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At least 469 records · Page 26

Impacts of Different Operation Conditions and Geological Formation Characteristics on CO2 Sequestration in Citronelle Dome, Alabama

Major concerns of carbon dioxide (CO2) sequestration in subsurface formations are knowledge of the well injectivity and gas storage capacity of the formation, the CO2 pressure and saturation plume extensions during and after injection, and the risks associated with CO2 leakage and fault reactivation. Saline reservoirs are considered as one of the target formations for CO2 sequestration through structural, residual, dissolution, and mineral trapping mechanisms. The boundary condition of the saline reservoir dictates the pressure and saturation plume extension of the injected supercritical CO2 that could expand over large distances. This can lead to sources of risk, e.g., leakage and/or fault reactivation due to presence of wells, thief zones, and geological discontinuities. Therefore, there is a critical need to develop a model that describes how risk-related performance metrics (i.e., the CO2 saturation plume size, the pressure differential plume area, and the pressure differential at specific locations) vary as a function of the size of injection, time following injection, injection operations, and geologic environment. In this study, a systematic reservoir modeling studies of anthropogenic CO2 sequestration in Citronelle dome, Alabama, was performed where all relevant scenarios and conditions to address the questions of the saturation and pressure plume size in the area of review (AoR) and post-injection site care (PISC) are considered. The objective for this study was firstly to systematically simulate CO2 sequestration, i.e., saturation dynamics, and pressure behavior over a range of operational and geological conditions and to derive conclusions about the factors influencing saturation and pressure plume size, post-injection behavior, and the risk associated with them, by developing third-generation reduced order models (ROMs) for reservoir behavior. Finally, to assess the uncertainty associated with our studies, Latin Hypercube Sampling (LHS) together with an experimental design technique, i.e., Plackett–Burman design, was used. Application of Pareto charts and respond surfaces enabled us to determine the most important parameters impacting saturation and pressure plume sizes and to quantify the auto- and cross-correlation among different parameters in both history-matched and upscaled models.

58 GEOSCIENCES↗

Inert gas thrusters

Inert gas thrusters considered for space propulsion systems were investigated. Electron diffusion across a magnetic field was examined utilizing a basic model. The production of doubly charged ions was correlated using only overall performance parameters. The use of this correlation is therefore possible in the design stage of large gas thrusters, where detailed plasma properties are not available. Argon hollow cathode performance was investigated over a range of emission currents, with the positions of the inert, keeper, and anode varied. A general trend observed was that the maximum ratio of emission to flow rate increased at higher propellant flow rates. It was also found that an enclosed keeper enhances maximum cathode emission at high flow rates. The maximum cathode emission at a given flow rate was associated with a noisy high voltage mode. Although this mode has some similarities to the plume mode found at low flows and emissions, it is encountered by being initially in the spot mode and increasing emission. A detailed analysis of large, inert-gas thruster performance was carried out. For maximum thruster efficiency, the optimum beam diameter increases from less than a meter at under 2000 sec specific impulse to several meters at 10,000 sec. The corresponding range in input power ranges from several kilowatts to megawatts.

Kaufman, H. R.↗

Solid impingement erosion mechanisms and characterization of erosion resistance of ductile metals

Experimental results pertaining to spherical glass bead and angular crushed glass particle impingement are presented. A concept of energy adsorption to explain the failure of material is proposed. The erosion characteristics of several pure metals were correlated with the proposed energy parameters and with other properties. Correlations of erosion and material properties were also carried out with these materials to study the effect of the angle of impingement. Analyses of extensive erosion data indicate that surface energy, strain energy, melting point, bulk modulus, hardness, ultimate resilience, atomic volume and product of linear coefficient of thermal expansion, bulk modulus, and temperature rise required for melting, and ultimate resilience, and hardness exhibit the best correlations. It appears that both energy and thermal properties contribute to the total erosion.

Rao, V. P.↗

Weld analysis and control system

The invention is a Weld Analysis and Control System developed for active weld system control through real time weld data acquisition. Closed-loop control is based on analysis of weld system parameters and weld geometry. The system is adapted for use with automated welding apparatus having a weld controller which is capable of active electronic control of all aspects of a welding operation. Enhanced graphics and data displays are provided for post-weld analysis. The system provides parameter acquisition, including seam location which is acquired for active torch cross-seam positioning. Torch stand-off is also monitored for control. Weld bead and parent surface geometrical parameters are acquired as an indication of weld quality. These parameters include mismatch, peaking, undercut, underfill, crown height, weld width, puddle diameter, and other measurable information about the weld puddle regions, such as puddle symmetry, etc. These parameters provide a basis for active control as well as post-weld quality analysis and verification. Weld system parameters, such as voltage, current and wire feed rate, are also monitored and archived for correlation with quality parameters.

Kennedy, Larry Z.↗

Recovery of motion parameters from distortions in scanned images

Scanned images, such as those produced by the scanning-laser ophthalmoscope (SLO), show distortions when there is target motion. This is because pixels corresponding to different image regions are acquired sequentially, and so, in essence, are slices of different snapshots. While these distortions create problems for image registration algorithms, they are potentially useful for recovering target motion parameters at temporal frequencies above the frame rate. Stetter, Sendtner and Timberlake measured large distortions in SLO images to recover the time course of rapid horizontal saccadic eye movements. Here, this work is extended with the goal of automatically recovering small eye movements in two dimensions. Eye position during the frame interval is modeled using a low dimensional parametric description, which in turn is used to generate predicted distortions of a reference template. The input image is then registered to the distorted template using normalized cross correlation. The motion parameters are then varied, and the correlation recomputed, to find the motion which maximizes the peak value of the correlation. The location and value of the correlation maximum are determined with sub-pixel precision using biquadratic interpolation, yielding eye position resolution better than 1 arc minute. This method of motion parameter estimation is tested using actual SLO images as well as simulated images. Motion parameter estimation might also be applied to individual video lines in order to reduce pipeline delays for a near real-time system.

Mulligan, Jeffrey B.↗

Exosomal microRNA-194 causes cardiac injury and mitochondrial dysfunction in obese mice

Highlights: • Circulating miR-194 level positively correlated with human cardiac dysfunction. • Exosomal miR-194 impairs mitochondrial activity. • MiR-194 inhibitor protects diet-induced mouse cardiomyopathy. Obesity is associated with increased cardiovascular morbidity and mortality, but the effects of circulating factors on cardiac function is not fully elucidated. Present study aims to explore the pathophysiological role of microRNA (miR)-194, one of hepatic enriched miRs, in the process of obesity-related cardiomyopathy in human subjects and mice. The expression level of circulating exosomal miR-194 was measured in 39 lean and 35 obese human subjects, and correlated with cardiac parameters. The effects of miR-194 on mitochondrial activity and cardiac function were investigated by administration of miR-194 sponge in mouse cardiomyocytes and obesity-related cardiomyopathy. The upregulation of circulating miR-194 level was closely correlated with impaired human cardiac function, including ejection fraction (r = −0.5002, p In vivo mouse study, high fat diet damaged cardiac function, normal structure and mitochondrial activity, whereas miR-194 sponge improved the cardiac status. Present study uncovered the correlation between circulating miR-194 and cardiac parameters in human subjects, and provided solid evidence of the therapeutic application of miR-194 sponge in combating obesity-mediated cardiac dysfunction.

60 APPLIED LIFE SCIENCES↗

Phase transitions and critical properties in the antiferromagnetic Ising model on a layered triangular lattice with allowance for intralayer next-nearest-neighbor interactions

The phase transitions (PTs) and critical properties of the antiferromagnetic Ising model on a layered (stacked) triangular lattice have been studied by the Monte Carlo method using a replica algorithm with allowance for the next-nearest-neighbor interactions. The character of PTs is analyzed using the histogram technique and the method of Binder cumulants. It is established that the transition from the disordered to paramagnetic phase in the adopted model is a second-order PT. Static critical exponents of the heat capacity (α), susceptibility (γ), order parameter (β), and correlation radius (ν) and the Fischer exponent η are calculated using the finite-size scaling theory. It is shown that (i) the antiferromagnetic Ising model on a layered triangular lattice belongs to the XY universality class of critical behavior and (ii) allowance for the intralayer interactions of next-nearest neighbors in the adopted model leads to a change in the universality class of critical behavior.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Graphite Characterization: Baseline Variability Analysis Report

The Idaho National INL’s Baseline Material Property program provides many measurements of different material properties on a variety of nuclear graphite grades being investigated for irradiation-induced changes in material properties. The baseline material properties provide an unirradiated reference for comparison with measurements of those properties after irradiation. This study describes how uncertainty, or variance, in estimates of important material properties, like compressive strength, may depend on sample size, sample distribution and parameter estimation methods. Compressive strength data from two large collections of specimens from a billet of PCEA graphite (sample size = 230) and a billet of IG-110 graphite (sample size = 48) are used to illustrate these dependencies. The grades of graphite used represent approximate end members in terms of relative variability in strength measurements. Monte Carlo simulation and bootstrapping methods were used to examine variance in Weibull-parameter estimates as a function of sample size. Results were consistent with what previous statistical analyses have shown about the relationship between sample size and width of the confidence interval for maximum likelihood (ML) estimated parameters when samples are repeatedly drawn from a Weibull distribution. As a function of sample size, the precision of the modulus estimate increases faster than that of the characteristic strength. The modulus maximum likelihood estimates (MLEs) are biased for low sample sizes. The American Society for Testing and Materials document ASTM D7846-16 provides equations that describe the dependence of the variance of parameter MLEs on sample size. Using the same methodology, we show that the polynomials provided for variance dependence on sample size are inaccurate for sample sizes greater than ~120. We provide approximations to that relationship that illustrate relative constancy for sample size > ~10, in the logspace relationship of the modulus variance and the log transformed characteristic strength variance. Bootstrapping provided a means of comparing Weibull parameters obtained using ASME’s guidance for specimen collection to those obtained using different weighting in a case where strength is related to position in a billet and to grain orientation and a single distribution is used to characterize the billet. ASME specifies that samples be collected with equal representation in all locations and grain orientations. Parameter values obtained using ASME’s method were different from those obtained using random sampling of the complete data sets, and this was particularly true for the PCEA data. In addition, while the ASME approach yielded more conservative parameters for the PCEA data, the opposite was true for the IG-110 data. The difference observed for the PCEA data set likely reflects the larger number of against-grain specimens collected, which had generally higher strength than the with-grain specimens. This emphasizes the importance of the dependence of strength on location or grain orientation and suggests that it may be prudent to weight specimen collection toward the weaker subgroups if a conservative estimate as desired, as the equal weighting method recommended by ASME would will not always provide the most conservative Weibull parameters. Because spatial correlations commonly exist in certain grades of graphite, future work may involve developing a methodology for parameter inference that relaxes the assumption of independent specimens. ASTM and ASME codes recommend different parameter estimation methods and models of the Weibull distribution in different situations. Descriptions of the effects on parameter estimates for the example billets used in this study provide an example of how the method may affect the parameter estimate, and how—in this case—that compares to differences due to other factors, such as sample size and dependence on grain orientation or sample location.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Experimental investigation of orthotropic panel flutter at arbitrary yaw angles, and comparison with theory

Flutter characteristics for yaw angles between 15 deg and 90 deg were determined experimentally for two types of corrugation-stiffened panels: those with weak twisting stiffness and those with strong twisting stiffness. By mounting the panels on a remotely controlled turntable, good definition of the flutter boundaries was obtained by rotating the panels into and out of flutter. Flutter tests were conducted at M = 2 and M = 1.6. Before testing, vibration tests and analyses were also performed. The experimental flutter data is compared with flutter theory for orthotropic panels utilizing quasi-steady aerodynamics. Five different corrugated panels were tested consisting of one single skin panel having a length-to-width ratio of 5 on clamped supports and four different square double skin panels on discrete flexible supports. The investigation indicated that flutter speed for corrugated panels is highly dependent on yaw angle. Reasonable flutter correlation between analysis and test was obtained for moderate yaw angles, but extreme sensitivity to structural parameters made the correlation at large yaw angles uncertain.

Shyprykevich, P.↗

Dependence of polar cap potential drop on interplanetary parameters

The convection potential drop across the polar cap is computed from data obtained on high-inclination low-altitude satellites. Potential measurements are correlated with various combinations of parameters measured simultaneously in the upstream solar wind. Most of the potential drop is successfully predicted by merging theory, although a significant background potential drop of 35 kV does not depend on IMF parameters and is attributed to a process other than merging. Results indicate that small values of the IMF are amplified by a factor of 5-10 at the dayside magnetopause, which, when taken into account, improves correlations between IMF parameters and polar cap potential drop. Potential drop is better correlated with IMF parameters than with geomagnetic indices, due to nonlinear response of the magnetosphere affecting geomagnetic activity indices.

Reiff, P. H.↗

Differential Exudation Creates Biogeochemically Distinct Microenvironments during Rhizosphere Evolution

Plant roots and associated microbes release a diverse range of functionally distinct exudates into the surrounding rhizosphere with direct impacts on soil carbon storage, nutrient availability, and contaminant dynamics. Yet mechanistic linkages between root exudation and emergent biogeochemical processes remain challenging to measure nondestructively, in real soil, over time. Here we used a novel combination of in situ microsensors with high-resolution mass spectrometry to measure, nondestructively, changing exudation and associated biogeochemical dynamics along single growing plant roots (Avena sativa). We found that metabolite and dissolved organic carbon (DOC) concentrations as well as microbial growth, redox potential (EH), and pH dynamics vary significantly among bulk soil, root tip, and more mature root zones. Surprisingly, the significant spike of rhizosphere DOC upon root tip emergence did not significantly correlate with any biogeochemical parameters. However, the presence of sugars significantly correlated with declines in EH following the arrival of the root tip, likely due to enhanced microbial oxygen demand. Similarly, the presence of organic acids significantly correlated to declines in pH upon root tip emergence. Altogether, our in situ measurements highlight how different exudates released along growing roots create functionally distinct soil microenvironments that evolve over time.

54 ENVIRONMENTAL SCIENCES↗

Physical Correlations and Predictions Emerging from Modern Core-collapse Supernova Theory

Abstract In this paper, we derive correlations between core-collapse supernova observables and progenitor core structures that emerge from our suite of 20 state-of-the-art 3D core-collapse supernova simulations carried to late times. This is the largest such collection of 3D supernova models ever generated and allows one to witness and derive testable patterns that might otherwise be obscured when studying one or a few models in isolation. From this panoramic perspective, we have discovered correlations between explosion energy, neutron star gravitational birth masses, 56 Ni and α -rich freezeout yields, and pulsar kicks and theoretically important correlations with the compactness parameter of progenitor structure. We find a correlation between explosion energy and progenitor mantle binding energy, suggesting that such explosions are self-regulating. We also find a testable correlation between explosion energy and measures of explosion asymmetry, such as the ejecta energy and mass dipoles. While the correlations between two observables are roughly independent of the progenitor zero-age main-sequence (ZAMS) mass, the many correlations we derive with compactness cannot unambiguously be tied to a particular progenitor ZAMS mass. This relationship depends on the compactness/ZAMS mass mapping associated with the massive star progenitor models employed. Therefore, our derived correlations between compactness and observables may be more robust than with ZAMS mass but can nevertheless be used in the future once massive star modeling has converged.

Astronomy & Astrophysics↗

Effects of Microstructural Variability on Thermo-Mechanical Properties of a Woven Ceramic Matrix Composite

The objectives of this paper include identifying important architectural parameters that describe the SiC/SiC five-harness satin weave composite and characterizing the statistical distributions and correlations of those parameters from photomicrographs of various cross sections. In addition, realistic artificial cross sections of a 2D representative volume element (RVE) are generated reflecting the variability found in the photomicrographs, which are used to determine the effects of architectural variability on the thermo-mechanical properties. Lastly, preliminary information is obtained on the sensitivity of thermo-mechanical properties to architectural variations. Finite element analysis is used in combination with a response surface and it is shown that the present method is effective in determining the effects of architectural variability on thermo-mechanical properties.

Goldsmith, Marlana B.↗

Predicting Adverse Events and their Precursors in Aviation Using Multi-Class Multiple-Instance Learning

In recent years, there has been a rapid growth in the application of machine learning techniques that leverage aviation data collected from commercial airline operations to improve safety. Anomaly detection and predictive maintenance have been the main targets for machine learning applications. However, this paper focuses on the identification of precursors, which is a relatively newer application. Precursors are events correlated with adverse events that happen prior to the adverse event itself. Therefore, precursor mining provides many benefits including understanding the reasons behind a safety incident and the ability to identify signatures, which can be tracked throughout a flight to alert the operators of an potential upcoming adverse event. This work proposes using the multiple-instance learning (MIL) framework, a weakly supervised learning task, combined with a carefully designed Multi-Head Convolutional Neural Networks-Recurrent Neural Networks (MHCNN-RNN) architecture to predict different type of adverse events for any given flights and identify their precursors with little to no post-processing.Results obtained show that the MHCNN-RNN is able to accurately forecast high speed and high path angle events during the approach, and that it is also capable of determining the aircraft’s parameters that are correlated to these events. These parameters can be considered precursors to the events.

multiple instance learning↗

Tricyclononenes and tricyclononadienes as efficient monomers for controlled ROMP: understanding structure–propagation rate relationships and enabling facile post-polymerization modification

Grubbs 3rd-generation (G3) pre-catalyst-initiated ring-opening metathesis polymerization (ROMP) remains an indispensable tool in the polymer chemist's toolbox. Tricyclononenes (TCN) and tricyclononadienes (TCND) represent under-explored classes of monomers for ROMP that have the potential to both advance fundamental knowledge (e.g., structure-polymerization kinetics relationships) and serve as practical tools for the polymer chemist (e.g., post-polymerization functionalization). In this work, a library of TCN and TCND imides, monoesters, and diesters, along with their exo-norbornene counterparts, were synthesized to compare their behaviors in G3-initiated ROMP. Real-time 1 H NMR was used to study their polymerization kinetics; propagation rates ( k p ) were extracted for each monomer. To understand the relationships between monomer structure and ROMP propagation rates, density functional theory methods were used to calculate a variety of electronic and steric parameters for each monomer. While electronic parameters (e.g., HOMO energy levels) correlated positively with the measured k p values, steric parameters generally gave improved correlations, which indicates that monomer size and shape are better predictors for k p than electronic parameters for this data set. Furthermore, the TCND diester—which contains an electron-deficient cyclobutene that is resistant to ROMP—and its polymer p(TCND) are shown to be highly reactive toward DBU-catalyzed conjugate addition reactions with thiols, providing a protecting- and activating-group free strategy for post-polymerization modification.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

A re-analysis of the spectrum of 2206-199

Recently Pettini, Hunstead, Smith and Mar, (PHSM 1991) performed an analysis of the Ly-alpha forest of QSO 2206-199N at very high resolution. On the basis of their observations they concluded that most Doppler parameters b = (square root of 2)(sigma) of Ly-alpha forest lines are below 22 km/s, with a range down to a few km/s and a median of 17 km/s. They also found a strong intrinsic correlation between Doppler parameter b and column density N. These results are in contrast to those of a similar study by Carswell, Lanzetta, Parnell, and Webb (CLPW 1991) at comparable resolution with the same instruments, who find that most of the Ly-alpha lines towards QSO 1100-264 have Doppler parameters above 15 km/s (median b = 34 km/s), and that there is no significant correlation between b and N. Whilst an intrinsic difference between the lines of sight to 2206-199 and to other QSO's can not be excluded a priori, previous disagreement between Doppler parameter estimates obtained by both groups pointed to a potential difference in estimation techniques and in the interpretation of the results. To investigate this possibility, the AAT/UCLES spectrum of 2206-199 obtained by PHSM were reanalyzed. The spectrum was extracted from the raw data and determined the line parameters using the method described by CLPW.

Rauch, M.↗

Global Aerosol Remote Sensing from MODIS

The physical characteristics, composition, abundance, spatial distribution and dynamics of global aerosols are still very poorly known, and new data from satellite sensors have long been awaited to improve current understanding and to give a boost to the effort in future climate predictions. The derivation of aerosol parameters from the MODerate resolution Imaging Spectro-radiometer (MODIS) sensors aboard the Earth Observing System (EOS) Terra and Aqua polar-orbiting satellites ushers in a new era in aerosol remote sensing from space. Terra and Aqua were launched on December 18, 1999 and May 4, 2002 respectively, with daytime equator crossing times of approximately 10:30 am and 1:30 pm respectively. Several aerosol parameters are retrieved at 10-km spatial resolution (level 2) from MODIS daytime data. The MODIS aerosol algorithm employs different approaches to retrieve parameters over land and ocean surfaces, because of the inherent differences in the solar spectral radiance interaction with these surfaces. The parameters retrieved include: aerosol optical thickness (AOT) at 0.47, 0.55 and 0.66 micron wavelengths over land, and at 0.47, 0.55, 0.66, 0.87, 1.2, 1.6, and 2.1 micron over ocean; Angstrom exponent over land and ocean; and effective radii, and the proportion of AOT contributed by the small mode aerosols over ocean. To ensure the quality of these parameters, a substantial part of the Terra-MODIS aerosol products were validated globally and regionally, based on cross correlation with corresponding parameters derived from ground-based measurements from AERONET (AErosol RObotic NETwork) sun photometers. Similar validation efforts are planned for the Aqua-MODIS aerosol products. The MODIS level 2 aerosol products are operationally aggregated to generate global daily, eight-day (weekly), and monthly products at one-degree spatial resolution (level 3). MODIS aerosol data are used for the detailed study of local, regional, and global aerosol concentration, distribution, and temporal dynamics, as well as for radiative forcing calculations. We show several examples of these results and comparisons with model output.

Ichoku, Charles↗

A design point correlation for losses due to part-span dampers on transonic rotors

The design-point losses caused by part-span dampers were correlated for 21 transonic axial-flow fan rotors that had tip speeds varying from 350 to 488 meters per second and design pressure ratios of 1.5 to 2.0. The additional loss attributable to the damper and the total region along the blade height influenced were correlated with selected aerodynamic and geometric parameters. The maximum damper loss correlated well with the mean inlet Mach number at the damper location, the geometric parameters of leading- and trailing-edge damper radius normalized by mean passage height and damper aerodynamic chord, respectively, and the aerodynamic loading parameter of the blade camber divided by the solidity at the damper location. The region of damper influence extended over a mean passage height of the order of 10 to 15 times the maximum damper thickness.

Roberts, W. B.↗