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At least 469 records · Page 26

High-Resolution and Analytical TEM Investigation of Space Radiation Processing Effects in Primitive Solar System Materials and Airless Planetary Surface Environments

Energetic ions present in the diverse plasma conditions in space play a significant role in the formation and modification of solid phases found in environments ranging from the interstellar medium (ISM) to the surfaces of airless bodies such as asteroids and the Moon. These effects are often referred to as space radiation processing, a term that encompasses changes induced in natural space-exposed materials that may be only structural, such as in radiation-induced amorphization, or may involve ion-induced nanoscale to microscale chemical changes, as occurs in preferential sputtering and ion-beam mixing. Ion sputtering in general may also be responsible for partial or complete erosion of space exposed materials, in some instances possibly bringing about the complete destruction of free-floating solid grains in the ISM or in circumstellar nebular dust clouds. We report here on two examples of the application of high-resolution and analytical transmission electron microscopy (TEM) to problems in space radiation processing. The first problem concerns the role of space radiation processing in controlling the overall fate of Fe sulfides as hosts for sulfur in the ISM. The second problem concerns the known, but as yet poorly quantified, role of space radiation processing in lunar space weathering.

Christoffersen, R.↗

Discovery of Interstellar Hydrogen Fluoride

We report the first detection of interstellar hydrogen fluoride. Using the Long Wavelength Spectrometer of the Infrared Space Observatory (ISO), we have detected the 121.6973 micron J = 2-1 line of HF in absorption toward the far-infrared continuum source Sagittarius B2. The detection is statistically significant at the 13 sigma level. On the basis of our model for the excitation of HF in Sgr B2, the observed line equivalent width of 1.0 nm implies a hydrogen fluoride abundance of about 3 x 10 (exp -10) relative to H, If the elemental abundance of fluorine in Sgr B2 is the same as that in the solar system, then HF accounts for about 2% of the total number of fluorine nuclei. We expect hydrogen fluoride to be the dominant reservoir of gas-phase fluorine in Sgr B2, because it is formed rapidly in exothermic reactions of atomic fluorine with either water or molecular hydrogen; thus, the measured HF abundance suggests a substantial depletion of fluorine onto dust grains. Similar conclusions regarding depletion have previously been reached for the case of chlorine in dense interstellar clouds. We also find evidence at a lower level of statistical significance (about 5 sigma) for an emission feature at the expected position of the 4(sub 32)-4(sub 23) 121.7219 micron line of water. The emission-line equivalent width of 0.5 mm for the water feature is consistent with the water abundance of 5 x 10(exp -6) relative to H, that has been inferred previously from observations of the hot core of Sgr B2.

Neufeld, David A.↗

Discovery of Interstellar Hydrogen Fluoride

We report the first detection of interstellar hydrogen fluoride. Using the Long Wavelength Spectrometer of the Infrared Space Observatory (ISO), we have detected the 121.6973 micron J = 2-1 line of HF in absorption toward the far-infrared continuum source Sagittarius B2. The detection is statistically significant at the 13 sigma level. On the basis of our model for the excitation of HF in Sgr B2, the observed line equivalent width of 1.0 nm implies a hydrogen fluoride abundance of approximately 3 x 10(exp -10) relative to H2. If the elemental abundance of fluorine in Sgr B2 is the same as that in the solar system, then HF accounts for approximately 2% of the total number of fluorine nuclei. We expect hydrogen fluoride to be the dominant reservoir of gas-phase fluorine in Sgr B2, because it is formed rapidly in exothermic reactions of atomic fluorine with either water or molecular hydrogen; thus, the measured HF abundance suggests a substantial depletion of fluorine onto dust grains. Similar conclusions regarding depletion have previously been reached for the case of chlorine in dense interstellar clouds. We also find evidence at a lower level of statistical significance (approximately 5 sigma) for an emission feature at the expected position of the 4(sub 32)-4(sub 23) 121.7219 micron line of water. The emission-line equivalent width of 0.5 nm for the water feature is consistent with the water abundance of 5 x 10(exp -6) relative to H2 that has been inferred previously from observations of the hot core of Sgr B2.

Neufeld, David A.↗

Star Formation In the Galaxy and the Fluctuating UV Radiation Field

We examine the formation of massive stars in the Galaxy, the resultant fluctuating UV (ultraviolet) radiation field, and the effect of this field on the star-forming interstellar medium. There are substantial fluctuations of the UV radiation field in space (scales of 100's of parsecs) and time (time-scales of order 100 million years). The FUV (far ultraviolet) (6 eV less than hv less than 13.6 eV) field and the pressure determines whether the thermal balance of the neutral gas results in cold clouds or warm (T approx. 10(exp 4) K) neutral medium. We show how to calculate the average fractions of the gas in the cold and warm phases when the interstellar gas is subject to this fluctuating FUV field. The knowledge of how these fractions depend on the gas properties and on the FUV sources is a basic step in building a model of the large scale behavior of the ISM (interstellar medium) and the mutual relation between the ISM and the star formation rate.

Hollenbach, David↗

The AstroBiology Explorer (ABE) MIDEX Mission Concept: Exploring the Links Between the Interstellar Medium and Meteorites

Infrared spectroscopy in the 2.5-16 micron range is a principle means by which organic compounds can be detected and identified in space via their vibrational transitions. Ground-based, airborne, and spaceborne IR spectral studies have already demonstrated that a significant fraction of the carbon in the interstellar medium (ISM) resides in the form of complex organic molecular species. Furthermore, the presence of D-enriched organics in meteorites suggests that a portion of these materials survives incorporation into protosolar nebulae. Unfortunately, neither the distribution of these materials nor their genetic and evolutionary relationships with each other or their environments are well understood. The Astrobiology Explorer (ABE) is a MIDEX mission concept currently under study at NASA's Ames Research Center in collaboration with Ball Aerospace and Technologies Corporation. ABE will conduct IR spectroscopic observations to address outstanding important problems in astrobiology, astrochemistry, and astrophysics. The core observational program would make fundamental scientific progress in understanding (1) the evolution of ices and organic matter in dense molecular clouds and young forming stellar systems, (2) the chemical evolution of organic molecules in the ISM as they transition from AGB outflows to planetary nebulae to the general diffuse ISM to HII regions and dense clouds, (3) the distribution of organics in the diffuse ISM, (4) the nature of organics in the Solar System (in comets, asteroids, satellites), and (5) the nature and distribution of organics in local galaxies. In addition, ABE will attempt to detect and quantify deuterium enrichments in a select set of these materials and environments. This should assist both with understanding the chemical processes that occur in these environments and with establishing any links that exist between interstellar and meteoritic organics.

Sandford, Scott A.↗

Sulfur Molecules in Space by X-rays: A Computational Study

X-ray astronomy lacks high resolution spectra of interstellar dust analogues and molecules, severely hampering interstellar medium studies based on upcoming X-ray missions. Various theoretical approaches may be used to address this problem, but they must first be shown to reproduce reliable spectra compared to the experiment. In this work, we calculate the sulfur Kedge X-ray absorption spectra of H2S, SO2, and OCS, whose spectra are already known from X-ray experiments and predict the X-ray spectrum of CS, which as far as we are aware has not been measured, thereby hampering its detection by X-ray telescopes. We chose these four molecules as the astrochemistry of sulfur is an unsolved problem and as the four molecules are already known to exist in space. We consider three types of methods for modeling the X-ray spectra: more accurate calculations with the algebraic-diagrammatic construction (ADC) and the CC2, CCSD, and CC3coupled cluster (CC) approaches as well as more affordable ones with transition potential density functional theory (TP-DFT). A comparison of our computational results to previously reported experimental spectra shows that the core−valence separation (CVS)approaches CVS-ADC(2)-x and CVS-CC3 generally yield a good qualitative level of agreement with the experiment, suggesting that they can be used for interpreting measured spectra, while the TP-DFT method is not reliable for these molecules. However, quantitative agreement with the experiment is still outside the reach of the computational methods studied in this work.

Goranka Bilalbegovic↗

High energy from space

The following subject areas are covered: (1) important scientific problems for high energy astrophysics (stellar activity, the interstellar medium in galaxies, supernovae and endpoints of stellar evolution, nucleosynthesis, relativistic plasmas and matter under extreme conditions, nature of gamma-bursts, identification of black holes, active nuclei, accretion physics, large-scale structures, intracluster medium, nature of dark matter, and the X- and gamma-ray background); (2) the existing experimental programs (Advanced X-Ray Astrophysics Facility (AXAF), Gamma Ray Observatory (GRO), X-Ray Timing Explorer (XTE), High Energy Transient Experiment (HETE), U.S. participation in foreign missions, and attached Shuttle and Space Station Freedom payloads); (3) major missions for the 1990's; (4) a new program of moderate missions; (5) new opportunities for small missions; (6) technology development issues; and (7) policy issues.

Margon, Bruce↗

Radio observations of molecules in the interstellar gas

Since 1968, radio astronomy has made it possible to identify nearly 50 molecules in the dense concentrations of the interstellar gas now generally termed molecular clouds. Most interstellar molecules are familiar stable compounds. However, one-fifth of the discovered species are ions, radicals, and acetylenic carbon chains so reactive in the laboratory that before being detected in space they had rarely been observed or were entirely unknown. The heavy atom backbone of the known interstellar molecules is a linear chain of C, N, O, or S. Si is found in two diatomic molecules. Rings and branched chains are missing. The most readily observed spectral lines of most interstellar molecules correspond to rotational transitions at millimeter wavelengths. These are generally excited by H2 collisions. A number of rare isotopic species are observed in interstellar molecules. Isotopic ratios differing from those on Earth exist, and can in almost all cases be attributed to stellar nucleosynthesis since the formation of the solar system.

Thaddeus, P.↗

The thermodynamics of dust formation - Evidence from meteorites

The paper examines the thermodynamics of dust formation indicated by meteorites. Much of interstellar dust probably formed in the nebulae around protostars, and mineralogy and composition of meteorites provides information that prevailed in the nebula. The fact that the gas associated with interstellar dust has solar H/S ratios indicates that FeS, which forms at 680 K, is not present in the dust, and since iron only becomes oxidized at even lower temperatures, oxidized iron is not expected in the dust. If most interstellar dust forms in the nebulae and is ejected back in space, a high temperature is indicated. High-temperature fractionation processes played an important role in the nebula, and much of the Al, Ca, and Ti evidently condensed and accreted into cm-sized objects, some of which are found in carbonaceous chondrites; they are explicable in terms of formation from a cooling neutral gas with cosmic composition.

Larimer, J. W.↗

Fullerenes in an impact crater on the LDEF spacecraft

The fullerenes C60 and C70 have been found to occur naturally on Earth and have also been invoked to explain features in the absorption spectra of interstellar clouds. But no definitive spectroscopic evidence exists for fullerenes in space and attempts to find fullerenes in carbonaceous chondrites have been unsuccessful. Here we report the observation of fullerenes associated with carbonaceous impact residue in a crater on the Long Duration Exposure Facility (LDEF) spacecraft. Laser ionization mass spectrometry and Raman spectroscopy indicate the presence of fullerenes in the crater and in adjacent ejecta. Man-made fullerenes survive experimental hypervelocity (approximately 6.1 km s-1) impacts into aluminium targets, suggesting that space fullerenes contained in a carbonaceous micrometeorite could have survived the LDEF impact at velocities towards the lower end of the natural particle encounter range (<13 km s-1). We also demonstrate that the fullerenes were unlikely to have formed as instrumental artefacts, nor are they present as contaminants. Although we cannot specify the origin of the fullerenes with certainty, the most plausible source is the chondritic impactor. If, alternatively, the impact produced the fullerenes in situ on LDEF, then this suggests a viable mechanism for fullerene production in space.

long duration↗

A new dimension in space experimentation

Based on the Space Shuttle's ability to place the Long Duration Exposure Facility (LDEF) in space and later retrieve it, a new opportunity for scientific exploration in space is studied. The LDEF which is scheduled to be placed in orbit in 1984 and returned to earth after one year in space is described. It is a large unmanned facility 9 m in length and 4 m in diameter and flying at an 482 km orbit. It is pointed out that the LDEF allows investigators to have their experiments returned to them for in-depth analysis, eliminates the need for complex systems to transmit data to earth, does not require propulsion equipment, and increases the kinds of experiments that can be performed. A description is given for each of the five categories of the experiments provided by the LDEF: (1) evaluation of the impact of space environments on materials used for thermal coatings on polymer-matrix composites, on optics, and on quartz-crystal oscillators; (2) experiments with unique heat pipe systems having the goal to achieve temperature control of + or - 6 F; (3) evaluation of solar array materials; (4) growth of single crystals of lead sulfite, calcium carbonate, and synthetic metals; and (5) scientific experiments to determine the chemistry of micrometeoroids and to identify isotopes in interstellar gas and ultra-heavy cosmic ray nuclei. Finally, the project SEEDS (Space Exposed Experiment Developed for Students) which experiments with tomato seeds behavior in zero gravity is discussed.

Sandy, M. L.↗

Star Formation in the Galaxy and the Fluctuating UV Radiation Field

We examine the formation of massive stars in the Galaxy, the resultant fluctuating UV radiation field, and the effect of this field on the star-forming interstellar medium (ISM). There are substantial fluctuations of the UV radiation field in space (scales of 100's of parsecs) and time (time-scales of order 100 million years) at the solar circle. The Far Ultraviolet (FUV) (6 eV< hv < 13.6 eV) field and the pressure determines whether the thermal balance of the neutral gas results in cold clouds or warm (T - 10(exp 4) neutral medium. We show how to calculate the average fractions of the gas in the cold and warm phases when the interstellar gas is subject to this fluctuating FUV field. The knowledge of how these fractions depend on the gas properties and on the FUV sources is a basic step in building a model of the large scale behavior of the ISM and the mutual relation between the ISM and the star formation rate. Application is made to observations of spiral galaxies which correlate the star formation rate per unit area with the surface density of the gas. We acknowledge support from the NASA Astrophysical Theory program.

Hollenbach, David↗

Cutting Silica Aerogel for Particle Extraction

The detailed laboratory analyses of extraterrestrial particles have revolutionized our knowledge of planetary bodies in the last three decades. This knowledge of chemical composition, morphology, mineralogy, and isotopics of particles cannot be provided by remote sensing. In order to acquire these detail information in the laboratories, the samples need be intact, unmelted. Such intact capture of hypervelocity particles has been developed in 1996. Subsequently silica aerogel was introduced as the preferred medium for intact capturing of hypervelocity particles and later showed it to be particularly suitable for the space environment. STARDUST, the 4th NASA Discovery mission to capture samples from 81P/Wild 2 and contemporary interstellar dust, is the culmination of these new technologies. In early laboratory experiments of launching hypervelocity projectiles into aerogel, there was the need to cut aerogel to isolate or extract captured particles/tracks. This is especially challenging for space captures, since there will be many particles/tracks of wide ranging scales closely located, even collocated. It is critical to isolate and extract one particle without compromising its neighbors since the full significance of a particle is not known until it is extracted and analyzed. To date, three basic techniques have been explored: mechanical cutting, lasers cutting and ion beam milling. We report the current findings.

Tsou, P.↗

Scientific returns from a program of space missions to comets

A program of cometary missions is proposed. The nature and size of interstellar dust, its origin and evolution; identification of new interstellar molecules; clarification of interstellar chemistry; accretion of grains into protosolar cometesimals; role of a T Tauri wind in the dissipation of the protosolar nebula; record of isotopic anomalies, better preserved in comets than in meteorites; cosmogenic and radiogenic dating of comets; cosmochronology and mineralogy of meteorites, as compared with that of cometary samples; origin of the earth's biosphere, and the origin of life are topics discussed in relation to comet exploration.

Delsemme, A. H.↗

Transformational Propulsion for In-Space Fast Transits

NASA has ambitious mission objectives requiring much faster transits to and from Mars, interstellar probes and a gravity lens observatory. However, there has been very little investment in transformational propulsion system development activities since the 1970s. There have been dozens of concepts proposed for high acceleration propulsion solutions, but nearly all have been limited to paper studies. A quick assessment was completed in 2023 to determine the potential of transformational propulsion concepts to enable faster transits, with a focus on crewed missions to and from Mars. Far-term conventional nuclear thermal propulsion is limited to very modest improvement in transfer times. Advanced nuclear propulsion options have significant performance potential, but limited interim evolutionary payoff for NASA. Advanced electric propulsion, both solar and nuclear, offers transformational performance potential with high payoff during interim progress for power production, conversion, and heat rejection technologies. Study results and recommendations for near-term investments are presented herein.

Propulsion↗

Cooling of the Interstellar Medium

This talk will review the various heating and cooling processes in the interstellar medium. The most important heating processes include the photoelectric effect on dust grains and PAH molecules. Cooling of the gas in the interstellar medium is dominated by emission in the far infrared fine-structure lines of OI, CII, SiII, and CI, and the rotational transitions of CO. Which of these heating and cooling processes dominates in a given region depends on its physical and especially chemical conditions, which in turn depend themselves on the interstellar UV radiation field. As a result of the interplay of these processes, the interstellar medium is organized in various structures with distinctly different physical conditions (i.e., temperature, density, and degree of ionization). The dominant cooling lines of the neutral interstellar medium have been studied using the Kuiper Airborne Observatory, balloon-borne instruments, and recently space-based missions (IRTS, ISO). These observations have concentrated on dense regions illuminated by strong UV fields from nearby stars, so-called PhotoDissociation Regions (PDRs). These observations allow us to study in detail the interaction of UV photons observations allow us to study in detail the interaction of UV photons and the interstellar gas and dust. Detailed theoretical models have been developed for PDRs. These will be reviewed and compared to the observations. Recent space based missions have measured the dominant cooling line of the galaxy, the [CII] 158 micron line. These observations and their implications will be reviewed.

Tielens, A. G. G. M.↗

Laboratory Spectroscopy of Large Carbon Molecules and Ions in Support of Space Missions

One of the major objectives of Laboratory Astrophysics is the optimization of data return from space missions by measuring spectra of atomic and molecular species in laboratory environments that mimic interstellar conditions (WhitePaper (2002, 2006)). Among interstellar species, PAHs are an important and ubiquitous component of carbon-bearing materials that represents a particularly difficult challenge for gas-phase laboratory studies. We present the absorption spectra of jet-cooled neutral and ionized PAHs and discuss the implications for astrophysics. The harsh physical conditions of the interstellar medium have been simulated in the laboratory. We are now, for the first time, in the position to directly compare laboratory spectra of PAHs and carbon nanoparticles with astronomical observations. This new phase offers tremendous opportunities for the data analysis of current and upcoming space missions geared toward the detection of large aromatic systems (HST/COS, FUSE, JWST, Spitzer).

Salana, Farid↗

Revealing Asymmetries in the HD181327 Debris Disk: A Recent Massive Collision or Interstellar Medium Warping

New multi-roll coronagraphic images of the HD181327 debris disk obtained using the Space Telescope Imaging Spectrograph on board the Hubble Space Telescope reveal the debris ring in its entirety at high signal-to-noise ratio and unprecedented spatial resolution. We present and apply a new multi-roll image processing routine to identify and further remove quasi-static point-spread function-subtraction residuals and quantify systematic uncertainties. We also use a new iterative image deprojection technique to constrain the true disk geometry and aggressively remove any surface brightness asymmetries that can be explained without invoking dust density enhancements/ deficits. The measured empirical scattering phase function for the disk is more forward scattering than previously thought and is not well-fit by a Henyey-Greenstein function. The empirical scattering phase function varies with stellocentric distance, consistent with the expected radiation pressured-induced size segregation exterior to the belt. Within the belt, the empirical scattering phase function contradicts unperturbed debris ring models, suggesting the presence of an unseen planet. The radial profile of the flux density is degenerate with a radially varying scattering phase function; therefore estimates of the ring's true width and edge slope may be highly uncertain.We detect large scale asymmetries in the disk, consistent with either the recent catastrophic disruption of a body with mass greater than 1% the mass of Pluto, or disk warping due to strong interactions with the interstellar medium.

Henyey Greenstein function↗