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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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NASA NTRS1988

Laboratory studies of sticking coefficients and heterogeneous reactions important in the Antarctic stratosphere

Laboratory studies of sticking coefficients of H2O, HCl, Cl2, and HNO3 on ice and heterogeneous reactions of ClONO2 with ice or HCl/ice have been performed in a fast flow reactor. A quadrupole mass spectrometer with electron impact ionization was used as a detector. Measured sticking coefficients are: 0.3 (+0.7, -0.1) for H2O, 0.4 (+0.6, -0.2) for HCL, less than 0.0001 for Cl2, and 0.3 (+0.7, -0.1) for HNO3 at 200 K. The reaction probability of ClONO2 on ice was found to be 0.06 (+ or - 0.03) while HOCl was observed as a sole product in the gas phase. With HCl present in ice, the reaction probability of ClONO2 is greatly enhanced, approaching 0.27 (+0.73, -0.13) while molecular chlorine was found to be the major product in the gas phase. Another reaction product was nitric acid which remained in the solid phase. Since the polar stratospheric clouds contain ice particles or possibly HCl/ice particles on the surface, the present results should be a major factor in producing the observed springtime ozone depletion in the Antarctic stratosphere.

Leu, Ming-Taun↗
NASA NTRS1988

Thin cirrus clouds - Seasonal distribution over oceans deduced from Nimbus-4 IRIS

Spectral differences in the extinction of the 10.8- and 12.6-micron bands of the IR window region, due to optically thin clouds, were found in the measurements made by both an airborne broadband IR radiometer and the IR interferometer spectrometer (IRIS) aboard the Nimbus-4 satellite; the extinction at 12.6 microns was significantly larger than that at 10.8 microns; both water and ice particles in the clouds can account for such spectral difference in extinction. Multiple scattering radiative transfer calculations of IRIS data revealed this spectral feature about 100 to 20 km away from the high-altitude cold clouds; it is assumed that this feature is related to the spreading of cirrus clouds. Based on this assumption, mean seasonal maps of the distribution of thin cirrus clouds over the oceans were deduced from the IRIS data. The maps show that such clouds are often present over the convectively active areas, such as ITCZ, SPCZ, and the Bay of Bengal during the summer monsoon.

Prabhakara, C.↗
NASA NTRS1988

Comet Halley's colorful outbursts

Two preperihelion outbursts by Comet Halley were observed, each showing different brightness changes at 2.3, 3.6, 4.6 and 10.3 micrometers. Neither event was observed from beginning to end. The first observation on 8 Nov. 1985 lasted on the order of a day and was accompanied by a tail-like appendage recorded photographically. During the outburst the IR colors changed dramatically, showing no significant change at 10.3 micrometers but showing progressively more change at shorter wavelengths over a time scale of a few hours. The second outburst measurement extended over several days (10 to 13 Jan. 1986) during which time the intensities at the four wavelengths increased by roughly the same amount. Although the outbursts were of different duration, the IR measurements suggest that the first event involved volatile ice particles that evaporated, while the second was associated with long lived nonvolatile dust grains.

Lynch, David K.↗
NASA NTRS1988

The sudden appearance of the tail of Comet Halley

An outburst event on Comet Halley, which was photographed in November 1985 when the comet was very near the ecliptic plane at 1.82 AU from the sun, is discussed. An irregular mass of material was observed, reaching about 1 arcmin south of the comet, approximately 70 degrees from the expected angle of the tail. Brightness changes during the event, up to a factor of 20, were shown in 2.3-10.3-micron IR measurements. The behavior of the outburst is consistent with the rapid expulsion of volatile ice particles. It is shown that the tail formed rather suddenly, though somewhat episodically. It is suggested that the outburst was not caused by a meteorite impact. It is concluded that the probable cause of the outburst was thermal heating of the nuclear crust with modest heat storage.

Lynch, D. K.↗
NASA NTRS1988

3 micron spectrophotometry of Comet Halley - Evidence for water ice

Structure has been observed in the 3-3.6 micron preperihelion spectrum of Comet Halley consistent with either an absorption band near 3.1 microns or emission near 3.3 microns. The results suggest that a large fraction of the water molecules lost by the comet are initially ejected in the form of small ice particles rather than in the gas phase.

Bregman, Jesse D.↗
NASA NTRS1989

Relation between increasing methane and the presence of ice clouds at the mesopause

The possiblity is investigated that a substantial change has occurred in middle-atmospheric water vapor as a result of the increase in atmospheric methane over the past century and a half. It is shown from modeling of mesospheric ice-particle formation that noctilucent cloud brightness should be a sensitive indicator of the water content at the high-latitude summertime mesopause. From an examination of the historical record of noctilucent cloud occurrence, it is found that such clouds are absent from the record before 1885, a finding which is consistent with the hypothesis proposed in this paper.

Thomas, Gary E.↗
NASA NTRS1989

Ozone minimum occurs in Antarctica in the springtime

Observations on the formation of the Antarctic ozone hole in the upper atmosphere are summarized, and the mechanism responsible for the ozone depletion in the spring is examined. It is shown that the sequence of events begins with the absorption of H2O, N2O5, HCl, and ClONO2 on the cloud ice particles in the winter and chemical reactions among absorbed chemicals which release (HNO3)s, Cl2, HOCl, and ClNO2. With the return of sunlight in the spring, the clouds evaporate, and the Cl2, HOCl, and ClONO2 molecules are destroyed by sunlight to form Cl atoms. These attack ozone, producing a reduction of ozone that accounts for the bulk of the ozone decrease observed by the ground-based ozone monitors. Data on the ozone concentration for the period between 1957 through 1987 indicate that the southern ozone hole has been intensifying since 1975 as the amount of man-made chlorine increases.

Aikin, Arthur C.↗
NASA NTRS1987

Development flight tests of JetStar LFC leading-edge flight test experiment

The overall objective of the flight tests on the JetStar aircraft was to demonstrate the effectiveness and reliability of laminar flow control under representative flight conditions. One specific objective was to obtain laminar flow on the JetStar leading-edge test articles for the design and off-design conditions. Another specific objective was to obtain operational experience on a Laminar Flow Control (LFC) leading-edge system in a simulated airline service. This included operational experience with cleaning requirements, the effect of clogging, possible foreign object damage, erosion, and the effects of ice particle and cloud encounters. Results are summarized.

Fisher, David F.↗
NASA NTRS1990

Aircraft microwave observations and simulations of deep convection from 18 to 183 GHz. I - Observations

Aircraft passive microwave observations of deep atmospheric convection at frequencies between 18 and 183 GHz are presented in conjunction with visible and infrared satellite and aircraft observations and ground-based radar observations. Deep convective cores are indicated in the microwave data by negative brightness temperature, T/(B) deviations from the land background (270 K) to extreme T(B) values below 100 K at 37, 92, and 183 GHz and below 200 K at 18 GHz. These T(B) minima, due to scattering by ice held aloft by the intense updrafts, are well correlated with areas of high radar reflectivity. For this land background case, T(B) is inversely correlated with rain rate at all frequencies due to T(B)-ice-rain correlations. Mean Delta-T between vertically polarized and horizontally polarized radiance in precipitation areas is approximately 6 K at both 18 GHz and 37 GHz, indicating nonspherical precipitation-size ice particles with a preferred horizontal orientation. Convective cores not observed in the visible and infrared data are clearly defined in the microwave observations, and borders of convective rain areas are well defined using the high-frequency (90 GHz and greater) microwave observations.

Adler, Robert F.↗
NASA NTRS1990

Lightning/rainfall relationships during COHMEX

Initial results of relationships between cloud-to-ground lightning and radar-derived precipitation measurements in air mass thunderstorms (multi- and single cell) occurring over the Southeastern United States are presented. Buoyancy values computed from soundings are used to estimate wind shear, the energy available to storms, and the ability of the environment to support strong updrafts. Precipitation measurements are utilized for sampling the rainfall history of entire storm life cycles. It is shown that the average rain volume per ground discharge decreases as the buoyancy increases; this is attributed to stronger updrafts elevating mass to higher levels in the storm where more frequent ice particle interactions may play a major role in separating charge leading to enhanced lightning activity. Thus, total lightning rates are expected to correlate better with rainfall production.

Goodman, S. J.↗
NASA NTRS1991

Advanced ice protection systems test in the NASA Lewis icing research tunnel

Tests of eight different deicing systems based on variations of three different technologies were conducted in the NASA Lewis Research Center Icing Research Tunnel (IRT) in June and July 1990. The systems used pneumatic, eddy current repulsive, and electro-expulsive means to shed ice. The tests were conducted on a 1.83 m span, 0.53 m chord NACA 0012 airfoil operated at a 4 degree angle of attack. The models were tested at two temperatures: a glaze condition at minus 3.9 C and a rime condition at minus 17.2 C. The systems were tested through a range of icing spray times and cycling rates. Characterization of the deicers was accomplished by monitoring power consumption, ice shed particle size, and residual ice. High speed video motion analysis was performed to quantify ice particle size.

Bond, Thomas H.↗
NASA NTRS1991

Microphysical and radiative characteristics of convective clouds during COHMEX

This paper has two purposes: first, to document the structure and evolution of two strong thunderstorms in Alabama using radar multiparameter data; and second, to relate the inferred microphysics to the resulting upwelling microwave radiance observed concurrently by high altitude aircraft. These measurements were collected during the COHMEX field program in the summer of 1986. The radar analysis includes a description of the parameters reflectivity Z, differential reflectivity Z(DR), linear depolarization ratio LDR, and hail signal HS for two thunderstorm cases on July 11, 1986. The simultaneous aircraft data include passive microwave brightness temperature, T(B), measurements at four frequencies ranging from 18 to 183 GHz, as well as visible and infrared data. The remote radar observations reveal the existence of large ice particles within the storms, which is likely to have caused the observed low microwave brightness temperatures. By relating the evolution of the radar measureables to the microwave T(B)s it has been found that knowledge of the storm microphysics and its evolution is important to adequately understand the microwave T(B)s.

Fulton, Richard↗
NASA NTRS1991

Retrieval of atmospheric water vapor profiles using radiometric measurements at 183 and 90 GHz

The algorithm developed by Wilheim (1990) dealt with the retrieval of water-vapor profiles from microwave radiometric measurements, even in the presence of clouds. This algorithm was tested using radiometric measurements at frequencies near 90 and 183 GHz; the results show that the retrieved water-vapor profiles were in general agreement with those derived from radiosonde data. In particular, retrieval over both land and ocean surfaces generated clouds at locations that could be verified from satellite photographs. The algorithm did not perform well where there were surface fronts. These clouds possibly contained ice particles as well as precipitating snow, which the algorithm was not expected to handle.

Lutz, Robert↗
NASA NTRS1991

Plume and wake dynamics, mixing, and chemistry behind an HSCT aircraft

The chemical evolution and mixing and vortical motion of a High Speed Civil Transport's engine exhausts must be analyzed in order to track the gas and its speciation as emissions are mixed to atmospheric scales. Attention is presently given to an analytic model of the wake dynamical processes which accounts for the roll-up of the trailing vorticity, its breakup due to the Crow instability, and the subsequent evolution and motion of the reconnected vorticity. The concentrated vorticity is noted to wrap up the buoyant exhaust and suppress its continued mixing and dilution. The species tracked encompass those which could be heterogeneously reactive on the surfaces of the condensed ice particles, and those capable of reacting with exhaust soot particle surfaces to form active contrail and/or cloud condensation nuclei.

Miake-Lye, R. C.↗
NASA NTRS1990

Analysis of troposphere-stratosphere exchange

The overall goal is to improve our understanding of stratosphere-troposphere exchange processes in the tropics and midlatitudes. Specifically, modeling and analysis are performed using aircraft, radiosonde, and satellite data from the 1980 and 1987 NASA tropical field experiments in Panama and Australia, respectively, and the 1986 NASA jet stream field experiment in California. The objectives are to: (1) examine the structure of ozone, temperature, horizontal winds, tropospheric tracers, water and ice particles, and water vapor within, around, and above cumulus anvils in the tropics and jet streams in midlatitudes; (2) establish the presence, during each of the experimental periods, of various potential mechanisms of exchange, such as direct injection by cumulus, gravity wave fluxes, turbulent fluxes, and radiative heating; and (3) evaluate quantitatively, if possible, the mass of air transferred by these mechanisms during specific transport events.

Pfister, Leonhard↗
NASA NTRS1991

Advanced ice protection systems test in the NASA Lewis Icing Research Tunnel

Tests of eight different deicing systems based on variations of three different technologies were conducted in the NASA Lewis Research Center Icing Research Tunnel (IRT) in June and July 1990. The systems used pneumatic, eddy current repulsive, and electroexpulsive means to shed ice. The tests were conducted on a 1.83 m span, 0.53 m chord NACA 0012 airfoil operated at a 4 degree angle of attack. The models were tested at two temperatures: a glaze condition at minus 3.9 C and a rime condition at minus 17.2 C. The systems were tested through a range of icing spray times and cycling rates. Characterization of the deicers was accomplished by monitoring power consumption, ice shed particle size, and residual ice. High speed video motion analysis was performed to quantify ice particle size.

Bond, Thomas H.↗
NASA NTRS1991

Multifrequency radio observations of Saturn at ring inclination angles between 5 and 26 degrees

In order to investigate hypothesized latitudinal variations in the thermal emission from Saturn, the planet has been imaged at different wavelengths by the VLA and BIMA arrays. A bright band is found at 6 and 20 cm at midnorthern latitudes. The latitudinal brightness variation is suggested to be due to variations in the location of the NH4SH cloud. The extant data base on ring brightness temperatures and optical depths has been expanded by the present efforts. The data obtained are congruent with ice particles of the order of millimeters-meters in size; the number of particles has a power-law distribution that is proportionate to the radius cubed.

De Pater, Imke↗
NASA NTRS1990

Stratospheric ice crystals

In situ sampling of the crystals is described with a NASA high-altitude aircraft to characterize the presence of ice particles and their role in Antarctic ozone chemistry. A NASA wire impactor was employed to collect the crystals, and the device was modified to permit Formvar crystal replication. The size distributions of the columnar crystals show that at the highest altitude the the smallest crystals are collected. The crystals provide surface area for heterogeneous chemical reactions as well as the removal of moisture and particles from the stratosphere and its ozone-related components.

Goodman, Jindra↗