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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 469 records · Page 26

Comparison of radiated noise from shrouded and unshrouded propellers

The ducted propeller in a free field is modeled using the finite element method. The generation, propagation, and radiation of sound from a ducted fan is described by the convened wave equation with volumetric body forces. Body forces are used to introduce the blade loading for rotating blades and stationary exit guide vanes. For an axisymmetric nacelle or shroud, the problem is formulated in cylindrical coordinates. For a specified angular harmonic, the angular coordinate is eliminated, resulting in a two-dimensional representation. A finite element discretization based on nine-node quadratic isoparametric elements is used.

Eversman, Walter↗

System Design of Dynamic Wireless Power Transfer for Automated Highways

Dynamic wireless power transfer (DWPT) has been proposed as a solution to power electric vehicles (EVs)on future electrified highways. However, there has been little consideration of how the coordination of electric connected and automated vehicles (CAVs) could impact DWPT system designs in future scenarios. In this paper, a DWPT system design is optimized for a future highway where CAVs travel in coordinated groups, with each CAV in the group powered by the same DWPT section. As the distribution of smaller light-duty vehicles (LDVs) and larger heavy-duty vehicles (HDVs) in each group is varied, the DWPT system power level, transmitter length, and the equivalent receiver loads are adjusted to minimize the infrastructure requirements and energy losses of the DWPT system. The outputs from this analysis are used to determine the optimal groupings of vehicles for a given DWPT system. The analysis suggests that CAV coordination could aid the deployment of DWPT systems and reduce the overall infrastructure and energy losses of DWPT systems.

Foote, Andrew↗

Reinforcement Learning to Enhance Optimal Operation of Resilient Community Energy Systems

This paper presents a novel model-free multi-agent Reinforcement Learning (RL) control method to enhance the resilience of community energy systems in island mode, which coordinates multiple objectives without the necessity of identifying system models that require expert knowledge. Specifically, a community-level coordinator agent is designed to allocate renewable energy resources among different buildings, and multiple building-level agents are developed to optimize load schedules based on limited energy resources and requirements of building loads and occupants’ comfort. In a two-day evaluation, our RL approach demonstrated a similar performance against MPC without requiring system models and formulation of optimization problems as required in MPC.

ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATION↗

Flexible Grid Interconnections

Key Considerations: - Long-term coordination and collaboration with utilities and ISOs may provide mutual benefits and support flexible interconnectivity. - Onsite storage and energy production can reduce load fluctuations and support grid resilience in the future. - Geography and resource availability can impact energy demand and grid flexibility.

29 - ENERGY PLANNING, POLICY AND ECONOMY↗

A Coordinated-Anion-Enriched Electrolyte for Lean-Electrolyte Li–S Batteries

The solid electrolyte interphase (SEI) on Li and cathode electrolyte interphase (CEI) at sulfurized polyacrylonitrile (SPAN) formed in the commonly used liquid electrolytes cannot accommodate the large volume change of both Li anode and SPAN cathode, resulting in severe electrolyte and Li consumption and fast capacity decay under high mass loading and lean electrolyte condition. Herein, a LiF-rich SEI and a LiF-Li x N y O z co-enriched CEI are simultaneously formed by adding ionic liquid (Py 13 TFSI) in the localized high-concentration electrolyte (LHCE), which forms a coordinated-anion-enriched solvation structure. In this study, the LiF-rich interphase results in less stress/strain during large volume changes of Li and SPAN and therefore achieving obviously improved stability even at a high areal capacity. Consequently, Li (50 μm)||SPAN (6 mg cm -2 ) pouch cells under the lean electrolyte condition (E/S ratio of 5 mL g SPAN -1 ) delivers a stable cycle life of 120 cycles with 79.2% capacity retention, demonstrating great promise for high-energy-density lithium-sulfur batteries.

25 ENERGY STORAGE↗

DSO+T: Expanded Study Results DSO+T Study: Volume 5

The Distribution System Operator with Transactive (DSO+T) study investigates the engineering and economic performance of a transactive energy retail market coordinating a high penetration of customer-side flexible energy assets. The study seeks to answer whether such an implementation is cost effective for customers, recovers sufficient revenue for DSOs, and is equally applicable and beneficial to a range of flexible asset types, renewable generation scenarios, and market assumptions. This report volume provides a detailed set of results for the DSO+T study extending results presented in Volumes 1, 2, and 4. The engineering and economic performance of the transactive energy scheme is presented for two separate flexible asset deployments: flexible loads (HVAC units and residential water heaters) and behind-the-meter batteries. The results of each transactive case are compared to a business-as-usual case. These cases are subject to two different renewable generation scenarios, a moderate renewable generation scenario, representative of current levels of renewable generation deployment, and a future high renewables scenario, including the increased deployment of rooftop solar photovoltaic and electric vehicles. The transactive coordination scheme is shown to produce effective and stable control and decrease peak loads 9–15%. The resulting annual demand flexibility provides net economic savings of $3.3–5.0B per year for a region the size of Texas. Detailed analysis shows that net benefits were seen for a range of distribution system operator, customer, and flexible asset types. Both participating customer (with transactive flexible assets) and nonparticipating customers (with nonflexible assets) see reductions in annual utility bills and net annual energy expenses in the range of 10–16%.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Understanding the Origin of Negative Temperature Dependence and Activity of N-Coordinated Cobalt Sites During Ethylene Dimerization

The on-demand production of short-chain linear alpha olefins (LAOs; C4-C8) via C2H4 dimerization and oligomerization is industrially attractive, prompting extensive research on designing active, selective, and stable catalysts for industrial use. Cobalt supported on ammoniated carbon (Co(NH3)x/C) catalysts have shown remarkable activity and selectivity in this process. However, critical aspects such as the active phase, active site structure, the role of the catalyst support, cobalt loading effects, and the inverse correlation of the reaction rate with temperature remain inadequately understood. This study systematically explores these factors using a combination of steady-state differential catalytic tests, in situ molecular characterization including diffuse reflectance UV-Vis (DR-UV-Vis), Infrared, and Raman spectroscopies, and ex situ X-ray diffraction (XRD) and high annular aberration-corrected dark field transmission electron microscopy (HAADF-STEM). Various supports (SiO2, Al2O3, NH4-ZSM-5, g-C3N4, and C) and cobalt loadings (1.0-3.0 Co nm-2) were studied to determine the optimal catalyst composition and identify the active phase and sites. Carbon-supported catalysts uniquely produce C4-8 LAOs during C2H4 dimerization, with site-time-yield remaining constant (~10-3 s-1) for 1.0-4.0 Co nm-2 at prolonged reaction times (24-48?h time-on-stream). At higher loadings of 6.0 Co nm-2, the formation of crystalline CoO and Co3O4 phases reduces catalytic activity and LAO selectivity. Our findings show that active catalysts lack crystalline cobalt oxides and instead feature dispersed Co2+ sites, tetra-coordinated to a mix of N/NH3 and O/H2O ligands, which catalyze C2H4 dimerization via the Cossee-Arlman mechanism, exhibiting 1st order dependence on C2H4 concentration. The observed inverse rate-temperature correlation is attributed to compensation effects (i.e., presence of Cremer-Constable relationship) linked to changes in adsorption enthalpic and entropic factors.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Intermediate temperature fuel cells via an ion-pair coordinated polymer electrolyte

Fuel cells are attractive devices that convert chemical energy into electricity through the direct electrochemical reaction of hydrogen and oxygen. Intermediate temperature fuel cells operated at 200–300°C can simplify water and thermal managements, enable the use of non-precious or low-loading precious metal catalysts and provide insensitivity toward fuel and air impurities such as carbon monoxide. However, the performance of current intermediate temperature fuel cells is poor due to a lack of highly-conductive membrane electrolytes and optimal electrodes designed for these fuel cells. We demonstrate high-performing intermediate temperature fuel cells that use SnP 2 O 7 –polymer composite membranes and a quaternary ammonium-biphosphate ion-pair coordinated polymer electrolyte in the electrodes. The peak power density of the fuel cell under H 2 and O 2 reached 870 mW cm -2 at 240°C with minimal performance loss under exposure to 25% carbon monoxide.

30 DIRECT ENERGY CONVERSION↗

High-Platinum-Content Catalysts on Atomically Dispersed and Nitrogen Coordinated Single Manganese Site Carbons for Heavy-Duty Fuel Cells

Fuel cells for heavy-duty vehicles (HDVs) have attracted considerable attention because of their unique scalability, better fuel economy, the less demand for hydrogen refilling infrastructure. However, the potential application requires more stringent fuel cell durability up to 25,000 h. Membrane electrode assemblies (MEAs) made from platinum group metal (PGM) catalyst with relatively high loading 0.3 mgPt cm –2 play a crucial role in ensuring high-power and long-term durability. Integrating fine PGM nanoparticles and robust carbon support with strengthened interactions is critical for improving MEA performance and durability. Herein, a unique atomically dispersed and nitrogen coordinated single Mn site-rich carbon (M–N–C) support was developed for high content (40 wt%) platinum catalysts for the oxygen reduction reaction (ORR) cathode with reduced thickness. Compared with two controls studied in this work (e.g., a porous graphitic carbon-supported Pt and a commercial TKK Pt/C catalysts), the Pt (40 wt%)/Mn–N–C catalyst exhibited much enhanced catalytic activity and stability for the ORR in both aqueous acidic electrolyte and polymer electrolyte-based MEA. Here, we carefully elucidated the—role of the Mn–N–C support in promoting Pt catalyst concerning its high surface area, partially graphitic structure, and nitrogen dopants, providing better Pt nanoparticle dispersion, and strengthened interactions between Pt and carbon. Consequently, the MEA from the Pt (40 wt%)/Mn–N–C catalyst generated a 1.61 A cm –2 at 0.7 V based on HDV conditions (0.2 mgPt cm –2 and 250 kPa air). More importantly, the MEA is highly durable and can retain 1.31 A cm –2 at 0.7 V after 30,000 voltage cycles (~19% loss), surpassing the commercial Pt/C catalyst (loss of ~56%). Therefore, the Mn–N–C carbon-supported Pt catalyst holds a great promise to meet the challenging DOE target (1.07 A cm –2 at 0.7 V after 150,000 cycles) for HDVs.

25 ENERGY STORAGE↗

Effects of penta‐coordinated Al 3+ sites and Ni defective sites on Ni/ Al 2 O 3 for CO methanation

Abstract Engineering sophisticated structure of Al 2 O 3 and controlling the structure of counterpart metal active sites remain challenges to achieve a high catalytic‐performance in heterogeneous catalysis. Herein, we present a confinement strategy to stabilize homogeneous Ni by penta‐coordinated Al 3+ anchoring sites in Al 2 O 3 . This approach is involved in using a metal–organic framework as host to load Ni 2+ ions, by the aim of producing a confined Ni/Al 2 O 3 catalyst after a standard calcination. Metal–support interaction between Ni and Al 2 O 3 was tailored to be medium to avoid the formation of inactive NiAl 2 O 4 , which favors the generation of more available Ni active sites accessible to the reactants. The resultant Ni/Al 2 O 3 exhibited superior catalytic performance in comparison with the control Ni/Al 2 O 3 in CO methanation owing to the presence of defective sites on sufficient Ni 0 surface. Furthermore, the presence of oxygen vacancies on Al 2 O 3 and hydrogen spillover contributed toward excellent coke resistance properties in the reaction.

Engineering↗

Model-Free Control of Grid-Interactive Efficient Buildings Under Communication Time Delays

Grid-interactive efficient buildings (GEBs) have recently been used to enhance the reliability and stability of the electric grid through demand response (DR) programs. However, most existing DR control strategies require accurate modeling of the various building thermostatically controlled loads (TCLs) and are computationally expensive. To address these challenges, a model-free control (MFC)-based strategy has recently been introduced for coordinating and controlling GEBs. MFC is a data-enabled control strategy that is computationally efficient and does not require the analytical models of the various building equipment. In this paper, we numerically investigate the impact of communication time delays on the performance of MFC in maintaining the TCLs' temperatures within the desired comfort levels while meeting the assigned power allocation constraint.

Telsang, Bhagyashri [University of Tennessee, Knox↗

Opportunities for Simultaneous Efficiency Improvement and Refrigerant Transition in Air Conditioning

In October of 2016, nearly 200 Parties agreed to amend the Montreal Protocol in Kigali, Rwanda, to phase-down consumption and production of hydrofluorocarbons (HFCs) by 2050. Growth in the use of HFCs, including those currently used as refrigerants in air-conditioning systems, is being driven by demand from emerging economies, hot climates, and rising incomes that are also undergoing rapid urbanization and electrification. Air conditioners (ACs), as an energy-intensive end-use technology, are also covered by a growing number of energy efficiency standards, labeling, procurement, incentive, and other supporting efficiency programs. Therefore, improving room AC energy efficiency and transitioning to low-global warming potential (GWP) refrigerants simultaneously presents significant opportunities to deploy energy efficient technology and reduce the energy and emissions impacts of room ACs, while keeping costs low for consumers. This report aims to provide an initial sense of the opportunities to improve efficiency and transition to low-GWP refrigerants by reviewing the HCFC and HFC regulatory framework and energy efficiency standards and labeling programs in 19 economies that account for roughly 65 percent of global room AC demand. Based on this analysis, we identified key opportunities for coordinated action on efficiency improvement and refrigerant transition for the domestic room AC sector (i.e., ductless mini-split ACs), such as: - implementing or revising standards and labeling programs to improve efficiency levels with the possibility of adding a low-GWP criterion. - combining fixed speed and inverter AC product categories to account for seasonal variations in climate and part-load operating conditions, and using seasonal energy efficiency ratio (SEER) instead of energy efficiency ratio (EER) to better reflect performance of inverter ACs. - implementing market transformation programs, such as bulk procurement programs, to drive down the costs of efficient technology through economies of scale. - aligning timelines for implementing efficiency standards with timelines for refrigerant management plans to coordinate policy actions. - maximizing the energy efficiency improvements of Montreal Protocol investments by coordinating efforts to help keep costs low for consumers and manufacturers during equipment redesign and manufacturing line retooling for refrigerant transition. In order to realize the significant peak load, energy saving and climate benefits of these opportunities associated with improving energy efficiency in tandem with the refrigerant transition, some risks may need to be mitigated, principally safety concerns over risks of accidental ignition with refrigerants rated flammable. This can be mitigated by continuing and accelerating the development of safety standards currently being updated, for example, by the International Electrotechnical Commission (IEC) and improving training for production, installation and maintenance during the use of flammable refrigerants. While some low-GWP refrigerants may cost more than the current baseline refrigerants, the cost of refrigerants is only ~1% of lifecycle costs for an AC. Costs can also be reduced through manufacturing advances and efficiency improvements, particularly if they are supported by policies that encourage technological development through deployment of superefficient ACs at scale. Finally, during the transition, there is a risk of obsolete technology being deployed in markets that either have not updated their standards or have later compliance dates. This risk can be mitigated by updating standards and reviewing them periodically to ensure their effectiveness.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Communication-Constrained Robust Control and Learning of Grid-Connected

The electric grid of things (EGoT) promises great potential for innovative grid services by tapping into vast load flexibility. However, the unique characteristics of EGoT, being a part of the cyber-physical electric power system, present both opportunities and challenges, especially concerning supply-demand balancing, stability, and communication constraints. Traditionally, centralized control was employed to ensure balance and stability in power systems. However, with the massive influx of EGoT devices, new strategies are needed to efficiently coordinate and control these distributed devices for optimal grid operations. While some studies have explored efficiency and economic models, there remains a gap in ensuring reliability under everyday operations and resilience during extreme conditions. Addressing this gap, this project develops the technology for an Energy Service Interface (ESI) that includes novel pricing, control, learning, and distributed optimization algorithms, which will enable utilities to recruit EGoT assets for crucial grid services such as load flexibility, voltage regulation, and situation-awareness. The key novelty of the proposed technology is the careful distribution of learning and control functions across utility and EGoT asset owners such that provably efficient and resilient grid operations are attained while respecting communication and information-exchange constraints. Specifically, the project team develops machine-learning enhanced load modeling methods to allow EGoT asset owners to learn their load capability and flexibility, and develops pricing-based and decentralized learning-based control so that asset owners can coordinate to meet system-wide demand-supply balance and reliability goals. For extreme situations involving high-impact, low-probability catastrophic events (termed the “black-sky” events), the team also develops (1) a “Feeder-Operating Center-on-a-Laptop” (FOCAL) software that can assist utility personnel in leveraging EGoT assets to accelerate the service recovery of damaged feeders, and (2) distributed optimization algorithms that can coordinate the operation points of EGoT devices under severe communication constraints. The proposed technology has been extensively tested and evaluated through simulations and on a testbed. In summary, as we transition into a more interconnected and digital power grid era, our project’s findings and developments offer a pivotal step toward guaranteeing both efficiency and resilience in the face of both everyday operations and rare “black-sky” events.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Architecture of a Residential Solid State Power Substation (SSPS) Node

High integration rates of new loads and distributed generation at the edge of the grid are posing new challenges. However, existing smart power electronic systems are not designed to coordinate and maximize grid support or provide multiple grid services simultaneously. This work presents the application of a solid-state power substation (SSPS) to residential systems to increase this coordination and reduce future challenges. The proposed residential SSPS is validated in simulation including power electronic converter models, feeder models, and optimization.

Krishna Moorthy, Radha↗

FLYING SERVING: On-the-Fly Parallelism Switching for Large Language Model Serving

Production LLM serving must simultaneously deliver high throughput, low latency, and sufficient context capacity under non-stationary traffic and mixed request requirements. Data parallelism (DP) maximizes throughput by running independent replicas, while tensor parallelism (TP) reduces per-request latency and pools memory for long-context inference. However, existing serving stacks typically commit to a static parallelism configuration at deployment; adapting to bursts, priorities, or long-context requests is often disruptive and slow. We present Flying Serving, a vLLM-based system that enables online DP-TP switching without restarting engine workers. Flying Serving makes reconfiguration practical by virtualizing the state that would otherwise force data movement: (i) a zero-copy Model Weights Manager that exposes TP shard views on demand, (ii) a KV Cache Adaptor that preserves request KV state across DP/TP layouts, (iii) an eagerly initialized Communicator Pool to amortize collective setup, and (iv) a deadlock-free scheduler that coordinates safe transitions under execution skew. Across three popular LLMs and realistic serving scenarios, Flying Serving improves performance by up to 4.79 × under high load and 3.47 × under low load while supporting latency- and memory-driven requests.

Gao, Shouwei [ORNL]↗

Transactive System: Part I: Theoretical Underpinnings of Payoff Functions, Control Decisions, Information Privacy, and Solution Concepts

The increased penetration of renewable energy has significantly changed the conditions and the operational timing of the electricity grid. More flexible, faster ramping resources are needed to compensate for the uncertainty and variability introduced by renewable energy. Distributed energy resources (DERs) such as distributed generators, energy storage, and controllable loads could help manage the power grid in terms of both economic efficiency and operational reliability. In order to realize the benefits of DERs, coordination and control approaches must be designed to enable seamless integration of DERs into the power grid. Transactive coordination and control is a new approach for DER integration, where individual resources are automated and engaged through market interaction. Transactive approaches use economic signals—prices or incentives—to engage DERs. These economic signals must reflect the true value of the DER contributions, so that they seamlessly and equitably compete for the opportunities that today are only available to grid-owned assets. Value signals must be communicated to the DERs in near-real time, the assets must be imbued with new forms of distributed intelligence and control to take advantage of the opportunities presented by these signals, and they must be capable of negotiating and transacting a range of market-driven energy services. The concepts of transactive energy systems are not new, but build upon evolutionary economic changes in financial and electric power markets. These concepts also recognize the different regional structures of wholesale power markets, electricity delivery markets, retail markets, and vertically integrated service provider markets. Although transactive energy systems are not revolutionary, they will be transformational in their ability to provide flexibility and operational efficiency. A main goal of this research is to establish useful foundation for analysis of transactive energy systems and to facilitate new transactive energy system design with demonstrable guarantees on stability and performance. Specifically, the goals are to (1) establish a theoretical basis for evaluating the performance of different transactive systems, (2) devise tools to address canonical problems that exemplify challenges and scenarios of transactive systems, and (3) provide guidelines for design of future transactive systems. This report, Part 1 of a two part series, advances the above-listed research objectives by reviewing existing transactive systems and identifying a theoretical foundation that integrates payoff functions, control decisions, information privacy, and mathematical solution concepts.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Transactive System: Part I: Theoretical Underpinnings of Payoff Functions, Control Decisions, Information Privacy, and Solution Concepts

The increased penetration of renewable energy has significantly changed the conditions and the operational timing of the electricity grid. More flexible, faster ramping resources are needed to compensate for the uncertainty and variability introduced by renewable energy. Distributed energy resources (DERs) such as distributed generators, energy storage, and controllable loads could help manage the power grid in terms of both economic efficiency and operational reliability. In order to realize the benefits of DERs, coordination and control approaches must be designed to enable seamless integration of DERs into the power grid. Transactive coordination and control is a new approach for DER integration, where individual resources are automated and engaged through market interaction. Transactive approaches use economic signals—prices or incentives—to engage DERs. These economic signals must reflect the true value of the DER contributions, so that they seamlessly and equitably compete for the opportunities that today are only available to grid-owned assets. Value signals must be communicated to the DERs in near-real time, the assets must be imbued with new forms of distributed intelligence and control to take advantage of the opportunities presented by these signals, and they must be capable of negotiating and transacting a range of market-driven energy services. The concepts of transactive energy systems are not new, but build upon evolutionary economic changes in financial and electric power markets. These concepts also recognize the different regional structures of wholesale power markets, electricity delivery markets, retail markets, and vertically integrated service provider markets. Although transactive energy systems are not revolutionary, they will be transformational in their ability to provide flexibility and operational efficiency. A main goal of this research is to establish useful foundation for analysis of transactive energy systems and to facilitate new transactive energy system design with demonstrable guarantees on stability and performance. Specifically, the goals are to (1) establish a theoretical basis for evaluating the performance of different transactive systems, (2) devise tools to address canonical problems that exemplify challenges and scenarios of transactive systems, and (3) provide guidelines for design of future transactive systems. This report, Part 1 of a two part series, advances the above-listed research objectives by reviewing existing transactive systems and identifying a theoretical foundation that integrates payoff functions, control decisions, information privacy, and mathematical solution concepts.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Nonlinear analysis of rotor-bearing systems using component mode synthesis

The method of component mode synthesis is developed to determine the forced response of nonlinear, multishaft, rotor-bearing systems. The formulation allows for simulation of system response due to blade loss, distributed unbalance, base shock, maneuver loads, and specified fixed frame forces. The motion of each rotating component of the system is described by superposing constraint modes associated with boundary coordinates and constrained precessional modes associated with internal coordinates. The precessional modes are truncated for each component and the reduced component equations are assembled with the nonlinear supports and interconnections to form a set of nonlinear system equations of reduced order. These equations are then numerically integrated to obtain the system response. A computer program, which is presently restricted to single shaft systems, has been written and results are presented for transient system response associated with blade loss dynamics with squeeze film dampers, and with interference rubs.

Nelson, H. D.↗