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NASA NTRS2001

Star Formation in the Galaxy and the Fluctuating UV Radiation Field

We examine the formation of massive stars in the Galaxy, the resultant fluctuating UV radiation field, and the effect of this field on the star-forming interstellar medium (ISM). There are substantial fluctuations of the UV radiation field in space (scales of 100's of parsecs) and time (time-scales of order 100 million years) at the solar circle. The Far Ultraviolet (FUV) (6 eV< hv < 13.6 eV) field and the pressure determines whether the thermal balance of the neutral gas results in cold clouds or warm (T - 10(exp 4) neutral medium. We show how to calculate the average fractions of the gas in the cold and warm phases when the interstellar gas is subject to this fluctuating FUV field. The knowledge of how these fractions depend on the gas properties and on the FUV sources is a basic step in building a model of the large scale behavior of the ISM and the mutual relation between the ISM and the star formation rate. Application is made to observations of spiral galaxies which correlate the star formation rate per unit area with the surface density of the gas. We acknowledge support from the NASA Astrophysical Theory program.

Hollenbach, David↗
NASA NTRS2002

Star Formation In the Galaxy and the Fluctuating UV Radiation Field

We examine the formation of massive stars in the Galaxy, the resultant fluctuating UV (ultraviolet) radiation field, and the effect of this field on the star-forming interstellar medium. There are substantial fluctuations of the UV radiation field in space (scales of 100's of parsecs) and time (time-scales of order 100 million years). The FUV (far ultraviolet) (6 eV less than hv less than 13.6 eV) field and the pressure determines whether the thermal balance of the neutral gas results in cold clouds or warm (T approx. 10(exp 4) K) neutral medium. We show how to calculate the average fractions of the gas in the cold and warm phases when the interstellar gas is subject to this fluctuating FUV field. The knowledge of how these fractions depend on the gas properties and on the FUV sources is a basic step in building a model of the large scale behavior of the ISM (interstellar medium) and the mutual relation between the ISM and the star formation rate.

Hollenbach, David↗
NASA NTRS2002

UV and Optical Detectors: Status and Prospects

UV and visible detectors - status and prospects. The status and prospects for UV and visible detectors for space astrophysics missions will be described, based on the findings of the NASA working group roadmap report, hopefully updated.

Woodgate, Bruce↗
NASA NTRS2002

Prominence Motions in the EUV and UV

We address the origin of prominence material by comparing high cadence (30-60 s) He I and O V EUV observations from SOHO/CDS wide slit movies, and also, for another prominence observation, observations from TRACE at 1216 A and 1600 A and SVST in H(alpha). The EUV and UV observations regularly show small scale structures with plane-of-the sky velocities of 20-80 km/s, and many, although not all, of these motions are seen in multiple wavelength bands, representing temperatures ranging from 10,000-100,000 K or 20,000 - 250,000 K, depending on the data set. The H(alpha) observations contain line shift information showing clearly that the UV prominence intensity motions do actually represent real mass motions, as opposed to temperature or density waves. The results also indicate that the "prominence-corona transition region" is not an outside layer to the prominence as a whole, but is rather associated with smaller scale structures all through the prominence. More work is needed to determine what mechanism can explain these fast, multi-temperature prominence motions.

Kucera, Therese A.↗
NASA NTRS2003

Laboratory Studies in UV and EUV Solar Physics

The Ion Beam Experiment at the Center for Astrophysics is dedicated to the study of ion-electron collision processes of importance in solar physics. A paper describing our most recent measurement 'Absolute cross section for Si(2+)(3s3p(sup 3)Rho (sup 0) yields 3s3p(sup 1)Rho(sup 0)) electron-impact excitation' was published during the past year. Dr. Paul Janzen received his PhD. from the Harvard Physics Department on the basis of this and other work, such as the new electron cyclotron resonance (ECR) ion source. The ion source is producing stable beams with large currents for our present work on C(2+), and it also produces stable beams with large currents of more highly charged systems, for future work on systems such as O(4+). The past year has been focussed on our current program to measure absolute cross sections for Electron Impact Excitation (EIE) in C(2+), one of the primary ions used for probing the solar transition region. C(2+) beams produced by the ion source have been transported to the interaction region of the experiment, where the collisions are studied, and Visiting Scientist Dr. Adrian Daw is currently collecting data to measure the C(2+)(2s2p(sup 3)Rho(sup 0) yields 2p(sup 2)(sup 3)Rho) EIE cross section as a function of collision energy, under the guidance of Drs. John Kohl, Larry Gardner and Bill Parkinson. Also this year, modifications were made to the ECR ion source in order to produce greater currents of highly charged ions. Testing of the ion source was completed. Modifications were designed to extend the photon detection capabilities of the apparatus to shorter UV wavelengths, or EUV. Following the work on C(2+)(2s2p(sup 3)Pho(sup 0) yields 2p(sup 2)(sup 3)Rho), the extended UV detection capabilities will be used to measure the C(2+)(2s(sup 2)(sup 1)S yields 2s2p(sup 1)Rho(sup 0)) EIE cross section. The EUV modifications complement those of the new ion source, by enabling detection of EUV light generated by high charge state ions and putting us in a position to measure the excitation cross sections for more highly charged ions as well.

Parkinson, William↗
NASA NTRS2004

UV Studies of Jupiter's Aerosols and Hydrocarbons

This project funded research related to our involvement in the Galileo Ultraviolet Spectrometer experiment. Pryor was a Co-I on that experiment, which recently ended when Galileo crashed into Jupiter's atmosphere. It also funded related research on HST observations of Jupiter's atmosphere, and Cassini observations of Jupiter's atmosphere, and ground-based studies of Jupiter's atmosphere using the facilities of McDonald Observatory. Specific activities related to this grant include study of UV spectra returned by Galileo UVS and Cassini UVIS, development of simple models to explain these spectra, participation in archiving activities for these data sets, travel to conferences, and publication of scientific papers. Highlights of our Jupiter research efforts include: 1.) evidence for heavy hydrocarbons in Jupiter's atmosphere (from HST) (Clarke et al. poster), that may be the source of Jupiter's stratospheric aerosols, 2.) detection of auroral flares in Jupiter's atmosphere from Galileo (Pryor et al., 2001). 3.) establishing a connection between coronal mass ejections and auroral outbursts (Gurnett et al., 2002), and 4) establishing a connection between short-term variations in Jupiter's auroral emissions and radio emissions (Pryor et al. presented at AGU in 2002, paper in preparation).

Pryor, Wayne↗
NASA NTRS2004

Lunar and Planetary Science XXXV: Astrobiology Stew: Pinch of Microbes, Smidgen of UV, Touch of Organics, and Dash of Meteorites

The session Astrobiology Stew: Pinch of Microbes, Smidgen of UV, Touch of Organics, and Dash of Meteorites includes the following topics: 1) Investigating the Impact of UV Radiation on High-Altitude Shallow Lake Habitats, Life Diversity, and Life Survival Strategies: Clues for Mars' Past Habitability Potential? 2) An Analysis of Potential Photosynthetic Life on Mars; 3) Radiation Inactivation of Bacterial spores on Mars; 4) Hydrophobic Surfaces of Spacecraft Components Enhance the Aggregation of Microorganisms and May Lead to Higher Survival Rates of Bacteria on Mars Landers; 5) Optical Detection of Organic Chemical Biosignatures at Hydrothermal Vents; 6) Signs of Life in Meridiani Planum-What Might Opportunity See (or Miss)? 7) Isolation of PUrines and Pyrimidines from the Murchison Meteorite Using Sublimation; and 8) Relative Amino Acid Composition of CM1 Carbonaceous Chondrites.

Source record↗
NASA NTRS2004

Atomic Oxygen Durability Evaluation of a UV Curable Ceramer Protective Coating

The exposure of most silicones to atomic oxygen in low Earth orbit (LEO) results in the oxidative loss of methyl groups with a gradual conversion to oxides of silicon. Typically there is surface shrinkage of oxidized silicone protective coatings which leads to cracking of the partially oxidized brittle surface. Such cracks widen and branch crack with continued atomic oxygen exposure ultimately allowing atomic oxygen to reach any hydrocarbon polymers under the silicone coating. A need exists for a paintable silicone coating that is free from such surface cracking and can be effectively used for protection of polymers and composites in LEO. A new type of silicone based protective coating holding such potential was evaluated for atomic oxygen durability in an RF atomic oxygen plasma exposure facility. The coating consisted of a UV curable inorganic/organic hybrid coating, known as a ceramer, which was fabricated using a methyl substituted polysiloxane binder and nanophase silicon-oxo-clusters derived from sol-gel precursors. The polysiloxane was functionalized with a cycloaliphatic epoxide in order to be cured at ambient temperature via a cationic UV induced curing mechanism. Alkoxy silane groups were also grafted onto the polysiloxane chain, through hydrosilation, in order to form a network with the incorporated silicon-oxo-clusters. The prepared polymer was characterized by H-1 and Si-29 NMR, FT-IR, and electrospray ionization mass spectroscopy. The paper will present the results of atomic oxygen protection ability of thin ceramer coatings on Kapton H as evaluated over a range of atomic oxygen fluence levels.

Banks, Bruce A.↗
NASA NTRS2003

An Expanded UV Irradiance Database from TOMS Including the Effects of Ozone, Clouds, and Aerosol Attenuation

The TOMS UV irradiance database (1978 to 2003) has been expanded to include five new products (noon irradiance at 305,310,324, and 380 nm, and noon erythemal-weighted irradiance), in addition to the existing erythemal daily exposure, that permit direct comparisons with ground-based measurements from spectrometers and broadband instruments. The new data are available on http://toms.gsfc.nasa.gov/>http://toms.gsfc.nasa.gov. Comparisons of the TOMS estimated irradiances with ground-based instruments are given along with a review of the sources of known errors, especially the recent improvements in accounting for aerosol attenuation. Trend estimations from the new TOMS irradiances permit the clear separation of changes caused by ozone and those caused by aerosols and clouds. Systematic differences in cloud cover are shown to be the most important factor in determining regional differences in UV radiation reaching the ground for locations at the same latitude (e.g., the summertime differences between Australia and the US southwest).

Herman, J.↗
NASA NTRS2005

Wavelengths, f-Values, and Cross Sections in the UV Spectra of Astrophysical, Atoms, Ions, and Molecules

Data analysis for Fe III was completed in 2004. The new spectra give wavelengths and some energy levels for Fe III that are at least an order of magnitude more accurate than values in the literature. However, the data set is missing - because they are outside the wavelength range that we can study at Imperial College or with ancillary FT spectroscopy measurements at NIST - important transitions that would allow all energy levels to be determined with improved accuracy. We are assessing collaborations at other labs. We have made test runs with a number of cathodes (pure metals and alloys) in the Penning discharge source and selected four iron group (3d) elements, Cr, Mn, Co, and Ni, for further measurements. Cathodes of pure Cr and Co and an alloy of Ni were found to be best. Mn has not nm stably yet, and other cathode geometries or alloys may need to be assessed. Optimum Penning discharge (PD) lamp conditions (buffer gas, gas pressure, and current/voltage) were established for Co, and investigations are underway for Cr and Ni. Definitive measurements for Co await purchase of new mirrors and photomultiplier tubes that will improve signal to noise ratio. Our plan for the next year is to continue evaluating cathodes and operating conditions through March 05, and then to begin definitive measurements. The UV wavelength measurements made at Imperial College with the unique UV FT spectrometer will be complemented by visible and near IR range measurements at NIST in June and/or July. Approximately one year from now, we intend to visit Lund University to collaborate on lifetime measurements that will allow our branching ration data to be used to determine f-values.

Raymond, John C.↗
NASA NTRS2005

APPARATUS AND METHOD FOR TREATING POLLUTANTS IN A GAS USING HYDROGEN PEROXIDE AND UV LIGHT

An apparatus for treating pollutants in a gas may include a source of hydrogen peroxide, and a treatment injector for creating and injecting dissociated hydrogen peroxide into the flow of gas. The treatment injector may further include an injector housing having an inlet, an outlet, and a hollow interior extending there between. The inlet may be connected in fluid communication with the source of hydrogen peroxide so that hydrogen peroxide flows through the hollow interior and toward the outlet. At least one ultraviolet (UV) lamp may be positioned within the hollow interior of the injector housing. The at least one UV lamp may dissociate the hydrogen peroxide flowing through the tube. The dissociated hydrogen peroxide may be injected into the flow of gas from the outlet for treating pollutants, such as nitrogen oxides.

Cooper, Charles David↗
NASA NTRS1995

Comparison of the Changes in the Visible and Infrared Irradiance Observed by the SunPhotometers on EURECA to the UARS Total Solar and UV Irradiances

Solar irradiance in the near-UV (335 nm), visible (500 nm) and infrared (778 nm) spectral bands has been measured by the SunPhotometers developed at the World Radiation Center, Davos, Switzerland on board the European Retrievable Carrier between August 1992 and May 1993. Study of the variations in the visible and infrared irradiance is important for both solar and atmospheric physics. The purpose of this paper is to examine the temporal variations observed in the visible and infrared spectral bands after eliminating the trend in the data mainly related to instrument degradation. The effect of active regions in these spectral irradiances is clearly resolved. Variations in the visible and infrared irradiances are compared to total solar irradiance observed by the SOVA2 radiometer on the EURECA platform and by the ACRIMII radiometer on UARS as well as to UV observations of the UARS and NOAA9 satellites. The space-borne spectral irradiance observations are compared to the photometric sunspot deficit and CaII K irradiance measured at the San Fernando Observatory, California State University at Northridge in order to study the effect of active regions in detail.

EURECA UARS↗
NASA NTRS2006

Extragalactic Backgrounds in the Far UV and Exploring Star Formation at High Redshifts with Gamma-ray Observations

The determination of the intergalactic photon densities from the FIR to the UV which is produced by stellar emission and dust reradiation at various redshifts can provide an independent measure of the star formation history of the universe. Using recent Spitzer and GALEX data in conjunction with other observational inputs, Stecker, Malkan and Scully have calculated the intergalactic photon density as a function of both energy and redshift for 0 < zeta < 6 for photon energies from 0.003 eV to the Lyman limit cutoff at 13.6 eV in a ACDM universe with Omega(sub Lambda) = 0.7 and Omega(sub m) = 0.3. Their results are based on backwards evolution models for galaxies which were developed by Malkan and Stecker previously. The calculated background SEDs at zeta = 0 are in good agreement with the present observational data and limits. The calculated intergalactic photon densities as a function of redshift were used to predict to extend the absorption of high energy 7-rays in intergalactic space from sources such as blazars and quasars, this absorption being produced by interactions the y-rays with the intergalactic FIR-UV photons having the calculated densities. The results are in excellent agreement with absorption features found in the low gamma-ray spectra of Mkn 421, Mkn 501 at, zeta = 0.03 and PKS

Stecker, Floyd W.↗
NASA NTRS2007

Constraining Galaxy Evolution Using Observed UV-Optical Spectra

Our understanding of galaxy evolution depends on model spectra of stellar populations, and the models are only as good as the observed spectra and stellar parameters that go into them. We are therefore evaluating modem UV-optical model spectra using Hubble's Next Generation Spectral Library (NGSL) as the reference standard. The NGSL comprises intermediate-resolution (R is approximately 1000) STIS spectra of 378 stars having a wide range in metallicity and age. Unique features of the NGSL include its broad wavelength coverage (1,800-10,100 A) and high-S/N, absolute spectrophotometry. We will report on a systematic comparison of model and observed UV-blue spectra, describe where on the HR diagram significant differences occur, and comment on current approaches to correct the models for these differences.

Heap, Sally↗
NASA NTRS2005

Apparatus and method for treating pollutants in a gas using hydrogen peroxide and UV light

An apparatus for treating pollutants in a gas may include a source of hydrogen peroxide, and a treatment injector for creating and injecting dissociated hydrogen peroxide into the flow of gas. The treatment injector may further include an injector housing having an inlet, an outlet, and a hollow interior extending therebetween. The inlet may be connected in fluid communication with the source of hydrogen peroxide so that hydrogen peroxide flows through the hollow interior and toward the outlet. At least one ultraviolet (UV) lamp may be positioned within the hollow interior of the injector housing. The at least one UV lamp may dissociate the hydrogen peroxide flowing through the tube. The dissociated hydrogen peroxide may be injected into the flow of gas from the outlet for treating pollutants, such as nitrogen oxides.

Cooper, Charles David↗
NASA NTRS2008

The Dual Wavelength UV Transmitter Development for Space Based Ozone DIAL Measurements

The objective of this research is to develop efficient 1-micron to UV wavelength conversion technology to generate tunable, single mode, pulsed UV wavelengths of 320 nm and 308 nm. The 532 nm wavelength radiation is generated by a 1064 nm Nd:YAG laser through second harmonic generation. The 532 nm pumps an optical parametric oscillator (OPO) to generate 803 nm. The 320 nm is generated by sum frequency generation (SFG) of 532 nm and 803 nm wavelengths The hardware consists of a conductively cooled, 1 J/pulse, single mode Nd:YAG pump laser coupled to an efficient RISTRA OPO and SFG assembly-Both intra and extra-cavity approaches are examined for efficiency.

Prasad, Narasimha S.↗
NASA NTRS2008

Quantitative Studies of the Optical and UV Spectra of Galactic Early B Supergiants

We undertake an optical and ultraviolet spectroscopic analysis of a sample of 20 Galactic B0-B5 supergiants of luminosity classes Ia, Ib, Iab, and II. Fundamental stellar parameters are obtained from optical diagnostics and a critical comparison of the model predictions to observed UV spectral features is made. Methods. Fundamental parameters (e.g., T(sub eff), log L(sub *), mass-loss rates and CNO abundances) are derived for individual stars using CMFGEN, a nLTE, line-blanketed model atmosphere code. The impact of these newly derived parameters on the Galactic B supergiant Ten scale, mass discrepancy, and wind-momentum luminosity relation is examined. Results. The B supergiant temperature scale derived here shows a reduction of about 1000-3000 K compared to previous results using unblanketed codes. Mass-loss rate estimates are in good agreement with predicted theoretical values, and all of the 20 BO-B5 supergiants analysed show evidence of CNO processing. A mass discrepancy still exists between spectroscopic and evolutionary masses, with the largest discrepancy occuring at log (L/(solar)L approx. 5.4. The observed WLR values calculated for B0-B0.7 supergiants are higher than predicted values, whereas the reverse is true for B1-B5 supergiants. This means that the discrepancy between observed and theoretical values cannot be resolved by adopting clumped (i.e., lower) mass-loss rates as for O stars. The most surprising result is that, although CMFGEN succeeds in reproducing the optical stellar spectrum accurately, it fails to precisely reproduce key UV diagnostics, such as the N v and C IV P Cygni profiles. This problem arises because the models are not ionised enough and fail to reproduce the full extent of the observed absorption trough of the P Cygni profiles. Conclusions. Newly-derived fundamental parameters for early B supergiants are in good agreement with similar work in the field. The most significant discovery, however, is the failure of CMFGEN to predict the correct ionisation fraction for some ions. Such findings add further support to revising the current standard model of massive star winds, as our understanding of these winds is incomplete without a precise knowledge of the ionisation structure and distribution of clumping in the wind. Key words. techniques: spectroscopic - stars: mass-loss - stars: supergiants - stars: abundances - stars: atmospheres - stars: fundamental parameters

Searle, S. C.↗
NASA NTRS2008

Electrostatic Charging of Lunar Dust by UV Photoelectric Emissions and Solar Wind Electrons

The ubiquitous presence of dust in the lunar environment with its high adhesive characteristics has been recognized to be a major safety issue that must be addressed in view of its hazardous effects on robotic and human exploration of the Moon. The reported observations of a horizon glow and streamers at the lunar terminator during the Apollo missions are attributed to the sunlight scattered by the levitated lunar dust. The lunar surface and the dust grains are predominantly charged positively by the incident UV solar radiation on the dayside and negatively by the solar wind electrons on the night-side. The charged dust grains are levitated and transported over long distances by the established electric fields. A quantitative understanding of the lunar dust phenomena requires development of global dust distribution models, based on an accurate knowledge of lunar dust charging properties. Currently available data of lunar dust charging is based on bulk materials, although it is well recognized that measurements on individual dust grains are expected to be substantially different from the bulk measurements. In this paper we present laboratory measurements of charging properties of Apollo 11 & 17 dust grains by UV photoelectric emissions and by electron impact. These measurements indicate substantial differences of both qualitative and quantitative nature between dust charging properties of individual micron/submicron sized dust grains and of bulk materials. In addition, there are no viable theoretical models available as yet for calculation of dust charging properties of individual dust grains for both photoelectric emissions and electron impact. It is thus of paramount importance to conduct comprehensive measurements for charging properties of individual dust grains in order to develop realistic models of dust processes in the lunar atmosphere, and address the hazardous issues of dust on lunar robotic and human missions.

Abbas, Mian M.↗