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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 469 records · Page 26

Online Monitoring of Catalytic Processes by Fiber-Enhanced Raman Spectroscopy

An innovative solution for real-time monitoring of reactions within confined spaces, optimized for Raman spectroscopy applications, is presented. This approach involves the utilization of a hollow-core waveguide configured as a compact flow cell, serving both as a conduit for Raman excitation and scattering and seamlessly integrating into the effluent stream of a cracking catalytic reactor. The analytical technique, encompassing device and optical design, ensures robustness, compactness, and cost-effectiveness for implementation into process facilities. Notably, the modularity of the approach empowers customization for diverse gas monitoring needs, as it readily adapts to the specific requirements of various sensing scenarios. As a proof of concept, the efficacy of a spectroscopic approach is shown by monitoring two catalytic processes: CO 2 methanation (CO 2 + 4H 2 → CH 4 + 2H 2 O) and ammonia cracking (2NH 3 → N 2 + 3H 2 ). Leveraging chemometric data processing techniques, spectral signatures of the individual components involved in these reactions are effectively disentangled and the results are compared to mass spectrometry data. This robust methodology underscores the versatility and reliability of this monitoring system in complex chemical environments.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Rocket study of the X-ray background

The X-ray optical detection system flown on Aerobee 17.08 is described in detail, and the preliminary results of the 24 June 1971 flight are discussed. The optical design, fabrication and parabolic nature of the mirrors, effective aperture of mirror array, and X-ray detectors are considered. Preliminary analysis of data from the flight confirms the extended nature and complex structure of the X-ray source in Virgo. A core of X-ray emission is indicated which is approximately 0.5 deg in diameter and surrounded by an emitting region at least 2 deg across. The Virgo source spectrum is observed to have few low energy photons.

Fisher, P. C.↗

Refracting lens system for low-scatter star-tracker: A Concept

''Low Scatter Lens Design/Development'' discusses studies of low-scatter lens system. Two sections cover optical design and scattering analysis for model of lens system which rejects radiation. Result of computations are shown on computer printouts attached to report.

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Solar rejection for an orbiting telescope

The present work discusses some of the constraints that the optical designer must deal with in optimizing spaceborne sensors that must look at or near the sun. Analytical techniques are described for predicting the effects of stray radiation from sources such as mirror scatter, baffle scatter, diffraction, and ghost images. In addition, the paper describes a sensor design that has been flown on the Apollo Telescope Mount (Skylab) to aid astronauts in locating solar flares. In addition to keeping stray radiation to a minimum, the design had to be nondegradable by the direct solar heat load.

Rehnberg, J. D.↗

Multiple detector focal plane array ultraviolet spectrometer for the AMPS laboratory

The possibility of meeting the requirements of the amps spectroscopic instrumentation by using a multi-element focal plane detector array in a conventional spectrograph mount was examined. The requirements of the detector array were determined from the optical design of the spectrometer which in turn depends on the desired level of resolution and sensitivity required. The choice of available detectors and their associated electronics and controls was surveyed, bearing in mind that the data collection rate from this system is so great that on-board processing and reduction of data are absolutely essential. Finally, parallel developments in instrumentation for imaging in astronomy were examined, both in the ultraviolet (for the Large Space Telescope as well as other rocket and satellite programs) and in the visible, to determine what progress in that area can have direct bearing on atmospheric spectroscopy.

Feldman, P. D.↗

Advanced Atmospheric Sounder and Imaging Radiometer (AASIR)

Design information for the Advanced Atmospheric Sounder and Imaging Radiometer is reported, which was developed to determine the configuration of a sensor for IR and visible imaging. The areas of technology reported include: systems design, optics, mechanics, electronics, detectors, radiative cooler, and radiometric calibration.

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Multilayered (Hg,Cd)Te infrared detector

Multilayered mercury-cadmium telluride photoconductive detectors were developed which are capable of providing individual coverage of three separate spectral wavelength bands without the use of beam splitters. The multilayered "three-color" detector on a single dewar takes the place of three separate detector/filter/dewar units and enables simpler and more reliable mechanical and optical designs for multispectral scanners and radiometers. Wavelength channel design goals (in micrometers) were: 10.1 to 11.0, 11.0 to 12.0, and 13.0. Detectivity for all channels was 1 x 10 to the 10th power cm-Hz 1/2/Watt. A problem occurred in finding an epoxy layer which had good infrared transmission properties and which also was chemically and mechanically compatible with HgCdTe processing techniques. Data on 6 candidate bonding materials are surveyed and discussed.

Rae, W. G.↗

Photo sensor array technology development

The development of an improved capability photo sensor array imager for use in a Viking '75 type facsimile camera is presented. This imager consists of silicon photodiodes and lead sulfide detectors to cover a spectral range from 0.4 to 2.7 microns. An optical design specifying filter configurations and convergence angles is described. Three electronics design approaches: AC-chopped light, DC-dual detector, and DC-single detector, are investigated. Experimental and calculated results are compared whenever possible using breadboard testing and tolerance analysis techniques. Results show that any design used must be forgiving of the relative instability of lead sulfide detectors. A final design using lead sulfide detectors and associated electronics is implemented by fabrication of a hybrid prototype device. Test results of this device show a good agreement with calculated values.

Rossman, M. W.↗

Advanced Meteorological Temperature Sounder (AMTS) study

The results of a system definition study (theoretical) for an Advanced Meteorological Temperature Sounder (AMTS) is described. From the data the atmospheric temperature and humidity profiles can be determined over the entire earth's surface with a spatial resolution of 45 km. x 45 km; amounts and type of cloud cover as well as surface temperatures of the earth are also determined. The major purpose of the study was to determine the feasibility of cooling twenty-eight detectors to the 80-90 Kelvin region by means of a radiative cooler. Other related considerations were achieving high signal-to-noise ratios, maximizing optical throughput through the grating spectrometer, and reducing preamplifier noise. A detailed optical design of an f/5 Ebert-Fastie spectrometer was carried out to verify that image quality is adequate; field lenses near the spectrometer focal plane were designed to image the grating onto the smallest size detectors for each channel.

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Infrared Astronomical Satellite

The objective of the Infrared Astronomical Satellite is to produce an unbiased all-sky survey in the wavelength region between 8 and 120 microns. Using a 60 cm diameter helium cooled telescope and detector arrays which are essentially zodiacal light background photon noise limited, heretofore unprecedented sensitivity can be achieved. The optical design, the focal plane layout and expected performance of the current design concept are discussed.

Aumann, H. H.↗

A 10 micron laser heterodyne spectrometer for remote detection of trace gases

Infrared heterodyne spectroscopy provides a means of measuring the intensity profiles of individual rotation-vibration spectral lines with high sensitivity. Considerable effort has been expended on optimizing these instruments for remote measurements of gases in planetary atmospheres with the result that present-generation spectrometers are beginning to provide new and startling results on the planets. The fundamental principles of laser heterodyne spectroscopy are discussed. Detailed considerations of the optical design and the electronic design of the spectral-line receiver are given. Representative results obtained with this spectrometer are discussed, including precision frequency measurements of NH3 (nu-2) lines, detection of auroral emission from Jupiter, and measurements of terrestrial O3 and CO2.

Mumma, M. J.↗