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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 469 records · Page 26
All sourcesNASA NTRSDOE OSTI
NASA NTRS1985

Observations of a monotectic solidification interface morphology

For detailed studies of the region around a solidification interface on a microscopic scale, a very thin (essentially two-dimensional) test cell may be translated across two temperature-controlled heating/cooling blocks and viewed with a microscope. Such a device is sometimes referred to as a temperature gradient microscope stage (TGS). Of particular interest in this study is the behavior of a monotectic type solution during solidification. Succinonitrile based model systems for metallic monotectic alloys, when solidified on a TGS, form an unusual 'worm-like' micromorphology. These interfaces are observable in situ under high optical magnification during growth.

Kaukler, W. F.↗
NASA NTRS1988

Synthetic Stromgren photometry for F dwarf stars

Recent synthetic spectrum and color calculations for cool dwarf star models are tested by comparison with observation. The accuracy of the computed dependence of the thermal colors B-V and b-y on effective temperature is examined, and H-beta indices are presented and compared with observed values. The accuracy of the predictions of the Stromgren uvby system metal-abundance indicator m1 and luminosity indicator c1 are tested. A new calibration of the c1, b-y diagram in terms of absolute magnitudes is given, making use of recent calculations of stellar isochrones. Observations of very metal-poor subdwarfs are used to study the accuracy of the isochrones. The c1, b-y diagram of the subdwarfs is compared with that of the turnoff-region stars in the very metal-poor globular cluster NGC 6397.

Bell, R. A.↗
NASA NTRS1988

Effect of surface catalysis on heating to ceramic coated thermal protection systems for transatmospheric vehicles

This paper describes the effect of surface catalysis on the heat transfer rate to the heat shield of a typical Transatmospheric Vehicle (TAV) during ascent and atmospheric entry. Surface kinetics and optical properties obtained from arc-jet tests on candidate thermal protection systems (coated metals) were used in a reacting boundary layer code to estimate the heating distribution along the surface of a TAV. Thermochemical stability of the coatings is described in terms of reduction in emittance and loss of opacifiers from the coatings during the arc-jet tests.

Stewart, David A.↗
NASA NTRS1990

Direct spectroscopy of electron and hole scattering

A new spectroscopy has been developed for the first direct probe of carrier-carrier scattering in materials. This spectroscopy provides spatial and energy resolution of the scattering process and has been used to investigate transport, scattering phenomena, and hot-carrier creation in two important metal-semiconductor systems. A theoretical treatment of this scattering spectroscopy yields excellent agreement with experimental spectra and provides direct evidence that carrier-carrier scattering is a dominant energy-loss mechanism in hot-carrier transport.

Bell, L. D.↗
NASA NTRS1989

Design, fabrication, and tests of a metallic shell tile thermal protection system for space transportation

A thermal protection tile for earth-to-orbit transports is described. The tiles consist of a rigid external shell filled with a flexible insulation. The tiles tend to be thicker than the current Shuttle rigidized silica tiles for the same entry heat load but are projected to be more durable and lighter. The tiles were thermally tested for several simulated entry trajectories.

Macconochie, Ian O.↗
NASA NTRS1991

Status of the advanced Stirling conversion system project for 25 kW dish Stirling applications

Technology development for Stirling convertors directed toward a dynamic power source for space applications is discussed. Space power requirements include high reliability with very long life, low vibration, and high system efficiency. The free-piston Stirling engine has the potential for future high power space conversion systems, either nuclear or solar powered. Although these applications appear to be quite different, their requirements complement each other. The advanced Stirling conversion system (ASCS) project at NASA Lewis Research Center is described. Each system design features a solar receiver/liquid metal heat transport system and a free-piston Stirling convertor with a means to provide nominally 25 kW of electric power to utility grid while meeting the US Department of Energy (DOE) performance and long term cost goals. The design is compared with other ASCS designs.

Shaltens, Richard K.↗
NASA NTRS1993

A new tape product for optical data storage

A new tape product has been developed for optical data storage. Laser data recording is based on hole or pit formation in a low melting metallic alloy system. The media structure, sputter deposition process, and media characteristics, including write sensitivity, error rates, wear resistance, and archival storage are discussed.

Larsen, T. L.↗
NASA NTRS1994

A study of ultraviolet absorption lines through the complete Galactic halo by the analysis of HST faint object spectrograph spectra of active Galactic nuclei, 1

The ultraviolet (1150 - 2850 A) spectra of a number of active galactic nuclei (AGNs) observed with the Hubble Space Telescope (HST) Faint Object Spectrograph (FOS) have been used to study the properties of the Galactic halo. The objects that served as probes are 3C 273, PKS 0454-220, Pg 1211+143, CSO 251, Ton 951, and PG 1351+640. The equivalent widths of certain interstellar ions have been measured, with special attention paid to the C IV/C II and Si IV/Si II ratios. These ratios have been intercompared, and the highest values are found in the direction of 3C 273, where C IV/C II = 1.2 and Si IV/Si II greater than 1. These high ratios may be due to a nearby supernova remnant, rather than to ionized gas higher up in the Galactic halo. Our data give some support to the notion that QSO metal-line systems may arise from intervening galaxies which contain high supernova rates, galactic fountains, and turbulent mixing layers.

Burks, Geoffrey S.↗
NASA NTRS1996

Thermal analysis of HGFQ using FIDAP(trademark): Solidification front motion

The High Gradient Furnace with Quench (HGFQ) is being designed by NASA/MSFC for flight on the International Space Station. The furnace is being designed specifically for solidification experiments in metal and metallic alloy systems. The HGFQ Product development Team (PDT) has been active since January 1994 and their effort is now in early Phase B. Thermal models have been developed both by NASA and Sverdrup (support contractor) to assist in the HGFQ design effort. Both these models use SINDA as a solution engine, but the NASA model was developed using PATRAN and includes more detail than the Sverdrup model. These models have been used to guide design decisions and have been validated through experimentation on a prototypical 'Breadboard' furnace at MSFC. One facet of the furnace operation of interest to the designers is the sensitivity of the solidification interface location to changes in the furnace setpoint. Specifically of interest is the motion (position and velocity) of the solidification front due to a small perturbation in the furnace temperature. FIDAP(TM) is a commercially available finite element program for analysis of heat transfer and fluid flow processes. Its strength is in solution of the Navier-Stokes equations for incompressible flow, but among its capabilities is the analysis of transient processes involving radiation and solidification. The models presently available from NASA and Sverdrup are steady-state models and are incapable of computing the motion of the solidification front. The objective of this investigation is to use FIDAP(TM) to compute the motion of the solidification interface due to a perturbation in the furnace setpoint.

Woodbury, Keith A.↗
NASA NTRS1997

Evaluation of HAN-TEAN Stabilizers using Microcalorimetry

HAN-TEAN (hydroxylammonium nitrate - triethanolammonium nitrate - in water) is being considered for various propellant applications. This propellant has advantages in terms of insensitivity to impact and fire, low vapor pressure and environmentally benign reaction products. One office concerns with HAN-TEAN is its stability and shelf-life, especially when contaminated with trace metals. Stabilizer systems, consisting of anti-oxidants and/or chealating agents were investigated for their ability to control the decomposition of HAN-TEAN. Isothermal microcalorimetry, an ultrasensitive heat measurement technique, was used to monitor the decomposition of HANTEAN at near ambient temperatures. Isothermal microcalorimetry measures the heat flow from a reaction vessel into a surrounding heat sink. Microcalorimetry is approximately 1,000 times more sensitive than accelerating rate calorimetry (ARC) or differential scanning calorimetry (DSC) for measuring heat flow. Samples of HAN-TEAN containing the stabilizers were spiked with 50 ppm iron and the heat evolution monitored for a period of at least 30 days. Ten stabilizer combinations were tested and the rates of HAN-TEAN decomposition were lowered by 74 to 95 percent in the presence of iron.

Hornung, Steven D.↗
NASA NTRS2000

X-33 Leading the Way to VentureStar(Trademark) in this Decade

The X-33, reusable space plane technology demonstrator is on course to begin the flights of the X-33 by the end of 2002 that will serve as a basis for industry and government decisions that could lead to VentureStar(Trademark). Lockheed Martin has placed the VentureStar(Trademark) LLC in it's Space Company and is now competing in an industry wide effort that will permit NASA to select a Second Generation RLV source by 2005. This move provides the focus for firm business planning needed to enable the decision by the time X-33 flies in mid 2002 and possibly with upgraded technologies a year or so later. Since the IAF 50th Congress in Amsterdam, most of the major hardware elements of X-33 have been through their assembly and test. The flight liquid oxygen tank was the first major element to complete final assembly. Aerospike Engine qualification testing has progressed successfully through its test objectives and the two flight engines are in preparation to be delivered to the Assembly Facility in Palmdale. All Thermal Protection System (TPS) metallic panels have completed qualification testing and have been delivered to Palmdale and all remaining TPS elements have been assembled and are ready for delivery. Flight Software and Avionics have been delivered and are in integration testing. In November 1999, the first graphite composite liquid hydrogen tank experienced a debond between the tank inner skin and the honeycomb core in testing. This tank had completed its third successful cryogenic and loads testing at MSFC. Replacement liquid hydrogen tanks have completed design and are in fabrication. The resulting delay from this change of design for the liquid hydrogen tank will be approximately two years.

Austin, Robert E.↗
NASA NTRS2001

The Role of Water in the Storage of Hydrogen in Metals

One major problem with the use of hydrogen is safe and efficient storage. In the pure form, bulky and heavy containers are required greatly reducing the efficiency of its use. Safety is also a great concern. Storage of hydrogen in the form of a metal hydride offers distinct advantages both in terms of volumetric efficiency and in terms of safety. As a result, an enormous amount of research is currently being done on metal-hydrogen systems. Practical application of these systems to storage of hydrogen can only occur when they are very well understood. In this paper, the preliminary results of a study of the surfaces of magnesium nickel alloys will be presented. Alloys that have been rendered totally unreactive with hydrogen as well as those that have been activated with liquid water and with water vapor were studied. Data obtained from XPS (X-ray Photoelectron Spectrometer) analysis, with samples held in vacuum for the shortest possible time to minimize the hydroxide degradation will be presented. Furthermore, TEM data on samples prepared in a new way that largely protects the surface from the high vacuum will be discussed.

Hampton, Michael D.↗
NASA NTRS1995

Using Density Functional Theory (DFT) for the Calculation of Atomization Energies

The calculation of atomization energies using density functional theory (DFT), using the B3LYP hybrid functional, is reported. The sensitivity of the atomization energy to basis set is studied and compared with the coupled cluster singles and doubles approach with a perturbational estimate of the triples (CCSD(T)). Merging the B3LYP results with the G2(MP2) approach is also considered. It is found that replacing the geometry optimization and calculation of the zero-point energy by the analogous quantities computed using the B3LYP approach reduces the maximum error in the G2(MP2) approach. In addition to the 55 G2 atomization energies, some results for transition metal containing systems will also be presented.

Bauschlicher, Charles W., Jr.↗
NASA NTRS2003

Development of Oxidation Protection Coatings for Gamma Titanium Aluminide Alloys

Metallic material systems play a key role in meeting the stringent weight and durability requirements for reusable launch vehicle (RLV) airframe hot structures. Gamma titanium aluminides (gamma-TiAl) have been identified as high-payoff materials for high-temperature applications. The low density and good elevated temperature mechanical properties of gamma-TiAl alloys make them attractive candidates for durable lightweight hot structure and thermal protection systems at temperatures as high as 871 C. However, oxidation significantly degrades gamma-TiAl alloys under the high-temperature service conditions associated with the RLV operating environment. This paper discusses ongoing efforts at NASA Langley Research Center to develop durable ultrathin coatings for protecting gamma-TiAl alloys from high-temperature oxidation environments. In addition to offering oxidation protection, these multifunctional coatings are being engineered to provide thermal control features to help minimize heat input into the hot structures. This paper describes the coating development effort and discusses the effects of long-term high-temperature exposures on the microstructure of coated and uncoated gamma-TiAl alloys. The alloy of primary consideration was the Plansee alloy gamma-Met, but limited studies of the newer alloy gamma-Met-PX were also included. The oxidation behavior of the uncoated materials was evaluated over the temperature range of 704 C to 871 C. Sol-gel-based coatings were applied to the gamma-TiAl samples by dipping and spraying, and the performance evaluated at 871 C. Results showed that the coatings improve the oxidation resistance, but that further development is necessary.

Wallace, T. A.↗
NASA NTRS2001

General Multimechanism Reversible-Irreversible Time-Dependent Constitutive Deformation Model Being Developed

Since most advanced material systems (for example metallic-, polymer-, and ceramic-based systems) being currently researched and evaluated are for high-temperature airframe and propulsion system applications, the required constitutive models must account for both reversible and irreversible time-dependent deformations. Furthermore, since an integral part of continuum-based computational methodologies (be they microscale- or macroscale-based) is an accurate and computationally efficient constitutive model to describe the deformation behavior of the materials of interest, extensive research efforts have been made over the years on the phenomenological representations of constitutive material behavior in the inelastic analysis of structures. From a more recent and comprehensive perspective, the NASA Glenn Research Center in conjunction with the University of Akron has emphasized concurrently addressing three important and related areas: that is, 1) Mathematical formulation; 2) Algorithmic developments for updating (integrating) the external (e.g., stress) and internal state variables; 3) Parameter estimation for characterizing the model. This concurrent perspective to constitutive modeling has enabled the overcoming of the two major obstacles to fully utilizing these sophisticated time-dependent (hereditary) constitutive models in practical engineering analysis. These obstacles are: 1) Lack of efficient and robust integration algorithms; 2) Difficulties associated with characterizing the large number of required material parameters, particularly when many of these parameters lack obvious or direct physical interpretations.

Saleeb, A. F.↗
NASA NTRS2006

Large Engine Technology (LET) Short Haul Civil Tiltrotor Contingency Power Materials Knowledge and Lifing Methodologies

This report documents the results of an experimental program conducted on two advanced metallic alloy systems (Rene' 142 directionally solidified alloy (DS) and Rene' N6 single crystal alloy) and the characterization of two distinct internal state variable inelastic constitutive models. The long term objective of the study was to develop a computational life prediction methodology that can integrate the obtained material data. A specialized test matrix for characterizing advanced unified viscoplastic models was specified and conducted. This matrix included strain controlled tensile tests with intermittent relaxtion test with 2 hr hold times, constant stress creep tests, stepped creep tests, mixed creep and plasticity tests, cyclic temperature creep tests and tests in which temperature overloads were present to simulate actual operation conditions for validation of the models. The selected internal state variable models where shown to be capable of representing the material behavior exhibited by the experimental results; however the program ended prior to final validation of the models.

Spring, Samuel D.↗
NASA NTRS2010

Conditions of Core Formation in the Early Earth: Single Stage or Heterogeneous Accretion?

Since approx.1990 high pressure and temperature (PT) experiments on metal-silicate systems have showed that partition coefficients [D(met/sil)] for siderophile (iron-loving) elements are much different than those measured at low PT conditions [1,2]. The high PT data have been used to argue for a magma ocean during growth of the early Earth [3,4]. In the ensuing decades there have been hundreds of new experiments carried out and published on a wide range of siderophile elements (> 80 experiments published for Ni, Co, Mo, W, P, Mn, V, Cr, Ga, Cu and Pd). At the same time several different models have been advanced to explain the siderophile elements in Earth's mantle: a) shallow depth magma ocean 25-30 GPa [3,5]; b) deep magma ocean; up to 50 GPa [6,7], and c) early reduced and later oxidized magma ocean [8,9]. Some studies have drawn conclusions based on a small subset of siderophile elements, or a set of elements that provides little leverage on the big picture (like slightly siderophile elements), and no single study has attempted to quantitatively explain more than 5 elements at a time. The purpose of this abstract is to identify issues that have lead to a difference in interpretation, and to present updated predictive expressions based on new experimental data. The resulting expressions will be applied to the siderophile element depletions in Earth's upper mantle.

Righter, Kevin↗