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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 469 records · Page 26
All sourcesNASA NTRSDOE OSTI
NASA NTRS1990

Kinetics and transport at AMTEC electrodes. I - The interfacial impedance model

Mixed mass-transport and kinetic control of sodium ion reduction at porous inert electrodes on sodium beta-double-prime alumina solid electrolyte (BASE) ceramic in a high-temperature electrochemical cell has been observed and modeled. The high ionic conductivity of BASE and the reversibility of the liquid sodium/BASE anodic half-cell led to assignment of potential-dependent (nonohmic) resistances to kinetic and mass-transport processes associated with the porous electrode. The morphology of these electrodes and typical sodium gas pressures are consistent with Knudsen, or free-molecular, flow through the electrode.

Williams, R. M.↗
NASA NTRS1968

A note on the Kapitza resistance.

Kinetic theory model for heat transfer across liquid He 2 boundary in contact with metal, noting agreement with Kapitza thermal resistance theory

Abbe, W. J.↗
NASA NTRS1972

Structure of ion acoustic solitons and shock waves in a two-component plasma.

Time-independent solitary waves and shocks are investigated in a two-component plasma using a fluid model and kinetic theory. It is found that very small concentrations of a light ion can drastically alter the structure, changing the potential maximum by an order of magnitude. For a fixed Mach number, a critical density ratio of light to heavy ions is found at which the potential maximum changes discontinuously from a value large enough to reflect the light ions to one which allows them to traverse the shock front and enter the downstream flow. The downstream oscillatory structure normally seen in a shock is completely quenched by dissipation due to light ion reflection at concentrations of 3-8% He in an Ar plasma for typical electron to ion temperature ratios and Mach number values.

White, R. B.↗
NASA NTRS1976

Non-equilibrium radiation from viscous chemically reacting two-phase exhaust plumes

A knowledge of the structure of the rocket exhaust plumes is necessary to solve problems involving plume signatures, base heating, plume/surface interactions, etc. An algorithm is presented which treats the viscous flow of multiphase chemically reacting fluids in a two-dimensional or axisymmetric supersonic flow field. The gas-particle flow solution is fully coupled with the chemical kinetics calculated using an implicit scheme to calculate chemical production rates. Viscous effects include chemical species diffusion with the viscosity coefficient calculated using a two-equation turbulent kinetic energy model.

Penny, M. M.↗
NASA NTRS1979

Viscid/inviscid interaction analysis of thrust augmenting ejectors

A method was developed for calculating the static performance of thrust augmenting ejectors by matching a viscous solution for the flow through the ejector to an inviscid solution for the flow outside the ejector. A two dimensional analysis utilizing a turbulence kinetic energy model is used to calculate the rate of entrainment by the jets. Vortex panel methods are then used with the requirement that the ejector shroud must be a streamline of the flow induced by the jets to determine the strength of circulation generated around the shroud. In effect, the ejector shroud is considered to be flying in the velocity field of the jets. The solution is converged by iterating between the rate of entrainment and the strength of the circulation. This approach offers the advantage of including external influences on the flow through the ejector. Comparisons with data are presented for an ejector having a single central nozzle and Coanda jet on the walls. The accuracy of the matched solution is found to be especially sensitive to the jet flap effect of the flow just downstream of the ejector exit.

Bevilacqua, P. M.↗
NASA NTRS1981

Rate of reaction of OH with HNO3

Measurements of the kinetics of the reaction of OH with HNO3, and mechanisms of HNO3 removal from the stratosphere, are reported. Bimolecular rate constants were determined at temperatures between 224 and 366 K by monitoring the concentrations of OH radicals produced by HNO3 photolysis and HNO3 according to their resonance fluorescence and 184.9-nm absorption, respectively. The rate constant measured at 298 K is found to be somewhat faster than previously accepted values, with a negative temperature dependence. Calculations of a one-dimensional transport-kinetic atmospheric model on the basis of the new rate constant indicate reductions in O3 depletion due to chlorofluoromethane release and NOx injection, of magnitudes dependent on the nature of the reaction products.

Wine, P. H.↗
NASA NTRS1981

Fuel/oxidizer-rich high-pressure preburners

The analyses, designs, fabrication, and cold-flow acceptance testing of LOX/RP-1 preburner components required for a high-pressure staged-combustion rocket engine are discussed. Separate designs of injectors, combustion chambers, turbine simulators, and hot-gas mixing devices are provided for fuel-rich and oxidizer-rich operation. The fuel-rich design addresses the problem of non-equilibrium LOX/RP-1 combustion. The development and use of a pseudo-kinetic combustion model for predicting operating efficiency, physical properties of the combustion products, and the potential for generating solid carbon is presented. The oxygen-rich design addresses the design criteria for the prevention of metal ignition. This is accomplished by the selection of materials and the generation of well-mixed gases. The combining of unique propellant injector element designs with secondary mixing devices is predicted to be the best approach.

Schoenman, L.↗
NASA NTRS1982

Plasmaspheric helium ion distribution from satellite observations of He II 304-A

High sensitivity and spatial resolution observations of the He II 304-A emission line intensity in the earth's nightglow have been carried out by the extreme ultraviolet telescope on the Apollo-Soyuz mission in July, 1975. The data, obtained over a wide range of plasmasphere parameters, are compared to the predictions of a kinetic equilibrium model of plasmaspheric ion density. Excellent agreement between observation and theory is found using as inputs a temperature model, solar flux and H(+) and O(+) number densities determined by extrapolating nearly simultaneous Atmospheric Explorer C measurements at 300 km. The observations in the Northern Hemisphere are well fit by a model having 285 He(+) ions/cu cm at 500 km independent of latitude or longitude, while those in the south require 430 He(+) ions/cu cm at the same altitude. This result is consistent with available information on the interhemispheric asymmetry of He(+) observed by a mass spectrometer on Explorer 32 and on the winter neutral helium bulge.

Chakrabarti, S.↗
NASA NTRS1982

The structure of perpendicular bow shocks

A hybrid simulation model with kinetic ions, massless fluid electrons, and phenomenological resistivity is used to investigate the perpendicular configuration of the bow shocks of the earth and other planets. The range of parameters investigated includes the upstream Mach number, electron and ion beta (ratios of thermal to magnetic pressure), and resistivity. It is found that electron beta and resistivity have little effect on the overall shock structure. Quasi-stationary structures are obtained at moderately high ion beta, whereas the shock is found to become more dynamic in the low ion beta, large Mach number regime. The simulation results are shown to agree well with a number of observational features of quasi-perpendicular bow shocks, including the morphology of the reflected ion stream, the magnetic field profile throughout the shock, and the Mach number dependence of the magnetic field overshoot.

Leroy, M. M.↗
NASA NTRS1986

Noise-driven sidebranching in the boundary-layer model of dendritic solidification

In the context of local models of solidification, it is suggested that the sidebranching which appears to be a characteristic feature of dendritic processes may be generated by selective amplification of noise near the tip and that, under some circumstances, thermal fluctuations may be strong enough to explain the observed effects. This proposal is discussed based on the two-dimensional boundary-layer model with kinetic crystalline anisotropy. Experimental methods to distinguish this stochastic process from a deterministic, dynamical sidebranching mechanism are suggested, including the possibility of space-based experiments.

Pieters, R.↗
NASA NTRS1987

MPD thruster plasma instability studies

Results of an ongoing experimental/theoretical effort to understand the influence of plasma waves and instabilities upon coaxial plasma thruster performance and longevity are discussed. An experiment which permits measurement of the plasma dispersion relation plus a suite of plasma parameters for each one millisecond quasi-steady discharge is described. This investigation is guided by a linearized Boltzmann-Poisson kinetic numerical model which can accommodate the effects of collisions, inhomogeneities and the magnetic field. Preliminary tests reveal the presence of the low-frequency branch of an ion cyclotron wave. Although the stability of these waves still has to be established through spatial growth rate measurements, it is well known that they are prone to 'current-driven' instabilities. 'Current-driven' instabilities in the collisional tensor conducting plasma of the MPD thruster are analytically discussed and their relevance to the MPD plasma is illustrated by estimating a critical total current at which their onset occurs.

Kelly, A. J.↗
NASA NTRS1988

Current driven instabilities of an electromagnetically accelerated plasma

A plasma instability that strongly influences the efficiency and lifetime of electromagnetic plasma accelerators was quantitatively measured. Experimental measurements of dispersion relations (wave phase velocities), spatial growth rates, and stability boundaries are reported. The measured critical wave parameters are in excellent agreement with theoretical instability boundary predictions. The instability is current driven and affects a wide spectrum of longitudinal (electrostatic) oscillations. Current driven instabilities, which are intrinsic to the high-current-carrying magnetized plasma of the magnetoplasmadynmic (MPD) accelerator, were investigated with a kinetic theoretical model based on first principles. Analytical limits of the appropriate dispersion relation yield unstable ion acoustic waves for T(i)/T(e) much less than 1 and electron acoustic waves for T(i)/T(e) much greater than 1. The resulting set of nonlinear equations for the case of T(i)/T(e) = 1, of most interest to the MPD thruster Plasma Wave Experiment, was numerically solved to yield a multiparameter set of stability boundaries. Under certain conditions, marginally stable waves traveling almost perpendicular to the magnetic field would travel at a velocity equal to that of the electron current. Such waves were termed current waves. Unstable current waves near the upper stability boundary were observed experimentally and are in accordance with theoretical predictions. This provides unambiguous proof of the existence of such instabilites in electromagnetic plasma accelerators.

Chouetri, E. Y.↗
NASA NTRS1988

Current driven instabilities of an electromagnetically accelerated plasma

Quantitative measurements of the plasma instability that strongly affects the efficiency and lifetime of electromagnetic plasma accelerators were obtained. Experimental results are presented for the dispersion relations (wave phase velocities), spatial growth rates, and stability boundaries of accelerators. The measured critical wave parameters are found to agree well with theoretical predictions. A kinetic theoretical model was used to study current driven instabilities which are intrinsic to the high-current-carrying magnetized plasma of a magnetoplasmadynamic accelerator. Under certain conditions, marginally stable waves travelling almost perpendicular to the magnetic field are found which travel at a velocity equal to that of the electron current.

Kelly, A. J.↗
NASA NTRS1989

Modeling of carbon monoxide oxidation kinetics over NASA carbon dioxide laser catalysts

The recombination of CO and O2 formed by the dissociation of CO2 in a sealed CO2 laser discharge zone is examined. Conventional base-metal-oxide catalysts and conventional noble-metal catalysts are not effective in recombining the low O2/CO ratio at the low temperatures used by the lasers. The use of Pt/SnO2 as the noble-metal reducible-oxide (NMRO), or other related materials from Group VIIIA and IB and SnO2 interact synergistically to produce a catalytic activity that is substantially higher than either componet separately. The Pt/SnO2 and Pd/SnO2 were reported to have significant reaction rates at temperatures as low as -27 C, conditions under which conventional catalysts are inactive. The gas temperature range of lasers is 0 + or - 40 C. There are three general ways in which the NMRO composite materials can interact synergistically: one component altering the properties of another component; the two components each providing independent catalytic functions in a complex reaction mechanism; and the formation of catalytic sites through the combination of two components at the atomic level. All three of these interactions may be important in low temperature CO oxidation over NMRO catalysts. The effect of the noble metal on the oxide is discussed first, followed by the effect of the oxide on the noble metal, the interaction of the noble metal and oxide to form catalytic sites, and the possible ways in which the CO oxidation reaction is catalyzed by the NMRO materials.

Herz, Richard K.↗
NASA NTRS1989

The carbon budget in the outer solar nebula

The compositional contrast between the giant-planet satellites and the significantly rockier Pluto/Charon system is indicative of different formation mechanisms; cosmic abundance calculations, in conjunction with an assumption of the Pluto/Charon system's direct formation from solar nebula condensates, strongly suggest that most of the carbon in the outer solar nebula was in CO form, in keeping with both the inheritance from the dense molecular clouds in the interstellar medium, and/or the Lewis and Prinn (1980) kinetic-inhibition model of solar nebula chemistry. Laboratory studies of carbonaceous chondrites and Comet Halley flyby studies suggest that condensed organic material, rather than elemental carbon, is the most likely candidate for the small percentage of the carbon-bearing solid in the outer solar nebula.

Simonelli, Damon P.↗