SEARCH · Search NASA

Results for “ordered growth”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

SourceResearch connectionFrom yearThrough year

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 469 records · Page 26

All sources NASA NTRS DOE OSTI

NASA NTRSDate not supplied

Simulating Sulfate Aerosol Size in the Hunga Tonga Plume: Comparisons with Observations

Using the NASA GEOS Chemistry Climate Model (CCM) coupled to a detailed sectional aerosol microphysical model, we have simulated the January 2022 Hunga Tonga-Hunga Ha’apai (HTHH) plume. We have developed a version of the Global Modeling Initiative (GMI) chemistry mechanism to include the requisite sulfur chemistry and coupled it to the Community Aerosol and Radiation Model for Atmospheres (CARMA) sectional aerosol microphysics within the GEOS CCM. Our simulations focus on the lifecycle of stratospheric sulfur injected by the eruption–from the oxidation of the injected sulfur dioxide to the nucleation, growth, coagulation, hydration, and eventual settling of the volcanic sulfate aerosol particles. In order to constrain the simulated microphysics, we focus on comparing our model to observations with aerosol size information, namely in-situ particle counter observations and multi-wavelength satellite observations from OMPS-LP and SAGE-III. This eruption provides an interesting test case for our model; both the modeled gas-phase chemistry as well as the modeled aerosol microphysics are perturbed by the massive injection of water that accompanied the primary sulfur emissions from the eruption.

aerosols↗

NASA NTRS1985

Experimental and Theoretical Studies of Wetting and Multilayer Adsorption

The recent work with partially miscible binary liquid mixtures has established that the structure of the liquid-vapor interface can undergo a first-order phase transition from incomplete to complete wetting of the vapor as the temperature is raised. A discontinuity in the change of interfacial tension as a function of temperature at the phase transition has been predicted to occur in many systems and to play an important role in the growth of uniform composites from alloy melts at monotectic points. These measurements are the first to establish the order of the transition. Studies of capillary rise in SF6 in a unique interferometer have led to the first measurements of the thickness of wetting layers (or equivalently, multilayer adsorbed films) on a solid surface near a liquid-vapor critical point. Instabilities in wetting layers were observed. A theory for the instabilities is being developed and will be checked by both static and dynamic optical experiments. The effect of gravity on the apparent thickness of interfaces (as measured by ellipsometry) is under study.

Moldover, M. R.↗

NASA NTRS1980

Instability process in low Reynolds number supersonic jets

The objective of the present research was to characterize the instability of supersonic jets of Mach numbers 1.4, 2.1, and 2.5 in the Reynolds number range around 8000. In this Reynolds number range the jet instability has its maximum coherence so that its properties as well as the acoustic properties can be most clearly identified. Growth rate, wavelength, and wave orientation of dominant spectral components of the instability for the three Mach number jets were measured in order to characterize the instability. The saturation and subsequent decay on the instability are coincident with a drastic decrease in the coherence of the instability. Associated research shows that the phenomenon of rapid growth and decay is of fundamental importance in the noise generation process.

Morrison, G. L.↗

NASA NTRS1974

Transmission of sound through annular ducts of varying cross sections and sheared mean flow

An asymptotic solution is presented for the transmission and attenuation of acoustic waves in an annular duct of slowly varying cross section which carries a sheared mean flow. The analysis also takes into account the growth of the boundary layer as well as any slow variations in the acoustic liner properties. The problem is reduced to the solution of a first-order ordinary differential equation for the amplitude. The analysis is used to estimate the effects of the variations of the duct cross section and boundary layer growth on the different acoustic modes.

Nayfeh, A. H.↗

NASA NTRS1992

Studies on the growth and indole-3-acetic acid and abscisic acid content of Zea mays seedlings grown in microgravity

Measurements were made of the fresh weight, dry weight, dry weight-fresh weight ratio, free and conjugated indole-3-acetic acid, and free and conjugated abscisic acid in seedlings of Zea mays grown in darkness in microgravity and on earth. Imbibition of the dry kernels was 17 h prior to launch. Growth was for 5 d at ambient orbiter temperature and at a chronic accelerational force of the order of 3 x 10(-5) times earth gravity. Weights and hormone content of the microgravity seedlings were, with minor exceptions, not statistically different from seedlings grown in normal gravity. The tissues of the shuttle-grown plants appeared normal and the seedlings differed only in the lack of orientation of roots and shoots. These findings, based upon 5 d of growth in microgravity, cannot be extrapolated to growth in microgravity for weeks, months, and years, as might occur on a space station. Nonetheless, it is encouraging, for prospects of bioregeneration of the atmosphere and food production in a space station, that no pronounced differences in the parameters measured were apparent during the 5 d of plant seedling growth in microgravity.

manned↗

NASA NTRS1986

Simple formulas for strain-energy release rates with higher order and singular finite elements

A general finite element procedure for obtaining strain-energy release rates for crack growth in isotropic materials is presented. The procedure is applicable to two-dimensional finite element analyses and uses the virtual crack-closure method. The procedure was applied to non-singular 4-noded (linear), 8-noded (parabolic), and 12-noded (cubic) elements and to quarter-point and cubic singularity elements. Simple formulas for strain-energy release rates were obtained with this procedure for both non-singular and singularity elements. The formulas were evaluated by applying them to two mode I and two mixed mode problems. Comparisons with results from the literature for these problems showed that the formulas give accurate strain-energy release rates.

Raju, I. S.↗

NASA NTRS1987

Calculation of strain-energy release rates with higher order and singular finite elements

A general finite element procedure for obtaining strain-energy release rates for crack growth in isotropic materials is presented. The procedure is applicable to two-dimensional finite element analyses and uses the virtual crack-closure method. The procedure was applied to nonsingular 4-noded (linear), 8-noded (parabolic), and 12-noded (cubic) elements and to quarter-point and cubic singularity elements. Simple formulas for strain-energy release rates were obtained with this procedure for both nonsingular and singularity elements. The formulas were evaluated by applying them to two mode I and two mixed mode problems. Comparisons with results from the literature for these problems showed that the formulas give accurate strain-energy release rates.

Raju, I. S.↗

NASA NTRS1975

Development of an economical silicon solar cell

The growth of electronically viable silicon films on inexpensive foreign substrates is studied, with the objective of creating a technology to radically reduce the overall cost of the silicon employed in photovoltaic solar energy conversion. The approach employed is to enhance crystalline ordering during film nucleation by confining arriving silicon atoms to a narrow band traveling across a substrate, i.e., the Lateral Growth Technique (LGT). The efforts have employed physical vapor deposition of silicon in a vacuum evaporator on glass and metal substrates with both slit masks and single defining edges, and subsequent chemical vapor deposition (CVD) of thicker films on these thin film structures by pyrolysis of silane at higher temperatures.

Lindmayer, J.↗

NASA NTRS1990

On the average rate of growth in sunspot number and the size of the sunspot cycle

The average rate of growth in sunspot number over selected time intervals and the maximum average value as they both relate to the size of the cycle are examined, in order to predict the size of cycle 22. The predictions are compared with those of Wilson (1990) to determine whether a consensus is apparent. The average rate of growth during the ascending portion of the sunspot cycle, defined as the difference in smoothed sunspot number values between elapsed time t and sunspot minimum divided by t, is shown to correlate with the size of the sunspot cycle, especially for t greater or equal to 18 months. The maximum value of the average rate of growth is also shown to highly correlate (r = 0.98) with the size of the cycle. Using 4.5 as the maximum value of the average rate of growth, a lower limit for R(M) is estimated. The results show that the findings are consistent with the previous single variate predictions for R(M) for cycle 22.

Wilson, Robert M.↗

NASA NTRS1989

Stability of compressible boundary layers

The stability of compressible 2-D and 3-D boundary layers is reviewed. The stability of 2-D compressible flows differs from that of incompressible flows in two important features: There is more than one mode of instability contributing to the growth of disturbances in supersonic laminar boundary layers and the most unstable first mode wave is 3-D. Whereas viscosity has a destabilizing effect on incompressible flows, it is stabilizing for high supersonic Mach numbers. Whereas cooling stabilizes first mode waves, it destabilizes second mode waves. However, second order waves can be stabilized by suction and favorable pressure gradients. The influence of the nonparallelism on the spatial growth rate of disturbances is evaluated. The growth rate depends on the flow variable as well as the distance from the body. Floquet theory is used to investigate the subharmonic secondary instability.

Nayfeh, Ali H.↗

NASA NTRS1990

Hydrogen induced fracture characteristics of single crystal nickel-based superalloys

A stereoscopic method for use with x ray energy dispersive spectroscopy of rough surfaces was adapted and applied to the fracture surfaces single crystals of PWA 1480E to permit rapid orientation determinations of small cleavage planes. The method uses a mathematical treatment of stereo pair photomicrographs to measure the angle between the electron beam and the surface normal. One reference crystal orientation corresponding to the electron beam direction (crystal growth direction) is required to perform this trace analysis. The microstructure of PWA 1480E was characterized before fracture analysis was performed. The fracture behavior of single crystals of the PWA 1480E nickel-based superalloy was studied. The hydrogen-induced fracture behavior of single crystals of the PWA 1480E nickel-based superalloy was also studied. In order to understand the temperature dependence of hydrogen-induced embrittlement, notched single crystals with three different crystal growth orientations near zone axes (100), (110), and (111) were tensile tested at 871 C (1600 F) in both helium and hydrogen atmospheres at 34 MPa. Results and conclusions are given.

Chen, Po-Shou↗

NASA NTRS1998

The Effects of Ground and Space Processing on the Properties of Organic, Polymeric, and Colloidal Materials

In recent years, a great deal of interest has been directed toward the use of organic materials in the development of high-efficiency optoelectronic and phototonic devices. There is a myriad of possibilities among organic materials which allow flexibility in the design of unique structures with a variety of functional groups. The use of nonlinear optical (NLO) organic materials as thin film wave-guides allows full exploitation of their desirable qualifies by permitting long interaction lengths and large susceptibilities allowing modest power input. There are several methods in use to prepare thin films such as Langmuir-Blodgett (LB) and self-assembly techniques, vapor deposition, growth from sheared solution or melt, and melt growth between glass plates. Organic-based materials have many features that make them desirable for use in optical devices, such as high second-and third-order nonlinearity, flexibility of molecular design, and damage resistance to optical radiation. However, their use in devices has been hindered by processing difficulties for crystals and thin films. We discuss the potential role of microgravity processing of a few organic and polymeric materials. It is of interest to note how materials with second-and third-order NLO behavior may be improved in a diffusion-limited environment and ways in which convection may be detrimental to these materials. We focus our discussion on third-order materials for all-optical switching, and second-order materials for frequency conversion and electrooptics. The goal of minimizing optical loss obviously depends on processing methods. For solution-based processes, such as solution crystal growth and solution photopolymerization, it is well known that thermal and solutal density gradients can initiate buoyancy-driven convection. Resultant fluid flows can affect transport of material to and from growth interfaces and become manifest in the morphology and homogeneity of the growing film or crystal. Likewise, buoyancy-driven convection can hinder production of defect-free, high-quality crystals or films during crystal and film growth by vapor deposition.

Frazier, Donald O.↗

NASA NTRS1990

Coupled effects of conduction in the crystal and thermo-solutal convection in a rectangular inclined enclosure

To date modeling of crystal growth of optoelectronic materials using Physical Vapor Transport has been limited to the study of the fluid phase. To achieve it, the equations of coupled heat, mass and momentum transfer in the gas have to be solved. The first objective of this study is to examine the effect of heat conduction in the crystal on the fluid flow in the neighborhood of the interface. Heat transfer boundary conditions on both interfaces were modified to take into account the additional heat flux between gas and solid. It is proved that heat conduction does not affect the fluid flow. In the presence of gravity, density gradients in the fluid phase generate convection responsible for the problem of a nonplanar growth of the interface. The second objective is to study systematically under one-g the different possible flows in order to solve this problem. Depending on the parameters, a diffusive mode and three convective modes (thermal, solutal and thermo-solutal) are observed. The competition between thermal and solutal convections leads to a mathematical condition which can be used to achieve a planar growth. It is proven that, under the physical conditions chosen, this mathematical condition cannot be thermodynamically satisfied.

Mennetrier, Christophe↗

NASA NTRS1992

Experimental observation of the influence of furnace temperature profile on convection and segregation in the vertical Bridgman crystal growth technique

Azulene-doped naphthalene was directionally solidified during the vertical Bridgman-Stockbarger technique. Doping homogeneity and convection were determined as a function of the temperature profile in the furnace and the freezing rate. Convection velocities were two orders of magnitude lower when the temperature increased with height. Rarely was the convection pattern axisymmetric, even though the temperature varied less than 0.1 K around the circumference of the growth ampoule. Correspondingly the cross sectional variation in azulene concentration tended to be asymmetric, especially when the temperature increased with height. This cross sectional variation changed dramatically along the ingot, reflecting changes in convection presumably due to the decreasing height of the melt. Although there was large scatter and irreproducibility in the cross sectional variation in doping, this variation tended to be least when the growth rate was low and the convection was vigorous. It is expected that compositional variations would also be small at high growth rates with weak convection and flat interfaces, although this was not investigated in the present experiments. Neither rotation of the ampoule nor deliberate introduction of thermal asymmetries during solidification had a significant influence on cross sectional variations in doping. It is predicted that slow directional solidification under microgravity conditions could produce greater inhomogeneities than on Earth. Combined use of microgravity and magnetic fields would be required to achieve homogeneity when it is necessary to freeze slowly in order to avoid constitutional supercooling.

Neugebauer, G. T.↗

NASA NTRS2009

Influence of Containment on Defects in GeSi Crystals

Crystals grown without being in contact with a container have superior quality to otherwise similar crystals grown in direct contact with a container, especially with respect to impurity incorporation, formation of dislocations, and residual stress in crystals. "Detached" or "dewetted" Bridgman growth is similar to regular Bridgman growth in that most of the melt is in contact with the crucible wall, but the crystal is separated from the wall by a small gap, typically of the order of 10(exp -5) m. A small meniscus bridges the gap between the top of the crystal and the wall. Key parameters involved in achieving detached growth are the contact angle between the melt and crucible and the pressure differential across the meniscus. Sessile drop measurements were used to determine the wetting angles of Ge(sub 1-x)Si(sub x) melts on a variety of substrates and found that the highest wetting angles were achieved with pyrolitic boron nitride (pBN). GeSi crystals have been repeatedly grown detached in pBN crucibles but only occasionally in crucibles with lower wetting angles. Experiments have been conducted to assess the effect of pressure differential across the meniscus in sealed crucibles. This was done by adjusting the temperature profile after partial melting of the starting material. In a separate set of experiments, the pressure was controlled by connecting the volume below the meniscus to a regulated gas supply. The experiments were in agreement with calculations which predicted that stable detachment will only occur in crucibles with a low wetting angle over a relatively narrow range of pressure differential. Detached-grown crystals exhibited superior structural quality as evidenced by measurements of etch pit density, synchrotron white beam X-ray topography and double axis X-ray diffraction.

Volz, M. P.↗

NASA NTRS1976

Alternative strategies for implementing silicon-ribbon technology for photovoltaic applications

Interactive computer models are being designed to support the development of technological and economic data required to define the potential of silicon sheet growth for large scale photovoltaic applications. Technology projection and sensitivity analysis suggest that single-ribbon growth systems offer the best potential for achieving low-cost silicon sheet material within the shortest period of time. Such systems must be highly reliable, be capable of near unattended growth, and feature automatic melt replenishment. Processing-technology improvement, such as the following, are the key elements for reducing the cost of silicon sheet material: (i) increasing ribbon width; (ii) speeding up the growth rate; and (iii) decreasing ribbon thickness. Such tasks should be pursued in that order to minimize sheet material cost. One interesting finding is that significant reductions in sheet material cost are achievable in the near future by increasing ribbon width to 5 cm.

Kran, A.↗

NASA NTRS1977

Stability of higher-order Bragg interactions in active periodic media

The stability of waves in unbounded, longitudinally periodic media is studied for index and gain coupling. Time-independent periodic media are found to support both stable and absolutely unstable waves. The wave characteristics depend upon average gain or loss, coupling type, and Bragg order. The extended coupled waves equations provide explicit values of threshold, frequency, and temporal growth rate for instabilities at all Bragg resonances through the dispersion relation. Applications to multiharmonic periodicities and complex couplings are briefly discussed with particular note taken of possible reductions of the stability thresholds and removal of threshold degeneracies. Comparisons are made to the longitudinally bounded case of distributed feedback lasers.

Jaggard, D. L.↗

NASA NTRS1980

Liquid-phase epitaxy grown PbSnTe distributed feedback laser diodes with broad continuous single-mode tuning range

Distributed feedback (DFB) pulsed laser operation has been demonstrated in stripe geometry Pb(1-x)Sn(x)Te double-heterostructures grown by liquid-phase epitaxy. The grating structure of 0.79 micron periodicity operates in first order near 12.8 microns and was fabricated prior to the liquid-phase epitaxial growth using holographic exposure techniques. These DFB lasers had moderate thresholds, 3.6 kA/sq cm, and the output power versus current curves exhibited a sharp turn-on free of kinks. Clean, single-mode emission spectra, continuously tunable over a range in excess of 20 per cm, centered about 780 per cm (12.8 microns), and at an average rate of 1.2 per cm-K from 9 to 26 K, were observed. While weaker modes could at times be seen in the spectrum, substantially single-mode operation was obtained over the entire operating range and to over 10 times threshold.

Hsieh, H.-H.↗