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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
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Electrochemical study of prospective electrode- electrolyte systems for high-energy primary battery with minimum of 200 watt hours per pound of total battery weight
Highly conductive nonaqueous electrolytes for high energy battery
Various methods of measuring the small thermally induced distortions experienced either by various points on the space vehicles or by deviations of surfaces from a known shape during solar thermal vacuum tests are examined. State-of-the-art application of both photographic and real time observation are discussed. The relative merits of each of the methods are compared and evaluated in their applications to different types of test articles and situations. Magnitudes of thermally induced distortions which may be expected to be routinely measurable by the various methods are presented and compared.
Zinc-silver oxide battery design for improved and activated charge retention, voltage control, and temperature stability
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Using models of the quasi-chemical theory of solutions, the activity coefficients of silicon are calculated in the melts Fe-Si, Ni-Si, and Fe-Ni-Si. The calculated free energies of solution of liquid nickel and silicon in liquid iron in the interval 0 to 1400 kbar and 1500 to 4000 K, shows that Fe-Ni-Si alloy is stable under the conditions of the outer core of the Earth and the cores of the terrestrial planets. The oxidation-reduction conditions are studied, and the fugacity of oxygen in the mantles of the planets and at the core-mantle boundary are calculated. The mechanism of reduction of silicon is analyzed over a broad interval of P and T. The interaction between the matter of the core and mantle is studied, resulting in the extraction of silicon from the mantle and its solution in the material of the core. It is concluded that silicon can enter into the composition of the outer core of the Earth and Venus, but probably does not enter into the composition of the cores of Mercury, Mars, and the Moon, if in fact the latter possesses one.
A discussion is given of a containerless microgravity experiment aimed at measuring the interfacial tension of immiscible liquid pairs using a compound drop rotation method. The reasons for the failure to execute such experiments in microgravity are described. Also, the results of post-flight analyses used to confirm our arguments are presented.
An examination of the effect of vortex flow on hybrid rocket combustion and performance is underway. Emphasis is on response of the fuel regression rate when subjected to vortex flow. Initial results show that there is a definite effect of the vortex on fuel regression rate. Future work will focus on quantitatively measuring this regression rate. This work is part of an overall program to develop an ultra low cost fuel system for hybrid rocket engines.
Evaluation of various anode-electrolyte and cathode-electrolyte combinations for high energy density battery
High energy density primary battery development - anode-electrolyte, cupric fluoride cathode, and chemical stability tests
Cathodic materials for high energy density storage battery
High energy density primary battery - film formation on cupric fluoride cathodes discharged in organic electrolytes
High energy density primary battery development - electrochemical half-cell screening of anode- electrolyte combinations, cell discharge, and potential studies
The generalized Newton-Raphson method, an iterative procedure for solving nonlinear operator equations, has been extended in application to variational problems with bounded control variables. A minimum fuel interplanetary low thrust orbital transfer problem is worked out in detail to demonstrate the practical aspects of the algorithm as well as its computational effectiveness. The control variables are the thrust magnitude, limited from zero to some prescribed maximum value, and the thrust steering angle.
Predicting whether or not vehicle batteries contain sufficient charge to support operations over the remainder of a given flight plan is critical for electric aircraft. This paper describes an approach for identifying upper and lower uncertainty bounds on predictions that aircraft batteries will continue to meet output power and voltage requirements over the remainder of a flight plan. Battery discharge prediction is considered here in terms of the following components; (i) online battery state of charge estimation; (ii) prediction of future battery power demand as a function of an aircraft flight plan; (iii) online estimation of additional parasitic battery loads; and finally, (iv) estimation of flight plan safety. Substantial uncertainty is considered to be an irremovable part of the battery discharge prediction problem. However, high-confidence estimates of flight plan safety or lack of safety are shown to be generated from even highly uncertain prognostic predictions.
Lithium anodes, inorganic and organic cathodes, vacuum-distilled solvents, and methods for sintering cupric fluoride on lightweight metal substrates - development of high energy battery
Studies of many objects in petrographic thin section, such as melt inclusions in igneous rocks, chondrules and Ca-Al rich inclusions in chondritic meteorites, or clasts in lunar and other breccias, require or can benefit from knowledge of their bulk compositions. Given the scarcity of these materials, the reluctance of curators to provide more abundant material, and the extreme difficulty of cleanly separating such objects from their rock matrices, geochemical and cosmochemical studies need the ability to determine their bulk compositions from in situ methods, such as defocused beam analysis, or quantitative chemical mapping by electron beam methods.
Although considerable scientific and technological advances have been made in recent years in additive manufacturing (AM) processes, these advances have not translated into significant market penetration of AM parts within the aviation industry. It is broadly acknowledged that using traditional qualification and certification (Q&C) approaches for AM components is one of the most significant barriers to broader adoption of AM, resulting in high costs, long product development and certification timelines, and complex design iterations during the product development cycle. A new approach is urgently needed. This document lays out a vision for a new Q&C paradigm with increased use of computational materials (CM) methods aimed at decreasing the time and cost of Q&C of process-intensive material (PIM) approaches in the aviation industry, with AM as the immediate use case. This vision was developed with substantial input from industry, regulatory agencies, government research organizations, and academia.