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At least 469 records · Page 26

Search for infrared absorption lines of atmospheric chlorine monoxide (ClO)

A search for features of the ClO (1-0) vibration-rotation band has been conducted based on a 5000 signal-to-rms noise ratio IR spectrum derived by coadding 39 high-quality 0.0053/cm resolution solar spectra recorded with the McMath Fourier transform spectrometer on Kitt Peak. Evidence for absorption has been found at the locations of several of the stronger ClO P-branch lines with minimal interference. Detailed results are presented for the P(8.5) and P(7.5) 2Pi3/2-2Pi3/2 lines of Cl-35O at 833.2974 and 834.6249/cm, respectively. If ClO is present in the stratosphere at the concentrations indicated by other methods, our analysis indicates that modest improvements in signal-to-noise ratio and spectral resolution would permit a definitive detection of ClO in IR ground-based spectra.

Rinsland, Curtis P.↗

General Relationships Between the Various Systems of Reference Axes Employed in Flight Mechanics

The different possibilities of orientation of the systems of axes currently employed in flight mechanics are compiled and described. Of the three possible couplings between the wind and aircraft axes, the most suitable coupling is that in which the y axis is made the principal axis of rotation for one of the two coupling angles (angles of attack). In connection with this coupling, an experimental system of axes is introduced, whose axes x(sub e) and z(sub e) are situated in the plane of symmetry of the airplane and rotate about the airplane lateral axis y = y(sub e). This system of axes enables the utilization of the coefficients obtained in the wind tunnel in the flight-mechanic equations by a simple transformation, with the aid of the angle of attack, measured in the plane of symmetry of the airplane.

Rautenberg, H J↗

Balloon measurements of stratospheric HCl and HF by far infrared emission spectroscopy

We have analyzed atmospheric thermal emission spectra obtained with the balloon-borne FIRS-2 far infrared Fourier transform spectrometer during balloon flights from Palestine, Texas on May 12-13, 1988 and from Fort Sumner, New Mexico on September 26-27, 1989 and on July 4-5, 1990. Seven and two pure rotational transition lines in 100-205 cm(exp -1) range are analyzed for deriving vertical profiles of stratospheric HCl and HF, respectively. We obtain both the daytime and nighttime average vertical profiles from 15 to 50 km. We compare these profiles with the ones obtained in June, 1983 with the first version of FIRS spectrometer during the Balloon Intercomparison Campaign (BIC-2). BIC-2 results were revised to be consistent with the present analysis which uses the latest spectral parameters. According to our comparison results no increase is recognized for HCl but about 3 percent per year increase for HF from 1983 to 1990, assuming a linear trend. These annual increase rates are smaller than those reported by other groups. Recently Rinsland et al. (1991) and Wallace and Livingston (1991) reported long term behavior of total HCl and HF observed on Kit Peak between 1977 and 1990. As Kit Peak is located near both balloon launching sites, Palestine and Fort Sumner, we think our results are favorably comparable with theirs. Comparison results with ours and ground-based measurements will be presented and discussed.

Shibasaki, Kazuo↗

REQUEST: A Recursive QUEST Algorithm for Sequential Attitude Determination

In order to find the attitude of a spacecraft with respect to a reference coordinate system, vector measurements are taken. The vectors are pairs of measurements of the same generalized vector, taken in the spacecraft body coordinates, as well as in the reference coordinate system. We are interested in finding the best estimate of the transformation between these coordinate system.s The algorithm called QUEST yields that estimate where attitude is expressed by a quarternion. Quest is an efficient algorithm which provides a least squares fit of the quaternion of rotation to the vector measurements. Quest however, is a single time point (single frame) batch algorithm, thus measurements that were taken at previous time points are discarded. The algorithm presented in this work provides a recursive routine which considers all past measurements. The algorithm is based on on the fact that the, so called, K matrix, one of whose eigenvectors is the sought quaternion, is linerly related to the measured pairs, and on the ability to propagate K. The extraction of the appropriate eigenvector is done according to the classical QUEST algorithm. This stage, however, can be eliminated, and the computation simplified, if a standard eigenvalue-eigenvector solver algorithm is used. The development of the recursive algorithm is presented and illustrated via a numerical example.

Bar-Itzhack, Itzhack Y.↗

Potential absence of observed π2 linear-chain structures in 14O via 10C(α,α) resonances scattering

Background: The preference for light nuclear systems to coagulate into -particle clusters has been well-studied. The possibility of a linear chain configuration of -particles would allow for a new way to study this phenomenon. Purpose: A rotational band of states in C has been claimed showing a linear chain structure. The mirror system, O, has been studied here to examine how this linear chain structure is affected by replacing the valence neutrons with protons. Method: A beam of C was incident into a chamber filled with He:CO gas with the tracks recorded inside the TexAT Time Projection Chamber and the recoil -particles detected by a silicon detector array to measure the cross section. Results: The experimental cross section was compared with previous studies and fit using R-Matrix theory with the previously-observed O states being transformed to the C using mirror symmetry. The measured cross section does not replicate the claimed states, with the predicted cross section exceeding that observed at several energies and angles. Conclusion: A series of possibilities are highlighted with the most likely being that the originally-seen C states did not constitute a rotational band with a potentially incorrect spin assignment due to the limitations of the angular correlation method with non-zero spin particles. The work highlights the difficulties in measuring broad resonances corresponding to a linear chain state in a high level density.

Bishop, J.↗

Modulating Transition Metal Reactivity with Force

The reactivity and selectivity of a transition metal catalyst is intimately related to its ligand-sphere geometry, and, in many cases, the ideal ligand geometry for one step of a catalytic cycle is poorly matched to the ideal ligand geometry for another. For this reason, methods for reversibly modulating ligand geometry on the time scale of catalytic turnover or monomer enchainment are highly desirable. Mechanical force represents a heretofore untapped approach to modulate catalyst geometry and/or reactivity, with the potential to do so on the timescale of catalytic turnover or monomer enchainment. Macroscopic mechanical forces are large, directional and localized to an extent that differentiates them from other forms of energy input such as heat or light. Here, in this Concept, we describe our efforts to address the fundamental challenges associated with force-modulated transition metal catalysis by employing molecular force probe ligands comprising a stiff stilbene photoswitch tethered to rotationally flexible biaryl bisphosphine ligand. Our efforts to date include the modulation of catalytic activity through force-mediated ligand perturbations, quantification of the force-coupled ligand effects on the energetics of elementary organometallic transformations, and evaluation of the mechanisms of force transduction in these systems.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Restricted invariance of the Navier-Stokes equation

It is well known that the classical Navier-Stokes equation for three-dimensional incompressible viscous flow is invariant under Galilean transformations. In the present paper, it is shown that, although the general invariance group is no larger than Galilean-scale dilitation, the Navier-Stokes equation for incompressible viscous flow admits time-dependent rotational invariance for solutions of special types.

Rosen, G.↗

The rigid shell component for superrotation in planetary atmospheres: Angular momentum budget, mechanical analog and simulation of the spin up process

An analysis of superrotation in the atmosphere of planets, with rotation axis perpendicular to the orbital plane is presented. As the atmosphere expands, Hadley cells develop producing a redistribution of mass and angular momentum. A three dimensional thermally driven zonally symmetric spectral model and Laplace transformation simulate the time evolution of a fluid leading from corotation under globally uniform heating to superrotation under globally nonuniform heating. For high viscosities the rigid shell component of atmospheric superrotation can be understood in analogy with a pirouette. During spin up angular momentum is transferred to the planet. For low iscosities, the process is reversed. A tendency toward geostrophy, combined with increase of surface pressure toward the poles (due to meridional mass transport), induces the atmosphere to subrotate temporarily at lower altitudes. Resultant viscous shear near the surface permits angular momentum to flow from the planet into the atmosphere propagating upwards to produce high altitude superrotation rates.

Mayr, H. G.↗

Primitive numerical simulation of circular Couette flow - Carrousel wind tunnel nonturbulent solutions

The azimuthal-invariant, three-dimensional cylindrical, incompressible Navier-Stokes equations are solved to steady state for a finite-length, physically realistic model. The numerical method relies on an alternating-direction implicit scheme that is formally second-order accurate in space and first-order accurate in time. The equations are linearized and uncoupled by evaluating variable coefficients at the previous time iteration. Wall grid clustering is provided by a Roberts transformation in radial and axial directions. A vorticity-velocity formulation is found to be preferable to a vorticity-streamfunction approach. Subject to no-slip, Dirichlet boundary conditions, except for the inner cylinder rotation velocity (impulsive start-up) and zero-flow initial conditions, nonturbulent solutions are obtained for sub- and supercritical Reynolds numbers of 100 to 400 for a finite geometry where R(outer)/R(inner) = 1.5, H/R(inner) = 0.73, and H/Delta-R = 1.5. An axially-stretched model solution is shown to asymptotically approach the one-dimensional analytic Couette solution at the cylinder midheight. Flowfield change from laminar to Taylor-vortex flow is discussed as a function of Reynolds number. Three-dimensional velocities, vorticity, and streamfunction are presented via two-dimensional graphs and three-dimensional surface and contour plots.

Hasiuk, Jan↗

Controlling telerobots with video data and compensating for time-delayed video using Omniview

Remote viewing is critical for teleoperations, but the inherent limitations of standard video reduce the operator's effectiveness. These limitations have been compensated for in many ways, from using the operator's adaptability, to augmenting his capability with feedback from a variety of sensors and simulations. Omniview can overcome some of these limitations and improve the operator's efficiency without adding additional sensors or computational burden. It can minimize the potential collisions with facility equipment, provide peripheral vision, and display multiple images simultaneously from a single input device. The Omniview technology provides electronic pan, tilt, magnify, and rotational orientation within a hemispherical field-of-view without any moving parts. Image sizes, viewing directions, scale, offset, etc., may be adjusted to fit operator needs. This paper discusses the derivation of the image transformation, the design of the electronics, and two applications to telepresence that are under development. These are Video Emulated Tweening (VET), and Manipulator Guidance and Positioning (ManGAP). The VET effort uses Omniview to compensate for time-delayed video in teleoperation of remote vehicles. In ManGAP two Omniview systems are used to provide two sets of orientation vectors to points in the field-of-view (FOV). These vectors then provide absolute position information to both control the position of the telerobot, and to avoid collisions with the work sight equipment.

Kuban, Dan↗

Annual and Semi-Annual Temperature Oscillations in the Upper Mesosphere

Fourier transform spectrometer observations of the mesosphere have been performed at the University of Michigan (latitude: 42.5 N) on a long term basis. A database of near infrared Meinel hydroxyl spectra has been accumulated from which rotational temperatures have been determined. Harmonic analysis of one-day averaged temperatures for the period 1992.0 to 1994.5 has shown a distinct annual and semi-annual variation. Subsequent fitting of a five term periodic function characterizing the annual and semi-annual temperature oscillations to the daily averaged temperatures was performed. The resultant mean temperature and the amplitudes and phases of the annual and semi-annual variations are shown to coincide with an emission height slightly above 85 km which is consistent with the mean rocket derived altitude for peak nocturnal hydroxyl emission.

Niciejewski, R. J.↗

Compact Polarimetry in a Low Frequency Spaceborne Context

Compact polarimetry has been shown to be an interesting alternative mode to full polarimetry when global coverage and revisit time are key issues. It consists on transmitting a single polarization, while receiving on two. Several critical points have been identified, one being the Faraday rotation (FR) correction and the other the calibration. When a low frequency electromagnetic wave travels through the ionosphere, it undergoes a rotation of the polarization plane about the radar line of sight for a linearly polarized wave, and a simple phase shift for a circularly polarized wave. In a low frequency radar, the only possible choice of the transmit polarization is the circular one, in order to guaranty that the scattering element on the ground is illuminated with a constant polarization independently of the ionosphere state. This will allow meaningful time series analysis, interferometry as long as the Faraday rotation effect is corrected for the return path. In full-polarimetric (FP) mode, two techniques allow to estimate the FR: Freeman method using linearly polarized data, and Bickel and Bates theory based on the transformation of the measured scattering matrix to a circular basis. In CP mode, an alternate procedure is presented which relies on the bare surface scattering properties. These bare surfaces are selected by the conformity coefficient, invariant with FR. This coefficient is compared to other published classifications to show its potential in distinguishing three different scattering types: surface, doublebounce and volume. The performances of the bare surfaces selection and FR estimation are evaluated on PALSAR and airborne data. Once the bare surfaces are selected and Faraday angle estimated over them, the correction can be applied over the whole scene. The algorithm is compared with both FP techniques. In the last part of the paper, the calibration of a CP system from the point of view of classical matrix transformation methods in polarimetry is proposed.

radar polarization diversity↗

L'CO/LFIR Relations with CO Rotational Ladders of Galaxies Across the Herschel SPIRE Archive

We present a catalog of all CO (carbon monoxide) (J (total angular momentum quantum number) equals 1-0 through J equals 13-12), [CI], and [NII] lines available from extragalactic spectra from the Herschel SPIRE (Spectral and Photometric Imaging Receiver) Fourier Transform Spectrometer (FTS) archive combined with observations of the low-J CO lines from the literature and from the Arizona Radio Observatory. This work examines the relationships between L (sub FIR (Far Infra Red)), L prime (sub CO), and L (sub CO) / L (sub CO, 1-0). We also present a new method for estimating probability distribution functions (PDFs) from marginal signal-to-noise ratio Herschel FTS spectra, which takes into account the instrumental "ringing" and the resulting highly correlated nature of the spectra. The slopes of Log (L (sub FIR)) versus Log (L prime (sub CO)) are linear for all mid- to high-J CO lines. The mid- to high-J CO luminosity relative to CO J equals 1-0 increases with increasing L (sub FIR), indicating higher excitement of the molecular gas, though these ratios do not exceed approximately 100. The luminosities relative to CO J equals 1-0 remain relatively at from J equals 6-5 through J equals13-2, across many orders of magnitude of L (sub FIR). Qualitative comparisons to current theoretical models do not match these flat SLED (spectral line energy distributions) shapes, indicating the need for more comprehensive modeling of the excitation processes of warm molecular gas in nearby galaxies.

Submillimeter Data↗

The Infrared Spectrum of H 2 S from 1 to 5 µm

The absorption spectra of H 2 S from 2000 to 11 147 cm -1 have been obtained with spectral resolutions of 0.006, 0.012, and 0.021 cm -1 and optical paths of 1.5 m to 433 m using the Fourier transform spectrometer at Kitt Peak National Observatory/National Solar Observatory. The 20 new vibrational bands have been assigned for the first time and 8 others re-analyzed so that accurate energy levels, band origins, and rotational parameters could be determined for a total of 29 states. Experimental band centers have been modeled by vibrational calculations. Line intensity measurements and analysis are in progress. A prediction of the 4 µm bands of H 2 S is currently available.

absorption↗

Robot Acting on Moving Bodies (RAMBO): Interaction with tumbling objects

Interaction with tumbling objects will become more common as human activities in space expand. Attempting to interact with a large complex object translating and rotating in space, a human operator using only his visual and mental capacities may not be able to estimate the object motion, plan actions or control those actions. A robot system (RAMBO) equipped with a camera, which, given a sequence of simple tasks, can perform these tasks on a tumbling object, is being developed. RAMBO is given a complete geometric model of the object. A low level vision module extracts and groups characteristic features in images of the object. The positions of the object are determined in a sequence of images, and a motion estimate of the object is obtained. This motion estimate is used to plan trajectories of the robot tool to relative locations rearby the object sufficient for achieving the tasks. More specifically, low level vision uses parallel algorithms for image enhancement by symmetric nearest neighbor filtering, edge detection by local gradient operators, and corner extraction by sector filtering. The object pose estimation is a Hough transform method accumulating position hypotheses obtained by matching triples of image features (corners) to triples of model features. To maximize computing speed, the estimate of the position in space of a triple of features is obtained by decomposing its perspective view into a product of rotations and a scaled orthographic projection. This allows use of 2-D lookup tables at each stage of the decomposition. The position hypotheses for each possible match of model feature triples and image feature triples are calculated in parallel. Trajectory planning combines heuristic and dynamic programming techniques. Then trajectories are created using dynamic interpolations between initial and goal trajectories. All the parallel algorithms run on a Connection Machine CM-2 with 16K processors.

Davis, Larry S.↗

Remote Thermal IR Spectroscopy of our Solar System

Indirect methods to detect extrasolar planets have been successful in identifying a number of stars with companion planets. No direct detection of an extrasolar planet has yet been reported. Spectroscopy in the thermal infrared region provides a potentially powerful approach to detection and characterization of planets and planetary systems. We can use knowledge of our own solar system, its planets and their atmospheres to model spectral characteristics of planets around other stars. Spectra derived from modeling our own solar system seen from an extrasolar perspective can be used to constrain detection strategies, identification of planetary class (terrestrial vs. gaseous) and retrieval of chemical, thermal and dynamical information. Emission from planets in our solar system peaks in the thermal infrared region, approximately 10 - 30 microns, substantially displaced from the maximum of the much brighter solar emission in the visible near 0.5 microns. This fact provides a relatively good contrast ratio to discriminate between stellar (solar) and planetary emission and optimize the delectability of planetary spectra. Important molecular constituents in planetary atmospheres have rotational-vibrational spectra in the thermal infrared region. Spectra from these molecules have been well characterized in the laboratory and studied in the atmospheres of solar system planets from ground-based and space platforms. The best example of such measurements are the studies with Fourier transform spectrometers, the Infrared Interferometer Spectrometers (IRIS), from spacecraft: Earth observed from NIMBUS 8, Mars observed from Mariner 9, and the outer planets observed from Voyager spacecraft. An Earth-like planet is characterized by atmospheric spectra of ozone, carbon dioxide, and water. Terrestrial planets have oxidizing atmospheres which are easily distinguished from reducing atmospheres of gaseous giant planets which lack oxygen-bearing species and are characterized by spectra containing hydrocarbons such as methane and ethane. Spectroscopic information on extrasolar planets thus can permit their classification. Spectra and spectral lines contain information on the temperature structure of the atmosphere. Line and band spectra can be used to identify the molecular constituents and retrieve species abundances, thereby classifying and characterizing the planet. At high enough spectral resolution characteristic planetary atmospheric dynamics and unique phenomena such as failure of local thermodynamic equilibrium can be identified. Dynamically induced effects such as planetary rotation and orbital velocity shift and change the shape of spectral features and must be modeled in detailed spectral studies. We will use our knowledge of the compositional, thermal and dynamical characteristics of planetary atmospheres in our own solar system to model spectra observed remotely on similar planets in extrasolar planetary systems. We will use a detailed radiative transfer and beam integration program developed for the modeling and interpretation of thermal infrared spectra measured from nearby planet planets to generate models of an extra-solar "Earth" and "Jupiter". From these models we will show how key spectral features distinguish between terrestrial and gaseous planets, what information can be obtained with different spectral resolution, what spectral features can be used to search for conditions for biogenic activity, and how dynamics and distance modify the observed spectra. We also will look at unique planetary phenomena such as atmospheric lasing and discuss their utility as probes for detection and identification of planets. Results of such studies will provide information to constrain design for instrumentation needed to directly detect extrasolar planets.

Kostiuk, Theodor↗

Coupling of organic cation and inorganic lattice in methylammonium lead halide perovskites: Insights into a pressure-induced isostructural phase transition

Organic-inorganic hybrid metal-halide perovskite (OIHP) materials provide a tunable platform for engineering their optoelectronic properties. Although several high-pressure studies have been conducted from the OIHP family of single crystals and films, the exact nature of the dynamic coupling of the CH 3 NH 3 (MA) cation with the octahedral lattice framework and the mechanisms responsible for the structural phase transformation under pressure are not well captured. By combined photoluminescence (PL), synchrotron-based x-ray diffraction, and Raman-scattering studies as a function of pressure from methylammonium lead bromide (MAPbBr 3 ), we shed light on an isostructural phase transition due to the coupling of the MA cation and the PbBr 6 lattice through hydrogen bonding. The sharp discontinuities at ~ 1 GPa and ~ 3 GPa in the PL peak positions correlate with the structural changes observed in high-pressure XRD and Raman-scattering studies. The electronic band edge as a function of pressure is calculated within density-functional theory. The PL peak position, intensity and width of the excitonic peak show significant changes at 2 GPa, which corroborate the changes observed in high-pressure Raman-scattering studies. The frequencies of the lattice modes and the C-H/N-H bending and stretching modes of the MA cation show anomalous changes and other nuances at 2 GPa. The suppression of rotational and orientational disorder of the organic moiety is initiated at 2 GPa and the ordering is completed by 3.0 GPa, leading to an order-disorder type cubic II (Im$\overline{3}$) to orthorhombic ( Pnma ) phase transition. Along with the revelation of an isostructural transformation at 2 GPa, this paper highlights the impact of molecular vibrations on the electronic properties of MAPbBr 3 under pressure.

36 MATERIALS SCIENCE↗

Probing Interfacial Reaction Pathways in Atomic Layer Deposition on Sulfide Superionic Conductors

Sulfide superionic conductors (e.g., argyrodite Li 6 PS 5 Cl, LPSCl) are extremely promising for all solid-state batteries, but poor atmospheric stability and high interfacial reactivity limit widespread adoption. Coating LPSCl powders with ultrathin coatings using atomic layer deposition (ALD) mitigates these problems, protecting against atmospheric degradation and reducing reactivity with Li metal, yielding more stable cycling. Despite significant promise, the ALD mechanism is unknown, hampering the development of new coating chemistries. In this study, we elucidate the mechanism for Al 2 O 3 ALD on LPSCl using trimethyl aluminum (TMA) and H 2 O by combining in situ Fourier transform infrared spectroscopy, ex situ solid-state magic angle spinning nuclear magnetic resonance, UV Raman spectroscopy, X-ray photoelectron spectroscopy, and density functional theory calculations. We determine that ALD Al 2 O 3 nucleates promptly via TMA reaction with native —OH, —SH, and PS 3 -OH groups to form transient C–Al–O(S) species that are rapidly hydrolyzed during the subsequent H 2 O exposure. This reversible transformation maintains surface nucleophilicity and prevents sulfide decomposition. The resulting layer-by-layer growth leads to highly conformal Al 2 O 3 coatings on LPSCl that are readily scalable to ≥ 50 g quantities using a rotating drum fixture. This detailed understanding of ALD surface reactions provides critical insights guiding the selection of future ALD chemistries with improved performance.

atomic layer deposition↗