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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 469 records · Page 26
All sourcesNASA NTRSDOE OSTI
DOE OSTI2017

An Advanced TALSPEAK Concept for Separating Minor Actinides. Part 2. Flowsheet Test with Actinide-spiked Simulant

A solvent extraction system has been developed for separating trivalent actinides from lanthanides. This “Advanced TALSPEAK” system uses 2-ethylhexylphosphonic acid mono-2-ethylhexyl ester to extract the lanthanides into a n-dodecane-based solvent phase, while the actinides are retained in a citrate-buffered aqueous phase by complexation to N-(2-hydroxyethyl)ethylenediamine-N,N',N'-triacetic acid. Batch distribution measurements indicate that the separation of americium from the light lanthanides decreases as the pH decreases. For example, the separation factor between La and Am increases from 2.5 at pH 2.0 to 19.3 at pH 3.0. However, previous investigations indicated that the extraction rates for the heavier lanthanides decrease with increasing pH. So, a balance between these two competing effects is required. An aqueous phase in which the pH was set at 2.6 was chosen for further process development because this offered optimal separation, with a minimum separation factor of ~8.4, based on the separation between La and Am. Centrifugal contactor single-stage efficiencies were measured to characterize the performance of the system under flow conditions.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2011

ACCRETION OF A TERRESTRIAL-LIKE MINOR PLANET BY A WHITE DWARF

We present optical and infrared characterization of the polluted DAZ white dwarf GALEX J193156.8+011745. Imaging and spectroscopy from the ultraviolet to the thermal infrared indicate that this white dwarf hosts excess infrared emission consistent with the presence of an orbiting dusty debris disk. In addition to the five elements previously identified, our optical echelle spectroscopy reveals chromium and manganese and enables restrictive upper limits on several other elements. Synthesis of all detections and upper limits suggests that GALEX J193156.8+011745 has accreted a differentiated parent body. We compare the inferred bulk elemental composition of the accreted parent body to expectations for the bulk composition of an Earth-like planet stripped of its crust and mantle and find relatively good agreement. At least two processes could be important in shaping the final bulk elemental composition of rocky bodies during the late phases of stellar evolution: irradiation and interaction with the dense stellar wind.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2012

ABELL 1201: A MINOR MERGER AT SECOND CORE PASSAGE

We present an analysis of the structures and dynamics of the merging cluster Abell 1201, which has two sloshing cold fronts around a cooling core, and an offset gas core approximately 500 kpc northwest of the center. New Chandra and XMM-Newton data reveal a region of enhanced brightness east of the offset core, with breaks in surface brightness along its boundary to the north and east. This is interpreted as a tail of gas stripped from the offset core. Gas in the offset core and the tail is distinguished from other gas at the same distance from the cluster center chiefly by having higher density, hence lower entropy. In addition, the offset core shows marginally lower temperature and metallicity than the surrounding area. The metallicity in the cool core is high and there is an abrupt drop in metallicity across the southern cold front. We interpret the observed properties of the system, including the placement of the cold fronts, the offset core, and its tail in terms of a simple merger scenario. The offset core is the remnant of a merging subcluster, which first passed pericenter southeast of the center of the primary cluster and is now close to its second pericenter passage, moving at {approx_equal} 1000 km s{sup -1}. Sloshing excited by the merger gave rise to the two cold fronts and the disposition of the cold fronts reveals that we view the merger from close to the plane of the orbit of the offset core.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2011

MINOR ACTINIDE SEPARATIONS USING ION EXCHANGERS OR IONIC LIQUIDS

This project seeks to determine if (1) inorganic-based ion exchange materials or (2) electrochemical methods in ionic liquids can be exploited to provide effective Am and Cm separations. Specifically, we seek to understand the fundamental structural and chemical factors responsible for the selectivity of inorganic-based ion-exchange materials for actinide and lanthanide ions. Furthermore, we seek to determine whether ionic liquids can serve as the electrolyte that would enable formation of higher oxidation states of Am and other actinides. Experiments indicated that pH, presence of complexants and Am oxidation state exhibit significant influence on the uptake of actinides and lanthanides by layered sodium titanate and hybrid zirconium and tin phosphonate ion exchangers. The affinity of the ion exchangers increased with increasing pH. Greater selectivity among Ln(III) ions with sodium titanate materials occurs at a pH close to the isoelectric potential of the ion exchanger. The addition of DTPA decreased uptake of Am and Ln, whereas the addition of TPEN generally increases uptake of Am and Ln ions by sodium titanate. Testing confirmed two different methods for producing Am(IV) by oxidation of Am(III) in ionic liquids (ILs). Experimental results suggest that the unique coordination environment of ionic liquids inhibits the direct electrochemical oxidation of Am(III). The non-coordinating environment increases the oxidation potential to a higher value, while making it difficult to remove the inner coordination of water. Both confirmed cases of Am(IV) were from the in-situ formation of strong chemical oxidizers.

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗
DOE OSTI2012

Fabrication and Pre-irradiation Characterization of a Minor Actinide and Rare Earth Containing Fast Reactor Fuel Experiment for Irradiation in the Advanced Test Reactor

The United States Department of Energy, seeks to develop and demonstrate the technologies needed to transmute the long-lived transuranic actinide isotopes contained in spent nuclear fuel into shorter lived fission products, thereby decreasing the volume of material requiring disposal and reducing the long-term radiotoxicity and heat load of high-level waste sent to a geologic repository. This transmutation of the long lived actinides plutonium, neptunium, americium and curium can be accomplished by first separating them from spent Light Water Reactor fuel using a pyro-metalurgical process, then reprocessing them into new fuel with fresh uranium additions, and then transmuted to short lived nuclides in a liquid metal cooled fast reactor. An important component of the technology is developing actinide-bearing fuel forms containing plutonium, neptunium, americium and curium isotopes that meet the stringent requirements of reactor fuels and materials.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
DOE OSTI2012

Atomistic Calculations of the Effect of Minor Actinides on Thermodynamic and Kinetic Properties of UO 2±x

The team will examine how the incorporation of actinide species important for mixed oxide (MOX) and other advanced fuel designs impacts thermodynamic quantities of the host UO 2 nuclear fuel and how Pu, Np, Cm and Am influence oxygen mobility. In many cases, the experimental data is either insufficient or missing. For example, in the case of pure NpO 2 , there is essentially no experimental data on the hyperstoichiometric form it is not even known if hyperstoichiometry NpO 2 ±x is stable. The team will employ atomistic modeling tools to calculate these quantities

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
DOE OSTI2013

Experimental Findings On Minor Actinide And Lanthanide Separations Using Ion Exchange

This project seeks to determine if inorganic or hybrid inorganic ion-exchange materials can be exploited to provide effective americium and curium separations. Specifically, we seek to understand the fundamental structural and chemical factors responsible for the selectivity of the tested ion-exchange materials for actinide and lanthanide ions. During FY13, experimental work focused in the following areas: (1) investigating methods to oxidize americium in dilute nitric acid with subsequent ion-exchange performance measurements of ion exchangers with the oxidized americium and (2) synthesis, characterization and testing of ion-exchange materials. Ion-exchange materials tested included alkali titanates, alkali titanosilicates, carbon nanotubes and group(IV) metal phosphonates. Americium oxidation testing sought to determine the influence that other redox active components may have on the oxidation of Am(III).

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗