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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 469 records · Page 26
All sourcesNASA NTRSDOE OSTI
DOE OSTI2022

On the mechanism of marine fouling-prevention performance of oil-containing silicone elastomers

For many decades, silicone elastomers with oil incorporated have served as fouling-release coating for marine applications. In a comprehensive study involving a series of laboratory-based marine fouling assays and extensive global field studies of up to 2-year duration, we compare polydimethylsiloxane (PDMS) coatings of the same composition loaded with oil via two different methods. One method used a traditional, one-pot pre-cure oil addition approach (o-PDMS) and another method used a newer post-cure infusion approach (i-PDMS). The latter displays a substantial improvement in biofouling prevention performance that exceeds established commercial silicone-based fouling-release coating standards. We interpret the differences in performance between one-pot and infused PDMS by developing a mechanistic model based on the Flory–Rehner theory of swollen polymer networks. Using this model, we propose that the chemical potential of the incorporated oil is a key consideration for the design of future fouling-release coatings, as the improved performance is driven by the formation and stabilization of an anti-adhesion oil overlayer on the polymer surface.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2016

Quantifying shallow subsurface water and heat dynamics using coupled hydrological-thermal-geophysical inversion

Improving our ability to estimate the parameters that control water and heat fluxes in the shallow subsurface is particularly important due to their strong control on recharge, evaporation and biogeochemical processes. The objectives of this study are to develop and test a new inversion scheme to simultaneously estimate subsurface hydrological, thermal and petrophysical parameters using hydrological, thermal and electrical resistivity tomography (ERT) data. The inversion scheme – which is based on a nonisothermal, multiphase hydrological model – provides the desired subsurface property estimates in high spatiotemporal resolution. A particularly novel aspect of the inversion scheme is the explicit incorporation of the dependence of the subsurface electrical resistivity on both moisture and temperature. The scheme was applied to synthetic case studies, as well as to real datasets that were autonomously collected at a biogeochemical field study site in Rifle, Colorado. At the Rifle site, the coupled hydrological-thermal-geophysical inversion approach well predicted the matric potential, temperature and apparent resistivity with the Nash–Sutcliffe efficiency criterion greater than 0.92. Synthetic studies found that neglecting the subsurface temperature variability, and its effect on the electrical resistivity in the hydrogeophysical inversion, may lead to an incorrect estimation of the hydrological parameters. The approach is expected to be especially useful for the increasing number of studies that are taking advantage of autonomously collected ERT and soil measurements to explore complex terrestrial system dynamics.

58 GEOSCIENCES↗
NASA NTRS1987

Solidifying Mn/Bi in a Magnetic Field

Report describes experiments in directional solidification of eutectic Mn/Bi in magnetic field. Study determines whether effects of gravitationally-induced convection reduced or eliminated by magnetic field. Morphological, thermal, and magnetic analyses done on samples grown at various speeds and various applied strengths. Magnetic effects similar to those of low gravity.

Decarlo, J. L.↗
NASA NTRS1974

Wind tunnel studies of Martian aeolian processes

In order to determine the nature of Martian aeolian processes, an investigation is in progress which involves wind tunnel simulations, geologic field studies, theoretical model studies, and analyses of Mariner 9 imagery; this report presents the preliminary results. Threshold speed experiments were conducted for particles ranging in relative density from 1.3 to 11.35 and diameter from 10.2 to 1290 microns to verify and better define Bagnold's (1941) expression for grain movement, particularly for low particle Reynolds numbers and to study the effects of aerodynamic lift and surface roughness. Wind tunnel simulations were conducted to determine the flow field over raised rim craters and associated zones of deposition and erosion.

Greeley, R.↗
NASA NTRS1990

Geoscience and a Lunar Base: A Comprehensive Plan for Lunar Exploration

This document represents the proceedings of the Workshop on Geoscience from a Lunar Base. It describes a comprehensive plan for the geologic exploration of the Moon. The document begins by explaining the scientific importance of studying the Moon and outlines the many unsolved problems in lunar science. Subsequent chapters detail different, complementary approaches to geologic studies: global surveys, including orbiting spacecraft such as Lunar Observer and installation of a global geophysical network; reconnaissance sample return mission, by either automated rovers or landers, or by piloted forays; detailed field studies, which involve astronauts and teleoperated robotic field geologists. The document then develops a flexible scenario for exploration and sketches the technological developments needed to carry out the exploration scenario.

Taylor, G. Jeffrey↗
DOE OSTI2024

Development of optimal methods for collection, transportation, holding, handling, and tagging of juvenile American shad

American shad (Alosa sapidissima) are an anadromous fish species native to the United States that have an extensive range along the east coast, but their populations are declining worldwide. Acoustic telemetry can play a vital role in better understanding the behavior and survival of this sensitive species. A stepwise, systematic approach was used to assess juvenile shad survival during multiple stressors typically associated with an acoustic telemetry study. Minimizing out-of-water handling and the use of saltwater during collection increased 24-hour survival (78 to 99%) between the first two shad transports. Several experiments were conducted to determine the best transmitter design method for implanting juvenile shad. Saltwater was fundamental in keeping tagged shad alive overnight and during the tagging process. Shad as small as 50 mm were tagged using the pectoral incision method with no suture. In a 60-d holding evaluation, tagged fish survived at a comparable rate as their non-tagged counterparts (81.5% for tagged, 70% for untagged). Also, when tagged and untagged shad were exposed to a tank of predators, there was no difference in their survival. Results from this study are encouraging for improving conservation efforts for small, sensitive species of fish, like American shad. The techniques identified may help broaden the application of telemetry studies by informing researchers of optimal methods to ensure survival of tagged fish in future field studies looking to evaluate survival and entrainment rates of juvenile American shad.

59 BASIC BIOLOGICAL SCIENCES↗
DOE OSTI2018

Differential degradation patterns of photovoltaic backsheets at the array level

There are relatively few field studies on the degradation of non-fluoropolymer-based backsheets, and understanding their in-field behavior is critical for further development of such products. In this paper, backsheet degradation of modules with one of these new types of backsheets (polyethylene naphthalate (PEN)-based) was documented at a four-year old utility-scale array located in Maryland (USA). Visual inspection, colorimetry, glossimetry, and Fourier-transform infrared spectroscopy (FTIR) revealed highly varied properties depending on module position within the array. Specifically, modules near the edge of the array and with higher mounting elevations underwent greater amounts of backsheet degradation, as indicated by yellowing and gloss-loss. The reason for these unique degradation patterns were differential backside exposure conditions, especially of ultraviolet light. This was strongly influenced by the array design, including array structural and environmental factors, such as module spacing and ground cover, respectively. Within the array, no clear link between backsheet degradation and module output or safety has been identified. However, such a relationship may be expected to become more pronounced with time, affecting system lifetime and ultimately the levelized cost of electricity (LCOE). Finally, the observed phenomena have implications for both backsheet product development and array design, especially for modules that utilize newer classes of non-fluoropolymer-based backsheets which are typically more susceptible to environmental degradation.

14 SOLAR ENERGY↗
NASA NTRS1970

Remote sensing of changes in morphology and physiology of trees under stress

Results of continuing studies of forest trees subjected to varying types of stress are reported. Both greenhouse and field studies are included. Greenhouse work with tree seedlings exposed to varying levels of NaCl and CaCl2 in the soil indicated that, in the initial stages, palisade cells shrink and the amount of air space in the leaf increases. As the severity of damage increases, the cells of the spongy mesophyll shrink and flatten, and the amount of air space in the leaf decreases. Statistical analysis of foliar reflectance and associated moisture content data led to a series of regression equations for predicting foliar moisture content from reflectance data. Equations were calculated for three species, yellow birch (Betula alleghaniensis Britton), sugar maple (Acer saccharum Marsh.) and white ash (Fraxinus americana L.) having multiple correlation coefficients of 0.98, 0.94 and 0.93 respectively. Interpretation of multispectral imagery of the Ann Arbor Forestry Test Site (NASA Site 190) provided evidence that infections of Fomes annosus can be detected in the early stages. Infections of two needle cast diseases were also detected in conifer plantations in the test site. A study of automatic interpretation of multispectral scanner imagery for tree species recognition provided encouraging results.

Olson, C. E., Jr.↗
NASA NTRS1984

Comprehensive Understanding for Vegetated Scene Radiance Relationships

The improvement of our fundamental understanding of the dynamics of directional scattering properties of vegetation canopies through analysis of field data and model simulation data is discussed. Directional reflectance distributions spanning the entire existance hemisphere were measured in two field studies; one using a Mark III 3-band radiometer and one using rapid scanning bidirectional field instrument called PARABOLA. Surfaces measured included corn, soybeans, bare soils, grass lawn, orchard grass, alfalfa, cotton row crops, plowed field, annual grassland, stipa grass, hard wheat, salt plain shrubland, and irrigated wheat. Some structural and optical measurements were taken. Field data show unique reflectance distributions ranging from bare soil to complete vegetation canopies. Physical mechanisms causing these trends are proposed based on scattering properties of soil and vegetation. Soil exhibited a strong backscattering peak toward the Sun. Complete vegetation exhibited a bowl distribution with the minimum reflectance near nadir. Incomplete vegetation canopies show shifting of the minimum reflectance off of nadir in the forward scattering direction because both the scattering properties or the vegetation and soil are observed.

Kimes, D. S.↗
NASA NTRS2020

Development and Evaluation of the Raindrop Size Distribution Parameters for the NASA Global Precipitation Measurement Mission Ground Validation Program

The National Aeronautics and Space Administration Global Precipitation Measurement (GPM) mission ground validation program uses dual-polarization radar moments to estimate raindrop size distribution (DSD) parameters, the mass-weighted mean drop diameter Dmass, and normalized intercept parameter NW, to validate the GPM Core Observatory–derived DSD parameters. The disdrometer-based Dmass and NW are derived through empirical relationships between Dmass and differential reflectivity ZDR, and between NW, reflectivity ZH, and Dmass. This study employs large datasets collected from two-dimensional video disdrometers (2DVD) during six different field studies to derive the requisite empirical relationships. The uncertainty of the derived Dmass(ZDR) relationship is evaluated through comparisons of 2DVD-calculated and ZDR-estimated Dmass, where ZDR is calculated directly from 2DVD observations. Similarly, the uncertainty of the NW(ZH, Dmass) relationship is evaluated through 2DVD-calculated and Dmass and ZH-estimated NW, where Dmass and ZH are directly calculated from 2DVD observations. This study also presents the sensitivity of Dmass(ZDR) relationships to climate regime and to disdrometer type after developing three additional Dmass(ZDR) relationships from second-generation Particle Size Velocity (PARSIVEL2) disdrometer (P2) observations collected in the Pacific Northwest, in Iowa, and at Kwajalein Atoll in the tropical Pacific Ocean. The application of P2-derived Dmass(ZDR) relationship based on precipitation in the northwestern United States to P2 observations collected over the tropical ocean resulted in the highest error among comparisons of the three datasets.

Ali Tokay↗
DOE OSTI2017

Secondary organic aerosol formation in biomass-burning plumes: theoretical analysis of lab studies and ambient plumes

Abstract. Secondary organic aerosol (SOA) has been shown to form in biomass-burning emissions in laboratory and field studies. However, there is significant variability among studies in mass enhancement, which could be due to differences in fuels, fire conditions, dilution, and/or limitations of laboratory experiments and observations. This study focuses on understanding processes affecting biomass-burning SOA formation in laboratory smog-chamber experiments and in ambient plumes. Vapor wall losses have been demonstrated to be an important factor that can suppress SOA formation in laboratory studies of traditional SOA precursors; however, impacts of vapor wall losses on biomass-burning SOA have not yet been investigated. We use an aerosol-microphysical model that includes representations of volatility and oxidation chemistry to estimate the influence of vapor wall loss on SOA formation observed in the FLAME III smog-chamber studies. Our simulations with base-case assumptions for chemistry and wall loss predict a mean OA mass enhancement (the ratio of final to initial OA mass, corrected for particle-phase wall losses) of 1.8 across all experiments when vapor wall losses are modeled, roughly matching the mean observed enhancement during FLAME III. The mean OA enhancement increases to over 3 when vapor wall losses are turned off, implying that vapor wall losses reduce the apparent SOA formation. We find that this decrease in the apparent SOA formation due to vapor wall losses is robust across the ranges of uncertainties in the key model assumptions for wall-loss and mass-transfer coefficients and chemical mechanisms.We then apply similar assumptions regarding SOA formation chemistry and physics to smoke emitted into the atmosphere. In ambient plumes, the plume dilution rate impacts the organic partitioning between the gas and particle phases, which may impact the potential for SOA to form as well as the rate of SOA formation. We add Gaussian dispersion to our aerosol-microphysical model to estimate how SOA formation may vary under different ambient-plume conditions (e.g., fire size, emission mass flux, atmospheric stability). Smoke from small fires, such as typical prescribed burns, dilutes rapidly, which drives evaporation of organic vapor from the particle phase, leading to more effective SOA formation. Emissions from large fires, such as intense wildfires, dilute slowly, suppressing OA evaporation and subsequent SOA formation in the near field. We also demonstrate that different approaches to the calculation of OA enhancement in ambient plumes can lead to different conclusions regarding SOA formation. OA mass enhancement ratios of around 1 calculated using an inert tracer, such as black carbon or CO, have traditionally been interpreted as exhibiting little or no SOA formation; however, we show that SOA formation may have greatly contributed to the mass in these plumes.In comparison of laboratory and plume results, the possible inconsistency of OA enhancement between them could be in part attributed to the effect of chamber walls and plume dilution. Our results highlight that laboratory and field experiments that focus on the fuel and fire conditions also need to consider the effects of plume dilution or vapor losses to walls.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2021

Magnetic and electronic phases of U 2 Rh 3 Si 5

We present a detailed study of the magnetic and electronic properties of U 2 Rh 3 Si 5 , a material that has been demonstrated to exhibit a first-order antiferromagnetic phase transition. From a high-magnetic-field study, together with extensive experiments in moderate fields, we establish the magnetic phase diagrams for all crystallographic directions. The possibility of an electronic phase in a narrow interval above the Néel temperature as a precursor of a magnetic phase is discussed.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
NASA NTRS1984

Comprehensive Understanding for Vegetated Scene Radiance Relationships

Directional reflectance distributions spanning the entire existent hemisphere were measured in two field studies; one using a Mark III 3-band radiometer and one using the rapid scanning bidirectional field instrument called PARABOLA. Surfaces measured included corn, soybeans, bare soils, grass lawn, orchard grass, alfalfa, cotton row crops, plowed field, annual grassland, stipa grass, hard wheat, salt plain shrubland, and irrigated wheat. Analysis of field data showed unique reflectance distributions ranging from bare soil to complete vegetation canopies. Physical mechanisms causing these trends were proposed. A 3-D model was developed and is unique in that it predicts: (1) the directional spectral reflectance factors as a function of the sensor's azimuth and zenith angles and the sensor's position above the canopy; (2) the spectral absorption as a function of location within the scene; and (3) the directional spectral radiance as a function of the sensor's location within the scene. Initial verification of the model as applied to a soybean row crop showed that the simulated directional data corresponded relatively well in gross trends to the measured data. The model was expanded to include the anisotropic scattering properties of leaves as a function of the leaf orientation distribution in both the zenith and azimuth angle modes.

Kimes, D. S.↗
NASA NTRS1988

Mars Observer - Science

The scientific objectives and experiments planned for the Mars Observer mission are discussed. Scientific instruments for the mission are described and illustrated, including a gamma-ray spectrometer, a visual and IR mapping spectrometer, a thermal emission spectrometer, an imaging camera, a radar altimeter and radiometer, a magnetometer, and a pressure modulate IR radiometer. Mission objectives include studying the global elemental and mineralogical character of the Martian surface, defining the topography and gravitational field, studying the atmospheric circulation, and determining the time and space distribution, abundance sources, and sinks of volatile material and dust over a seasonal cycle.

Albee, Arden L.↗
NASA NTRS2023

Remotely Sensed Soil Moisture Can Capture Dynamics Relevant to Plant Water Uptake

A frequently expressed viewpoint across the Earth science community is that global soil moisture estimates from satellite L-band (1.4 GHz) measurements represent moisture only in a shallow surface layer (0–5 cm) and consequently are of limited value for studying global terrestrial ecosystems because plants use water from deeper rootzones. Using this argumentation, many observation-based land surface studies avoid satellite-observed soil moisture. Here, based on peer-reviewed literature across several fields, we argue that such a viewpoint is overly limiting for two reasons. First, microwave soil emission depth considerations and statistical considerations of vertically correlated soil moisture information together indicate that L-band measurements carry information about soil moisture extending below the commonly referenced 5 cm in many conditions. However, spatial variations of effective depths of representation remain uncertain. Second, in reviewing isotopic tracer field studies of plant water uptake, we find a prevalence of vegetation that primarily draws moisture from these upper soil layers. This is especially true for grasslands and croplands covering more than a third of global vegetated surfaces. Even some deeper-rooted species (i.e., shrubs and trees) preferentially or seasonally draw water from the upper soil layers. Therefore, L-band satellite soil moisture estimates are more relevant to global vegetation water uptake than commonly appreciated (i.e., relevant beyond only shallow soil processes like soil evaporation). Our commentary encourages the application of satellite soil moisture across a broader range of terrestrial hydrosphere and biosphere studies while urging more rigorous estimates of its effective depth of representation.

Andrew F. Feldman↗
DOE OSTI2022

Global dipole symmetry, compact Lifshitz theory, tensor gauge theory, and fractons

We study field theories with global dipole symmetries and gauge dipole symmetries. The famous Lifshitz theory is an example of a theory with a global dipole symmetry. We study in detail its 1+1d version with a compact field. When this global symmetry is promoted to a $U(1)$ dipole gauge symmetry, the corresponding gauge field is a tensor gauge field. This theory is known to lead to fractons. In order to resolve various subtleties in the precise meaning of these global or gauge symmetries, we place these 1+1d theories on a lattice and then take the continuum limit. Interestingly, the continuum limit is not unique. Different limits lead to different continuum theories, whose operators, defects, global symmetries, etc. are different. We also consider a lattice gauge theory with a $\mathbb Z_N$ dipole gauge group. Surprisingly, several physical observables, such as the ground state degeneracy and the mobility of defects depend sensitively on the number of sites in the lattice. Our analysis forces us to think carefully about global symmetries that do not act on the standard Hilbert space of the theory, but only on the Hilbert space in the presence of defects. We refer to them as time-like global symmetries and discuss them in detail. Furthermore, these time-like global symmetries allow us to phrase the mobility restrictions of defects (including those of fractons) as a consequence of a global symmetry.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
NASA NTRS1987

Magnetic studies of high Tc superconducting (La0.9Sr0.1)2CuO4-y

The magnetic moment of La(0.9Sr0.1)2CuO4-y was measured as a function of temperature and magnetic field, and the onset of superconductivity was found to occur at a temperature of 35 K. At 2 K, the dc magnetic susceptibility was found to reach 83 percent of perfect diamagnetism. Field studies have shown that the sample is a type-II superconductor and that the temperature dependences of the critical fiedls are anomalous. Its critical fields, kappa, and lambda(eff) are much larger than those for (La0.9Ba0.1)2CuO4-y, and their temperature dependences cannot be explained in terms of BCS theory.

Zirngiebl, E.↗