Search NASA⌕ Search

SEARCH · Search NASA

Results for “outgassing”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 469 records · Page 26

Spacecraft self-contamination due to back-scattering of outgas products

The back-scattering of outgas contamination near an orbiting spacecraft due to intermolecular collisions was analyzed. Analytical tools were developed for making reasonably accurate quantitative estimates of the outgas contamination return flux, given a knowledge of the pertinent spacecraft and orbit conditions. Two basic collision mechanisms were considered: (1) collisions involving only outgas molecules (self-scattering) and (2) collisions between outgas molecules and molecules in the ambient atmosphere (ambient-scattering). For simplicity, the geometry was idealized to a uniformly outgassing sphere and to a disk oriented normal to the freestream. The method of solution involved an integration of an approximation of the Boltzmann kinetic equation known as the BGK (or Krook) model equation. Results were obtained in the form of simple equations relating outgas return flux to spacecraft and orbit parameters. Results were compared with previous analyses based on more simplistic models of the collision processes.

Robertson, S. J.↗

Results of an analytical study of spacecraft deposition contamination by internal reflection spectroscopy

Outgassing, deposition, and desorption kinetics of silicone compounds, are examined as examples of optical surface contaminants of spacecraft windows. Their behavior in a space environment after exposure to ultraviolet radiation is also examined. The use of internal reflection spectroscopy is shown to provide a viable means of real-time, in-situ identification of contaminants of orbiting spacecraft. The instrumental techniques are proposed as the basis of further investigations and the development of flight hardware.

Mookherji, T.↗

Theories of the origin and nature of the universe

The origin of life on earth is seen arising as a natural consequence of a long series of physical and chemical processes taking place in association with evolution of the universe. The present theory is that any premordial earth atmosphere, resulting from accumulation from the primitive solar nebula, was probably swept away by the very intensive T Tauri stage of the solar wind. Subsequently, the present atmosphere and oceans of the earth were outgassed from the interior. Biochemical components of the gases were mainly water vapor and carbon dioxide.

A. G. W. Cameron↗

Heterogeneous reaction of ozone with aluminum oxide

Rates and collision efficiencies for ozone decomposition on aluminum oxide surfaces were determined. Samples were characterized by BET surface area, X-ray diffraction, particle size, and chemical analysis. Collision efficiencies were found to be between 2 times 10 to the -10 power and 2 times 10 to the -9 power. This is many orders of magnitude below the value of 0.000001 to 0.00001 needed for appreciable long-term ozone loss in the stratosphere. An activation energy of 7.2 kcal/mole was found for the heterogeneous reaction between -40 C and 40 C. Effects of pore diffusion, outgassing and treatment of the aluminum oxide with several chemical species were also investigated.

Keyser, L. F.↗

Molecular beam mass spectrometer development

An analytical model, based on the kinetics theory of a drifting Maxwellian gas is used to determine the nonequilibrium molecular density distribution within a hemispherical shell open aft with its axis parallel to its velocity. The concept of a molecular shield in terrestrial orbit above 200 km is also analyzed using the kinetic theory of a drifting Maxwellian gas. Data are presented for the components of the gas density within the shield due to the free stream atmosphere, outgassing from the shield and enclosed experiments, and atmospheric gas scattered off a shield orbiter system. A description is given of a FORTRAN program for computating the three dimensional transition flow regime past the space shuttle orbiter that employs the Monte Carlo simulation method to model real flow by some thousands of simulated molecules.

Brock, F. J.↗

Advanced composites: Environmental effects on selected resin matrix materials

The effects that expected space flight environment has upon the mechanical properties of epoxy and polyimide matrix composites were analyzed. Environmental phenomena covered water immersion, high temperature aging, humidity, lightning strike, galvanic action, electromagnetic interference, thermal shock, rain and sand erosion, and thermal/vacuum outgassing. The technology state-of-the-art for graphite and boron reinforced epoxy and polyimide matrix materials is summarized to determine the relative merit of using composites in the space shuttle program. Resin matrix composites generally are affected to some degree by natural environmental phenomena with polyimide resin matrix materials less affected than epoxies.

Welhart, E. K.↗

Interconnnect and bonding technologies for large flexible solar arrays

Thermocompression bonding and conductive adhesive bonding are developed and evaluated as alternate methods of joining solar cells to their interconnect assemblies. Bonding materials and process controls applicable to fabrication of large, flexible substrate solar cell arrays are studied. The primary potential use of the techniques developed is on the solar array developed by NASA/MSFC and LMSC for solar electric propulsion (SEP) and shuttle payload applications. This array is made up of flexible panels approximately 0.7 by 3.4 meters. It is required to operate in space between 0.3 and 6 AU for 5 years with limited degradation. Materials selected must be capable of enduring this space environment, including outgassing and radiation.

Source record↗

The seven ages of a planet

On the basis of almost universally held assumptions concerning the formation of the planets and the isolation of the solar system from outside influences it follows rather plausibly that all terrestrial planets pass in principle through seven stages. The processes involved include the solidification of grains from gas in the condensation stage, planetesimal interactions, and formation processes. Vigorous convection processes lead to the gravitational separation of iron and the outgassing of oceans. Other stages are related to plate tectonics and terminal volcanism. The ultimate stage of quiescence is characterized by a thick lithosphere and no volcanism.

Kaula, W. M.↗

Mercury's atmosphere - A perspective after Mariner 10

Implications of Mariner 10 observations are discussed regarding the composition and structure of Mercury's atmosphere as well as its interaction with the solar wind. The Mariner 10 data cited indicate that Mercury's atmosphere is apparently similar to that on the moon. It is shown that helium could be supplied to the atmosphere either by the radioactive decay of uranium and thorium in the planetary crust or by accretion of a small fraction of the solar-wind flux. It is noted that the absence of argon could be explained by a potassium-deficient crust, but this conclusion is by no means firm. Upper limits for outgassing of H2O and CO2 are estimated which suggest that either the planet is deficient in volatiles or is relatively inactive in comparison with earth.

Kumar, S.↗

Composition of the atmosphere at the surface of Mars - Detection of argon-36 and preliminary analysis

The composition of the Martian atmosphere was determined by the mass spectrometer in the molecular analysis experiment. The presence of argon and nitrogen was confirmed and a value of 1 to 2750 plus or minus 500 for the ratio of argon-36 to argon-40 was established. A preliminary interpretation of these results suggests that Mars had a slightly more massive atmosphere in the past, but that much less total outgassing has occurred on Mars than on earth.

Owen, T.↗

Solar cell array design handbook, volume 1

Twelve chapters discuss the following: historical developments, the environment and its effects, solar cells, solar cell filters and covers, solar cell and other electrical interconnections, blocking and shunt diodes, substrates and deployment mechanisms, material properties, design synthesis and optimization, design analysis, procurement, production and cost aspects, evaluation and test, orbital performance, and illustrative design examples. A comprehensive index permits rapid locating of desired topics. The handbook consists of two volumes: Volume 1 is of an expository nature while Volume 2 contains detailed design data in an appendix-like fashion. Volume 2 includes solar cell performance data, applicable unit conversion factors and physical constants, and mechanical, electrical, thermal optical, magnetic, and outgassing material properties. Extensive references are provided.

Rauschenbach, H. S.↗

Internal friction Q factor measurements in lunar rocks

Investigations to aid in the interpretation of seismic data obtained below the lunar surface are reported. Fine grained basalt with about 1.0% open core porosity was encapsulated under hard vacuum and measured. A Q value just under 2,000 at 0.5 kbar was achieved for a terrestrial analog of lunar basalt. In contrast to the modulus which increases by as much as 10%, the quality factor Q shows little or no change with pressure (a well outgassed sample maintains a high Q, whereas one exposed to laboratory atmosphere maintains a low Q). This result suggests that the absence of volatiles plays an important role in determining the q factor even at a depth of 10 km below the lunar surface.

Tittmann, B. R.↗

X-ray photoelectron spectroscopy study of radiofrequency sputtered chromium bromide, molybdenum disilicide, and molybdenum disulfide coatings and their friction properties

Radiofrequency sputtered coatings of CRB2, MOSI2, and MOS2 were examined by X-ray photoelectron spectroscopy. The effects of sputtering target history, deposition time, RF power level, and substrate bias on film composition were studied. Friction tests were run on RF sputtered surfaces of 440-C steel to correlate XPS data with lubricating properties. Significant deviations from stoichiometry and high oxide levels for all three compounds were related to target outgassing. The effect of biasing on these two factors depended on the compound. Improved stoichiometry correlated well with good friction and wear properties.

Wheeler, D. R.↗

Atmospheric analyzer, carbon monoxide monitor and toluene diisocyanate monitor

The purpose of the atmospheric analyzer and the carbon monoxide and toluene diisocyanate monitors is to analyze the atmospheric volatiles and to monitor carbon monoxide and toluene diisocyanate levels in the cabin atmosphere of Skylab. The carbon monoxide monitor was used on Skylab 2, 3, and 4 to detect any carbon monoxide levels above 25 ppm. Air samples were taken once each week. The toluene diisocyanate monitor was used only on Skylab 2. The loss of a micrometeoroid shield following the launch of Skylab 1 resulted in overheating of the interior walls of the Orbital Workshop. A potential hazard existed from outgassing of an isocyanate derivative resulting from heat-decomposition of the rigid polyurethane wall insulation. The toluene diisocyanate monitor was used to detect any polymer decomposition. The atmospheric analyzer was used on Skylab 4 because of a suspected leak in the Skylab cabin. An air sample was taken at the beginning, middle, and the end of the mission.

Shannon, A. V.↗

Comet Halley - The orbital motion

The orbital motion of Comet Halley is investigated over the interval from A.D. 837 to 2061. Using the observations from 1607 through 1911, least-squares differential orbit corrections were successfully computed using the existing model for the nongravitational forces. The nongravitational-force model was found to be consistent with the outgassing-rocket effect of a water-ice cometary nucleus and, prior to the 1910 return, these forces are time-independent for nearly a millennium. For the 1986 return, viewing conditions are outlined for the comet and the related Orionid and Eta Aquarid meteor showers.

Yeomans, D. K.↗

What the exploration of Mars tells us about earth

Data obtained from the Viking missions to Mars have lead to comparisons between characteristics of that planet and certain aspects of earth. Topics discussed include: thermal and compositional evolution of the planets' interiors, the origin of their atmospheres, the history of their fluid environments, the evolution of organic material, and climatic changes. Examples of convective and magmatic activity on the crusts of the two planets are contrasted; outgassing evidenced in the crustal zones is related to the evolution of atmosphere. Analysis of experimental degassing of meteorites provides further insight into the origin and composition of planetary atmospheres. Attributes of the Martian surface, which is apparently an oxidizing rather than reducing medium, are reviewed, and explanations proposed to account for its lack of an organic richness comparable to that found on earth. Data on long-range climatic changes on earth, related to precession, obliquity, and eccentricity of the planet, may contribute to understanding of the Martian polar caps, and vice versa.

Rasool, S. I.↗

Cure-rate data for silicone adhesive

Report describes work with concentrations down to 0.07 percent and is useful when applying adhesives in terrestrial and space applications. Cured Silicone retains low-outgassing properties as well as its snap, elongation, and resilience. Tests for hardness of silicone material also showed good results. No gross hysteresis observable on recovery from stretching nor was there any decrease in hardness.

Clatterbuck, C.↗