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At least 469 records · Page 26

High-Temperature Characterization of Alumina Substrates and Folded Slot Antenna

The characterization of 99.6% polycrystalline alumina substrates and folded slot antennas is presented in this paper. Coplanar Waveguide (CPW) calibration standards where fabricated on 99.6% polycrystalline alumina substrates. Thru-Reflect-Line (TRL) calibrations were performed at temperatures of 25 to 400 C over a frequency range from 0.5 to 50 GHz. The effective dielectric constant of the alumina substrates was determined to be relatively constant at 5.4 from 25 to 200 C and then increased steadily to approximately 6 at 400 C. The loss of the CPW lines increased as temperature and frequency increased as well noting that the increase in loss is even more profound as both the temperature and frequency increased simultaneously. A CPW fed folded slot antenna fabricated on the alumina substrates is also presented. The Return Loss (RL) of a CPW fed folded slot antenna exhibits a self impedance matching technique. The RL of the folded slot antenna at 25 C displays a resonance at 3.5 GHz and is approximately 16 dB in magnitude. At 300 C the resonance shifts down in frequency to approximately 3.3 dB and has roughly the same magnitude. However the loss of the antenna response also increases at this elevated temperature. This work is part of the initial stages of an effort at NASA Glenn research Center to develop wireless sensors for harsh environments. This work can reduce cost, space to house all the hard wired connections, and reduce the weight of the overall units such as aerospace engines and allow for the placement of the wireless sensors in the engine which are not possible with hard wired sensors.

Scardelletti, Maximilian C.↗

Assessing High Resolution Thermal Monitoring of Complex Intertidal Environments From Space: the Case of ECOSTRESS at Rias Baixas, NW Iberia

Currently, thermal sensors on satellites and other orbital platforms with high spatial resolution designed to monitor the oceans are often insufficient to assess the surface temperature of small bodies of water or within the coastal boundary layer. As the accuracy and sensitivity of remote sensing satellites improve, the demand for more accurate and up-to-date basic data sets for calibration increases. The quality of the thermal data collected by ECOSTRESS on the International Space Station allows the characterization of thermal stress levels in coastal ecosystems with a high spatial resolution of 70 m and a return time from hours to 5 days. This study focused on the calibration of ECOSTRESS estimates with in situ surface temperature data from sensors installed at 3 cm depth in the sediment on the intertidal muddy sandflats of three of the Rías Baixas in Galicia, NW Iberian Peninsula, from 2019 to 2021. A final number of 45 ECOSTRESS temperature images were analyzed. From these, 20% contained substantial georeferencing errors which had to be corrected manually with GIS software tools. We applied the Fourier's law of Heat Conduction to derive surface estimates from loggers sub-surface measurements that could be directly compared with ECOSTRESS data. Overall, a good calibration which explained more than 80% of ECOSTRESS temperature estimates for the whole dataset was obtained, but with an intrinsic cold bias around 1.39 °C. When temperatures at a depth of 3 cm were used, the linear fit became worse and the negative bias increased to 1.49 °C. Closer inspection revealed that night measurements were responsible for this larger deviation, as ECOSTRESS estimates became much colder compared to within sediment measurements because of the combined effect of the instrument intrinsic bias and nocturnal surface cooling. The best calibration was obtained when surface estimates were calculated just for the nighttime, as the cold bias decreased to 0.93 °C. More importantly, during hot daytime conditions in emersion above 20 °C, ECOSTRESS data matched surface temperature estimates, probably because of a better performance of ECOSTRESS algorithm at dry surfaces with lower emissivity. Thus, during the most ecologically relevant periods when high temperatures could drive thermal stress in many commercially-important bivalve species, ECOSTRESS provides accurate surface estimates that can be used to derive sub surface temperatures at the depths at which the different burrowing organisms live. We thus conclude that this instrument constitutes an important global tool to examine thermal stress at an unprecedented spatial scale for complex sea-land boundary systems.

ECOSTRESS↗

BELINDA: Broadband Emission Lidar with Narrowband Determination of Absorption. A new concept for measuring water vapor and temperature profiles

We present a new concept for differential absorption lidar measurements of water vapor and temperature profiles. The idea is to use one broadband emission laser and a narrowband filter system for separation of the 'online' and 'offline' return signals. It is shown that BELINDA offers improvements as to laser emission shape and stability requirements, background suppression, and last and most important a significant reduction of the influence of Rayleigh scattering. A suitably designed system based on this concept is presented, capable of measuring water vapor or temperature profiles throughout the planetary boundary layer.

Theopold, F. A.↗

Net current measurements and secondary electron emission characteristics of the Voyager plasma science experiment and their impact on data interpretation

The Voyager Plasma Science (PLS) instrument is capable of returning integral (DC) current measurements, similar in some respects to measurements made with a Langmuir probe or a retarding potential analyzer, although there are significant differences. The integral measurements were made during a calibration sequence in the solar wind, during Cruise Science Maneuvers, and within the magnetospheres of Jupiter and Saturn by Voyager 1. After the failure of the PLS experiment following the Saturn encounter, that instrument was placed in the DC return mode returning possibly usable data from early 1981 through early 1985. The DC return measurements are difficult to interpret and are above threshold values only for relatively large fluxes; the determination of the measured current level is dependent on the operating temperature of the preamplifiers which further complicates the interpretation. Nevertheless, these measurements can be used to determine the efficiency of the suppressor grid at preventing the loss of secondary electrons off the collector plate. Some DC return measurements have been invaluable in aiding in the interpretation of some electron plasma measurements not previously understood. It is found that electron spectra can be significantly modified by the presence of second generation secondary electrons produced by either first generation secondaries or photoelectrons on the support ring of the negative high voltage modulator grid within the instrument housing.

Mcnutt, Ralph L., Jr.↗

Off-design operation and performance of pumped thermal energy storage

In this article, we describe off-design models and control strategies for a Pumped Thermal Energy Storage (PTES) system that uses liquid thermal energy storage: specifically molten salt for hot storage and methanol for cold storage. Off-design conditions arise when load-following, or due to variations in storage tank temperatures or ambient temperatures. We propose a control strategy that uses inventory control to manage the mass flow rate in the thermodynamic cycles, which facilitates load following. We also propose a control strategy for the storage fluid mass flow rates, which are varied to ensure the molten salt is maintained at its design temperature. This maximizes efficiency and minimizes problems with salt freezing or degradation. The cold storage fluid mass flow rate is varied so that the cold tanks have the same state-of-charge as the hot tanks. This leads to variations in cold fluid temperature, but these variations are shown to be acceptably small (e.g. 7.5% increase), and this control method is shown to be simpler and more efficient than an alternative strategy where tanks become unbalanced. The ambient temperature and storage tank temperatures are moved ±50 °C from the design values and the impact on power, duration, and tank temperatures is quantified. Results demonstrate that the proposed control strategy is stable and self-correcting - that is, storage temperatures converge on stable values after two-to-three charge-discharge cycles. When inputs return to design values, the system returns to its design point after two charge-discharge cycles. We also demonstrate that inventory control enables delivery of the target power output even when off-design conditions exist that would normally reduce the power output.

25 ENERGY STORAGE↗

Negative thermal expansion and magnetoelastic coupling in the breathing pyrochlore lattice material LiGaCr 4 S 8

In this paper, the physical properties of the spinel LiGaCr 4 S 8 have been studied with neutron diffraction, x-ray diffraction, magnetic susceptibility, and heat capacity measurements. The neutron diffraction and synchrotron x-ray diffraction data reveal negative thermal expansion (NTE) below 111(4) K. The magnetic susceptibility deviates from Curie-Weiss behavior with the onset of NTE. At low temperature a broad peak in the magnetic susceptibility at 10.3(3) K is accompanied by the return of normal thermal expansion. First-principles calculations find a strong coupling between the lattice and the simulated magnetic ground state. Finally, these results indicate strong magnetoelastic coupling in LiGaCr 4 S 8 .

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Advanced Strategy Guideline: Air Distribution Basics and Duct Design

This report discusses considerations for designing an air distribution system for an energy efficient house that requires less air volume to condition the space. Considering the HVAC system early in the design process will allow adequate space for equipment and ductwork and can result in cost savings. Principles discussed that will maximize occupant comfort include delivery of the proper amountof conditioned air for appropriate temperature mixing and uniformity without drafts, minimization of system noise, the impacts of pressure loss, efficient return air duct design, and supply air outlet placement, as well as duct layout, materials, and sizing.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Gas retention and cosmic-ray exposure ages of a basalt fragment from Mare Fecunditatis.

The Ar40-Ar39 gas retention age and the Ar38-Ar37 cosmic ray exposure age have been determined on a total rock sample of the basalt fragment B-1 returned from Mare Fecunditatis by the Luna 16 mission. This sample shows a large low-temperature loss of radiogenic Ar40 but defines a reasonably good high-temperature plateau at 3.45 plus or minus 0.04 b.y. This is presumed to identify the period of igneous activity in Mare Fecunditatis. This activity is found to be later than that in the area of Mare Tranquilitatis, but earlier than that in the area of Oceanus Procellarum and Mare Imbrium. The cosmic-ray exposure age was found to be 475 m.y.

Huneke, J. C.↗

Apollo 14 - Oxide, metal, and olivine mineral chemistries in 14072 with a bearing on the temporal relationships of subsolidus reduction

One of three primary objectives of the reported study is related to the definition of the distribution of troilite and Fe and the evaluation of the role of FeS in subsolidus reduction assemblages. Another objective was concerned with the definition of the lower limit of stabilizing elements such as Mg, Al, and Cr in ulvospinel to determine the terminal compositions at which reduction is inhibited. The third objective involves a comparison of the mineral chemistries of decomposed olivine with unaltered olivine in an attempt to determine the temperature limits. The sample was selected because it is one of the most intensely reduced samples returned from the moon. The model invoked for reduction is a magmatic-deuteric process which requires an environment approximating that of a closed system in which the volatile constituents are contained and in which reduction proceeds continuously with crystallization.

Haggerty, S. E.↗

Computations of ion diffusion coefficients from the Boltzmann-Fokker-Planck equation

The Boltzmann-Fokker-Planck equation is solved with the Chapman-Enskog method of analysis for the velocity distribution functions of helium, carbon, nitrogen, and oxygen. The analysis is a perturbation scheme based on the assumption of a collision-dominated gas, and the calculations are carried out to first order. The elements considered are treated as trace constituents in an electron-proton gas. From the resulting distribution functions, diffusion coefficients are computed which are found to be 20-30% less than those obtained by Chapman and Burgers. In addition, it is shown that the return current of cold electrons needed to maintain quasi-neutrality in a plasma with a temperature gradient contributes a term in the thermal diffusion coefficient omitted erroneously in previous works. This added term resolves the longstanding controversy over the discrepancy between the coefficients of Chapman and Burgers, which are seen to be completely equivalent in the light of this analysis. The viscosity coefficient for an electron-proton gas is also computed and found to be 7% less than that obtained by Braginskii.

Roussel-Dupre, R.↗

AMTEC vapor-vapor series connected cells

An alkali metal thermoelectric converter (AMTEC) having a plurality of cells structurally connected in series to form a septum dividing a plenum into two chambers, and electrically connected in series, is provided with porous metal anodes and porous metal cathodes in the cells. The cells may be planar or annular, and in either case a metal alkali vapor at a high temperature is provided to the plenum through one chamber on one side of the wall and returned to a vapor boiler after condensation at a chamber on the other side of the wall in the plenum. If the cells are annular, a heating core may be placed along the axis of the stacked cells. This arrangement of series-connected cells allows efficient generation of power at high voltage and low current.

Underwood, Mark L.↗

Regolith Evolved Gas Analyzer

The Regolith Evolved Gas Analyzer (REGA) is a high-temperature furnace and mass spectrometer instrument for determining the mineralogical composition and reactivity of soil samples. REGA provides key mineralogical and reactivity data that is needed to understand the soil chemistry of an asteroid, which then aids in determining in-situ which materials should be selected for return to earth. REGA is capable of conducting a number of direct soil measurements that are unique to this instrument. These experimental measurements include: (1) Mass spectrum analysis of evolved gases from soil samples as they are heated from ambient temperature to 900 C; and (2) Identification of liberated chemicals, e.g., water, oxygen, sulfur, chlorine, and fluorine. REGA would be placed on the surface of a near earth asteroid. It is an autonomous instrument that is controlled from earth but does the analysis of regolith materials automatically. The REGA instrument consists of four primary components: (1) a flight-proven mass spectrometer, (2) a high-temperature furnace, (3) a soil handling system, and (4) a microcontroller. An external arm containing a scoop or drill gathers regolith samples. A sample is placed in the inlet orifice where the finest-grained particles are sifted into a metering volume and subsequently moved into a crucible. A movable arm then places the crucible in the furnace. The furnace is closed, thereby sealing the inner volume to collect the evolved gases for analysis. Owing to the very low g forces on an asteroid compared to Mars or the moon, the sample must be moved from inlet to crucible by mechanical means rather than by gravity. As the soil sample is heated through a programmed pattern, the gases evolved at each temperature are passed through a transfer tube to the mass spectrometer for analysis and identification. Return data from the instrument will lead to new insights and discoveries including: (1) Identification of the molecular masses of all of the gases liberated from heated soil samples; (2) Identification of the asteroid soil mineralogy to aid in the selection process for returned samples; (3) Existence of oxygen in the asteroid soil and the potential for in-situ resource utilization (ISRU); and (4) Existence of water and other volatiles in the asteroid soil. Additional information is contained in the original extended abstract.

Hoffman, John H.↗

Cryogenic Curation: Isolated Technology and Mission Operational Requirements for Sample Return

Future lunar, Mars, asteroid, and comet sample return missions may collect samples that have been preserved at sub-freezing or even cryogenic temperatures. For such samples, the study of volatiles and temperature-sensitive minerals will have high priority. Valuable geochemical and mineralogical information will be lost if such samples are allowed to reach ambient temperatures on Earth. The ability to store, document, subdivide, and transport extraterrestrial geologic samples while maintaining sub-freezing or cryogenic temperatures, possibly as low as 40 K, is required for the complete scientific study of samples from cold environments.

Calaway, Michael J.↗

Assessment of Cryogenic Analog Electronics for Lunar Environment

Assessment of Analog Electronics for Lunar Power Hibernation Non-nuclear robotic spacecraft on the Moon may not reliably operate past the first lunar day due to the subsequent long lunar night with an extreme low temperature range of 50K-100K. To address this concern, the NASA Glenn Research Center is developing a lunar power hibernation protocol that could enable spacecraft to passively survive the lunar night without any additional heating source and then reactivate at lunar dawn. Low cost lunar robotic missions could extend their mission lifetime from a single lunar cycle to potentially many months, thus greatly extending science data gathering and return on investment for commercial missions. This approach centers on evidence that lithium-ion battery cells can recover to full operation after being subjected to cryogenic temperatures. Exploiting this battery capability requires that all spacecraft electronics, including power system and avionics, passively tolerate the extreme cold without degradation. Key elements in the power system will also need to be capable of actively operating in the extreme cold to perform the functions required to restore the system to full operation after solar power returns at lunar dawn. This presentation provides an assessment of extreme-cold tolerance and operational capability of analog electronics where choices in semiconductor material, device type, and circuit fabrication technology has a dramatic impact on circuit behavior and reliability at low temperatures.

Lunar↗

Alternatives to the Maroni Process for Tritium Recovery in Fusion Reactors: Avoiding Volatile Hydrogen Fluoride and High-Temperature High-Speed Rotating Machinery

Fusion reactors now on the drawing table, including LLNL’s LIFE reactor, require liquid lithium blankets for cooling and breeding tritium fuel. The tritium fuel must be continuously removed from the blanket so that it can be returned to the reactor for burning, via target manufacturing in the case of LIFE. The baseline process for accomplishing this in the LIFE reactor is the well-known Maroni process which uses high-temperature molten mixed alkali-metal halide salts (LiCl:LiF:LiBr at 530°C) as an extraction solvent. With the generation of hydrogen isotopes, liquid and gaseous acids such as HCl, HF and HBr (and the deuterium and tritium analogs) form in the salt phase, making these solvents very corrosive, with other problems due to volatility. Following extraction of lithium tritide from the molten lithium, the tritide anion must undergo electrochemical oxidation in a high-temperature electrochemical cell to form tritium gas, which can then be separated by stripping in a stream of inert gas such as xenon or helium. The volatility of hydrogen chloride or the tritium analog (HCl or TCl), hydrogen fluoride or the tritium analog (HF or TF) and hydrogen bromide or the tritium analog (HBr or TBr) complicate this separation. An alternative electrolytic process for the conversion of lithium tritide to tritium gas and metallic lithium is based upon the use of a benign lithium hydroxide (LiOH) or lithium carbonate (Li 2 CO 3 ), which is an extremely attractive alternative to the very volatile and corrosive lithium halide electrolyte. The separation of the molten lithium and molten chloride salt phases requires numerous high-temperature (530°C) high-speed centrifugal separators, with bearings and seals exposed to the highly corrosive fluids. Currently, centrifugal contactors are proposed to contact the liquid lithium in which the tritium is bred with a molten salt extraction solvent. These high-speed centrifugal contactors must operate at high temperature for prolonged periods of time without failure. Such rotating machinery, with a highly corrosive molten salt electrolyte, and a liquid lithium phase threatening liquid metal embrittlement is a source of substantial concern. The invention disclosed here is a non-centrifugal contactor capable of operating without any moving parts.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Dark Material at the Surface of Polar Crater Deposits on Mercury

Earth-based radar measurements [1-3] have yielded images of radar-bright material at the poles of Mercury postulated to be near-surface water ice residing in cold traps on the permanently shadowed floors of polar impact craters. The Mercury Laser Altimeter (MLA) on board the MErcury Surface, Space ENvironment, GEochemistry, and Ranging (MESSENGER) spacecraft has now mapped much of the north polar region of Mercury [4] (Fig. 1). Radar-bright zones lie within polar craters or along poleward-facing scarps lying mainly in shadow. Calculations of illumination with respect to solid-body motion [5] show that at least 0.5% of the surface area north of 75deg N lies in permanent shadow, and that most such permanently shadowed regions (PSRs) coincide with radar-bright regions. MLA transmits a 1064-nm-wavelength laser pulse at 8 Hz, timing the leading and trailing edges of the return pulse. MLA can in some cases infer energy and thereby surface reflectance at the laser wavelength from the returned pulses. Surficial exposures of water ice would be optically brighter than the surroundings, but persistent surface water ice would require temperatures over all seasons to remain extremely low (<110 K). Thermal models [6,7] incorporating direct and scattered radiation, Mercury s eccentric orbit, 3:2 spin-orbit resonance, and near-zero obliquity generally do not support such conditions in all permanently shadowed craters but suggest that water ice buried near the surface (<0.5 m depth) could survive for > 1 Gy. We describe measurements of reflectivity derived from MLA pulse returns. These reflectivity data show that surface materials in the shadowed regions are darker than their surroundings, enough to strongly attenuate or extinguish laser returns. Such measurements appear to rule out widespread surface exposures of water ice. We consider explanations for the apparent low reflectivity of these regions involving other types of volatile deposit.

Neumann, Gregory A.↗

Simultaneous fine structure observation of wind and temperature profiles by the Arecibo 430-MHz radar and in situ measurements

A simultaneous campaign of balloon and radar measurements took place on March 14 to 16, 1984, above the Arecibo 430-MHz radar. This radar was operating with a vertical resolution of 150 m following two antenna beam directions: 15 deg. from the zenith, respectively, in the N-S and E-W directions. The main results concerning the comparison between the flight and simultaneous radar measurements obtained on March 15, 1984 are analyzed. The radar return power profile (S/N ratio in dB) exhibits maxima which are generally well correlated with step-like structures in the potential temperature profile. These structures are generally considered as the consequence of the mixing processes induced by the turbulence. A good correlation appears in the altitude range 12.5 to 19 km between wind shears induced by a wave structure observed in the meridional wind and the radar echo power maxima. This wave structure is characterized by a vertical wavelength of about 2.5 km, and a period in the range 30 to 40 hours. These characteristics are deduced from the twice daily rawinsonde data launched from the San Juan Airport by the National Weather Service. These results pointed out an example of the interaction between wave and turbulence in the upper troposphere and lower stratosphere. Turbulent layers are observed at locations where wind shears related to an internal inertia-gravity wave are maxima.

Thomas, D.↗

Re‐establishing the paradigm for evaluating halide salt compatibility to study commercial chloride salts at 600°C–800°C

Abstract Chloride salts are one candidate for a >700°C concentrating solar power (CSP) cycle, however, many reports from the literature suggest very high reaction rates between chloride salts and structural alloys. Historically, a specific methodology was established for evaluating halide salt compatibility based on solution kinetics. This study returned to that paradigm where the salts are purified and evaluated in sealed capsules before moving to a flowing experiment to determine a true corrosion rate in a temperature gradient for a commercial K–Mg–Na chloride salt. Isothermal testing focused on Ni‐based alloys 230 and 600 at 600°C–800°C. The results indicated there were promising combinations of salt chemistry, temperature, and alloy composition that reduce the extent of reaction. The results of the first monometallic thermal convection loop of alloy 600 run for 1,000 hr with a peak temperature of 700°C showed low attack with rates ≤9 µm/yr.

Pint, Bruce A.↗