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At least 469 records · Page 26

Switchable 1,8-diazabicycloundec-7-ene and 1-hexanol ionic liquid analyzed by liquid ToF-SIMS

Switchable ionic liquids (SWIL) play an important role in green chemistry. Due to the nature of SWIL chemistry, such as air sensitivity and pressure and temperature dependence, it is difficult to characterize SWIL using vacuum-based surface techniques. The fully CO2 loaded and none-loaded DBU and hexanol mixtures, a SWIL system, were analyzed in situ by time-of-flight secondary ion mass spectrometry (ToF-SIMS) coupled with the System for Analysis at the Liquid Vacuum Interface (SALVI), respectively. The DBU/Hexanol/CO2 SWIL was injected into the microchannel before liquid SIMS analysis. Bi3+ primary ion beam was used. The positive and negative spectra of the SWIL chemical components are presented. The characteristic peaks m/z 153 (reduced DBU) in the positive mode and m/z 101 (oxidized hexanol) in negative mode were observed. In addition, ion pair peaks including m/z 253, 319, 305, 451 in the positive mode and m/z 145, 223, 257 in the negative mode are first observed using this approach. These results demonstrate that the SALVI microfluidic reactor enables the vacuum-based surface technique (i.e., ToF-SIMS) for in situ characterization of challenging liquid samples such as ionic liquids.

DBU, hexanol↗

Dynamic signature of molecular association in methanol

Quasielastic neutron scattering measurements and molecular dynamics simulations were combined to investigate the collective dynamics of deuterated methanol, CD{sub 3}OD. In the experimentally determined dynamic structure factor, a slow, non-Fickian mode was observed in addition to the standard density-fluctuation heat mode. The simulation results indicate that the slow dynamical process originates from the hydrogen bonding of methanol molecules. The qualitative behavior of this mode is similar to the previously observed α-relaxation in supercooled water [M. C. Bellissent-Funel et al., Phys. Rev. Lett. 85, 3644 (2000)] which also originates from the formation and dissolution of hydrogen-bonded associates (supramolecular clusters). In methanol, however, this mode is distinguishable well above the freezing transition. This finding indicates that an emergent slow mode is not unique to supercooled water, but may instead be a general feature of hydrogen-bonding liquids and associating molecular liquids.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Validating hydrodynamic growth in National Ignition Facility implosions

We present new hydrodynamic growth experiments at the National Ignition Facility, which extend previous measurements up to Legendre mode 160 and convergence ratio 4, continuing the growth factor dispersion curve comparison of the low foot and high foot pulses reported by Casey et al. [Phys. Rev. E 90, 011102(R) (2014)]. We show that the high foot pulse has lower growth factor and lower growth rate than the low foot pulse. Using novel on-capsule fiducial markers, we observe that mode 160 inverts sign (changes phase) for the high foot pulse, evidence of amplitude oscillations during the Richtmyer-Meshkov phase of a spherically convergent system. Post-shot simulations are consistent with the experimental measurements for all but the shortest wavelength perturbations, reinforcing the validity of radiation hydrodynamic simulations of ablation front growth in inertial confinement fusion capsules.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Three-dimensional structures of Plasmodium falciparum spermidine synthase with bound inhibitors suggest new strategies for drug design

In this work, X-ray crystallography was used to examine ligand complexes of spermidine synthase from the malaria parasite Plasmodium falciparum (PfSpdS). The enzymes of the polyamine-biosynthesis pathway have been proposed to be promising drug targets in the treatment of malaria. Spermidine synthase (SpdS; putrescine aminopropyltransferase) catalyzes the transfer of the aminopropyl moiety from decarboxylated S-adenosylmethionine to putrescine, leading to the formation of spermidine and 5′-methylthioadenosine (MTA). In this work, X-ray crystallography was used to examine ligand complexes of SpdS from the malaria parasite Plasmodium falciparum (PfSpdS). Five crystal structures were determined of PfSpdS in complex with MTA and the substrate putrescine, with MTA and spermidine, which was obtained as a result of the enzymatic reaction taking place within the crystals, with dcAdoMet and the inhibitor 4-methylaniline, with MTA and 4-aminomethylaniline, and with a compound predicted in earlier in silico screening to bind to the active site of the enzyme, benzimidazol-(2-yl)pentan-1-amine (BIPA). In contrast to the other inhibitors tested, the complex with BIPA was obtained without any ligand bound to the dcAdoMet-binding site of the enzyme. The complexes with the aniline compounds and BIPA revealed a new mode of ligand binding to PfSpdS. The observed binding mode of the ligands, and the interplay between the two substrate-binding sites and the flexible gatekeeper loop, can be used in the design of new approaches in the search for new inhibitors of SpdS.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Access to pedestal pressure relevant to burning plasmas on the high magnetic field tokamak Alcator C-Mod

Experiments on the Alcator C-Mod tokamak have utilized reactor-relevant magnetic fields to sustain substantially higher pedestal pressure than in other devices and allow close approach to the ITER H-mode baseline target pedestal pressure of 90 kPa. The EPED model, which couples the physics of transport driven by kinetic ballooning modes and MHD instabilities arising from peeling-ballooning modes, predicts the pressure profile at the onset of edge-localized modes (ELMs), and yields to lowest order a critical-βN like behavior for the pedestal: p∝Bt×Bp ( ∝Bt^2 for fixed edge q). C-Mod routinely accesses edge plasma pressure in excess of 30 kPa, often by using a high-density (ne>3×10^20 m^-3) approach to high confinement, taking advantage of a regime known as enhanced D-alpha (EDA) H-mode. In the EDA H-mode, plasma transport regulates both the pedestal profiles and the core impurity content, thus holding the pedestal stationary at just below the peeling-ballooning stability boundary. This stationary ELM-suppressed regime has approached the maximum pedestal predicted by EPED at these densities: 60 kPa. This in turn gives rise to volume-averaged core plasma pressure in excess of 0.2MPa, a world record value for a magnetic fusion device. Another approach to achieving high pressure utilizes a pedestal limited by current-driven modes at low collisionality, in which pressure increases with density and which allows access to a higher EPED solution, termed “super-H”. C-Mod experiments at reduced density (ne<2×10^20 m^-3) and strong plasma shaping (δ>0.5) accessed this regime, producing pedestals with pressures up to 80kPa (approximately 90% of the ITER target) and temperatures of nearly 2 keV. In a number of these hot H-modes, we observe strong edge instabilities at low toroidal mode number (n=1) when pedestal pressure approaches predicted values from EPED, showing that current-driven MHD modes can serve as a limit on the pedestal in a metal-walled tokamak at high pressure and low collisionality.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Angular dependence of optical modes in metal-insulator-metal coupled quantum well infrared photodetector

We report the dependence of the near-field optical modes in metal-insulator-metal quantum well infrared photodetector (MIM-QWIP) on the incident angles. Three optical modes are observed and attributed to the 2nd- and the 3rd-order surface plasmon polariton (SPP) modes and the localized surface polariton (LSP) mode. In addition to the observation of a responsivity enhancement of 14 times by the LSP mode, the varying pattern of the three modes against the incident angle are revealed, in which the LSP mode is fixed while the 2nd SPP mode splits into two branches and the 3rd SPP mode red-shifts. The detailed mechanisms are analyzed and numerically simulated. The results fit the experiments very well, demonstrating the wavevector coupling effect between the incident light and the metal gratings on the SPP modes. Our work will pave the way to fully understanding the influence of incident angles on a detector’s response for applying the MIM-QWIP to focal plane arrays.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Simultaneous X-ray and radio observations of the radio-mode-switching pulsar PSR B1822$-$09

Here, we report on simultaneous X-ray and radio observations of the radio-mode-switching pulsar PSR B1822–09 with ESA's XMM–Newton and the Westerbork Synthesis Radio Telescope, Giant Metrewave Radio Telescope and Lovell radio telescopes. PSR B1822–09 switches between a radio-bright and radio-quiet mode, and we discovered a relationship between the durations of its modes and a known underlying radio-modulation time-scale within the modes. We discovered X-ray (energies 0.2–1.4 keV) pulsations with a broad sinusoidal pulse, slightly lagging the radio main pulse in phase by 0.094 ± 0.017, with an energy-dependent pulsed fraction varying from ~0.15 at 0.3 keV to ~0.6 at 1 keV. No evidence is found for simultaneous X-ray and radio mode switching. The total X-ray spectrum consists of a cool component (T ~0.96 × 10 6 K, hotspot radius R ~2.0 km) and a hot component (T ~2.2 × 10 6 K, R ~100 m). The hot component can be ascribed to the pulsed emission and the cool component to the unpulsed emission. The high-energy characteristics of PSR B1822–09 resemble those of middle-aged pulsars such as PSR B0656+14, PSR B1055–52 and Geminga, including an indication for pulsed high-energy gamma-ray emission in Fermi Large Area Telescope data. Explanations for the high pulsed fraction seem to require different temperatures at the two poles of this orthogonal rotator, or magnetic anisotropic beaming effects in its strong magnetic field. In our X-ray skymap, we found a harder source at only 5.1 ± 0.5 arcsec from PSR B1822–09, which might be a pulsar wind nebula.

79 ASTRONOMY AND ASTROPHYSICS↗

Cysteine sensing by plasmons of silver nanocubes

Noble metal nanoparticles are considered to be valuable nanostructures in the field of sensors due to their spectral response sensitivity to small changes in the surrounding refractive index which enables them to detect a small amount of molecules. In this research, we use silver nanocubes of about 50 nm length to detect low concentrations of cysteine, a semi-essential amino acid. Following cysteine adsorption onto the nanocubes, a redshift in the plasmonic modes was observed, enabling the detection of cysteine down to 10 µM and high sensitivity of about 125 nm/RIU (refractive index units). Furthermore, we found that multilayer adsorption of cysteine leads to the stabilization of the silver nanocubes. The cysteine growth onto the nanocubes was also characterized by high-resolution transmission electron microscopy (HR-TEM). - Highlights: • Silver nanocubes (50 nm length) are used to detect low concentrations of cysteine. • A redshift in the plasmonic modes was observed following cysteine adsorption onto the nanocubes. • The cysteine growth onto the nanocubes is also characterized by TEM.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Tunable Spectral Ordering of Magnetic Plasmon Resonances in Noble Metal Nanoclusters

Experimental characterization of the optical and magnetic properties of noble metal nanoclusters has exposed a size regime in between single-ring and extended two-dimensional nanocluster networks where the behavior of magnetic plasmon resonances is not well understood. In this intermediate size regime, individual electric dipole plasmons on each nanoparticle within the cluster can hybridize into delocalized magnetic modes that couple to either the electric or magnetic field of light with seemingly arbitrary energy ordering. In this work, using a coupled-dipole model that includes fully retarded interactions between electric dipole plasmons, we show that magnetic plasmon resonance energies can be controllably tuned and even made to cross as a function of nanocluster size. Experimental confirmation of this prediction is challenging because optical selection rules dictate the simultaneous excitation of many spectrally overlapping magnetic plasmon modes. However, based on analytic modeling and numerical simulation, we show that angle-resolved cathodoluminescence offers an approach to cleanly isolate these magnetic modes and observe the size-dependence of their spectrum. Not only does our work clarify the rich optical and magnetic behavior of noble metal nanoclusters in the intermediate-size regime, but it also suggests strategies to design negative-index plasmonic metamaterials with multiple tunable resonances in the visible spectrum.

36 MATERIALS SCIENCE↗

Study of structural and optical properties of YAG and Nd:YAG single crystals

Highlights: • Transparent YAG and pale pink Nd:YAG single crystals were produced by the Czochralski technique. • Growth mechanisms and shape of the liquid/solid interface and incorporation of Nd{sup 3+} were studied. • The structure of the crystals was investigated by X-ray diffraction, Raman and IR spectroscopy. • The 15 Raman and 17 IR modes were observed. • The obtained YAG and Nd:YAG single crystals were without core and of good optical quality. - Abstract: Yttrium aluminum garnet (YAG, Y{sub 3}Al{sub 5}O{sub 12}) and yttrium aluminum garnet doped with neodymium (Nd:YAG) single crystals were grown by the Czochralski technique. The critical diameter and the critical rate of rotation were calculated. Suitable polishing and etching solutions were determined. As a result of our experiments, the transparent YAG and pale pink Nd:YAG single crystals were produced. The obtained crystals were studied by X-ray diffraction, Raman and IR spectroscopy. The crystal structure was confirmed by XRD. The 15 Raman and 17 IR modes were observed. The Raman and IR spectroscopy results are in accordance with X-ray diffraction analysis. The obtained YAG and Nd:YAG single crystals were without core and of good optical quality. The absence of a core was confirmed by viewing polished crystal slices. Also, it is important to emphasize that the obtained Nd:YAG single crystal has a concentration of 0.8 wt.% Nd{sup 3+} that is characteristic for laser materials.

36 MATERIALS SCIENCE↗

Constraint on the potassium content for the superconductivity of potassium-intercalated phenanthrene

Raman-scattering measurements were performed on K{sub x}phenanthrene (0 ⩽ x ⩽ 6.0) at room temperature. Three phases (x = 3.0, 3.5, and 4.0) are identified based on the obtained Raman spectra. Only the K{sub 3}phenanthrene phase is found to exhibit the superconducting transition at 5 K. The C–C stretching modes are observed to broaden and become disordered in K{sub x}phenanthrene with x = 2.0, 2.5, 6.0, indicating some molecular disorder in the metal intercalation process. This disorder is expected to influence the nonmetallic nature of these materials. The absence of metallic character in these nonsuperconducting phases is found from the calculated electronic structures based on the local density approximation.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Shallow and Deep Latent Heating Modes Over Tropical Oceans Observed with TRMM PR Spectral Latent Heating Data

The global hydrological cycle is central to the Earth's climate system, with rainfall and the physics of its formation acting as the key links in the cycle. Two-thirds of global rainfall occurs in the Tropics. Associated with this rainfall is a vast amount of heat, which is known as latent heat. It arises mainly due to the phase change of water vapor condensing into liquid droplets; three-fourths of the total heat energy available to the Earth's atmosphere comes from tropical rainfall. In addition, fresh water provided by tropical rainfall and its variability exerts a large impact upon the structure and motions of the upper ocean layer. Three-dimensional distributions of latent heating estimated from Tropical Rainfall Measuring Mission Precipitation Radar (TRMM PR)utilizing the Spectral Latent Heating (SLH) algorithm are analyzed. Mass-weighted and vertically integrated latent heating averaged over the tropical oceans is estimated as approx.72.6 J/s (approx.2.51 mm/day), and that over tropical land is approx.73.7 J/s (approx.2.55 mm/day), for 30degN-30degS. It is shown that non-drizzle precipitation over tropical and subtropical oceans consists of two dominant modes of rainfall systems, deep systems and congestus. A rough estimate of shallow mode contribution against the total heating is about 46.7 % for the average tropical oceans, which is substantially larger than 23.7 % over tropical land. While cumulus congestus heating linearly correlates with the SST, deep mode is dynamically bounded by large-scale subsidence. It is notable that substantial amount of rain, as large as 2.38 mm day-1 in average, is brought from congestus clouds under the large-scale subsiding circulation. It is also notable that even in the region with SST warmer than 28 oC, large-scale subsidence effectively suppresses the deep convection, remaining the heating by congestus clouds. Our results support that the entrainment of mid-to-lower-tropospheric dry air, which accompanies the large-scale subsidence is the major factor suppressing the deep convection. Therefore, representation of the realistic entrainment is very important for proper reproduction of precipitation distribution and resultant large-scale circulation.

Takayabu, Yukari N.↗

Durability of polymeric encapsulation materials in a PMMA/glass concentrator photovoltaic system

We examined the durability of polymeric encapsulation materials using outdoor exposure at the nominal geometric concentration of 500 suns. The results for 36-month cumulative field deployment are presented for materials including: poly(ethylene-co-vinyl acetate), (EVA); polyvinyl butyral (PVB); ionomer; polyethylene/polyoctene copolymer (PO); thermoplastic polyurethane (TPU); poly(dimethylsiloxane) (PDMS); poly(diphenyl dimethyl siloxane) (PDPDMS); and poly(phenyl-methyl siloxane) (PPMS). Measurements of the field conditions including ambient temperature and ultraviolet (UV) dose were recorded at the test site during the experiment. Our measurements for the experiment included optical transmittance (with subsequent analysis of solar-weighted transmittance, UV cut-off wavelength, and yellowness index), mass, visual photography, photoelastic imaging, and fluorescence spectroscopy. While the results to date for EVA are presented and discussed, examination here focuses more on the siloxane materials. A specimen recently observed to fail by thermal decomposition is discussed in terms of the implementation of the experiment as well as its fluorescence signature, which was observed to become more pronounced with age. Modulated thermogravimetry (allowing determination of the activation energy of thermal decomposition) was performed on a subset of the siloxanes to quantify the propensity for decomposition at elevated temperatures. Supplemental, Pt-catalyst- and primer-solutions as well as peroxide-cured PDMS specimens were examined to assess the source of the luminescence. Furthermore, our results, including the change in optical transmittance, observed failure modes, and subsequent analyses of the failure modes are described in the conclusions.

14 SOLAR ENERGY↗

Reconciling BICEP2 and Planck results with right-handed Dirac neutrinos in the fundamental representation of grand unified E{sub 6}

The tensor-to-scalar ratio (r=0.20{sub −0.05}{sup +0.07}) inferred from the excess B-mode power observed by the Background Imaging of Cosmic Extragalactic Polarization (BICEP2) experiment is almost twice as large as the 95% CL upper limits derived from temperature measurements of the WMAP (r<0.13) and Planck (r<0.11) space missions. Very recently, it was suggested that additional relativistic degrees of freedom beyond the three active neutrinos and photons can help to relieve this tension: the data favor an effective number of light neutrino species N{sub eff}=3.86±0.25. Since the BICEP2 ratio implies the energy scale of inflation (V{sub ∗}{sup 1/4}∼2×10{sup 16} GeV) is comparable to the grand unification scale, in this paper we investigate whether we can accommodate the required N{sub eff} with three right-handed (partners of the left-handed standard model) neutrinos living in the fundamental representation of a grand unified exceptional E{sub 6} group. We show that the superweak interactions of these Dirac states (through their coupling to a TeV-scale Z{sup ′} gauge boson) lead to decoupling of right-handed neutrino just above the QCD cross over transition: 175 MeV≲T{sub ν{sub R}{sup dec}}≲250 MeV. For decoupling in this transition region, the contribution of the three right-handed neutrinos to N{sub eff} is suppressed by heating of the left-handed neutrinos (and photons). Consistency (within 1σ) with the favored N{sub eff} is achieved for 4.5 TeV<M{sub Z{sup ′}}<7.5 TeV. The model is fully predictive and can be confronted with future data from LHC14.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Magneto-hydrodynamics simulation study of deflagration mode in co-axial plasma accelerators

Experimental studies by Poehlmann et al. [Phys. Plasmas 17(12), 123508 (2010)] on a coaxial electrode magnetohydrodynamic (MHD) plasma accelerator have revealed two modes of operation. A deflagration or stationary mode is observed for lower power settings, while higher input power leads to a detonation or snowplow mode. A numerical modeling study of a coaxial plasma accelerator using the non-ideal MHD equations is presented. The effect of plasma conductivity on the axial distribution of radial current is studied and found to agree well with experiments. Lower conductivities lead to the formation of a high current density, stationary region close to the inlet/breech, which is a characteristic of the deflagration mode, while a propagating current sheet like feature is observed at higher conductivities, similar to the detonation mode. Results confirm that plasma resistivity, which determines magnetic field diffusion effects, is fundamentally responsible for the two modes.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Observation of Persistent Zero Modes and Superconducting Vortex Doublets in UTe 2

Superconducting vortices can reveal electron pairing details and nucleate topologically protected states. Yet, vortices of bulk spin-triplet superconductors have never been visualized at the atomic scale. Recently, UTe 2 has emerged as a prime spin-triplet superconductor, but its superconducting order parameter is elusive, and whether time-reversal symmetry (TRS) is broken remains unsettled. Here, in this work, we visualize vortices on the (011) surface of ultraclean UTe 2 single crystals (T c = 2.1 K) using scanning tunneling microscopy (STM). We introduce $\frac{d^{2}𝐼}{d𝑉^{2}}$ imaging as an effective technique for vortex visualization in superconductors with substantial residual zero-energy density of states (DOS), as in UTe 2 . Anisotropic single-flux-quantum vortices, with coherence lengths of ∼12 nm (4 nm) parallel (perpendicular) to the a -axis, form a triangular vortex lattice (VL) under a small out-of-plane magnetic field. The invariance of vortex structures and VL under changes of field polarity and cooling history strongly supports time-reversal invariant superconductivity under zero field. At vortex cores (VCs), nonsplit, spectrally sharp zero-bias conductance peaks (ZBPs) persist up 8 T that are consistent with symmetry-protected Majorana zero modes (MZMs) in a topological vortex line. Close examination of vortex structures reveals a mirror-asymmetric doublet─one with ZBPs and another with an enhanced apparent gap, possibly originating from a field-induced multicomponent order parameter.

UTe2↗

Development of drift-resistive-inertial ballooning transport model for tokamak edge plasmas

A new model is developed for transport driven by drift-resistive-inertial ballooning modes (DRIBMs) in axisymmetric tokamak plasmas. The model is derived using two-fluid reduced Braginskii equations in a generalized s-{alpha} geometry. The unified theory includes diamagnetic effects, parallel electron and ion dynamics, electron inertia, magnetic perturbations, transverse particle diffusion, gyroviscous stress terms, electron and ion equilibrium temperature gradients, and temperature perturbations. A mixing length approximation is used to compute electron and ion thermal transport as well as particle fluxes from eigenvalues and eigenvectors of the linearized equations. The prediction for the saturation level is obtained by balancing the DRIBM growth rate against the nonlinear ExB convection. The parametric dependence of DRIBMs is investigated in systematic scans over density gradient, electron and ion temperature gradients, magnetic-q, collision frequency, magnetic shear, and Larmor radius. The DRIBM threshold is determined as a function of the collision frequency and the density and temperature gradients. The transition from DRIBM to the toroidal ion temperature gradient (ITG) mode is observed for small density gradients. For steep density gradients, the effect of ITG on DRIBM is found to be stabilizing. The transport seen in the DRIBM is of a scale that is consistent with the observed experimental anomalous transport, suggesting that the DRIBM mode could be the principle agent responsible for edge transport in Ohmic and L-mode discharges.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Modeling of fast neutral-beam-generated ion effects on MHD-spectroscopic observations of resistive wall mode stability in DIII-D plasmas

Experiments conducted at DIII-D investigate the role of drift kinetic damping and fast neutral beam injection (NBI)-ions in the approach to the no-wall β{sub N} limit. Modelling results show that the drift kinetic effects are significant and necessary to reproduce the measured plasma response at the ideal no-wall limit. Fast neutral-beam ions and rotation play important roles and are crucial to quantitatively match the experiment. In this paper, we report on the model validation of a series of plasmas with increasing β{sub N}, where the plasma stability is probed by active magnetohydrodynamic (MHD) spectroscopy. The response of the plasma to an externally applied field is used to probe the stable side of the resistive wall mode and obtain an indication of the proximity of the equilibrium to an instability limit. We describe the comparison between the measured plasma response and that calculated by means of the drift kinetic MARS-K code [Liu et al., Phys. Plasmas 15, 112503 (2008)], which includes the toroidal rotation, the electron and ion drift-kinetic resonances, and the presence of fast particles for the modelled plasmas. The inclusion of kinetic effects allows the code to reproduce the experimental results within ∼13% for both the amplitude and phase of the plasma response, which is a significant improvement with respect to the undamped MHD-only model. The presence of fast NBI-generated ions is necessary to obtain the low response at the highest β{sub N} levels (∼90% of the ideal no-wall limit). The toroidal rotation has an impact on the results, and a sensitivity study shows that a large variation in the predicted response is caused by the details of the rotation profiles at high β{sub N}.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗