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At least 469 records · Page 26

X-ray photoelectron spectroscopic study of surface chemistry of dibenzyl disulfide on steel under mild and severe wear conditions

X-ray photoelectron spectroscopy was used to characterize the chemical composition of 304 stainless steel surfaces run in oil containing dibenzyl disulfide under both mild and severe wear conditions. In severe wear a sulfide was formed at the expense of the normal oxide. This was due to either chemical attack on the oxide or reaction with clean metal exposed by the wear process. In the mild wear scars there was no evidence of either sulfide or mercaptide. The oxide, however, was approximately twice as thick as the normal oxide on an unworn surface. The change in surface chemistry was primarily a function of wear rate rather than load.

Wheeler, D. R.↗

Applications of thermal energy storage to process heat and waste heat recovery in the iron and steel industry

The system identified operates from the primary arc furnace evacuation system as a heat source. Energy from the fume stream is stored as sensible energy in a solid medium (packed bed). A steam-driven turbine is arranged to generate power for peak shaving. A parametric design approach is presented since the overall system design, at optimum payback is strongly dependent upon the nature of the electric pricing structure. The scope of the project was limited to consideration of available technology so that industry-wide application could be achieved by 1985. A search of the literature, coupled with interviews with representatives of major steel producers, served as the means whereby the techniques and technologies indicated for the specific site are extrapolated to the industry as a whole and to the 1985 time frame. The conclusion of the study is that by 1985, a national yearly savings of 1.9 million barrels of oil could be realized through recovery of waste heat from primary arc furnace fume gases on an industry-wide basis. Economic studies indicate that the proposed system has a plant payback time of approximately 5 years.

Katter, L. B.↗

Automatic Welding of Stainless Steel Tubing

To determine if the use of automatic welding would allow reduction of the radiographic inspection requirement, and thereby reduce fabrication costs, a series of welding tests were performed. In these tests an automatic welder was used on stainless steel tubing of 1/2, 3/4, and 1/2 inch diameter size. The optimum parameters were investigated to determine how much variation from optimum in machine settings could be tolerate and still result in a good quality weld. The process variables studied were the welding amperes, the revolutions per minute as a function of the circumferential weld travel speed, and the shielding gas flow. The investigation showed that the close control of process variables in conjunction with a thorough visual inspection of welds can be relied upon as an acceptable quality assurance procedure, thus permitting the radiographic inspection to be reduced by a large percentage when using the automatic process.

Clautice, W. E.↗

Measurement of post-shock temperatures in aluminum and stainless steel

Until recently experimental measurements of post-impact temperatures have been obtained only for metals at high pressures. Our aim has been to develop a technique for measuring post-shock temperatures in a variety of materials, including metals and silicates, at pressures in the range of 5 to 50 GPa, providing further insight into the shock process in these substances and additional constraints to available equation of state data. This paper describes the method we have developed, and its application to the determination of post-shock temperatures in aluminum-2024 and stainless steel-304.

Raikes, S. A.↗

Design, fabrication, and test of a steel spar wind turbine blade

The design and fabrication of wind turbine blades based on 60 foot steel spars are discussed. Performance and blade load information is given and compared to analytical prediction. In addition, performance is compared to that of the original MOD-O aluminum blades. Costs for building the two blades are given, and a projection is made for the cost in mass production. Design improvements to reduce weight and improve fatigue life are suggested.

Sullivan, T. L.↗

Design study of steel V-Belt CVT for electric vehicles

A continuously variable transmission (CVT) design layout was completed. The intended application was for coupling the flywheel to the driveline of a flywheel battery hybrid electric vehicle. The requirements were that the CVT accommodate flywheel speeds from 14,000 to 28,000 rpm and driveline speeds of 850 to 5000 rpm without slipping. Below 850 rpm a slipping clutch was used between the CVT and the driveline. The CVT was required to accommodate 330 ft-lb maximum torque and 100 hp maximum transient. The weighted average power was 22 hp, the maximum allowable full range shift time was 2 seconds and the required lift was 2600 hours. The resulting design utilized two steel V-belts in series to accommodate the required wide speed ratio. The size of the CVT, including the slipping clutch, was 20.6 inches long, 9.8 inches high and 13.8 inches wide. The estimated weight was 155 lb. An overall potential efficiency of 95 percent was projected for the average power condition.

Swain, J. C.↗

Performance of a steel spar wind turbine blade on the Mod-0 100 kW experimental wind turbine

The performance and loading of a large wind rotor, 38.4 m in diameter and composed of two low-cost steel spar blades were examined. Two blades were fabricated at Lewis Research Center and successfully operated on the Mod-0 wind turbine at Plum Brook. The blades were operated on a tower on which the natural bending frequency were altered by placing the tower on a leaf-spring apparatus. It was found that neither blade performance nor loading were affected significantly by this tower softening technique. Rotor performance exceeded prediction while blade loads were found to be in reasonable agreement with those predicted. Seventy-five hours of operation over a five month period resulted in no deterioration in the blade.

Keith, T. G., Jr.↗

Burning rate for steel-cased, pressed binderless HMX

The burning behavior of pressed binderless HMX laterally confined in 6.4 mm i.d. steel cases was measured over the pressure range 1.45 to 338 MPa in a constant pressure strand burner. The measured regression rates are compared to those reported previously for unconfined samples. It is shown that lateral confinement results in a several-fold decrease in the regression rate for the coarse particle size HMX above the transition to super fast regression. For class E samples, confinement shifts the transition to super fast regression from low pressure to high pressure. These results are interpreted in terms of the previously proposed progressive deconsolidation mechanism. Preliminary holographic photography and closed bomb tests are also described. Theoretical one dimensional modeling calculations were carried out to predict the expected flame height (particle burn out distance) as a function of particle size and pressure for binderless HMX burning by a progressive deconsolidation mechanism.

Fifer, R. A.↗

Corrosion of 310 stainless steel in H2-H2O-H2S gas mixtures: Studies at constant temperature and fixed oxygen potential

Corrosion of SAE 310 stainless steel in H2-H2O-H2S gas mixtures was studied at a constant temperature of 1150 K. Reactive gas mixtures were chosen to yield a constant oxygen potential of approximately 6 x 10 to the minus 13th power/cu Nm and sulfur potentials ranging from 0.19 x 10 to the minus 2nd power/cu Nm to 33 x 10 to the minus 2nd power/cu Nm. The kinetics of corrosion were determined using a thermobalance, and the scales were analyzed using metallography, scanning electron microscopy, and energy dispersive X-ray analysis. Two corrosion regimes, which were dependent on sulfur potential, were identified. At high sulfur potentials (p sub S sub 2 less than or equal to 2.7 x 10 to the minus 2nd power/cu Nm) the corrosion rates were high, the kinetics obeyed a linear rate equation, and the scales consisted mainly of sulfide phases similar to those observed from pure sulfication. At low sulfur potentials (P sub S sub 2 less than or equal to 0.19 x 10 to the minus 2nd power/cu Nm) the corrosion rates were low, the kinetics obeyed a parabolic rate equation, and scales consisted mainly of oxide phases.

Rao, D. B.↗

Passivation of carbon steel through mercury implantation

An experiment, in which carbon steel samples were implanted with mercury ions from a broad beam ion source and their corrosion characteristics in air were evaluated, is described. Mercury doses of a few mA min/square cm at energies of a few hundred electron volts are shown to effect significant improvements in the corrosion resistance of the treated surfaces. In a warm moist environment the onset of rusting was extended from 15 min. for an untreated sample to approximately 30 hrs. for one implanted at a dose of 33 mA min/square cm with 1000 eV mercury ions.

Wilbur, P. J.↗

Contact angle measurements of a polyphenyl ether to 190 C on M-50 steel

Contact angle measurements were performed for a polyphenyl ether on steel in nitrogen. A tilting plate and a sessile drop apparatus were used. Surface tension was measured with a maximum bubble pressure apparatus. Critical surface energies of spreading were found to be 30.1 and 31.3 dynes/cm. It was concluded that the polyphenyl ether is inherently autophobic and will not spread on its own surface film.

Jones, W. R., Jr.↗

The Structure and Properties of Diffusion Assisted Bonded Joints in 17-4 PH, Type 347, 15-5 PH and Nitronic 40 Stainless Steels

Diffusion assisted bonds are formed in 17-4 PH, 15-5 PH, type 347 and Nitronic 40 stainless steels using electrodeposited copper as the bonding agent. The bonds are analyzed by conventional metallographic, electron microprobe analysis, and scanning electron microscopic techniques as well as Charpy V-notch impact tests at temperatures of 77 and 300 K. Results are discussed in terms of a postulated model for the bonding process.

Wigley, D. A.↗

Thermal fatigue behavior of H-13 die steel for aluminum die casting with various ion sputtered coatings

Sputtered coatings of Mo, W, Pt, Ag, Au, Co, Cr, Ni, Ag + Cu, Mo + Pt, Si3N4, A1N, Cr3C2, Ta5Si3, and ZrO2 were applied to a 2-inch-square, 7-inch-long thermal fatigue test specimen which was then internally water cooled and alternately immersed in molten aluminum and cooled in air. After 15,000 cycles the thermal fatigue cracks at the specimen corners were measured. Results indicate that a significant improvement in thermal fatigue resistance was obtained with platinum, molybdenum, and tungsten coatings. Metallographic examination indicates that the improvement in thermal fatigue resistance resulted from protection of the surface of the die steel from oxidation. The high yield strength and ductility of molybdenum and tungsten contributed to the better thermal fatigue resistance.

Nieh, C. Y.↗

Adherence of ion beam sputter deposited metal films on H-13 steel

An electron bombardment argon ion source sputter deposited 17 metals and metal oxides on H-13 steel. The films ranged 1 to 8 micrometers in thickness and their adherence was generally greater than the capacity of the measuring device; adherence quality depended on proper precleaning of the substrate before deposition. N2 or air was introduced for correct stoichiometry in metallic compounds. Au, Ag, MgO, and Ta5Si3 films 8 microns thick have bond strength equal to 1 micron coatings; the bond strength of pure metallic films up to 5 microns thick was greater than the epoxy to film bond (8000 psi). The results of exposures of coated material to temperatures up to 700 C are presented.

Mirtich, M. J.↗

Investigation of Effectiveness of Air-Heating a Hollow Steel Propeller for Protection Against Icing. 1: Unpartitioned Blades

An investigation to determine the effectiveness of icing protection afforded by air-heating hollow steel unpartitioned propeller blades has been conducted In the NACA Cleveland icing research tunnel. The propeller used was a production model modified with blade shank and tip openings to permit internal passage of heated air. Blade-surface and heated-air temperatures were obtained and photographic observations of Ice formations were made with variations In icing intensity and heating rate to the blades. For the conditions of Icing to which the propeller was subjected, it was found that adequate ice protection was afforded with a heating rate of 40 1 000 Btu per hour per blade. With less than 40,000 Btu per hour per blade, ice protection failed because of significant ice accretions on the leading edge. The chordwise distribution of heat was unsatisfactory with most of the available heat dissipated well back of the leading edge on both the thrust and camber face's instead of at the leading edge where it was most needed. A low utilization of available heat for icing protection is indicated by a beat-exchanger effectiveness of approximately 47 percent.

Mulholland, Donald R.↗

Investigation of Effectiveness of Air-Heating a Hollow Steel Propeller for Protection Against Icing. 2: 50% Impartitioned Blades

The icing protection afforded an internal air-heated propeller blade by radial partitioning at 50-percent chord to confine the heated air to the forward half of the blade was determined in the NACA Cleveland icing research tunnel. A modified production-model hollow steel propeller, was used for the investigation. Temperatures of the blade surfaces for several heating rates were measured under various tunnel Icing' conditions. Photographic observations of ice formations on blade surfaces and blade heat-exchanger effectiveness were obtained. With 50-percent partitioning of the blades, adequate icing protection at 1050 rpm was obtained with a heating rate of 26,000 Btu per hour per blade at the blade shank using an air temperature of 400 F with a flow rate of 280 pounds per hour per blade, which is one-third less heat than was found necessary for similar Ice protection with unpartitioned blades. The chordwise distribution of the applied heat, as determined by surface temperature measurements, was considered unsatisfactory with much of the heat dissipated well back of the leading edge. Heat-exchanger effectiveness of approximately 56 percent also Indicated poor utilization of available heat. This effectiveness was, however, 9 percent greater than that obtained from unpartitioned blades.

Perkins, Porter J.↗

Investigation of Effectiveness of Air-Heating a Hollow Steel Propeller for Protection Against Icing. 3: 25% Partitioned Blades

The icing protection obtained from an internally air-heated propeller blade partitioned to confine the heated air forward of 25-percent chord was investigated in the NACA Cleveland icing research tunnel. A production-model hollow steel propeller was modified with an Internal radial partition at 25-percent chord and with shank and tip openings to admit and exhaust the heated air. Temperatures were measured on the blade surfaces and in the heated-air system during tunnel icing conditions. Heat-exchanger effectiveness and photographs of Ice formations on the blades were obtained. Surface temperature measurements indicated that confining the heated air forward of the 25-percent chord gave.a more economical distribution of the applied heat as compared with unpartitioned and 50-percent partitioned blades, by dissipating a greater percentage of the available heat at the leading edge. At a propeller speed of 850 rpm, a heating rate of 7000 Btu per hour per blade at a shank air temperature of 400 F provided adequate Icing protection at ambient-air temperatures of 23 F but not at temperatures as low as 15 F. With the heating rate used, a heat-exchanger effectiveness of 77 percent was obtained as compared to 56 percent for 50-percent partitioned and 47 percent for unpartitioned blades.

Mulholland, Donald R.↗

An Investigation Utilizing an Electrical Analogue of Cyclic Deicing of a Hollow Steel Propeller with an External Blade Shoe

A study has been made of the heat requirement for the cyclic de-icing of hollow steel propellers fitted with external blade heating shoes. Solutions to the equations for the heat flow in cyclic heating of propellers were obtained, using an electrical analogy. The study showed how the energy requirement for propeller de-icing with existing blade shoes could be decreased, and illustrated the effect of blade-shoe design on the energy requirement. It was demonstrated, for example, that by increasing the heating intensity and decreasing the heating period from those currently used the energy requirement could be decreased in the order of 60 percent. ' In addition, ft was shown that heating requirements could be decreased further, by as much as 60 percent, through proper design of the shoes. The' investigation also showed the energy requirement to increase with decreasing liquid-water content and air temperature. Uncertainties as to the exact values of convective heat-transfer coefficient prevailing over the surface of the blade and ice layer resulted in uncertainties of approximately proportional magnitude in the values of required heating intensity.

Neel, Carr B., Jr.↗