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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 469 records · Page 26

Study of excitation transfer in a flowing helium afterglow pumped with a tuneable dye laser. II - Measurement of the rate coefficient for the rotational relaxation of He2/3p 3Pi-g/.

The results of the use of a fast-transient fluorescence technique in the examination of rotational relaxation caused by collisions with neutral helium atoms are discussed. Details regarding the production and detection of reacting species are considered, together with the analytical method used. A dye laser system with 4-methylcoumarin producing a pumping flux in the 4650 A region was employed in the investigations.

Collins, C. B.↗

A flash photolysis-resonance fluorescence kinetics study of the reaction S/3P/ + OCS

Using the technique of flash photolysis-resonance fluorescence, the reaction of ground-state atomic sulfur with carbonyl sulfide has been investigated over the temperature range from 233 to 445 K. Over this temperature range, the experimental data were fitted to an Arrhenius equation of the form k sub 1 = (1.52 plus or minus 0.20) x 10 to the minus 12th power exp(-3.63 plus or minus 0.12 kcal/mol/RT) cu cm/molecule/sec. A comparison of these results with previous investigations on this reaction system is presented.

Klemm, R. B.↗

Development of an economical silicon solar cell

The growth of electronically viable silicon films on inexpensive foreign substrates is studied, with the objective of creating a technology to radically reduce the overall cost of the silicon employed in photovoltaic solar energy conversion. The approach employed is to enhance crystalline ordering during film nucleation by confining arriving silicon atoms to a narrow band traveling across a substrate, i.e., the Lateral Growth Technique (LGT). The efforts have employed physical vapor deposition of silicon in a vacuum evaporator on glass and metal substrates with both slit masks and single defining edges, and subsequent chemical vapor deposition (CVD) of thicker films on these thin film structures by pyrolysis of silane at higher temperatures.

Lindmayer, J.↗

The concertina hydrogen maser

A description is presented of a promising approach for measuring the wall shift in a hydrogen maser with a net uncertainty of one or two parts in 100 trillion. The hydrogen maser principles are briefly examined and the wall shift is discussed, taking into account the interaction of the atom with the wall, the wall shift relationship, and previous wall shift measurement techniques. The essential principles of a 'concertina' variable volume bulb maser are considered along with variable volume maser wall shift errors, design details, and the fabrication of the storage bulb.

Peters, H. E.↗

A temperature dependence kinetics study of the reactions of Cl/2-P-3/2/ with O3, CH4, and H2O2

The temperature dependence of two chlorine atom reactions of considerable fundamental importance to stratospheric chemistry was studied using the technique of flash photolysis-resonance fluorescence. The reactions of interest were: (1) Cl + O3 yields ClO + O2 studied at 220-350 K, and (2) Cl + CH4 yields CH3 + HCl studied at 218-401 K. In addition, the reaction Cl + H2O2 yields HCl + HO2 was studied at 300 K. The corresponding rate constants are provided for the three reactions. The new rate data implies the need to revise downward by a factor of 2.4-3 the magnitude of the ozone perturbation due to the presence of ClO/x/ species in the stratosphere, predicted by earlier model calculations.

Watson, R.↗

Studies of volatiles in Apollo 17 samples and their implication to vapor transport processes

Flameless atomic absorption (FLAA), X-ray photoemission spectroscopy (XPS) and grain size separation techniques were adopted to analyze Pb, Cd, Zn and S in orange and black droplets from Apollo 17 samples. The FLAA and XPS investigations show volatile trace metal enrichment in smaller grain fractions (broken droplets); thus a part of the volatiles was probably deposited after break-up of the droplets. In addition, redistribution of the volatiles by a cratering event is indicated by continuous decreases in Pb and Cd with core depth. Studies of Zn on individual regolith grains are also reported.

Cirlin, E. H.↗

Studies of laser and laser devices

The generation of tunable, infrared, and ultraviolet light, and the control of this light by mode-locking and modulation techniques are discussed. Particular emphasis is given to energy storage and extraction using atomic levels, the development of a tunable narrowband vacuum ultraviolet light source, and to the generation and applications of ultrashort optical pulses.

Harris, S. E.↗

Progress of the LASSO experiment

The LASSO (Later Synchronisation from Stationary Orbit) experiment, designed to demonstrate the feasibility of achieving time synchronization between remote atomic clocks with an accuracy of one nanosecond or better by using laser techniques for the first time is described. The experiment uses groundbased laser stations and the SIRIO-2 geostationary satellite to be launched towards the end of 1981. The qualification of the LASSO on-board equipment is discussed with a brief description of the electrical and optical test equipment used. The progress of the operational organization is included.

Serene, B. E. H.↗

Electron-photon coincidence technique for the absolute calibration of VUV detectors

A method is described whereby VUV photon detectors can be accurately calibrated. This method is illustrated by taking the 58.4-nm transition of He as an example. The technique consists of crossing a monoenergetic electron beam with a beam of He atoms. When inelastically scattered electrons which have excited the 2 1P state are detected in coincidence with the 58.4-nm photons emitted in the decay of the excited state, the interaction volume formed by the crossed beams constitutes a standard source of photons. By comparing the number of detected coincidences with the predicted number the calibration can be made. A total detector efficiency of 0.024 + or - 0.003 is obtained for a Galileo 4830 channeltron.

Mcadams, R.↗

Velocity mapping in a 30-kW arcjet plume using laser-induced fluorescence

A method for measuring the axial and transverse plume velocities and internal energy distributions in rarified thruster plumes by using pulsed laser-induced fluorescence (LIF) of atomic hydrogen Balmer lines is described. The results of an application of this technique for velocity mapping of a 30-kW ammonia arc-jet plume generated in the JPL arc-jet testing facility (which is uniquely suited for these measurements due to the end-on optical access provided by its ninety-degree-bent diffuser) are described. A schematic diagram of the JPL facility with LIF setup is included.

Pham-Van-diep, Gerald↗

Structural ceramics

This presentation gives a brief history of the field of materials sciences and goes on to expound the advantages of the fastest growing area in that field, namely ceramics. Since ceramics are moving to fill the demand for lighter, stronger, more corrosion resistant materials, advancements will rely more on processing and modeling from the atomic scale up which is made possible by advanced analytical, computer, and processing techniques. All information is presented in viewgraph format.

Craig, Douglas F.↗

Low earth simulation and materials characterization

Oxygen plasma ashers and an electron cyclotron resonance (ECR) sources are currently being used for low Earth orbit (LEO) simulation. The suitability of each of these simulation techniques is considered. Thin film coatings are characterized by optical techniques, including variable-angle spectroscopic ellipsometry, optical spectrophotometry, and laser light scatterometry. Atomic force microscopy (AFM) has been used to characterize the surface morphology of thin aluminum films as a function of substrate temperature during deposition. Results on diamondlike carbon (DLC) films show that DLC degrades with simulated atomic oxygen (AO) exposure at a rate comparable to Kapton polyimide. Since DLC is not as susceptible as Kapton to environmental factors such as moisture absorption, it could potentially provide more accurate measurements of AO fluence on short space flights.

Synowicki, R. A.↗

Transition probabilities for the 3s2 3p(2P0)-3s3p2(4P) intersystem lines of Si II

Intensity ratios of lines of the spin-changing 'intersystem' multiplet of S II (4P yields 2P0) at 234 nm have been used to determine electron densities and temperatures in a variety of astrophysical environments. However, the accuracy of these diagnostic calculations have been limited by uncertainties associated with the available atomic data. We report the first laboratory measurement, using an ion-trapping technique, of the radiative lifetimes of the three metastable levels of the 3s3p2 4P term of Si II. Our results are 104 +/- 16, 406 +/- 33, and 811 +/- 77 micro-s for lifetimes of the J = 1/2, 5/2, and 3/2 levels, respectively. A-values were derived from our lifetimes by use of measured branching fractions. Our A-values, which differ from calculated values by 30 percent or more, should give better agreement between modeled and observed Si II line ratios.

Calamai, Anthony G.↗

A Competitive Kinetics Study of the Reaction of Cl with CS2 in Air at 298 K

The relative rate technique has been used to investigate the kinetics of the reaction of Cl atoms with carbon disulfide, CS2, at 700 Torr total pressure of air at 298 K. The decay rate of CS2 was measured relative to CH4, CH3Cl and CHF2CL. For experiments using CH4 and CH3Cl references, the decay rate of CS2 was dependent on the ratio of the concentration of the reference to that of CS2. We ascribe this behavior to the generation of OH radicals in the system leading to complicated secondary chemistry. From experiments using CHF2Cl we are able to assign an upper limit of 4 x 10(exp -15) cu cm/(molecule s) for the overall reaction, Cl + CS2 yields products.

Wallington, Timothy J.↗

Infrared Spectroscopy of Star Formation in Galactic and Extragalactic Regions

In this program we proposed to perform a series of spectroscopic studies, including data analysis and modeling, of star formation regions using an ensemble of archival space-based data from the Infrared Space Observatory's Long Wavelength Spectrometer and Short Wavelength Spectrometer, and to take advantage of other spectroscopic databases including the first results from SIRTF. Our emphasis has been on star formation in external, bright IR galaxies, but other areas of research have included young, low or high mass pre-main sequence stars in star formation regions, and the galactic center. The OH lines in the far infrared were proposed as one key focus of this inquiry, because the Principal Investigator (H. Smith) had a full set of OH IR lines from IS0 observations. It was planned that during the proposed 2-1/2 year timeframe of the proposal other data (including perhaps from SIRTF) would become available, and we intended to be responsive to these and other such spectroscopic data sets. The program has the following goals: 1) Refine the data analysis of IS0 observations to obtain deeper and better SNR results on selected sources. The IS0 data itself underwent pipeline 10 reductions in early 2001, and the more 'hands-on data reduction packages' have been released. The IS0 Fabry-Perot database is particularly sensitive to noise and can have slight calibration errors, and improvements are anticipated. We plan to build on these deep analysis tools and contribute to their development. Model the atomic and molecular line shapes, in particular the OH lines, using revised montecarlo techniques developed by the Submillimeter Wave Astronomy Satellite (SWAS) team at the Center for Astrophysics. 2) 3) Use newly acquired space-based SIRTF or SOFIA spectroscopic data as they become available, and contribute to these observing programs as appropriate. 4) Attend scientific meetings and workshops. 5) E&PO activities, especially as related to infrared astrophysics and/or spectroscopy.

Smith, Howard A.↗

Dielectric constant of liquid alkanes and hydrocarbon mixtures

The complex dielectric constants of n-alkanes with two to seven carbon atoms have been measured. The measurements were conducted using a slotted-line technique at 1.2 GHz and at atmospheric pressure. The temperature was varied from the melting point to the boiling point of the respective alkanes. The real part of the dielectric constant was found to decrease with increasing temperature and correlate with the change in the molar volume. An upper limit to all the loss tangents was established at 0.001. The complex dielectric constants of a few mixtures of liquid alkanes were also measured at room temperature. For a pentane-octane mixture the real part of the dielectric constant could be explained by the Clausius-Mosotti theory. For the mixtures of n-hexane-ethylacetate and n-hexane-acetone the real part of the dielectric constants could be explained by the Onsager theory extended to mixtures. The dielectric constant of the n-hexane-acetone mixture displayed deviations from the Onsager theory at the highest fractions of acetone. The dipole moments of ethylacetate and acetone were determined for dilute mixtures using the Onsager theory and were found to be in agreement with their accepted gas-phase values. The loss tangents of the mixtures exhibited a linear relationship with the volume fraction for low concentrations of the polar liquids.

NASA Program Exobiology↗

NASA Tech Briefs, May 2008

Topics covered inclde: Deployable Wireless Camera Penetrators; Hand-Held Units for Short-Range Wireless Biotelemetry; Wearable Wireless Telemetry System for Implantable BioMEMS Sensors; Electronic Escape Trails for Firefighters; Architecture for a High-to-Medium-Voltage Power Converter; 24-Way Radial Power Combiner/Divider for 31 to 36 GHz; Three-Stage InP Submillimeter-Wave MMIC Amplifier; Fast Electromechanical Switches Based on Carbon Nanotubes; Solid-State High-Temperature Power Cells; Fast Offset Laser Phase-Locking System; Fabricating High-Resolution X-Ray Collimators; Embossed Teflon AF Laminate Membrane Microfluidic Diaphragm Valves; Flipperons for Improved Aerodynamic Performance; System Estimates Radius of Curvature of a Segmented Mirror; Refractory Ceramic Foams for Novel Applications; Self-Deploying Trusses Containing Shape-Memory Polymers; Fuel-Cell Electrolytes Based on Organosilica Hybrid Proton Conductors; Molecules for Fluorescence Detection of Specific Chemicals; Cell-Detection Technique for Automated Patch Clamping; Redesigned Human Metabolic Simulator; Compact, Highly Stable Ion Atomic Clock; LiGa(OTf)(sub 4) as an Electrolyte Salt for Li-Ion Cells; Compact Dielectric-Rod White-Light Delay Lines; Single-Mode WGM Resonators Fabricated by Diamond Turning; Mitigating Photon Jitter in Optical PPM Communication; MACOS Version 3.31; Fiber-Optic Determination of N2, O2, and Fuel Vapor in the Ullage of Liquid-Fuel Tanks; Spiking Neurons for Analysis of Patterns; Symmetric Phase-Only Filtering in Particle-Image Velocimetry; Efficient Coupler for a Bessel Beam Dispersive Element; and Attitude and Translation Control of a Solar Sail Vehicle.

Source record↗

A numerical model for atomization-spray coupling in liquid rocket thrust chambers

The physical process of atomization is an important consideration in the stable operation of liquid rocket engines. Many spray combustion computational fluid dynamics (CFD) codes do not include an atomization sub-model but assume arbitrary drop size distributions, drop initial locations, and velocities. A method of coupling an atomization model with the spray model in a REFLEQS CFD code is presented. This method is based on a jet-embedding technique in which the equations governing the liquid jet core are solved separately using the surrounding gas phase conditions. The droplet initial conditions are calculated using a stability analysis appropriate for the atomization regime of liquid jet break-up. This novel coupling model is used to analyze the SSME fuel preburner single injector flow. Results of the diffusion flame characteristics in a single injection element will be presented. The effect of relative velocity, mixture ratio and droplet initial conditions will be shown. The predictions of present atomization model is compared with that of the widely used CICM correlation. The results are also compared with the predictions of volume-of-fluid method.

M. G. Giridharan↗