space, a perturbed orbit resonant scattering theory for pitch angle diffusion in a slab model of magnetostatic turbulence is slightly generalized and used to compute the diffusion coefficient for spatial propagation parallel to the mean magnetic field. This diffusion coefficient has been useful for describing the solar modulation of the galactic cosmic rays, and for explaining the diffusive phase in solar flares in which the initial anisotropy of the particle distribution decays to isotropy.

Goldstein, M. L.↗

Elevated-temperature flow strength, creep resistance and diffusion welding characteristics of Ti-gAl-2Nb-1Ta-0.8Mo

A study of the flow strength, creep resistance and diffusion welding characteristics of the titanium alloy Ti-6Al-2Nb-1Ta-0.8Mo was conducted. Two mill-processed forms of this alloy were examined. The forged material was essentially processed above the beta transus while the rolled form was subjected to considerable work below the beta transus. Between 1150 and 1250 K, the forged material was stronger and more creep resistant than the rolled alloy. Both forms exhibit superplastic characteristics in this temperature range. Strain measurements during diffusion welding experiments at 1200 K reveal that weld interfaces have no measurable effect on the overall creep deformation. Significant deformation appears to be necessary to produce a quality diffusion weld between superplastic materials. A 'soft' interlayer inserted between faying surfaces would seemingly allow manufacture of quality diffusion welds with little overall deformation.

Whittenberger, J. D.↗