Precipitable Water Vapor Variation in the Clear-Cloud Transition Zone From the ARM Shortwave Spectrometer
A new technique to retrieve precipitable water vapor (PWV)amount in the clear-cloud transition zone using ground-based zenith spectral radiance is developed. The method uses zenith radiances at the water vapor band at 720 nm and adjacent non-absorbing band at 750 nm.Radiative transfer calculations show that the relative difference in zenith radiance between the two bands depends on PWV and the variations in cloud optical depth introduce a small change in the relative difference which is independent of PWV amount. This allows us to retrieve PWV variations in the cloud-clear transition zone for clouds over dark ocean surface. We applied this method to a Cu cloud case with zenith radiance observations by the Shortwave Array Spectroradiometer-Zenith (SASZe) during the Marine ARM GPCI Investigation of Clouds (MAGIC) field campaign. We found that there is about 10% change in PWV amount from known-cloudy region to known-clear sky in cloud edges.