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At least 469 records · Page 26

Managing TRU waste processing and storage issues/challenges - 15487

Operational events at the Waste Isolation Pilot Plant (WIPP) facility resulted in suspension of disposal operations and waste shipments to WIPP creating significant challenges for the Department of Energy (DOE) complex. The Oak Ridge Transuranic (TRU) Waste Program which was poised to re-start shipping after a 2.5 year suspension of the Carlsbad Field Office (CBFO) certification activities which resulted in on-site accumulation of the highest activity contact handled (CH) TRU waste containers. As a result, Transuranic Waste Processing Center (TWPC) is nearing its physical storage capacity for CH waste and has already reached storage capacity limits for remote handled (RH) TRU waste. The TWPC storage capacity for RH-TRU waste is very limited and dependent on real time shipping support to continue RH waste processing activities in the facilities Hot Cell. Additionally, changes in dispersion modeling (i.e., dry deposition factor changes) used in the TWPC Documented Safety Analysis (DSA) present Material at Risk (MAR) management challenges to effectively manage off-site dose consequences. These facts necessitated the identification of alternative waste storage options for both CH and RH waste to continue waste processing operations at TWPC. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

ION Advanced Solvent CO 2 Capture Pilot Project

This final report to DOE/NETL presents all the work and tests performed during ION Engineering’s (ION) carbon dioxide (CO 2 ) capture pilot test campaign: “ION Advanced Solvent CO 2 Capture Project”. This project is comprised of three budget periods (BP): BP1 – Design of a 0.6 MWe system, BP2 – 0.5 MWe National Carbon Capture Center (NCCC) Testing Campaign, and BP3 – 12 MWe Technology Center at Mongstad (TCM) Testing Campaign. The program began in October 2013 and continued until December 2017. The campaign at NCCC, which took place from June to August of 2015, resulted in 1,116 operational hours where ~350 tonnes of CO 2 were captured from the 0.5 MWe coal-fired flue gas slipstream. The follow-up campaign at TCM took place from Oct 2016 to April 2017, where 2,775 hours of operation resulted in the capture of 14,820 tonnes of CO 2 , which is a cumulative of capturing CO 2 from the natural gas-fired Combined Heat and Power (CHP) plant, and a residue fluid catalytic cracker gas (RFCC) from Statoil at Mongstad. ION has conducted a thoughtful, comprehensive, and successful program in close collaboration with all its partners. CO 2 was successfully removed and captured for extended periods of time using three gas sources (NCCC Coal-fired Power plant, TCM CHP flue gas with and without CO 2 recycle, and TCM RFCC flue gas with air dilution) at various slipstream flows ranging from 0.5 MWe to 12 MWe. The data gathered on its solvent continues to strengthen the development of ION’s advanced solvent and positive track record in executing on-site test campaigns in highly industrialized settings. These existing pilot plants do not include the necessary process modifications that ION requires to obtain the lowest possible regeneration energy; processes such as a cold-rich bypass and intercooling, would allow for lowering the demonstrated specific reboiler duty. The resulting data was also used to validate the process model, and, in the absence of testing on a custom test rig specifically designed for ION’s advanced solvent, the results of the process model have shown specific reboiler duties under 2.5 MJ/kg CO 2 (1075 BTU/lb CO 2 ). When these regeneration energies are factored into the Techno-Economic Analysis (TEA), where ION’s technology is compared to the DOE/NETL BBS Case 12, which integrates a highly optimized and commercially available CO 2 capture technology, ION’s technology shows: 38% incremental reduction in capital cost of CO 2 capture; 28% incremental reduction in annual operating and maintenance costs of CO 2 capture; and $35-44 per tonne of CO 2 capture, which is a 20% to 40% reduction in cost of CO 2 capture. Throughout pilot testing, ION has confirmed its understanding of process improvements and analytics that will enable successful operation of its advanced solvent at significantly lower L/G circulation rates, packing heights and regeneration energies than MEA. ION has identified routes to further develop its technology and is looking forward to testing a fully optimized solvent and capture system in the near future.

01 COAL, LIGNITE, AND PEAT↗

Light Water Reactor Sustainability Program: Digital Architecture Project Plan

There are many technologies available to the nuclear power industry to improve efficiency in plant work activities. These range from new control room technologies to those for mobile field workers. They can make a positive impact on a wide range of performance objectives – increase in productivity, human error reduction, validation of results, accurate transfer of data, and elimination of repetitive tasks. It is expected that the industry will more and more turn to these technologies to achieve these operational efficiencies to lower costs. At the same time, this will help utilities manage a looming staffing problem as the inevitable retirement wave of the more seasoned workers affects both staffing levels and knowledge retention. A barrier to this wide-scale implementation of new technologies for operational efficiency is the lack of a comprehensive digital architecture that can support the real-time information exchanges needed to achieve the desired operational efficiencies. This project will define an advanced digital architecture that will accommodate the entire range of system, process, and plant worker activity to enable the highest degree of integration, thereby creating maximum efficiency and productivity. This pilot project will consider a range of open standards that are suitable for the various data and communication requirements of a seamless digital environment. It will map these standards into an overall architecture to support the II&C developments of this research program.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

National Hurricane Program Hurricane Evacuation Study Tool End-User Engagement and Usability Analysis

The Hurricane Evacuation Study (HES) Tool prototype is a key component of the Federal Emergency Management Agency (FEMA) National Hurricane Program (NHP) Technology Modernization (TM) effort. To ensure the HES Tool captured the necessary capabilities and functionality, engagement with potential end-users and key stakeholders was considered a priority throughout development. Pilot studies with representatives from North Carolina and New York City were done to validate the HES Tool process with their current HES undertaking. These pilot studies let the development of additional capabilities and feedback on the needs of diverse regions. A usability study was carried out with key stakeholders identified by NHP leadership through individualized sessions with identified personnel. The results showed the value of the HES Tool compared to the current process as well as key issues that must be addressed to ensure a final transition.

54 ENVIRONMENTAL SCIENCES↗

Integrated Oxygen Production and CO 2 Separation through Chemical Looping Combustion with Oxygen Uncoupling (Final Report)

The project "Integrated Oxygen Production and CO 2 Separation through Chemical Looping Combustion with Oxygen Uncoupling" focused on advancing fluidized bed chemical looping combustion technology to semi-pilot scale. An important aspect of technology scale-up is production of well-performing oxygen carrier materials economically and at a scale sufficient for industrial-scale systems. Under this program, a new technique for oxygen carrier production was developed and a prototype system capable of producing up to 150 lb per batch of oxygen carrier was constructed. Chemical looping combustion testing was performed in a large process development unit designed for operation at more than 200 kW using coal as fuel. Complementary evaluation of carbon conversion pathways was conducted and quantitative analysis of the fate of carbon in a CLOU-based chemical looping system was performed. As an aid for design, optimization, troubleshooting and scale-up, robust CFD models for fluidized bed chemical looping combustion systems were developed.

01 COAL, LIGNITE, AND PEAT↗

2024 NSUF User Development Workshop on Irradiation Testing

Monday, May 20 – Thursday, May 23, 2024 at Center for Advanced Energy Studies at Idaho National Laboratory, Idaho Falls, Idaho. This pilot workshop was hosted to expand the NSUF user community and introduce irradiation testing of nuclear fuel and materials to new researchers, and to build long-term relationships between the NSUF program office, NSUF partner facilities, and NSUF university-affiliated users to provide better utilization of NSUF resources in addressing United States energy challenges.

Starks, Alexis↗

In-Can Incineration and Vitrification Process for the Treatment of Transuranic Wastes - 20035

Technological alpha contaminated wastes are produced by the nuclear fuel cycle management industry, essentially from MOX fuel production units. These Plutonium Contaminated Materials (PCM) contain a mixture of organic, metal and mineral materials, contaminated with uranium, plutonium and americium. One treatment scenario under study is to incinerate the organic materials, melt the metallic fraction and incorporate the mineral fraction (including ashes from organics incineration) into a glass matrix without sorting or pretreatment (grinding for instance). A scale 1 pilot of this PIVIC process (Process for Incineration and Vitrification In Can) has been commissioned in 2018 at the CEA R and D vitrification facility in Marcoule site. A R and D program aiming to demonstrate the feasibility of this process is currently on going. This paper starts with a description of PIVIC process with explanation of the technologies involved. Then, main results of the first year of operation with the technological demonstration goal are presented. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Fuel Flexible Combustion Systems for High-Efficiency Utilization of Opportunity Fuels in Gas Turbines

The purpose of this program was to develop low-emissions, efficient fuel-flexible combustion technology which enables operation of a given gas turbine on a wider range of opportunity fuels that lie outside of current natural gas-centered fuel specifications. The program encompasses a selection of important, representative fuels of opportunity for gas turbines with widely varying fundamental properties of combustion. The research program covers conceptual and detailed combustor design, fabrication, and testing of retrofitable and/or novel fuel-flexible gas turbine combustor hardware, specifically advanced fuel nozzle technology, at full-scale gas turbine combustor conditions. This project was performed over the period of October 2008 through September 2011 under Cooperative Agreement DE-FC26-08NT05868 for the U.S. Department of Energy/National Energy Technology Laboratory (USDOE/NETL) entitled "Fuel Flexible Combustion Systems for High-Efficiency Utilization of Opportunity Fuels in Gas Turbines". The overall objective of this program was met with great success. GE was able to successfully demonstrate the operability of two fuel-flexible combustion nozzles over a wide range of opportunity fuels at heavy-duty gas turbine conditions while meeting emissions goals. The GE MS6000B ("6B") gas turbine engine was chosen as the target platform for new fuel-flexible premixer development. Comprehensive conceptual design and analysis of new fuel-flexible premixing nozzles were undertaken. Gas turbine cycle models and detailed flow network models of the combustor provide the premixer conditions (temperature, pressure, pressure drops, velocities, and air flow splits) and illustrate the impact of widely varying fuel flow rates on the combustor. Detailed chemical kinetic mechanisms were employed to compare some fundamental combustion characteristics of the target fuels, including flame speeds and lean blow-out behavior. Perfectly premixed combustion experiments were conducted to provide experimental combustion data of our target fuels at gas turbine conditions. Based on an initial assessment of premixer design requirements and challenges, the most promising sub-scale premixer concepts were evaluated both experimentally and computationally. After comprehensive screening tests, two best performing concepts were scaled up for further development. High pressure single nozzle tests were performed with the scaled premixer concepts at target gas turbine conditions with opportunity fuels. Single-digit NOx emissions were demonstrated for syngas fuels. Plasma-assisted pilot technology was demonstrated to enhance ignition capability and provide additional flame stability margin to a standard premixing fuel nozzle. However, the impact of plasma on NOx emissions was observed to be unacceptable given the goals of this program and difficult to avoid.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Subtask – CO 2 storage and enhanced bakken recovery research program

Small improvements in productivity could increase technically recoverable oil in the Bakken Petroleum System by billions of barrels. The use of CO 2 for enhanced oil recovery (EOR) in tight oil reservoirs is a relatively new concept. The large-scale injection of CO 2 into the Bakken would also result in the geological storage of significant amounts of CO 2 . The Energy & Environmental Research Center (EERC) has conducted laboratory and modeling activities to examine the potential for CO 2 storage and EOR in the Bakken. Specific activities included the characterization and subsequent modeling of North Dakota study areas as well as dynamic predictive simulations of possible CO 2 injection schemes to predict the potential CO 2 storage and EOR in those areas. Laboratory studies to evaluate the ability of CO 2 to remove hydrocarbons from Bakken rocks and determine minimum miscibility pressures for Bakken oil samples were conducted. Data from a CO 2 injection test conducted in the Elm Coulee area of Montana in 2009 were evaluated with an eye toward the possible application of knowledge gained to future injection tests in other areas. A first-order estimation of potential CO 2 storage capacity in the Bakken Formation in North Dakota was also conducted. Key findings of the program are as follows. The results of the research activities suggest that CO 2 may be effective in enhancing the productivity of oil from the Bakken and that the Bakken may hold the ability to geologically store between 120 Mt and 3.2 Gt of CO 2 . However, there are no clear-cut answers regarding the most effective approach for using CO 2 to improve oil productivity or the storage capacity of the Bakken. The results underscore the notion that an unconventional resource will likely require unconventional methods of both assessment and implementation when it comes to the injection of CO 2 . In particular, a better understanding of the fundamental mechanisms controlling the interactions between CO 2 , oil, and other reservoir fluids in these unique formations is necessary to develop accurate assessments of potential CO 2 storage and EOR in the Bakken. In addition, existing modeling and simulation software packages do not adequately address or incorporate the unique properties of these tight, unconventional reservoirs in terms of their impact on CO 2 behavior. These knowledge gaps can be filled by conducting scaled-up laboratory activities integrated with improved modeling and simulation techniques, the results of which will provide a robust foundation for pilot-scale field injection tests. Finally, field-based data on injection, fluid production, and long-term monitoring from pilot-scale CO 2 injection tests in the Bakken are necessary to verify and validate the findings of the laboratory- and modeling-based research efforts. This subtask was funded through the EERC–U.S. Department of Energy (DOE) Joint Program on Research and Development for Fossil Energy-Related Resources Cooperative Agreement No. DE-FC26-08NT43291. Nonfederal funding was provided by the North Dakota Industrial Commission, Marathon Oil Corporation, Continental Resources Inc., and TAQA North, Ltd.

54 ENVIRONMENTAL SCIENCES↗

Subtask1.10 – CO 2 storage and enhanced bakken recovery research program

Small improvements in productivity could increase technically recoverable oil in the Bakken Petroleum System by billions of barrels. The use of CO 2 for enhanced oil recovery (EOR) in tight oil reservoirs is a relatively new concept. The large-scale injection of CO 2 into the Bakken would also result in the geological storage of significant amounts of CO 2 . The Energy & Environmental Research Center (EERC) has conducted laboratory and modeling activities to examine the potential for CO 2 storage and EOR in the Bakken. Specific activities included the characterization and subsequent modeling of North Dakota study areas as well as dynamic predictive simulations of possible CO 2 injection schemes to predict the potential CO 2 storage and EOR in those areas. Laboratory studies to evaluate the ability of CO 2 to remove hydrocarbons from Bakken rocks and determine minimum miscibility pressures for Bakken oil samples were conducted. Data from a CO 2 injection test conducted in the Elm Coulee area of Montana in 2009 were evaluated with an eye toward the possible application of knowledge gained to future injection tests in other areas. A first-order estimation of potential CO 2 storage capacity in the Bakken Formation in North Dakota was also conducted. Key findings of the program are as follows. The results of the research activities suggest that CO 2 may be effective in enhancing the productivity of oil from the Bakken and that the Bakken may hold the ability to geologically store between 120 Mt and 3.2 Gt of CO 2 . However, there are no clear-cut answers regarding the most effective approach for using CO 2 to improve oil productivity or the storage capacity of the Bakken. The results underscore the notion that an unconventional resource will likely require unconventional methods of both assessment and implementation when it comes to the injection of CO 2 . In particular, a better understanding of the fundamental mechanisms controlling the interactions between CO 2 , oil, and other reservoir fluids in these unique formations is necessary to develop accurate assessments of potential CO 2 storage and EOR in the Bakken. In addition, existing modeling and simulation software packages do not adequately address or incorporate the unique properties of these tight, unconventional reservoirs in terms of their impact on CO 2 behavior. These knowledge gaps can be filled by conducting scaled-up laboratory activities integrated with improved modeling and simulation techniques, the results of which will provide a robust foundation for pilot-scale field injection tests. Finally, field-based data on injection, fluid production, and long-term monitoring from pilot-scale CO 2 injection tests in the Bakken are necessary to verify and validate the findings of the laboratory- and modeling-based research efforts. This subtask was funded through the EERC–U.S. Department of Energy (DOE) Joint Program on Research and Development for Fossil Energy-Related Resources Cooperative Agreement No. DE-FC26-08NT43291. Nonfederal funding was provided by the North Dakota Industrial Commission, Marathon Oil Corporation, Continental Resources Inc., and TAQA North, Ltd.

54 ENVIRONMENTAL SCIENCES↗

Integrated pre-feasibility study for CO 2 geological storage in the Cascadia Basin, offshore Washington State, British Columbia

The Cascadia CarbonSAFE project conducted a pre-feasibility study to evaluate technical and nontechnical aspects of storing 50 million metric tons (MMT) of carbon dioxide in a safe, ocean basalt reservoir offshore Washington State and British Columbia. Sub-seafloor basalts are very common on Earth and enable geological mineralization as a long-term storage mechanism, permanently sequestering the carbon in solid rock form. This project evaluated the offshore storage complex, developed potential industrial source/transport scenarios, built an inventory of existing geophysical/geological data and environmental monitoring capabilities, conducted laboratory studies and reservoir modeling to determine storage capacity, and analyzed economic factors, regulatory requirements, and project management risks. Our team included researchers at Columbia University in New York, Pacific Northwest National Laboratory (PNNL) in Washington, University of Victoria in British Columbia, University of California at Santa Cruz, and GHG Underground in Maine, as well as collaborators at University of Iceland in Reykjavik and University of Washington in Saint Louis. In the study region, large emitters (>100,000 MT/year) generate a total of approximately 40 MMT annually from stationary sources, such as power plants, refineries, ammonia production, and mineral processing plants. Five potential industry source/transport scenarios were identified (three in U.SA S. and two in Canada) to potentially provide 50 MMT of carbon dioxide to the offshore reservoir. One scenario included net carbon-negative sources that would reduce atmospheric levels. The inventory of existing data illustrated that basalt properties in the region are potentially beneficial for long-term storage. Permeability is on the order of 0.1 to 1 Darcies within the uppermost 600 m of ocean crust and density-derived porosity reaches 10–20% in thin layers that provide act as flow channels and provide access to porous and permeable basalt. Fine-grained sediments overlying basalt provide a low-permeability barrier separating the storage reservoir from the overlying ocean. Subsurface monitoring of the storage complex benefits from a unique opportunity close proximity of to the nearby NEPTUNE cabled seafloor observatory, which actively transmits data to shore and could be used to monitor reservoir properties. Injection pressure changes, reservoir chemistry, seismicity, well head corrosion, and potential leakage monitoring would be feasible in real time. Using existing data and published models, the STOMP-CO 2 modeling code developed at PNNL was used to simulate carbon dioxide injection, storage, and mineralization in the reservoir. Preliminary simulations indicate that a 50 MMT carbon dioxide plume injected over a 20-year period remains well within the reservoir area, both laterally and vertically, for at least a 50-year period of post-injection monitoring. Laboratory studies on core samples from Cascadia measured dissolution rates in CO 2 –basalt–seawater mixtures and indicated large variability in rates with the potential for complete mineralization. Compared to published data, the dissolution rate measured in these samples is faster, decreasing the time until full conversion to carbonate minerals would occur. Adding geochemical reactivity in the STOMP-CO 2 model indicates that carbon dioxide would be fully converted to carbonate minerals in 135 years or less after injection ceases. The project assessed the viability and costs for the five scenarios using either dedicated offshore pipelines or shipping vessels. Carbon dioxide capture costs were not considered. Shipping incurred lower upfront CAPEX costs, and because most viable sources were located near the shore and waterways, shipping is preferred; no dedicated carbon dioxide pipelines exist in the region. The project also considered potential risks from mixed-use impacts on surrounding lands and ocean areas, such as active use by commercial and recreational fisherman, and other community considerations in planning for public engagement in the future. Other project risks were identified, including project management, permitting and compliance, and financing, as well as technical issues such as long-term instrumentation, plume migration, and model development. Geological concerns like reservoir permeability, seal, and induced seismicity held relatively low risk. The regulatory framework for offshore storage in the U.S. and Canada may be covered by general legal/regulatory programs, but is not yet fully defined. Existing programs appear to restrict the transportation of carbon dioxide across national boundaries (e.g., Canada to U.S.) and its sub-seabed disposal in some circumstances. Our assessment suggests that developing specific and separate pilot projects will help to advance the technical feasibility and regulatory requirements in each country, and lessons learned from such activities may be transferable elsewhere around the globe.

42 ENGINEERING↗

Effects of Borate and Organics on U(VI) Solubility in WIPP Brine

The solubility of uranium (VI) in Waste Isolation Pilot Plant (WIPP)-relevant brine was determined to support ongoing WIPP recertification activities. This research was performed by the Los Alamos National Laboratory Carlsbad Operations (LANL-CO) Actinide Chemistry and Repository Science Program (ACRSP). The WIPP Actinide Source Term Program (ASTP) did not develop a model for the solubility of actinides in the VI oxidation state. The solubility of UO 2 2+ , in the absence of WIPP specific data, is presently set to be equal to a conservatively high 1 mM within the WIPP Performance Assessment (PA) for all expected WIPP conditions (SOTERM, 2019) as selected at the recommendation of the Environment Protection Agency (EPA) (EPA, 2005). According to the current WIPP chemistry model assumptions and conditions, the expected pC H+ is about 9.5 and controlled by MgO buffering CO 3 2- . The goal of this study is to perform screening experiments that account for the contributions of organics and borate on uranium solubility. In this report, the solubility of U(VI) was determined at pC H+ 9 WIPP brine in the absence or presence of borate and organics at under-saturation approach. Experiments were equilibrated for about 135 days. Organic compounds present in WIPP waste can form strong complexes with actinides and can affect the oxidation states of actinides. The organic compounds addressed in WIPP performance assessment include EDTA (Ethylenediaminetetraacetic Acid), oxalate, citrate, and acetate (SOTERM, 2019). These data quantify the effects of WIPP-relevant concentrations of borate and organics effects on the solubility of U(VI) to challenge the predictions of the WIPP actinide model and inform decisions and recommendations made in the upcoming recertification of the WIPP (CRA-2024). The experiments performed were done according to the U.S. Department of Energy (DOE) approved Test Plan entitled “Experimental Strategy to Challenge Actinide Solubility Predictions” and designated LCO-ACP-26. All data reported were obtained under the LANL-CO Quality Assurance Program, which is compliant with the DOE Carlsbad Field Office, Quality Assurance Program Document (CBFO/QAPD) (QAPD, 2017).

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Cybersecurity Standards for Distributed Energy Resources: Gaps and Harmonization Strategy

This report examines cybersecurity standards for Distributed Energy Resources (DERs) in light of their rapid growth and increasing integration into energy systems. It identifies critical gaps in existing frameworks, including inadequate coverage of DER-specific challenges, complexities in implementing comprehensive standards, integration issues with legacy systems, adoption hurdles for newer standards, and a lack of harmonization across regulatory landscapes. The analysis highlights vulnerabilities such as data integrity risks, unauthorized device control, and denial-of-service attacks across various DER technologies like solar PV, wind turbines, energy storage systems, and hydrogen fuel cells. The report proposes a harmonization strategy to address these deficiencies by developing unified cybersecurity requirements, certification programs, and training resources while fostering collaboration among stakeholders such as government agencies, industry groups, DER operators, manufacturers, and research institutions. A phased roadmap is outlined to refine and implement these measures through pilot testing and widespread adoption. Ultimately, the report underscores the urgent need for coordinated efforts to enhance DER cybersecurity and ensure the reliable operation of future energy systems.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

New In Situ Imaging and Measurement Technologies for Biological Systems (Brochure)

The U.S. Department of Energy’s (DOE) Office of Biological and Environmental Research (BER) supports fundamental research to advance a predictive understanding of complex biological and environmental systems relevant to DOE’s missions in energy and the environment. Starting with the genetic potential encoded by organisms’ genomes, BER scientists seek to define the principles guiding translation of the genetic code into functional proteins and the metabolic and regulatory networks underlying plant and microbial systems. Concurrent with this research is a need for enabling technologies to place understanding of gene expression, regulation, and function into the spatiotemporal context of whole-cell environments. Imaging and measurement technologies that can resolve multiple key metabolic processes over time within or among cells will act as a crucial bridge toward linking molecular-scale information to whole-cell, systems-level understanding. This brochure outlines the pilot projects at the DOE national laboratories and the investigators leading these efforts. This initial description of BER’s new effort serves as an informational resource for the evolving imaging and measurement technology program.

59 BASIC BIOLOGICAL SCIENCES↗

Deep Geologic Nuclear Waste Disposal - No New Taxes - 12469

To some, the perceived inability of the United States to dispose of high-level nuclear waste justifies a moratorium on expansion of nuclear power in this country. Instead, it is more an example of how science yields to social pressure, even on a subject as technical as nuclear waste. Most of the problems, however, stem from confusion on the part of the public and their elected officials, not from a lack of scientific knowledge. We know where to put nuclear waste, how to put it there, how much it will cost, and how well it will work. And it's all about the geology. The President's Blue Ribbon Commission on America's Nuclear Future has drafted a number of recommendations addressing nuclear energy and waste issues (BRC 2011) and three recommendations, in particular, have set the stage for a new strategy to dispose of high-level nuclear waste and to manage spent nuclear fuel in the United States: 1) interim storage for spent nuclear fuel, 2) resumption of the site selection process for a second repository, and 3) a quasi-government entity to execute the program and take control of the Nuclear Waste Fund in order to do so. The first two recommendations allow removal and storage of spent fuel from reactor sites to be used in the future, and allows permanent disposal of actual waste, while the third controls cost and administration. The Nuclear Waste Policy Act of 1982 (NPWA 1982) provides the second repository different waste criteria, retrievability, and schedule, so massive salt returns as the candidate formation of choice. The cost (in 2007 dollars) of disposing of 83,000 metric tons of heavy metal (MTHM) high-level waste (HLW) is about $ 83 billion (b) in volcanic tuff, $ 29 b in massive salt, and $ 77 b in crystalline rock. Only in salt is the annual revenue stream from the Nuclear Waste Fund more than sufficient to accomplish this program without additional taxes or rate hikes. The cost is determined primarily by the suitability of the geologic formation, i.e., how well it performs on its own for millions of years with little engineering assistance from humans. It is critical that the states most affected by this issue (WA, SC, ID, TN, NM and perhaps others) develop an independent multi-state agreement in order for a successful program to move forward. Federal approval would follow. Unknown to most, the United States has a successful operating deep permanent geologic nuclear repository for high and low activity waste, called the Waste Isolation Pilot Plant (WIPP) near Carlsbad, New Mexico. Its success results from several factors, including an optimal geologic and physio-graphic setting, a strong scientific basis, early regional community support, frequent interactions among stakeholders at all stages of the process, long-term commitment from the upper management of the U.S. Department of Energy (DOE) over several administrations, strong New Mexico State involvement and oversight, and constant environmental monitoring from before nuclear waste was first emplaced in the WIPP underground (in 1999) to the present. WIPP is located in the massive bedded salts of the Salado Formation, whose geological, physical, chemical, redox, thermal, and creep-closure properties make it an ideal formation for long-term disposal, long-term in this case being greater than 200 million years. These properties also mean minimal engineering requirements as the rock does most of the work of isolating the waste. WIPP has been operating for twelve years, and as of this writing, has disposed of over 80,000 m{sup 3} of nuclear weapons waste, called transuranic or TRU waste (>100 nCurie/g but <23 Curie/1000 cm{sup 3}) including some high activity waste from reprocessing of spent fuel from old weapons reactors. All nuclear waste of any type from any source can be disposed in this formation better, safer and cheaper than in any other geologic formation. At the same time, it is critical that we complete the Yucca Mountain license application review so as not to undermine the credibility of the Nuclear Regulatory Commission and the scientific community. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Borehole EM Monitoring at Aquistore: Final Report to the Carbon Capture Project (CCP)

Geologic carbon sequestration (GCS) is a technology whose goal is to prevent atmospheric release of greenhouse gases via injection of carbon dioxide (CO 2 ) into an underground reservoir for long term storage. GCS is typically part of a program of carbon capture and storage (CCS) that captures CO 2 from point sources such as power plants, transports the CO 2 to a storage site, and operates an injection facility. One recent CCS pilot project is the Aquistore CO 2 sequestration project, near Estevan, Saskatchewan, Canada. The Aquistore project is managed by the Petroleum Technology Research Centre (PTRC) and will be one of the first integrated CCS projects storing CO 2 in a deep saline aquifer from a coal fired power plant (PTRC, 2011). Aquistore is expected to store 500,000 tons of CO 2 during its lifetime (Ministry of Environment, 2012). Assuring the long-term, safe storage of CO 2 requires the development of effective monitoring strategies. As part of the geophysical monitoring effort at Aquistore, there were initial plans for deployment of borehole electrodes for electrical or electromagnetic measurements to monitor CO 2 within the reservoir. The injected CO 2 displaces saline brine in the reservoir, and because CO 2 has a high resistivity compared to brine, the overall resistivity of the formation increases and can be monitored by measuring electric or magnetic fields. Previous work by Lawrence Berkeley National Laboratory (LBNL) had indicated that borehole-to-surface electromagnetic monitoring, using an electric dipole source near the bottom of a well penetrating the reservoir, could detect the resistivity change induced by GCS. To assess the potential application of electromagnetic monitoring at Aquistore, Lawrence Berkeley National Laboratory and Multi-Phase Technologies collaborated on a two-part study including (1) numerical forward modeling of a time-lapse, controlled-source electromagnetic (CSEM) monitoring survey, and (2) an initial engineering study of instrumentation and proposed design for a borehole electric dipole source and electrode sensors.

54 ENVIRONMENTAL SCIENCES↗

Low Cost Chemical Feedstocks Using an Improved and Energy Efficient Natural Gas Liquid (NGL) Removal Process (Final Technical Report)

The overall objective of this project is to develop a new low-cost and energy efficient Natural Gas Liquid (NGL) recovery process - through a combination of theoretical, bench-scale and pilot-scale testing - so that it could be offered to the natural gas industry for commercialization. The new process, known as the IROA process, is based on U.S. patent No. 6,553,784, which if commercialized, has the potential of achieving substantial energy savings compared to currently used cryogenic technology. When successfully developed, this technology will benefit the petrochemical industry, which uses NGL as feedstocks, and will also benefit other chemical industries that utilize gas-liquid separation and distillation under similar operating conditions. Specific goals and objectives of the overall program include: (i) collecting relevant physical property and Vapor Liquid Equilibrium (VLE) data for the design and evaluation of the new technology, (ii) solving critical R&D issues including the identification of suitable dehydration and NGL absorbing solvents, inhibiting corrosion, and specifying proper packing structure and materials, (iii) designing, construction and operation of bench and pilot-scale units to verify design performance, (iv) computer simulation of the process using commercial software simulation platforms such as Aspen-Plus and HYSYS, and (v) preparation of a commercialization plan and identification of industrial partners that are interested in utilizing the new technology.

03 NATURAL GAS↗

2024 University of Puerto Rico at Mayagüez Civic Innovation Challenge Study

# 2024 University of Puerto Rico at Mayagüez Civic Innovation Challenge Study The 2024 University of Puerto Rico at Mayagüez Civic Innovation Challenge (CIVIC) Study provided insight into the travel patterns and associated energy consumption of participants. Study results helped researchers identify opportunities for the development of shared mobility strategies—such as collaborative ride-sharing programs—that could address the mobility needs of rural communities in Puerto Rico. The Civic Innovation Challenge is a multiagency, federal government research and action competition that funds ready-to-implement, research-based pilot projects that have the potential for scalable, sustainable, and transferable impact on community-identified priorities. ## Data Collection Agency The University of Puerto Rico at Mayagüez conducted the study. ## Survey Methodology The study was conducted in Spanish. Data collection was enabled via the open-source [NREL OpenPATH platform](https://www.nrel.gov/transportation/openpath). The resulting dataset consists of partially automated travel diaries—combining sensed and surveyed data reflecting patterns of multimodal, end-to-end, individual human mobility—as well as demographic and socioeconomic information from the 31 participants. ## Survey Records, Data, and Documentation Survey records include 31 participants. The total number of trips was 1,373 and the total non-air-miles traveled was approximately 8,260.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗