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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 469 records · Page 26
All sourcesNASA NTRSDOE OSTI
NASA NTRS1979

Three methods for in situ cross-linking of polyvinyl alcohol films for application as ion-conducting membranes in potassium hydroxide electrolyte

Three methods of in situ cross-linking polyvinyl alcohol films are presented. They are: (1) acetalization with a dialdehyde such as glutaraldehyde, (2) acetalization with aldehyde groups formed by selective oxidative cleaving of the few percent of 1,2 diol units present in polyvinyl alcohol, and (3) cross-linking by hydrogen abstraction by reaction with hydrogen atoms and hydroxyl radicals from irradiated water. For the third method, improvement in film conductivity in KOH solution at the expense of mechanical strength is obtained by the presence of polyacrylic acid in the polyvinyl alcohol films. Resistivities in 45 percent KOH are given for in situ cross-linked films prepared by each of the three methods.

Philipp, W. H.↗
NASA NTRS1979

A review of issues and strategies in nondestructive evaluation of fiber reinforced structural composites

Techniques for quantitative assessment of the mechanical strength and integrity of fiber composites during manufacture and service and following repair operations are presented. Problems and approaches are discussed relative to acceptance criteria, calibrating standards, and methods for nondestructive evaluation of composites in strength-critical applications. Acousto-ultrasonic techniques provide the methods of choice in this area.

Vary, A.↗
NASA NTRS1979

Planetary rings

Two models of planetary ring formation are discussed: the break-up of a large body coming nearer to the planet than the Roche limit for the particular mechanical strength of the body would allow; and condensation of the protoplanetary nebula within a suitable Roche limit without formation of a large satellite. The location of the newly discovered Uranian rings has been interpreted in terms of three-body orbital resonance with satellites. A possible relationship between the origin and characteristics of the Uranian rings and the unusual tilt of the planetary axis is also discussed. In addition, attention is given to the polarization of light characteristic of planetary rings.

Smoluchowski, R.↗
NASA NTRS1980

Filter development for the extreme ultraviolet explorer

Thin film filters with extreme ultraviolet bandpasses unattainable with previously available filter materials were developed. Titanium and antimomy were identified as the most promising materials for providing the scientifically important 350-500 A bandpass heretofore unattainable with thin film filters. Titanium foils and titanium-antimony sandwich foils of the required uniformity and durability were fabricated. Transmission measurements and optimization studies indicate that the titanium-antimony combination provides an ideal bandpass for scientifically valuable, high-sensitivity observations with EUVE. Environmental testing of the mechanical strength, moisture sensitivity and aging characteristics of the newly developed filter materials demonstrate flightworthy performance.

Kimble, R.↗
NASA NTRS1979

A review of issues and strategies in nondestructive evaluation of fiber reinforced structural composites

The need for advanced nondestructive evaluation (NDE) techniques for quantitative assessment of the mechanical strength and integrity of fiber composites during manufacture and service and following repair operations is stressed. The discussion covers problems and different approaches in regard to acceptance criteria, calibration standards, and methods for NDE of composites in strength critical applications. Finally, it is concluded that acousto-ultrasonic techniques provide the 'methods of choice' in this area.

Vary, A.↗
NASA NTRS1982

Adhesive-Bonded Tab Attaches Thermocouples to Titanium

Mechanical strength of titanium-alloy structures that support thermocouples is preserved by first spotwelding thermocouples to titanium tabs and then attaching tabs to titanium with a thermosetting adhesive. In contrast to spot welding, a technique previously used for thermocouples, fatigue strength of the titanium is unaffected by adhesive bonding. Technique is also gentler than soldering or attaching thermocouples with a tap screw.

Cook, C. F.↗
NASA NTRS1976

Ion-exchange hollow fibers

An ion-exchange hollow fiber is prepared by introducing into the wall of the fiber polymerizable liquid monomers, and polymerizing the monomers therein to form solid, insoluble, crosslinked, ion-exchange resin particles which embed in the wall of the fiber. Excess particles blocking the central passage or bore of the fiber are removed by forcing liquid through the fiber. The fibers have high ion-exchange capacity, a practical wall permeability and good mechanical strength even with very thin wall dimensions. Experimental investigation of bundles of ion-exchange hollow fibers attached to a header assembly have shown the fiber to be very efficient in removing counterions from solution.

Rembaum, A.↗
NASA NTRS1981

PBI treated polypropylene battery separator

A generalized procedure for fabricating the separator is described. Some of the desired properties considered in fabricating the separator material for nickel-cadmium cells were good mechanical strength, good chemical stability, good wettability to the electrolyte, high electrolyte retention, and gas passage.

Veryzwyvelt, S. A.↗
NASA NTRS1980

Testing of the permanent magnet material Mn-Al-C for potential use in propulsion motors for electric vehicles

The development of Mn-Al-C permanent magnets is reviewed. The general properties of the material are discussed and put into perspective relative to alnicos and ferrites. The commercial material now available is described by the manufacturer's data. The traction motor designer's demands of a permanent magnet for potential use in electric vehicle drives are reviewed. From this, a list of the needed specific information is extracted. A plan for experimental work is made which would generate this information, or verify data supplied by the producer. The results of these measurements are presented in the form of tables and graphs. The tests determined magnetic design data and some mechanical strength properties. Easy axis hysteresis and demagnetization curves, recoil loops and other minor loop fields were measured over a temperature range from -50 C to +150 C. Hysteresis loops were also measured for three orthogonal directions (the easy and 2 hard axes of magnetization).

Abdelnour, Z. A.↗
NASA NTRS1982

Metal ion-containing epoxies

A variety of metallic and organometallic complexes to be used as potential additives for an epoxy used by the aerospace industry as a composite matrix resin were investigated. A total of 9 complexes were screened for compatibility and for their ability to accelerate or inhibit the cure of a highly crosslinkable epoxy resin. Methods for combining the metallic complexes with the resin were investigated, gel times recorded, and cure exotherms studied by differential scanning calorimetry. Glass transition temperatures of cured metal ion containing epoxy castings were determined by thermomechanical analysis. Thermal stabilities of the castings were determined by thermogravimetric analysis. Mechanical strength and stiffness of these doped epoxies were also measured.

Stoakley, D. M.↗
NASA NTRS1983

Experimental design

The design of long life, low weight nickel cadmium cells is studied. The status of a program to optimize nickel electrodes for the best performance is discussed. The pore size of the plaque, the mechanical strength and active material loading are considered in depth.

Lim, H. S.↗
NASA NTRS1983

The structural response of a rail accelerator

The transient response of a 0.4 by 0.6 cm rectangular bore rail accelerator was analyzed by a three dimensional finite element code. The copper rail deflected to a peak value of 0.08 mm in compression and then oscillated at an amplitude of 0.02 mm. Simultaneously the insulating side wall of glass fabric base, epoxy resin laminate (G-1o) was compressed to a peak value of 0.13 mm and rebounded to a steady state in extension. Projectile pinch or blowby due to the rail extension or compression, respectively, can be identified by examining the time history of the rail displacement. The effect of blowby was most significant at the side wall characterized by mm size displacement in compression. Dynamic stress calculations indicate that the G-10 supporting material behind the rail is subjected to over 21 MPa at which the G-10 could fail if the laminate was not carefully oriented. Results for a polycarbonate resin (Lexan) side wall show much larger displacements and stresses than for G-10. The tradeoff between the transparency of Lexan and the mechanical strength of G-10 for sidewall material is obvious. Displacement calculations from the modal method are smaller than the results from the direct integration method by almost an order of magnitude, because the high frequency effect is neglected.

Wang, S. Y.↗
NASA NTRS1984

Fabrication of highly dense SiN4 ceramics without additives by high pressure sintering

Silicon nitride (Si3N4) is one of candidate materials for the engineering ceramics which is used at high temperatures. The mechanical strengths of hot pressed or sintered Si2N4 ceramics containing some amount of additives, however, are deteriorated at elevated temperatures. To improve the high temperature strength of Si3N4 ceramics, an attempt to consolidate Si3N4 without additives was made by high pressure sintering technique. Scanning electron micrographs of fracture surfaces of the sintered bodies showed the bodies had finely grained and fully self-bonded sintered bodies were 310N sq m at room temperature and 174N/sq m at 1200 C.

Takatori, K.↗
NASA NTRS1983

Long life nickel electrodes for a nickel-hydrogen cell. I Initial performance

In order to develop a long life nickel electrode for a Ni/H2 cell, an investigation was begun to study the effects of sinter structure and active material loading level on the long life performance of nickel electrodes. This paper is a report on the initial performance of these electrodes as a part of an accelerated life test program. Seven different types of nickel plaques were made which included three levels of both their mechanical strength and median pore size. These plaques were impregnated with three levels of active material loading. The resultant electrodes were tested by a 200-cycle stress test which was conducted in flooded electrolyte, and also for initial performance in a Ni/H2 boiler plate cell. An interesting and unexpected observation was that an increased initial utilization of the active material was due more to its complete discharge to the lower average oxidation state than its increased charge acceptance in the charged state.

Lim, H. S.↗
NASA NTRS1984

The structural response of a rail acceleration

The transient response of a 0.4 by 0.6 cm rectangular bore rail accelerator was analyzed by a three dimensional finite element code. The copper rail deflected to a peak value of 0.08 mm in compression and then oscillated at an amplitude of 0.02 mm. Simultaneously the insulating side wall of glass fabric base, epoxy resin laminate (G-10) was compressed to a peak value of 0.13 mm and rebounded to a steady state in extension. Projectile pinch or blowby due to the rail extension or compression, respectively, can be identified by examining the time history of the rail displacement. The effect of blowby was most significant at the side wall characterized by mm size displacement in compression. Dynamic stress calculations indicate that the G-10 supporting material behind the rail is subjected to over 21 MPa at which the G-10 could fail if the laminate was not carefully oriented. Results for a polycarbonate resin (Lexan) side wall show much larger displacements and stresses than for G-10. The tradeoff between the transparency of Lexan and the mechanical strength of G-10 for sidewall material is obvious. Displacement calculations from the modal method are smaller than the results from the direct integration method by almost an order of magnitude, because the high frequency effect is neglected. Previously announced in STAR as N83-35412

Wang, S. Y.↗
NASA NTRS1984

Transformation toughened ceramics for the heavy duty diesel engine technology program

The objective of this program is to develop an advanced high temperature oxide structural ceramic for application to the heavy duty diesel engine. The approach is to employ transformation toughening by additions of ZrO.5HfO.5O2 solid solution to the oxide ceramics, mullite (2Al2O3S2SiO2) and alumina (Al2O3). The study is planned for three phases, each 12 months in duration. This report covers Phase 1. During this period, processing techniques were developed to incorporate the ZrO.5HfO.5O2 solid solution in the matrices while retaining the necessary metastable tetragonal phase. Modulus of rupture and of elasticity, coefficient of thermal expansion, fracture toughness by indent technique and thermal diffusivity of representative specimens were measured. In Phase 2, the process will be improved to provide higher mechanical strength and to define the techniques for scale up to component size. In Phase 3, full scale component prototypes will be fabri-]cated.

Musikant, S.↗
NASA NTRS1984

High temperature properties of equiatomic FeAl with ternary additions

The aluminide intermetallic compounds are considered potential structural materials for aerospace applications. The B2 binary aluminide FeAl has a melting point in excess of 1500 K, is of simple cubic structure, exits over a wide range of composition with solubility for third elements and is potentially self-protecting in extreme environments. The B2 FeAl compound has been alloyed with 1 to 5 at % ternary additions of Si, Ti, Zr, Hf, Cr, Ni, Co, Nb, Ta, Mo, W, and Re. The alloys were prepared by blending a third elemental powder with prealloyed binary FeAl powder. Consolidation was by hot extrusion at 1250 K. Annealing studies on the extruded rods showed that the third element addition can be classified into three categories based upon the amount of homogenization and the extent of solid solutioning. Constant strain rate compression tests were performed to determine the flow stress as a function of temperature and composition. The mechanical strength behavior was dependent upon the third element homogenization classification.

Titran, R. H.↗
NASA NTRS1985

Hgi2 Sub 2 Crystal Growth for Nuclear Detectors

The objectives of this program are to obtain a benchmark quality sample grown at low-g conditions and to study vapor growth phenomena under space conditions. Ground-based crystals show a defect structure which impairs their performance as nuclear radiation detectors. These defects may be caused by the gravitational force acting on the crystal in its weakended state at the elevated growth temperature and by irregular convection patterns in the vapor during growth. Mechanical strength measurements have been performed (uniaxial compression tests) which show that the crystals exhibit slip parallel to the c-planes at stresses as low as 1/2 psi. Preliminary calculations using a simple linearized model indicate the oscillating instabilities in the convection part of the vapor transport system are unlikely, even at 1-g, provided that the utmost care is taken in the preparation of the crystal growth source material.

Schnepple, W. F.↗