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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 469 records · Page 26

Red clouds in reducing atmospheres

A dark reddish-brown high-molecular weight polymer is produced by long wavelength ultraviolet irradiation of abundant gases in reducing planetary atmospheres. The polymer is examined by paper chromatography, mass spectrometry, and infrared, visible, and ultraviolet spectroscopy. High carbon-number straight-chain alkanes with NH2 and, probably, OH and C = O groups are identified, along with amino acids. There are chemical similarities between this polymer and organic compounds recovered from carbonaceous chondrites and precambrian sediments. The visible and near-ultraviolet transmission spectrum of the polymer shows its absorption optical depth to be redder than lambda(-2) and perhaps similar in coloration to the clouds of Jupiter, Saturn, and Titan. The nitrile content is small, and the polymer should be semitransparent in the 5 micrometer atmospheric window. Such polymers may be a common constituent of clouds in the outer solar system and on the early earth.

Khare, B. N.↗

Leaf optical system modeled as a stochastic process

A stochastic leaf radiation model based upon physical and physiological properties of dicot leaves has been developed. The model accurately predicts the absorbed, reflected, and transmitted radiation of normal incidence as a function of wavelength resulting from the leaf-irradiance interaction over the spectral interval of 0.40-2.50 micron. The leaf optical system has been represented as Markov process with a unique transition matrix at each 0.01-micron increment between 0.40 micron and 2.50 micron. Probabilities are calculated at every wavelength interval from leaf thickness, structure, pigment composition, and water content. Simulation results indicate that this approach gives accurate estimations of actual measured values for dicot leaf absorption, reflection, and transmission as a function of wavelength.

Tucker, C. J.↗

The structure of extruded NiAl

The deformation structure of Ni-rich NiAl extruded at 550 C has been characterized by transmission electron microscopy and by optical microscopy. Dislocations having a(100) Burgers vectors were found as complex networks, tangles, and prismatic loops. a(110) dislocations, which were rare, were concluded to arise from reactions of a(100) dislocations. Evidence of recovery and recrystallization was obtained. Extrusion was deemed to have been possible by the operation of (hko)(001) slip systems (often in plane strain flow) plus diffusion-assisted processes.

Baker, I.↗

Statistics of Cloud Optical Properties from Airborne Lidar Measurements

Cloud optical properties, such as extinction-to-backscatter ratio and depolarization ratio, have a significant impact on the accuracy of cloud extinction retrievals from lidar systems because parameterizations of these variables are often used in non-ideal conditions to determine cloud type and optical depth. Statistics and trends of these optical parameters were analyzed for four years, 2003-2007, of Cloud Physics Lidar data during five projects of varying geographic locations. Extinction-to-backscatter ratio (at 532 nm) was derived by calculating the transmission loss through the cloud layer, while depolarization ratio was computed using the parallel and perpendicular polarized 1064 nm channels. The majority of the cloud layers yielded an S-ratio between 10 and 40 sr with the S-ratio frequency distribution centered at 25 sr for ice clouds, 21 sr for mixed phase clouds, and 11 sr for water clouds. On average for ice clouds, S ratio slightly decreased with decreasing temperature, while depolarization ratio increased significantly as temperatures decreased. Trends for water and mixed phase clouds were also observed. Ultimately, these observed trends in optical properties as a function of temperature and geographic location will improve current parameterizations of extinction-to-backscatter ratio, which consequently increases accuracy in cloud optical depth and radiative forcing estimates.

Yorks, John E.↗

The SuperCam Instrument Suite on the NASA Mars 2020 Rover: Body Unit and Combined System Tests

The SuperCam instrument suite provides the Mars 2020 rover, Perseverance, with a number of versatile remote-sensing techniques that can be used at long distance as well as within the robotic-arm workspace. These include laser-induced breakdown spectroscopy (LIBS), remote time-resolved Raman and luminescence spectroscopies, and visible and infrared (VISIR; separately referred to as VIS and IR) reflectance spectroscopy. A remote micro-imager (RMI) provides high-resolution color context imaging, and a microphone can be used as a stand-alone tool for environmental studies or to determine physical properties of rocks and soils from shock waves of laser-produced plasmas. SuperCam is built in three parts: The mast unit (MU), consisting of the laser, telescope, RMI, IR spectrometer, and associated electronics, is described in a companion paper. The on-board calibration targets are described in another companion paper. Here we describe SuperCam’s body unit (BU) and testing of the integrated instrument. The BU, mounted inside the rover body, receives light from the MU via a 5.8 m optical fiber. The light is split into three wavelength bands by a demultiplexer, and is routed via fiber bundles to three optical spectrometers, two of which (UV and violet; 245–340 and 385–465 nm) are crossed Czerny-Turner reflection spectrometers, nearly identical to their counterparts on ChemCam. The third is a high-efficiency transmission spectrometer containing an optical intensifier capable of gating exposures to 100 ns or longer, with variable delay times relative to the laser pulse. This spectrometer covers 535–853 nm ( $105\text{--}7070~\text{cm}^{-1}$ Raman shift relative to the 532 nm green laser beam) with $12~\text{cm}^{-1}$ full-width at half-maximum peak resolution in the Raman fingerprint region. The BU electronics boards interface with the rover and control the instrument, returning data to the rover. Thermal systems maintain a warm temperature during cruise to Mars to avoid contamination on the optics, and cool the detectors during operations on Mars.Results obtained with the integrated instrument demonstrate its capabilities for LIBS, for which a library of 332 standards was developed. Examples of Raman and VISIR spectroscopy are shown, demonstrating clear mineral identification with both techniques. Luminescence spectra demonstrate the utility of having both spectral and temporal dimensions. Finally, RMI and microphone tests on the rover demonstrate the capabilities of these subsystems as well.

47 OTHER INSTRUMENTATION↗

Mars Orbiter Sample Return Power Design

The NASA/JPL 2003/2005 Mars Sample Return (MSR) Missions will each have a sample return canister that will be filled with samples cored from the surface of MARS. These spherical canisters will be 14.8 cm in diameter and must be powered only by solar cells on the surface and must communicate using RF transmission with the recovery vehicle that will be coming in 2006 or 2009 to retrieve the canister. This paper considers the aspect and conclusion that went into the design of the power system that achieves the maximum power with the minimum risk. The power output for the spherical orbiting canister was modeled and plotted in various views of the orbit by the SOAP program developed by JPL. The requirements and geometry for a solar array on a sphere are unique and place special constraints on the design. These requirements include 1) accommodating a lid for sample loading into the canister, surface area was restricted from use on the Northern pole of the spherical canister. 2) minimal cell surface coverage (maximum cell efficiency), less than 40%, for recovery vehicle to locate the canister by optical techniques. 3) a RF transmission during 50% of MARS orbit time on any spin axis, which requires optimum circuit placement of the solar cell onto the spherical canister. The best configuration would have been a 4.5 volt round cell, but in the real world we compromised with six triangular silicon cells connected in series to form a hexagon. These hexagon circuits would be mounted onto a flat facet cut into the spherical canister. The surface flats are required in order to maximize power, the surface of the cells connected in series must be at the same angle relative to the sun. The flat facets intersect each other to allow twelve circuits evenly spaced just North and twelve circuits South of the equator of the spherical canister. Connecting these circuits in parallel allows sufficient power to operate the transmitter at minimum solar exposure, Northern pole of the canister facing the sun. Additional power, as much as 20%, is also generated by the circuits facing MARS due to albedo of MARS.

Mardesich, N.↗

R$\&$D of Power Over Fiber in harsh environments and its novel application for the DUNE Photon Detection System

The Deep Underground Neutrino Experiment (DUNE) is a next generation long-baseline neutrino experiment that will send an intense beam of neutrinos through two detector complexes: a near detector complex located at Fermilab (Chicago), and a far detector complex located $\sim$ 1.5 km underground at Sanford Underground Research Facility (SURF) in South Dakota. One of the DUNE Far Detector (FD) modules will employ the Vertical Drift (VD) Technology, which will vertically drift the ionized electrons from the cathode plane suspended at the mid-height of the active volume of the cryostat. The Photon Detection System (PDS) will be installed along the cathode and behind the field cage to increase the photon detection coverage. Due to the high voltage ($\sim$300 kV) present at the cathode, conventional copper cables cannot be used to power the photon detectors. Therefore, Power-over-Fiber (PoF) technology will be deployed to power the PDS based on optical power transmission over optical fibers. This poster presents the R$&$D campaign on different PoF components under harsh environments and its novel application in the DUNE PDS.

Martinez caicedo, David Alejandro [South Dakota Sc↗

Optimum design of antireflection coating for silicon solar cells

Based on classical electromagnetic theory, reflectivity calculations for various single and double optical coating systems for silicon solar cells are presented. From calculations and considerations of solar spectral response of the solar cells, the number and thickness of coating materials needed to obtain efficient solar cells can be predicted. Some experimental results on single layer coated cells are also presented for comparison with calculations, and agreement is good. By means of microwave transmission line analogy, the design of the multilayer coating can be simplified by using Tchebycheff polynomials.

Wang, E. Y.↗

Multispectral scanner flight model (F-1) radiometric calibration and alignment handbook

This handbook on the calibration of the MSS-D flight model (F-1) provides both the relevant data and a summary description of how the data were obtained for the system radiometric calibration, system relative spectral response, and the filter response characteristics for all 24 channels of the four band MSS-D F-1 scanner. The calibration test procedure and resulting test data required to establish the reference light levels of the MSS-D internal calibration system are discussed. The final set of data ("nominal" calibration wedges for all 24 channels) for the internal calibration system is given. The system relative spectral response measurements for all 24 channels of MSS-D F-1 are included. These data are the spectral response of the complete scanner, which are the composite of the spectral responses of the scan mirror primary and secondary telescope mirrors, fiber optics, optical filters, and detectors. Unit level test data on the measurements of the individual channel optical transmission filters are provided. Measured performance is compared to specification values.

Source record↗

Pulsed laser spectral measurement using a Fabry-Perot interferometer: Limits to resolution

We are developing a Doppler lidar system using the edge technique to measure atmospheric wind profiles. The edge technique requires a laser with a narrow spectral bandwidth and a high resolution optical filter. The lidar system will use a Nd:YAG laser operating at 1.064 microns and a high resolution Fabry-Perot interferometer for the edge filter. The Doppler shift measurement is made by locating the laser on the edge of the filter's spectral response function. Due to the steep slope on the edge, large changes in the filter transmission will be observed for small changes in frequency. The Doppler shift can be determined from a measurement of this change in filter transmission if the filter spectral response function in the region of the measurement is well known. Recently developed injection seeded solid state lasers have made near transform limited laser output readily available for lidar work. Injection-seeded Nd:YAG laser exhibit single mode output with smooth Gaussian temporal pulse shapes. Results of an experiment we conducted to evaluate the effects of a short Gaussian temporal input pulse on the spectral response of a high resolution Fabry-Perot interferometer are presented.

Notari, Anthony↗

Monolithic millimeter-wave diode array beam controllers: Theory and experiment

In the current work, multi-function beam control arrays have been fabricated and have successfully demonstrated amplitude control of transmitted beams in the W and D bands (75-170 GHz). While these arrays are designed to provide beam control under DC bias operation, new designs for high-speed electronic and optical control are under development. These arrays will fill a need for high-speed watt-level beam switches in pulsed reflectometer systems under development for magnetic fusion plasma diagnostics. A second experimental accomplishment of the current work is the demonstration in the 100-170 GHz (D band) frequency range of a new technique for the measurement of the transmission phase as well as amplitude. Transmission data can serve as a means to extract ('de-embed') the grid parameters; phase information provides more complete data to assist in this process. Additional functions of the array beam controller yet to be tested include electronically controlled steering and focusing of a reflected beam. These have application in the areas of millimeter-wave electronic scanning radar and reflectometry, respectively.

Sjogren, L. B.↗

In situ quantum verification of polarization-stabilized optical channels

The active stabilization of polarization channels is a task of growing importance as quantum networks move to deployed demonstrations over existing fiber infrastructure. However, the uniquely strict requirements for high-fidelity qubit transmission complicate the extent to which classical solutions may apply to future quantum networks, particularly in terms of recognizing noise sources present in low-flux, nonunitary channels. Here we introduce an in situ benchmarking approach that augments a classical polarization tracking system, limited to unitary correction, with simultaneously transmitted quantum light for ancilla-assisted process tomography of the full quantum map. Implemented in a quantum local-area network, our method uses the reconstructed map both to validate the classical compensation and to expose noise sources it fails to capture. A sliding measurement window that continuously updates the estimated quantum process further increases sensitivity to rapid channel fluctuations. Our results should unlock new opportunities for in situ channel characterization in quantum-classical coexistence networks.

Stevens, Matthew L [Arizona State University]↗

Multiple wavelength geodesy

An apparatus is being constructed which should be able to measure baselines up to 50 km long with a fractional uncertainty of about 5 x 10 to the -8 power. The instrument will measure both the optical length and the required correction due to the refractivity of the atmosphere, using three wavelengths transmitted in one direction over the path to an active receiver. The three wavelengths are 632.8 nm, 441.6 nm and 3.7 cm. The two endpoint instruments are synchronized using subsidiary return transmissions at 632.8 nm and another telemetry signal. The one-way nature of the system allows an increase in range over existing round-trip systems.

Levine, J.↗

Optical and Probe Diagnostics Applied to Reacting Flows

The general theme of the research my NASA colleague and I have planned is "Optical and probe diagnostics applied to reacting flows". We plan to explore three major threads during the fellowship period. The first interrogates the flame synthesis of carbon nanotubes using aerosol catalysts. Having demonstrated the viability of the technique for nanotube synthesis, we seek to understand the details of this reacting system which are important to its practical application. Laser light scattering will reveal changes in particle size at various heights above the burner. Analysis of the flame gas by mass spectroscopy will reveal the chemical composition of the mixture. Finally, absorption measurements will map the nanotube concentration within the flow. The second thread explores soot oxidation kinetics. Despite the impact of soot on engine performance, fire safety and pollution, models for its oxidation are inhibited by uncertainty in the values of the oxidation rate. We plan to employ both optical and microscopic measurements to refine this rate. Cavity ring-down absorption measurements of the carbonaceous aerosol can provide a measure of the mass concentration with time and, hence, an oxidation rate. Spectroscopic and direct probe measurements will provide the temperature of the system needed for subsequent modeling. These data will be benchmarked against changes in soot nanostructures as revealed by transmission electron microscopic images from directly sampled material.

Ticich, Thomas M.↗

Real-time tracking of structural evolution in 2D MXenes using theory-enhanced machine learning

In situ Electron Energy Loss Spectroscopy (EELS) combined with Transmission Electron Microscopy (TEM) has traditionally been pivotal for understanding how material processing choices affect local structure and composition. However, the ability to monitor and respond to ultrafast transient changes, now achievable with EELS and TEM, necessitates innovative analytical frameworks. Here, we introduce a machine learning (ML) framework tailored for the real-time assessment and characterization of in operando EELS Spectrum Images (EELS-SI). We focus on 2D MXenes as the sample material system, specifically targeting the understanding and control of their atomic-scale structural transformations that critically influence their electronic and optical properties. This approach requires fewer labeled training data points than typical deep learning classification methods. By integrating computationally generated structures of MXenes and experimental datasets into a unified latent space using Variational Autoencoders (VAE) in a unique training method, our framework accurately predicts structural evolutions at latencies pertinent to closed-loop processing within the TEM. This study presents a critical advancement in enabling automated, on-the-fly synthesis and characterization, significantly enhancing capabilities for materials discovery and the precision engineering of functional materials at the atomic scale.

47 OTHER INSTRUMENTATION↗

Ocean Drifter Project

Four drifting buoys were fabricated from mostly local hardware plus animal locating transmitters. The first two working models were dropped from a Wallops aircraft, to test the mechanical integrity and to test the ability of the whole system to withstand the drop and provide usable data. There are two temperature sensors on board, one to measure sea surface temperature and the other to measure air temperature. An onboard computer controls the transmissions, sending three water temperature readings for each air temperature reading in order to differentiate one from the other after data reduction. Guidelines for the development and test of optical drifting buoys include: air deployable and expendable, reasonable cost for multiple deployment, 1 year lifetime, use of existing technology and a minimal validation parameter set.

Mason, C. D.↗

Holographic Optical Elements as Scanning Lidar Telescopes

We have investigated and developed the use of holographic optical elements (HOE) and holographic transmission gratings for scanning lidar telescopes. By rotating a flat HOE in its own plane with the focal spot on the rotation axis, a very simple and compact conical scanning telescope is possible. We developed and tested transmission and reflection HOES for use with the first three harmonics of Nd:YAG lasers, and designed, built, and tested two lidar systems based on this technology.

Schwemmer, Geary K.↗

Optical encryption interface

An analog optical encryption system based on phase scrambling of two-dimensional optical images and holographic transformation for achieving large encryption keys and high encryption speed. An enciphering interface uses a spatial light modulator for converting a digital data stream into a two dimensional optical image. The optical image is further transformed into a hologram with a random phase distribution. The hologram is converted into digital form for transmission over a shared information channel. A respective deciphering interface at a receiver reverses the encrypting process by using a phase conjugate reconstruction of the phase scrambled hologram.

Jackson, Deborah J.↗