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At least 469 records · Page 26

Studies of volatiles and organic materials in early terrestrial and present-day outer solar system environments

A review and partial summary of projects within several areas of research generally involving the origin, distribution, chemistry, and spectral/dielectric properties of volatiles and organic materials in the outer solar system and early terrestrial environments are presented. The major topics covered include: (1) impact delivery of volatiles and organic compounds to the early terrestrial planets; (2) optical constants measurements; (3) spectral classification, chemical processes, and distribution of materials; and (4) radar properties of ice, hydrocarbons, and organic heteropolymers.

Sagan, Carl↗

The environmental distribution of late proterozoic organisms

Along present day coast lines, the environmental distributions of prokaryotic and protistan populations are often sharply delimited. Realized habitat ranges are generally narrower than those circumscribed by physiological tolerances, suggesting the importance of organism-organism interactions in the determination of population distributions. Microfossil populations preserved in silicified carbonates, dolomites, and shales of the 700-800 Ma old Akademikerbreen Group, Svalbard, and elsewhere indicate that the environmental distributions were defined equally clearly during the Proterozoic Eon. The Draken Conglomerate Formation is a tidal flat/lagoonal complex in which we have distinguished five principle biofacies containing a total of 42 taxa. Supratidal to subtidal gradients include the increasing abundance and diversity of both mat dweller microbenthos and allochthonous (principally planktonic) organisms, as well as a taphonomically important pattern of decreasing sheath thickness among mat builder microorganisms. The seaward barriers of Akademikerbreen lagoons were oolitic shoals, and these contain about a dozen endolithic and epilithic species not observed elsewhere in the group. Subtidal environments below fair weather wave base are represented by mudstones of the Svanbergfjellet Formation. These contain abundant and diverse cyanobacteria-like fossils generally similar to but specifically different from those found in tidal flat sediments, as well as diverse unicellular protists (some of impressive morphological complexity) and at least half a dozen cellularly preserved metaphyte populations. In all, more than 80 species are distributed among Akademikerbreen lithologies. Fossil assemblages from Svalbard and elsewhere illustrate the potential for a much finer paleoecological, biostratigraphic, and, hence, evolutionary resolution of the early fossil record.

Knoll, A. H.↗

Titan's organic chemistry: Results of simulation experiments

Recent low pressure continuous low plasma discharge simulations of the auroral electron driven organic chemistry in Titan's mesosphere are reviewed. These simulations yielded results in good accord with Voyager observations of gas phase organic species. Optical constants of the brownish solid tholins produced in similar experiments are in good accord with Voyager observations of the Titan haze. Titan tholins are rich in prebiotic organic constituents; the Huygens entry probe may shed light on some of the processes that led to the origin of life on Earth.

Sagan, Carl↗

Organization of rainfall by an unstable jet with an application to African waves

It is hypothesized that a shear instability can organize rainfall if it converges sufficient amounts of moisture. This convergence is calculated by specifying the amplitude of a downgoing wave just beneath the jet and calculating the ascent induced below as a function of the zonal wind. Data obtained question whether a jet can organize rainfall from an arbitrary large distance above the moist layer. While in the absence of shear, a wave can reach the moist layer with undiminished amplitude, the induced ascent is small - less than the estimated ascent during phase I of the GARP Atlantic Tropical Experiment (GATE) when rainfall remained unorganized. It is suggested that organization can occur only if the unstable jet is within a few kilometers of the moist and separated by large shear. A wind profile resembling the observed 600-mb African jet is considered as an example. The waves are found to be closer to the moist layer during the later summer, causing larger ascent at this time.

Miller, R. L.↗

Methods development for total organic carbon accountability

This report describes the efforts completed during the contract period beginning November 1, 1990 and ending April 30, 1991. Samples of product hygiene and potable water from WRT 3A were supplied by NASA/MSFC prior to contract award on July 24, 1990. Humidity condensate samples were supplied on August 3, 1990. During the course of this contract chemical analyses were performed on these samples to qualitatively determine specific components comprising, the measured organic carbon concentration. In addition, these samples and known standard solutions were used to identify and develop methodology useful to future comprehensive characterization of similar samples. Standard analyses including pH, conductivity, and total organic carbon (TOC) were conducted. Colorimetric and enzyme linked assays for total protein, bile acid, B-hydroxybutyric acid, methylene blue active substances (MBAS), urea nitrogen, ammonia, and glucose were also performed. Gas chromatographic procedures for non-volatile fatty acids and EPA priority pollutants were also performed. Liquid chromatography was used to screen for non-volatile, water soluble compounds not amenable to GC techniques. Methods development efforts were initiated to separate and quantitate certain chemical classes not classically analyzed in water and wastewater samples. These included carbohydrates, organic acids, and amino acids. Finally, efforts were initiated to identify useful concentration techniques to enhance detection limits and recovery of non-volatile, water soluble compounds.

Benson, Brian L.↗

Meridional fluxes of dissolved organic matter in the North Atlantic Ocean

Biooptical estimates of gelbstoff and a few platinum measurements of dissolved organic carbon (DOCpt) are used to construct a budget of the meridional flux of DOC and dissolved organic nitrogen (DON) across 36 deg 25 min N in the North Atlantic from previous inverse models of water and element transport. Distinct southward subsurface fluxes of dissolved organic matter within subducted shelf water, cabelled slope water, and overturned basin water are inferred. Within two cases of a positive gradient of DOCpt between terrestrial/shelf and offshore stocks, the net equatorward exports of O2 and DOCpt from the northern North Atlantic yield molar ratios of 2.1 to 9.1, compared to the expected Redfield O2/C ratio of 1.3. It is concluded that some shelf export of DOC, with a positive gradient between coastal and oceanic stocks, as well as falling particles, are required to balance carbon, nitrogen, and oxygen budgets of the North Atlantic.

Walsh, John J.↗

Hydrothermal organic synthesis experiments

Ways in which heat is useful in organic synthesis experiments are described, and experiments on the hydrothermal destruction and synthesis of organic compounds are discussed. It is pointed out that, if heat can overcome kinetic barriers to the formation of metastable states from reduced or oxidized starting materials, abiotic synthesis under hydrothermal conditions is a distinct possibility. However, carefully controlled experiments which replicate the descriptive variables of natural hydrothermal systems have not yet been conducted with the aim of testing the hypothesis of hydrothermal organic systems.

Shock, Everett L.↗

Green icebergs formed by freezing of organic-rich seawater to the base of Antarctic ice shelves

Samples of Antarctic seawater, basal ice, and green ice from ice cliffs and green icebergs are analyzed in order to examine green icebergs formed by the freezing of organic-rich seawater to the base of Antarctic ice shelves. Spectral reflectance of a green iceberg measured near 67 deg S, 62 deg E confirms that the color is inherent in the ice, not an artifact of the illumination. A constituent that absorbs blue photons is identified by spectrophotometric analysis of core samples from this iceberg and from the Amery basal ice, and of seawater samples from Prydz Bay off the Amery Ice Shelf. Analysis of the samples by fluorescence spectroscopy indicates that the blue absorption, and hence the inherent green color, is due to the presence of marine-derived organic matter in the green iceberg, basal ice, and seawater. Thick accumulations of green ice, in icebergs, and at the base of ice shelves indicate that high concentrations of organic matter exist in seawater for centuries at the depth of basal freezing.

Warren, Stephen G.↗

Formaldehyde and organic molecule production in astrophysical ices at cryogenic temperatures

Thermally promoted formaldehyde (H2CO) reactions in cryogenic ices have been studied to test their importance as a source of organic molecules in comets and interstellar ices. Ices containing H2CO, H2O, CH3OH, CO, and NH3 were investigated by using infrared spectroscopy. Small traces of NH3 (NH3/H2CO equal to or greater than 0.005) are sufficient to convert significant fractions (40 percent or greater) of the H2CO into more complex organics. However, H2CO reactions do not proceed without NH3. Spectral evidence for reaction onset appeared between 40 and 80 K, depending on the ice. Five distinct products were formed. These principally consist of polyoxymethylene and related derivatives. Polyoxymethylene itself was not made in significant amounts in cometary analogs. These products differ from those produced by ultraviolet and particle irradiation. The nature and relative amounts of the products depend on the initial composition, making these materials excellent tracers of a comet's history. About 3 percent of the organics in p-Halley's coma could have been produced by thermal H2CO reactions.

Schutte, W. A.↗

Performance of redundant disk array organizations in transaction processing environments

A performance evaluation is conducted for two redundant disk-array organizations in a transaction-processing environment, relative to the performance of both mirrored disk organizations and organizations using neither striping nor redundancy. The proposed parity-striping alternative to striping with rotated parity is shown to furnish rapid recovery from failure at the same low storage cost without interleaving the data over multiple disks. Both noncached systems and systems using a nonvolatile cache as the controller are considered.

Mourad, Antoine N.↗

Modeling personnel turnover in the parametric organization

A model is developed for simulating the dynamics of a newly formed organization, credible during all phases of organizational development. The model development process is broken down into the activities of determining the tasks required for parametric cost analysis (PCA), determining the skills required for each PCA task, determining the skills available in the applicant marketplace, determining the structure of the model, implementing the model, and testing it. The model, parameterized by the likelihood of job function transition, has demonstrated by the capability to represent the transition of personnel across functional boundaries within a parametric organization using a linear dynamical system, and the ability to predict required staffing profiles to meet functional needs at the desired time. The model can be extended by revisions of the state and transition structure to provide refinements in functional definition for the parametric and extended organization.

Dean, Edwin B.↗

Growing Organic Crystals By The Czochralski Method

Apparatus grows high-quality single crystals of organic compounds by Czochralski method. In Czochralski process, growing crystal lifted from middle of molten material without touching walls. Because of low melting temperatures of organic crystals, glass vessels usable. Traditional method for inorganic semiconductors adapted to optically nonlinear organic materials.

Shields, Angela↗

Apparatus Removes Organic Contaminants From Water

Catalytic-oxidation apparatus removes low-molecular-weight, polar, nonionizable organic contaminants from wastewater. Wastewater stream, previously treated by multifiltration process, pumped through apparatus for removal of trace organic contaminants. After injection of oxygen, flow preheated and enters catalytic reactor, where organic contaminants broken down into carbon dioxide and water. Carbon dioxide and unused oxygen removed in degasser.

Akse, James R.↗

Organic matter on the early surface of Mars: An assessment of the contribution by interplanetary dust

Calculations by Anders and Chyba et al. have recently revived interest in the suggestion that organic compounds important to the development of life were delivered to the primitive surface of the Earth by comets, asteroids or the interplanetary dust derived from these two sources. Anders has shown that the major post-accretion contribution of extraterrestrial organic matter to the surface of the Earth is from interplanetary dust. Since Mars is a much more favorable site for the gentle deceleration of interplanetary dust particles than is Earth, model calculations show that biologically important organic compounds are likely to have been delivered to the early surface of Mars by the interplanetary dust in an order-of-magnitude higher surface density than onto the early Earth. Using the method described by Flynn and McKay, the size frequency distribution, and the atmospheric entry velocity distribution of IDP's at Mars were calculated. The entry velocity distribution, coupled with the atmospheric entry heating model developed by Whipple and extended by Fraundorf was used to calculate the fraction of the particles in each mass decade which survives atmospheric entry without melting (i.e., those not heated above 1600K). The incident mass and surviving mass in each mass decade are shown for both Earth and Mars.

Flynn, G. J.↗

Space research with intact organisms: The role of Space Station Freedom

The study of intact organisms has provided biologists with a good working knowledge of most of the common organisms that have evolved in the 1 g environment of Earth. Reasonably accurate predictions can be made about organismal responses to most stimuli on Earth. To extend this knowledge to life without gravity, we must have access to the space environment for prolonged periods. Space Station Freedom will provide a facility with which to begin this type of research. Spaceflight research to date has been limited to relatively short-term exposures that have been informative but incomplete. This paper provides a brief background of known changes that have occurred in intact organisms in the space environment and proposes the kinds of experiments that are needed to expand our knowledge of life on Earth and in space.

Phillips, Robert W.↗

Space research on organs and tissues

Studies in space on various physiological systems have and will continue to provide valuable information on how they adapt to reduced gravitational conditions, and how living in a 1 g (gravity) environment has guided their development. Muscle and bone are the most notable tissues that respond to unweighting caused by lack of gravity. The function of specific muscles and bones relates directly to mechanical loading, so that removal of 'normal forces' in space, or in bedridden patients, causes dramatic loss of tissue mass. The cardiovascular system is also markedly affected by reduced gravity. Adaptation includes decreased blood flow to the lower extremities, thus decreasing the heart output requirement. Return to 1 g is associated with a period of reconditioning due to the deconditioning that occurs in space. Changes in the cardiovascular system are also related to responses of the kidney and certain endocrine (hormone-producing) organs. Changes in respiratory function may also occur, suggesting an effect on the lungs, though this adaptation is poorly understood. The neurovestibular system, including the brain and organs of the inner ear, must adapt to the disorientation caused by lack of gravity. Preliminary findings have been reported for liver. Additionally, endocrine organs responsible for release of hormones such as insulin, growth hormone, glucocorticoids, and thyroid hormone may respond to spaceflight.

Tischler, Marc E.↗

International organizations to enable world-wide mobile satellite services

Numbers of systems exist or have been proposed to provide world-wide mobile satellite services (MSS). Developers of these systems have formulated institutional structures they consider most appropriate for profitable delivery of these services. MSS systems provide niche services and complement traditional telecommunications networks; they are not integrated into world-wide networks. To be successful, MSS system operators must be able to provide an integrated suite of services to support the increasing globalization, interconnectivity, and mobility of business. The critical issue to enabling 'universal roaming' is securing authority to provide MSS in all of the nations of the world. Such authority must be secured in the context of evolving trends in international telecommunications, and must specifically address issues of standardization, regulation and organization. Today, only one existing organization has such world-wide authority. The question is how proponents of new MSS systems and services can gain similar authority. Securing the appropriate authorizations requires that these new organizations reflect the objectives of the nations in which services are to be delivered.

Anglin, Richard L., Jr.↗

Ordered organic thin films self-assembled from the vapor phase

Organic films self-assembled from a liquid phase, as in Langmuir-Blodgett or adsorption from solution, have received much attention in the past decade as techniques to achieve highly oriented-ordered polymeric thin films. Many organic compounds including some of the same fatty acids have been vapor deposited as well. However, organic pigments and dyes comprise a major class of important materials which have very low solubilities yet excellent thermal stabilities, making them ideally suited for film deposition from the vapor phase. Surprisingly, such molecular systems exhibit a significant propensity to self order, a high sensitivity to deposition parameters, and a range of microstructural forms that cannot be duplicated by the less energetic mechanisms associated with solution adsorption processes. Molecular solids such as heterocyclic polynuclear aromatics are excellent candidates for film formation by vacuum deposition means. Over the past decade, our work and that of others investigating a wide variety of perylene and phthalocyanine derivatives identified five deposition parameters that can significantly affect film morphology, physical microstructure, and type and extent of ordering developed in vacuum and vapor transport grown films. These parameters are substrate temperature, deposition rate, substrate chemistry and epitaxy, ambient gas convective flows, and post deposition annealing. Examples of how each of these conditions manifest themselves in the film structure and ordering, most frequently revealed by scanning electron microscopy, reflection absorption infrared spectroscopy (RAIR), and grazing incidence x-ray diffraction (GIX), are presented.

Debe, M. K.↗