Search NASA⌕ Search

SEARCH · Search NASA

Results for “layered crystals”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 469 records · Page 26
All sourcesNASA NTRSDOE OSTI
NASA NTRS2004

Process for Making Single-Domain Magnetite Crystals

A process for making chemically pure, single-domain magnetite crystals substantially free of structural defects has been invented as a byproduct of research into the origin of globules in a meteorite found in Antarctica and believed to have originated on Mars. The globules in the meteorite comprise layers of mixed (Mg, Fe, and Ca) carbonates, magnetite, and iron sulfides. Since the discovery of the meteorite was announced in August 1996, scientists have debated whether the globules are of biological origin or were formed from inorganic materials by processes that could have taken place on Mars. While the research that led to the present invention has not provided a definitive conclusion concerning the origin of the globules, it has shown that globules of a different but related chemically layered structure can be grown from inorganic ingredients in a multistep precipitation process. As described in more detail below, the present invention comprises the multistep precipitation process plus a subsequent heat treatment. The multistep precipitation process was demonstrated in a laboratory experiment on the growth of submicron ankerite crystals, overgrown by submicron siderite and pyrite crystals, overgrown by submicron magnesite crystals, overgrown by submicron siderite and pyrite. In each step, chloride salts of appropriate cations (Ca, Fe, and Mg) were dissolved in deoxygenated, CO2- saturated water. NaHCO3 was added as a pH buffer while CO2 was passed continuously through the solution. A 15-mL aliquot of the resulting solution was transferred into each of several 20 mL, poly(tetrafluoroethylene)-lined hydrothermal pressure vessels. The vessels were closed in a CO2 atmosphere, then transferred into an oven at a temperature of 150 C. After a predetermined time, the hydrothermal vessels were removed from the oven and quenched in a freezer. Supernatant solutions were decanted, and carbonate precipitates were washed free of soluble salts by repeated decantations with deionized water.

Golden, D. C.↗
NASA NTRS1993

Shear sensitive monomer-polymer laminate structure and method of using same

Monomer cholesteric liquid crystals have helical structures which result in a phenomenon known as selective reflection, wherein incident white light is reflected in such a way that its wavelength is governed by the instantaneous pitch of the helix structure. The pitch is dependent on temperature and external stress fields. It is possible to use such monomers in flow visualization and temperature measurement. However, the required thin layers of these monomers are quickly washed away by a flow, making their application time dependent for a given flow rate. The laminate structure according to the present invention comprises a liquid crystal polymer substrate attached to a test surface of an article. A light absorbing coating is applied to the substrate and is thin enough to permit bonding steric interaction between the liquid crystal polymer substrate and an overlying liquid crystal monomer thin film. Light is directed through and reflected by the liquid crystal monomer thin film and unreflected light is absorbed by the underlying coating. The wavelength of the reflected light is indicative of the shear stress experienced by the test surface. Novel aspects of the invention include its firm bonding of a liquid crystal monomer to a model and its use of a coating to reduce interference from light unreflected by the monomer helical structure.

Singh, Jag J.↗
NASA NTRS2016

DIAMOND - an Architecture for Persistent Space Platforms

We define DIAMOND, an architecture for generalized, persistent platforms in space, providing support infrastructure for multiple payloads with diverse missions, and able to accept the integration of payloads delivered to the platform after it is established in space. Such platforms would create a new space ecosystem with opportunities for much larger platforms than currently exist, for adaptation to changing technological and market conditions over long periods of time, and for tenants of the platform to launch only their unique payloads without having to carry all the equipment needed to support them. The DIAMOND architecture uses a novel “Architectural Shearing Layer” approach combining long-lived but replaceable structural and support infrastructure components with shorter-lived, higher-value service and tenant facilities. The structural aspect of the proposed architecture is a regular lattice constructed of tetrahedral cells, constructed of only a few types of simple structural components, patterned according to the cubic lattice of natural diamond crystals. The cubic lattice is arranged on larger scales to be fractal sponge, providing a disproportionately large number of surface attachment points while maintaining overall low mass of the entire structure. Generalized architectural shearing layers are also provided that permit easy separation between structural, power, thermal, propulsion/attitude control, pointing/vibration control, computing/data storage, and communication, and various operational aspects of the architecture. The combined result ensures longevity by enabling space platforms to undergo many cycles of change with little peril and at low cost, changing any part of the platform at different times and rates while leaving the remaining parts of the platform undisturbed.

Breidenthal, Julian↗
NASA NTRS1997

ZnSe Window Layers for GaAs and GaInP2 Solar Cells

This report concerns studies of the use of n-type ZnSe as a window layer for n/p GaAs and GaInP2 solar cells. Emphasis was placed in this phase of the project on characterizing the interface between n-type ZnSe films grown on epi-GaAs films grown onto single crystal GaAs. Epi-GaAs and heteroepitaxial ZnSe films were grown by MOCVD with a Spire 50OXT Reactor. After growing epitaxial GaAs films on single crystal GaAs wafers, well-oriented crystalline ZnSe films were grown by MOCVD. ZnSe films were grown with substrate temperatures ranging from 250 C to 450 C. Photoluminescence studies carried out by researchers at NASA Lewis determined that the surface recombination velocity at a GaAs surface was significantly reduced after the deposition of a heteroepitaxial layer of ZnSe. The optimum temperature for ZnSe deposition appears to be on the order of 350 C.

Olsen, Larry C.↗
NASA NTRS1974

Some results of track method of investigating Luna 16 lunar material

Preliminary data from an investigation of tracks in olivine crystals, separated from the five zones of a lunar surface material core, are reported. The gradients of track densities, their lengths, and their angular distribution were measured with an optical microscope. Throughout the core depth (35 cm) crystals bearing traces of exposure to low energy solar cosmic rays were found, indicating the occurrence of mixing processes in the surficial layer of lunar surface material. The age of the occurrence of the samples investigated on the lunar surface, calculated from the track density, is in the interval 0.7 to 16 million years.

Kashkarov, L. L.↗
NASA NTRS1978

Studies of snowpack properties by passive microwave radiometry

Research involving the microwave characteristics of snow was undertaken in order to expand the information content currently available from remote sensing, namely the measurement of snowcovered area. Microwave radiation emitted from beneath the snow surface can be sensed and thus permits information on internal snowpack properties to be inferred. The intensity of radiation received is a function of the average temperature and emissivity of the snow layers and is commonly referred to as the brightness temperature (T sub b). The T sub b varies with snow grain and crystal sizes, liquid water content and snowpack temperature. The T sub b of the 0.8 cm wavelength channel was found to decrease moreso with increasing snow depth than the 1.4 cm channel. More scattering of the shorter wavelength radiation occurs thus resulting in a lower T sub b for shorter wavelengths in a dry snowpack. The longer 21.0 cm wavelength was used to assess the condition of the underlying ground. Ultimately it may be possible to estimate snow volume over large areas using calibrated brightness temperatures and consequently improve snowmelt runoff predictions.

Chang, A. T. C.↗
NASA NTRS1979

Studies of snowpack properties by passive microwave radiometry

Research involving the microwave characteristics of snow was undertaken in order to expand the information content currently available from remote sensing, namely the measurement of snowcovered area. Microwave radiation emitted from beneath the snow surface can be sensed and thus permits information on internal snowpack properties to be inferred. The intensity of radiation received is a function of the average temperature and emissivity of the snow layers and is commonly referred to as the brightness temperature (T sub B). The T sub B varies with snow grain and crystal sizes, liquid water content, and snowpack temperature. The T sub B of the 0.8 cm wavelength channel was found to decrease more so with increasing snow depth than the 1.4 cm channel. More scattering of the shorter wavelength radiation occurs thus resulting in a lower T sub B for shorter wavelengths in a dry snowpack. The longer 21.0 cm wavelength was used to assess the condition of the underlying ground.

Chang, A. T. C.↗
NASA NTRS1979

Shallow-homojunction GaAs solar cells

Single-crystal GaAs shallow-homojunction solar cells on GaAs or Ge substrates, without Ga sub 1-x Al sub x As window layers, that have conversion efficiencies exceeding 20% at AM1 (17% at AMO). Using a simple theoretical model, good fits were obtained between computer calculations and experimental data for external quantum efficiency and conversion efficiency of cells with different values of n+ layer thickness. The calculations not only yield values for material properties of the GaAs layers composing the cells but will also permit the optimization of cell designs for space and terrestrial applications. Preliminary measurements indicate that the shallow-homojunction cells are resistant to electron irradiation. In the best test so far, bombardment with 1 x 10 to the 16th power/sq cm fluence of 1 MeV electrons reduced the short-circuit current by only about 6%.

Fan, J. C. C.↗
NASA NTRS1983

Refractory inclusions in the Murchison meteorite

Although melilite-rich and feldspathoid-bearing inclusions have been revealed in the Murchison C2 chondrite by mineralogical and petrographic studies, none of these is identical to the inclusions found to date in Allende. Each type of inclusion is characterized by a different suite of alteration products and/or rim layers from all the other types, indicating modification of the inclusions in a wide range of different physicochemical environments after their primary crystallization. All of these inclusions contain some iron-free rim phases which could not have formed by reaction of the inclusions with fluids in the Murchison parent body, because the latter would presumably have been rich in oxidized iron.

Macpherson, G. J.↗
NASA NTRS2000

Aerosol and Plasma Measurements in Noctilucent Clouds

The purpose of this project was to develop rocket-borne probes to detect charged aerosol layers in the mesosphere. These include sporadic E layers, which have their origin in meteoric dust, and noctilucent clouds, which form in the arctic summer and are composed of ice crystals. The probe being developed consists of a charge collecting patch connected to a sensitive electrometer which measures the charge deposited on the patch by impacting aerosols. The ambient electrons and light ions in the mesosphere are prevented from being collected by a magnetic field. The magnetic force causes these lighter particles to turn so that they miss the collecting patch.

Robertson, Scott↗
NASA NTRS2010

Volcanic Coatings on Picritic Apollo 17 Glasses; Submicrometer-Deposits of Fe-CR-Metal

The purposes of our ongoing investigations of Apollo 15 green and Apollo 17 orange and black volcanic glasses are threefold: first, to increase our understanding of the volcanic origin of the glasses; second, to determine the nature of the coating materials deposited on the glasses during their cooling in the volcanic environment; and, third, to help determine the nature of the gases involved in the volcanic fire-fountaining that occurred at approximately 3.5 Ga on the moon. We are continuing studies of coatings on volcanic glasses using analytical techniques not available when these glasses were originally studied; these include high-resolution FE-TEM and X-ray mapping, along with other highly detailed methods including TEM electron diffraction analysis. Initial studies of Apollo 15 green volcanic glasses using the techniques described above revealed for the first time the presence of areas containing distinct layering of volcanic surface deposits. S was associated with some of the inner layer of metallic Fe but was absent from the outer layer. Zn was associated with S in some places in the inner layer. An example of a typical spherule used for this study is shown in Fig. 1. It is a black (quench-crystallized) bead from near the bottom of the 74001/2 double drive tube; black beads such as this one are essentially identical in composition to the orange (uncrystallized) beads of the 74001/2 core.

McKay, David S.↗
NASA NTRS2016

Propellantless Attitude Control of Solar Sail Technology Utilizing Reflective Control Devices

Solar sails offer an opportunity for a CubeSatscale, propellant-free spacecraft technology that enables long-term and long-distance missions not possible with traditional methods. Solar sails operate using the transfer of linear momentum from photons of sunlight reflected from the surface of the sail. To propel the spacecraft, no mechanically moving parts, thrusters, or propellant are needed. However, attitude control, or orientation, is still performed using traditional methods involving reaction wheels and propellant ejection, which severely limit mission lifetime. For example, the current state of the art solutions employed by upcoming missions couple solar sails with a state of the art propellant ejection gas system. Here, the use of the gas thruster has limited the lifetime of the mission. To solve the limited mission lifetime problem, the Propellantless Attitude Control of Solar Sail Technology Utilizing Reflective Control Devices project team is working on propellantless attitude control using thin layers of material, an optical film, electrically switchable from transparent to reflective. The technology is based on a polymer-dispersed liquid crystal (PDLC), which allows this switch upon application of a voltage. This technology removes the need for propellant, which reduces weight and cost while improving performance and lifetime.

Solar sail technology↗
NASA NTRS1987

Crystallization behavior of a melt-spun Fe-Ni based steel

Whether Fe-Ni-based alloys solidify with a bcc or fcc structure has been observed by many investigators to be a stronger function of kinetics and undercooling than strictly free-energy minimization. Such behavior has been observed in an Fe(52.8)Ni(28.7)Al(3.4)Ti(6.1)B(9.0) alloy. The alloy was cast as ribbons about 45 microns thick using a dual free-jet variation of chillbock melt spinning against a Cu wheel. Optical, X-ray, and electron analyses of the as-cast and annealed ribbons were performed. A microstructure of at least four layers containing combinations of ecc, bcc, and amorphous phases in differing proportions was observed in the as-cast ribbon. The midthickness layer had the most unusual features, containing fcc grains about 75 nm in size encompassing spherulitic regions as large as 15 microns comprised of fcc grains about 25 nm in size. The crystallization sequence responsible for the as-cast microstructure is discussed in terms of the competition between the formation of bcc and fcc phases as influenced by undercooling, recalescence, and variations in cooling rate experienced by the as-cast ribbon.

Michal, G. M.↗
NASA NTRS1981

Controlled in situ etch-back

A controlled in situ etch-back technique is disclosed in which an etch melt and a growth melt are first saturated by a source-seed crystal and thereafter etch-back of a substrate takes place by the slightly undersaturated etch melt, followed by LPE growth of a layer by the growth melt, which is slightly supersaturated.

Mattauch, R. J.↗
NASA NTRS1988

The Kara and Ust-Kara impact structures (USSR) and their relevance to the K/T boundary event

The Kara and Ust-Kara craters are twin impact structures situated at about 69 deg 10 min N; 65 deg 00 min E at the Kara Sea. For Kara a diameter of about 55 km would be a very conservative estimate, and field observations indicate a maximum current diameter of about 60 km. The diameter of Ust-Kara has to be larger than 16 km. A better estimate might be 25 km but in all likelihood it is even larger. Suevites and impactites from the Kara area have been known since the beginning of the century, but had been misidentified as glacial deposits. Only about 15 years ago the impact origin of the two structures was demonstrated, following the recognition of shock metamorphism in the area. The composition of the target rocks is mirrored by the composition of the clasts within the suevites. In the southern part of Kara, Permian shales and limestones are sometimes accompanied by diabasic dykes, similar to in the central uplift. Due to the high degree of shock metamorphism the shocked magmatic rocks are not easily identified, although most of them seem to be of diabasic or dioritic composition. The impact melts (tagamites) are grey to dark grey fine grained crystallized rocks showing very fine mineral components and are the product of shock-melting with later recrystallization. The impact glasses show a layered structure, inclusions, and vesicles, and have colors ranging from translucent white over brown and grey to black. A complete geochemical characterization of the Kara and Ust-Kara impact craters was attempted by analyzing more than 40 samples of target rocks, shocked rocks, suevites, impact melts, and impact glasses for major and trace elements.

Koeberl, Christian↗
NASA NTRS1990

Transient magmatic convection prolonged by solidification

Fluid dynamic experiments have been conducted on the solidification of a paraffin layer, in order to elucidate the transient stage of convection created in cooling magma by the fact that strong changes in viscosity with crystallization lock up within an inwardly propagating crust much buoyancy that would otherwise be available to drive convection. The interior of the magma remains isothermal, and the temperature decreases uniformly until it is locked at the convective liquidus; the crystals are fine hairlike dendrites without major compositional differentiations. Measurements over time are presented of crust thickness, convective velocity, and heat transfer.

Brandeis, Genevieve↗
NASA NTRS1992

Polarized-Cathodoluminescence Study Of Stress In GaAs/Si

Report describes experiments in which linearly polarized cathodoluminesce scanning electron microscopy, in both imaging and spectroscopic forms, used to analyze spatial variations in stress tensors in specimens of GaAs/Si. Specimens fabricated by atmospheric-pressure metallo-organic chemical vapor deposition of GaAs to thickness of 4 micrometers on Si substrates. Combination of mismatch between Si and GaAs crystal lattices and differential thermal contraction of materials from deposition temperature (700 degrees C) to room temperature gives rise to stresses in GaAs layer. Experiments conducted to contribute to understanding of effects of these stresses and ramifications thereof for fabrication of electronic devices in GaAs/Si system.

Rich, Daniel H.↗