Nickel-copper-zirconium alloy for catalytic creactors
Catalytic and improved mechanical properties of alloy indicate its potential use as catalyst for reduction of nitrogen oxide from internal combustion engines.
Whittenberger, J. D.↗
SEARCH · Search NASA
Results for “nitrogen oxides”
Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.
Emissions and performance of catalysts for gas turbine catalytic combustors
Three noble-metal monolithic catalysts were tested in a 12-centimeter diameter combustion test rig to obtain emissions and performance data at conditions simulating the operation of a catalytic combustor for an automotive gas turbine engine. Tests with one of the catalysts at 800 K inlet mixture temperature 300,000 pa (3 atm) pressure, and a reference velocity (catalyst bed inlet velocity) of 10 m/sec demonstrated greater than 99 percent combustion efficiency for reaction temperatures higher than 1300 K. With a reference velocity of 25 m/sec the reaction temperature required to achieve the same combustion efficiency increased to 1380 K. The exit temperature pattern factors for all three catalysts were below 0.1 when adiabatic reaction temperatures were higher than 1400 K. The highest pressure drop was 4.5 percent at 25 m/sec reference velocity. Nitrogen oxides emissions were less than 0.1 g NO2/kg fuel for all test conditions.
Anderson, D. N.↗
Zirconium modified nickel-copper alloy
An improved material for use in a catalytic reactor which reduces nitrogen oxide from internal combustion engines is in the form of a zirconium-modified, precipitation-strengthened nickel-copper alloy. This material has a nominal composition of Ni-30 Cu-0.2 Zr and is characterized by improved high temperature mechanical properties.
Whittenberger, J. D.↗
High pressure flame system for pollution studies with results for methane-air diffusion flames
A high pressure flame system was designed and constructed for studying nitrogen oxide formation in fuel air combustion. Its advantages and limitations were demonstrated by tests with a confined laminar methane air diffusion flame over the pressure range from 1 to 50 atm. The methane issued from a 3.06 mm diameter port concentrically into a stream of air contained within a 20.5 mm diameter chimney. As the combustion pressure is increased, the flame changes in shape from wide and convex to slender and concave, and there is a marked increase in the amount of luminous carbon. The height of the flame changes only moderately with pressure.
Miller, I. M.↗
Emissions and performance of catalysts for gas turbine catalytic combustors
Three noble-metal monolithic catalysts were tested in a 12-cm-dia. combustion test rig to obtain emissions and performance data at conditions simulating the operation of a catalytic combustor for an automotive gas turbine engine. Tests with one of the catalysts at 800 K inlet mixture temperature, 3 x 10 to the 5th Pa pressure, and a reference velocity (catalyst bed inlet velocity) of 10 m/sec demonstrated greater than 99 percent combustion efficiency for reaction temperatures higher than 1300 K. With a reference velocity of 25 m/sec the reaction temperature required to achieve the same combustion-efficiency increased to 1380 K. The exit temperature pattern factors for all three catalysts were below 0.1 when adiabatic reaction temperatures were higher than 1400 K. The highest pressure drop was 4.5 percent at 25 m/sec reference velocity. Nitrogen oxides emissions were less than 0.1 g NO2/kg fuel for all test conditions.
Anderson, D. N.↗
Environmental protection agency aircraft emissions standards
Emissions of air pollutants from aircraft were investigated in order to determine: (1) the extent to which such emissions affect air quality in air quality control regions throughout the United States; and (2) the technological feasibility of controlling such emissions. The basic information supporting the need for aircraft emissions standards is summarized. The EPA ambient air quality standards are presented. Only the primary (health related) standards are shown. Of the six pollutants, only the first three, carbon monoxide (CO), hydrocarbons (HC), and nitrogen oxides, are influenced significantly by aircraft.
Kittredge, G. D.↗
Effect of fuel properties on performance of single aircraft turbojet combustor at simulated idle, cruise, and takeoff conditions
The performance of a single-can JT8D combustor was investigated with a number of fuels exhibiting wide variations in chemical composition and volatility. Performance parameters investigated were combustion efficiency, emissions of CO, unburned hydrocarbons and nitrogen oxides, as well as liner temperatures and smoke. The most pronounced effects of changes in fuel composition were observed at simulated cruise and takeoff conditions where smoke and liner temperatures increased significantly as the hydrogen content of the fuel decreased. At the simulated idle condition, emissions of CO and unburned hydrocarbons increased slightly and, accordingly, combustion efficiencies decreased slightly as the hydrogen content of the fuels decreased.
Butze, H. F.↗
Temporal and latitudinal variations of stratospheric trace gases - A critical comparison between theory and experiment
Global calculations of stratospheric HOx, Clx, and NOx are presented which include the effects of planetary albedo and diurnal and seasonal variations of the insolation. Comparisons are made with a wide range of atmospheric measurements at different latitudes and altitudes. Agreement between theory and observations is generally within a factor of 2. The theory appears to explain adequately the major features of latitude and seasonal distributions of NO2 and HNO3. The results indicate that mesospheric OH makes an appreciable contribution to the total OH column abundance and strongly suggest that nitrogen oxides exist principally in the form of HNO3 at high latitudes in winter. There are difficulties in reconciling OH, ClO, and O3 observations in the upper stratosphere.
Wofsy, S. C.↗
Degree of vaporization using an airblast type fuel injector for a premixed-prevaporized combustor
Vaporization data are presented which could be useful in designing premixed-prevaporized fuel preparation systems for gas turbine combustors. Lean, premixed-prevaporized combustion systems are being developed because they operate with low flame temperatures and, therefore, produce low levels of nitrogen oxides. Parametric tests of the effect of inlet air temperature, length (residence time), reference velocity, pressure and fuel-air ratio on the degree of vaporization are reported. Jet A and Diesel no. 2 fuel were tested. A formula is provided which shows the effect of inlet air temperature, residence time, reference velocity, and pressure on the degree of vaporization for a constant fuel-air ratio of 0.020. The results of the effect of inlet air temperature on the degree of vaporization using Jet A and Diesel no. 2 are nearly identical.
Tacina, R. R.↗
Emission measurements for a lean premixed propane/air system at pressures up to 30 atmospheres
The emissions of a lean premixed system of propane/air were measured in a flametube apparatus. Tests were conducted at inlet temperatures of 600K and 800K and pressures of 10 atm and 30 atm over a range of equivalence ratios. The data obtained were combined with previous data taken in the same apparatus to correlate nitrogen oxide emissions with operating conditions. Sampling probe design was found to have a pronounced effect on measured CO levels but did not influence measurements. The most effective probe tested was one which combined thermal and pressure quenching of the gas sample.
Roffe, G.↗
Combuster
A combuster is provided for utilizing a combustible mixture containing fuel and air, to heat a load fluid such as water or air, in a manner that minimizes the formation of nitrogen oxide. The combustible mixture passes through a small diameter tube where the mixture is heated to its combustion temperature, while the load fluid flows past the outside of the tube to receive heat. The tube is of a diameter small enough that the combustible mixture cannot form a flame, and yet is not subject to wall quench, so that combustion occurs, but at a temperature less than under free flame conditions. Most of the heat required for heating the combustible mixture to its combustion temperature, is obtained from heat flow through the walls of the pipe to the mixture.
Mckay, R. A.↗
Application of interferential correlation of spectrum to the detection of atmospheric pollutants
The general correlation principles for spectra and spectra derivatives are studied by using the Fourier transform of the spectral distribution of energy from a source illuminating a double beam interferometer with transverse splitting by dividing luminance. In this correlation technique, the use of such an interferometer has the advantage of greater luminosity as compared with a slit spectrometer. However, the correlation example indicates that it is necessary to adapt the correlator to the particular case considered, in order to obtain the best gain in the signal to noise ratio. In the case of sulfur dioxide detection, a very simple mounting which could be used in some interesting industrial applications was developed. This mounting can be used each time that the substance to be analyzed has a quasi-periodic absorption spectrum: in particular this is often the case with absorption spectra of gases, and a mounting identical to the one described for sulfur dioxide proved to be effective in the detection of nitrogen oxides.
Fortunato, G.↗
Preliminary comparison of theory and experiment for a conical, pressurized-fluidized-bed coal combustor
A published model was used for a comparison of theory with an actual combustor burning caking bituminous coal and using limestone to reduce sulfur dioxide emission. Theoretical bed pressure drop was in good agreement with experiment. The burnable carbon elutriated was not in agreement with experiment, at least partly because the exhaust port was apparently below the transport disengaging height. The observed nitrogen oxides emission rate was about half the theoretical value. There was order-or-magnitude agreement of sulfur dioxide emission rates.
Patch, R. W.↗
Summary of southeastern Virginia urban plume measurement data for August 4 and 5, 1977
The measurement program was conducted to define the characteristics of the Southeastern Virginia urban plume with emphasis on the photooxidant species. The measurement area was a rectangle approximately 200 km by 60 km centered in the Hampton Roads area of Tidewater Virginia. This area includes the cities of Norfolk, Virginia Beach, Chesapeake, Newport News, and Hampton. The data set presented includes aircraft measurements for ozone, nitrogen oxides, carbon monoxide, methane, and meteorological parameters such as dewpoint temperature. Surface level data for ozone are presented for 10 stations located throughout the test area. Comprehensive meteorological data from existing National Weather Service stations and special locations selected for the urban plume program are summarized.
Gregory, G. L.↗
Experimental Clean Combustor Program (ECCP), phase 3
A double annular advanced technology combustor with low pollutant emission levels was evaluated in a series of CF6-50 engine tests. Engine lightoff was readily obtained and no difficulties were encountered with combustor staging. Engine acceleration and deceleration were smooth, responsive and essentially the same as those obtainable with the CF6-50 combustor. The emission reductions obtained in carbon monoxide, hydrocarbons, and nitrogen oxide levels were 55, 95, and 30 percent, respectively, at an idle power setting of 3.3 percent of takeoff power on an EPA parameter basis. Acceptable smoke levels were also obtained. The exit temperature distribution of the combustor was found to be its major performance deficiency. In all other important combustion system performance aspects, the combustor was found to be generally satisfactory.
Gleason, C. C.↗
Nitrogen-sulfur compounds in stratospheric aerosols
Two forms of nitrosyl sulfuric acid (NOHSO4 and NOHS2O7) have been tentatively identified in stratospheric aerosols. The first of these can be formed either directly from gas reactions of NO2 with SO2 or by gas-particle interactions between NO2 and H2SO4. The second product may form when SO3 is involved. Estimates based on these reactions suggest that the maximum quantity of NO that might be absorbed in stratospheric aerosols could vary from one-third to twice the amount of NO in the surrounding air. If these reactions occur in the stratosphere, then a mechanism exists for removing nitrogen oxides from that region by aerosol particle fallout. This process may typify another natural means that helps cleanse the lower stratosphere of excessive pollutants.
Farlow, N. H.↗
Stratospheric trace gas sampling with chemical absorption filters
Recent interest in stratospheric chemistry, sparked in part by the suggested roles of atomic chlorine (Cl) and nitrogen oxides (NOx) in the catalytic destruction of ozone (O3), has made sampling and measurement of trace constituents above the tropopause highly desirable. An ongoing research program in the In Situ Studies Project at the National Center for Atmospheric Research carries out aircraft and balloon-borne stratospheric chemical sampling at regular intervals by using chemically impregnated filters to collect particles and reactive gases.
Bonelli, J. E.↗
Airborne atmospheric sampling system
The atmospheric sampling system developed for use on board commercial airliners as part of the Global Atmospheric Sampling Program (GASP) is described. The automated air-constituent measuring system is installed in a Boeing 747 airliner below the passenger cabin floor near the nose wheel well. It consists of an air sample flow system, composed of air inlet and pressurization systems, computerized data acquisition and system control units which direct system operation in 15 modes, and commercial instruments significantly modified to measure low levels of atmospheric constituents (ozone, water vapor, nitrogen oxides, carbon monoxide, chlorofluoromethanes, particulates, condensation nuclei, sulfates and nitrates). Flight and meteorological data, including air temperature and altitude, are also recorded. The system is designed for servicing at 14-day intervals, and to require a minimum of aircrew involvement.
Gustafsson, U. R. C.↗