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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 469 records · Page 26
All sourcesNASA NTRSDOE OSTI
DOE OSTI2019

Dark Energy Survey Year 1 results: validation of weak lensing cluster member contamination estimates from P(z) decomposition

Weak lensing source galaxy catalogues used in estimating the masses of galaxy clusters can be heavily contaminated by cluster members, prohibiting accurate mass calibration. In this study, we test the performance of an estimator for the extent of cluster member contamination based on decomposing the photometric redshift P(z) of source galaxies into contaminating and background components. We perform a full scale mock analysis on a simulated sky survey approximately mirroring the observational properties of the Dark Energy Survey Year One observations (DES Y1), and find excellent agreement between the true number profile of contaminating cluster member galaxies in the simulation and the estimated one. We further apply the method to estimate the cluster member contamination for the DES Y1 redMaPPer cluster mass calibration analysis, and compare the results to an alternative approach based on the angular correlation of weak lensing source galaxies. We find indications that the correlation based estimates are biased by the selection of the weak lensing sources in the cluster vicinity, which does not strongly impact the P(z) decomposition method. Collectively, these benchmarks demonstrate the strength of the P(z) decomposition method in alleviating membership contamination and enabling highly accurate cluster weak lensing studies without broad exclusion of source galaxies, thereby improving the total constraining power of cluster mass calibration via weak lensing.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2021

New Determinations of the UV Luminosity Functions from z ~ 9 to 2 Show a Remarkable Consistency with Halo Growth and a Constant Star Formation Efficiency

Here we provide the most comprehensive determinations of the rest-frame UV luminosity function (LF) available to date with the Hubble Space Telescope (HST) at z ~ 2–9. Essentially all of the noncluster extragalactic legacy fields are utilized, including the Hubble Ultra Deep Field, the Hubble Frontier Fields parallel fields, and all five CANDELS fields, for a total survey area of 1136 arcmin{sup 2}. Our determinations include galaxies at z ~ 2–3 leveraging the deep HDUV, UVUDF, and ERS WFC3/UVIS observations available over an ~150 arcmin{sup 2} area in the GOODS-North and GOODS-South regions. All together, our collective samples include >24,000 sources, >2.3× larger than previous selections with HST. We identify 5766, 6332, 7240, 3449, 1066, 601, 246, and 33 sources at z ~ 2, 3, 4, 5, 6, 7, 8, and 9, respectively. Combining our results with an earlier z ~ 10 LF determination by Oesch et al., we quantify the evolution of the UV LF. Our results indicate that there is (1) a smooth flattening of the faint-end slope α from α ~ -2.4 at z ~ 10 to α ~ -1.5 at z ~ 2, (2) minimal evolution in the characteristic luminosity M* at z ≥ 2.5, and (3) a monotonic increase in the normalization log{sub 10}ϕ* from z ~ 10 to 2, which can be well described by a simple second-order polynomial, consistent with an “accelerated” evolution scenario. We find that each of these trends (from z ~ 10 to 2.5 at least) can be readily explained on the basis of the evolution of the halo mass function and a simple constant star formation efficiency model.

47 OTHER INSTRUMENTATION↗
DOE OSTI2017

X-Ray Spectral Properties of Seven Heavily Obscured Seyfert 2 Galaxies

We present the combined Chandra and Swift -BAT spectral analysis of seven Seyfert 2 galaxies selected from the Swift -BAT 100 month catalog. We selected nearby ( z ≤ 0.03) sources lacking a ROSAT counterpart that never previously been observed with Chandra in the 0.3–10 keV energy range, and targeted these objects with 10 ks Chandra ACIS-S observations. The X-ray spectral fitting over the 0.3–150 keV energy range allows us to determine that all the objects are significantly obscured, with N{sub H} ≥ 10{sup 23} cm{sup −2} at a >99% confidence level. Moreover, one to three sources are candidate Compton-thick Active Galactic Nuclei (CT-AGNs; i.e., N{sub H}≥10{sup 24} cm{sup −2}). We also test the recent spectral curvature method developed by Koss et al. to find candidate CT-AGNs, finding a good agreement between our results and their predictions. Because the selection criteria we adopted were effective in detecting highly obscured AGNs, further observations of these and other Seyfert 2 galaxies selected from the Swift -BAT 100 month catalog will allow us to create a statistically significant sample of highly obscured AGNs, therefore providing a better understanding of the physics of the obscuration processes.

79 ASTRONOMY AND ASTROPHYSICS↗
NASA NTRS1981

High Frequency Plasma Generators for Ion Thrusters

The results of a one year program to experimentally adapt two new types of high frequency plasma generators to Argon ion thrusters and to analytically study a third high frequency source concept are presented. Conventional 30 cm two grid ion extraction was utilized or proposed for all three sources. The two plasma generating methods selected for experimental study were a radio frequency induction (RFI) source, operating at about 1 MHz, and an electron cyclotron heated (ECH) plasma source operating at about 5 GHz. Both sources utilize multi-linecusp permanent magnet configurations for plasma confinement. The plasma characteristics, plasma loading of the rf antenna, and the rf frequency dependence of source efficiency and antenna circuit efficiency are described for the RFI Multi-cusp source. In a series of tests of this source at Lewis Research Center, minimum discharge losses of 220+/-10 eV/ion were obtained with propellant utilization of .45 at a beam current of 3 amperes. Possible improvement modifications are discussed.

Divergilio, W. F.↗
DOE OSTI2024

The Integration and Mapping of an Open-Source National Well Resource to Inform Geologic Carbon Storage Site Selection and Risk Prevention: The CO2-Locate Database

Geologic carbon storage (GCS) offers a way to capture and permanently store CO₂ from fossil fuel operations in underground geologic structures, aiding in the transition to a carbon-neutral energy economy. However, CO₂ injection sites can experience gas leakage through existing wells that penetrate storage reservoirs, making knowledge of well locations and characteristics crucial for permitting, infrastructure reusability, and risk assessment in GCS. Currently, public wellbore data from state, federal, and tribal entities are inconsistent and fragmented, with gaps and redundancies. To address this, the National Energy Technology Laboratory (NETL) developed CO2-Locate, an open-source, geospatial database and online application. CO2-Locate integrates over 50 data sources from federal, state, and tribal entities, creating a standardized national well database. Funded by the Bipartisan Infrastructure Law, the database is publicly available through the Energy Data eXchange (EDX) and viewable via the CO2-Locate web mapping application. This tool allows users to query, filter, and visualize well data to support GCS planning, permitting, and risk assessments. This presentation covers the methods used to create CO2-Locate, including data acquisition, processing, attribute mapping, and integration, much of which is automated for future updates. The web mapping application and its role in GCS site selection will also be discussed.

Tetteh, Daniel A.↗
NASA NTRS2008

Preliminary Analysis of Acoustic Measurements from the NASA-Gulfstream Airframe Noise Flight Test

The NASA-Gulfstream joint Airframe Noise Flight Test program was conducted at the NASA Wallops Flight Facility during October, 2006. The primary objective of the AFN flight test was to acquire baseline airframe noise data on a regional jet class of transport in order to determine noise source strengths and distributions for model validation. To accomplish this task, two measuring systems were used: a ground-based microphone array and individual microphones. Acoustic data for a Gulfstream G550 aircraft were acquired over the course of ten days. Over twenty-four test conditions were flown. The test matrix was designed to provide an acoustic characterization of both the full aircraft and individual airframe components and included cruise to landing configurations. Noise sources were isolated by selectively deploying individual components (flaps, main landing gear, nose gear, spoilers, etc.) and altering the airspeed, glide path, and engine settings. The AFN flight test program confirmed that the airframe is a major contributor to the noise from regional jets during landing operations. Sound pressure levels from the individual microphones on the ground revealed the flap system to be the dominant airframe noise source for the G550 aircraft. The corresponding array beamform maps showed that most of the radiated sound from the flaps originates from the side edges. Using velocity to the sixth power and Strouhal scaling of the sound pressure spectra obtained at different speeds failed to collapse the data into a single spectrum. The best data collapse was obtained when the frequencies were left unscaled.

Khorrami, Mehdi R.↗
DOE OSTI2015

Concluding a steam injection remediation project at a dense non-aqueous phase liquid source zone at the Savannah River site - 15303

Multiple subsurface dense non-aqueous phase liquid (DNAPL) source zones served as the sources for a groundwater plume within the A/M Area of the Savannah River Site. Between 1952 and 1985 over 1,600 metric tons of trichloroethylene, tetrachloroethylene, and 1,1,1-trichloroethane were released to the environment resulting in a 648 hectare plume with the M-Area Settling Basin receiving over half of the solvent discharges. In 1991, DNAPL was found in a water table well and steam injection technology was selected to remediate the source zone. Based on characterization data, the treatment area was 1.21 hectare with depths between 13.7 to 50.3 m. The remediation system included 96 vertical, horizontal, and angled steam injection and soil vapor extraction wells and a thermal monitoring system. Construction of the system began in 2004 and operation began in 2005. Steam was applied to the deep vadose zone first, then progressed to the aquifer, followed by the mid-vadose zone. Multiple steam strategies were utilized to enhance mass removal and were concluded in 2009. Soil vapor extraction continues, with residual temperatures in the deep permeability zones still exceeding 65 deg.C. To date over 204 metric tons of volatile organic compounds (VOCs) have been removed. Post-remediation soil, vapor, temperature, and groundwater data were used to evaluate steam injection effectiveness and demonstrated significant reduction in soil concentration, including removal of DNAPL that was evident in several soil cores prior to treatment. Heating the subsurface increased VOC solubility in groundwater and increased mass removal rates outside the target zone. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2020

Anthropogenic Markers in Alta Irrigation District Water Supply Wells

In July 2016, LLNL produced a report for the Kings River Watershed Coalition Authority (KRWCA) entitled “Groundwater Age and Nitrate Isotopic Composition in Alta Irrigation District Water Supply Wells” (Esser et al., 2016). That report summarized groundwater age and nitrate isotopic composition data produced by LLNL for Alta Irrigation District (AID) groundwater wells sampled by KRWCA in a pilot project to test the utility of advanced isotopic methods for constraining the timing and source of nitrate in groundwater at selected sites in the Kings River service area. One section of that report made recommendations for follow-on study. The first and strongest recommendation was to measure a wider suite of source tracers including co-contaminants such as herbicides, pesticides, pharmaceuticals, personal care products, and food constituents and additives. KRWCA followed up on this recommendation in Phase II of the pilot study by re-sampling the original set of wells and submitting the samples to a commercial laboratory for analysis of a limited range of co-contaminants (including pharmaceuticals, personal care products , and food constituents and additives, but not including herbicides or pesticides). They have asked that LLNL review and interpret these data in the context of previous LLNL analyses and to evaluate the utility of such co-contaminant analyses in providing additional constraints on the source of groundwater nitrate contamination in Alta Irrigation District water supply wells. The goal of the second phase of this pilot project is to evaluate the utility of co-contaminant occurrence for constraining nitrate source in groundwater at selected sites in the Kings River service area, with special reference to the use of such data in conjunction with advanced isotopic methods such as nitrate isotopic composition and groundwater age. Nitrate isotopic composition alone cannot distinguish nitrate derived from animal manure from nitrate derived from human septic waste. The presence or absence of agricultural chemicals (herbicides, pesticides, veterinary pharmaceuticals) or chemicals associated with people (human pharmaceuticals, artificial sweeteners) can help make this distinction. Co-contaminant analyses using multi-analyte LC-MS-MS protocols are now commercially available and reasonably priced. The feasibility and utility of the using co-contaminants for nitrate source attribution can be evaluated by 1) determining the degree to which co-contaminants occur in distinct and easily attributable groupings (e.g. agricultural chemicals vs personal care products and food additives); 2) determining the degree to which co-contaminant occurrence is consistent with nitrate isotopic composition and groundwater age (e.g. no co-contaminant occurrence in very old groundwater; co-contaminants consistent with animal manure or human septic waste occurring in groundwaters having nitrate isotopic composition also consistent with animal manure or human septic waste); and 3) determining the degree to which co-contaminants provide additional constraint on nitrate source over and beyond nitrate isotopic composition and groundwater age (e.g. distinguishing between animal manure and human septic waste).

58 GEOSCIENCES↗
DOE OSTI2023

Hydrothermal catalytic conversion of oleic acid to heptadecane over Ni/ZrO 2

There is growing interest in the substitution of expensive noble metal catalysts with low-cost earth-abundant metals in applications targeting biofuels production from waste organic feedstocks. Here, nickel (Ni) catalysts supported on zirconium dioxide (ZrO 2 ), both with and without copper (Cu) as a co-metal, were tested in hydrothermal reactions of unsaturated and saturated C18 fatty acids as models for waste oil feedstocks. In contrast to recent reports, this study showed no enhancement of nickel's activity for fatty acid conversion to alkane products when Cu was present. Ni/ZrO 2 prepared by metal coprecipitation methods converted 100% of oleic acid with 25% selectivity to heptadecane after 5h of reaction at 350 °C using methanol as a hydrogen donor source, increasing to 41% heptadecane after 20 h. Lower yields were observed with catalysts prepared by wet impregnation and using alternative hydrogen donor sources (glycerol, formic acid). Greater selectivity to heptadecane was also observed at higher temperatures (370 °C) and when the initial fatty acid had greater saturation. Longer term exposure to hydrothermal media led to metal sintering and catalyst deactivation. Findings support a path forward to the development of earth-abundant metal catalysts for the upgrading of waste organic feedstocks.

09 BIOMASS FUELS↗
DOE OSTI2022

The relation between optical and γ-ray emission in BL Lac sources

ABSTRACT The relativistic jets produced by some Active Galactic Nuclei (AGNs) are among the most efficient persistent sources of non-thermal radiation and represent an ideal laboratory for studying high-energy interactions. In particular, when the relativistic jet propagates along the observer’s line of sight, the beaming effect produces dominant signatures in the observed spectral energy distribution (SED), from the radio domain up to the highest energies, with the further possibility of resulting in radiation-particle multimessenger associations. In this work, we investigate the relationships between the emission of γ rays and the optical spectra of a sample of AGN, selected from BL Lac sources detected by the Fermi Large Area Telescope (Fermi-LAT). We find that there is a close relationship between the optical and γ-ray spectral indices. Despite all the limitations due to the non-simultaneity of the data, this observation strongly supports a substantial role of Synchrotron-Self Compton (SSC) radiation in a single zone leptonic scenario for most sources. This result simplifies the application of theoretical models to explore the physical parameters of the jets in this type of sources.

79 ASTRONOMY AND ASTROPHYSICS↗
NASA NTRS1986

Continuum radiation from active galactic nuclei: A statistical study

The physics of the continuum spectrum of active galactic nuclei (AGNs) was examined using a large data set and rigorous statistical methods. A data base was constructed for 469 objects which include radio selected quasars, optically selected quasars, X-ray selected AGNs, BL Lac objects, and optically unidentified compact radio sources. Each object has measurements of its radio, optical, X-ray core continuum luminosity, though many of them are upper limits. Since many radio sources have extended components, the core component were carefully selected out from the total radio luminosity. With survival analysis statistical methods, which can treat upper limits correctly, these data can yield better statistical results than those previously obtained. A variety of statistical tests are performed, such as the comparison of the luminosity functions in different subsamples, and linear regressions of luminosities in different bands. Interpretation of the results leads to the following tentative conclusions: the main emission mechanism of optically selected quasars and X-ray selected AGNs is thermal, while that of BL Lac objects is synchrotron; radio selected quasars may have two different emission mechanisms in the X-ray band; BL Lac objects appear to be special cases of the radio selected quasars; some compact radio sources show the possibility of synchrotron self-Compton (SSC) in the optical band; and the spectral index between the optical and the X-ray bands depends on the optical luminosity.

Isobe, T.↗
NASA NTRS2012

Five New Millisecond Pulsars from a Radio Survey of 14 Unidentified Fermi-LAT Gamma-Ray Sources

We have discovered five millisecond pulsars (MSPs) in a survey of 14 unidentified Ferm;'LAT sources in the southern sky using the Parkes radio telescope. PSRs J0101-6422, J1514-4946, and J1902-5105 reside in binaries, while PSRs J1658-5324 and J1747-4036 are isolated. Using an ephemeris derived from timing observations of PSR JOl01-6422 (P=2.57ms, DH=12pc/cubic cm ), we have detected gamma-ray pulsations and measured its proper motion. Its gamma-ray spectrum (a power law of Gamma = 0.9 with a cutoff at 1.6 GeV) and efficiency are typical of other MSPs, but its radio and gamma-ray light curves challenge simple geometric models of emission. The high success rate of this survey -- enabled by selecting gamma-ray sources based on their detailed spectral characteristics -- and other similarly successful searches indicate that a substantial fraction of the local population of MSPs may soon be known.

Kerr, M.↗
DOE OSTI2017

Characterization and Modeling of Contamination for Lyman Break Galaxy Samples at High Redshift

The selection of high-redshift sources from broadband photometry using the Lyman-break galaxy (LBG) technique is a well established methodology, but the characterization of its contamination for the faintest sources is still incomplete. We use the optical and near-IR data from four (ultra)deep Hubble Space Telescope legacy fields to investigate the contamination fraction of LBG samples at z∼5--8 selected using a color–color method. Our approach is based on characterizing the number count distribution of interloper sources, that is, galaxies with colors similar to those of LBGs, but showing detection at wavelengths shorter than the spectral break. Without sufficient sensitivity at bluer wavelengths, a subset of interlopers may not be properly classified, and contaminate the LBG selection. The surface density of interlopers in the sky gets steeper with increasing redshift of LBG selections. Since the intrinsic number of dropouts decreases significantly with increasing redshift, this implies increasing contamination from misclassified interlopers with increasing redshift, primarily by intermediate redshift sources with unremarkable properties (intermediate ages, lack of ongoing star formation and low/moderate dust content). Using Monte-Carlo simulations, we estimate that the CANDELS deep data have contamination induced by photometric scatter increasing from ∼2% at z∼5 to ∼6% at z∼8 for a typical dropout color ⩾1 mag, with contamination naturally decreasing for a more stringent dropout selection. Contaminants are expected to be located preferentially near the detection limit of surveys, ranging from 0.1 to 0.4 contaminants per arcmin{sup 2} at J{sub 125} = 30, depending on the field considered. This analysis suggests that the impact of contamination in future studies of z>10 galaxies needs to be carefully considered.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2018

Microbeam X-Ray Absorption Near-Edge Spectroscopy of Alloying Elements in the Oxide Layers of Irradiated Zircaloy-2

Hydrogen pickup of zirconium-based fuel cladding and structural materials during in-reactor corrosion can degrade fuel components because the ingress of hydrogen can lead to the formation of brittle hydrides. In the boiling water reactor (BWR) environment, Zircaloy-2 fuel cladding and structural components such as water rods and channels can experience accelerated hydrogen pickup, whereas Zircaloy-4 components exposed to similar conditions do not. Because the principal difference between the two alloys is that Zircaloy-2 contains nickel, accelerated hydrogen pickup has been hypothesized to result from the presence of nickel. However, an understanding of the mechanism by which this acceleration occurs is still lacking. We investigated the link between hydrogen pickup and the oxidation behavior of alloying elements when incorporated into the oxide layers formed on zirconium alloys when corroded in the reactor. Synchrotron radiation microbeam X-ray absorption near-edge spectroscopy (XANES) at the Advanced Photon Source was performed on carefully selected BWR-corroded Zircaloy-2 water rods at an assembly-averaged burnup ranging from 32.8 to 74.6 GWd/MTU to determine the oxidation states of alloying elements, such as iron and nickel, within the oxide layers as a function of distance from the oxide-metal interface at high burnup. Samples were chosen for comparison based on having similar oxide thicknesses, processing, elevation, reactors, and fluences but different hydrogen pickup fractions. Examinations of the oxide layers formed on these samples showed that (1) the oxidation states of these alloying elements changed with distance from the oxide-metal interface, (2) these elements exhibited delayed oxidation relative to the host zirconium, and (3) nickel in Zircaloy-2 remained metallic in the oxide layer at a longer distance from the oxide-metal interface than iron. An analysis of these results showed an apparent correlation between the delayed oxidation of nickel and higher hydrogen pickup of Zircaloy-2 at high burnup.

alloying elements↗
NASA NTRS1976

Development of dynamic calibration methods for POGO pressure transducers

Two dynamic pressure sources are described for the calibration of pogo pressure transducers used to measure oscillatory pressures generated in the propulsion system of the space shuttle. Rotation of a mercury-filled tube in a vertical plane at frequencies below 5 Hz generates sinusoidal pressures up to 48 kPa, peak-to-peak; vibrating the same mercury-filled tube sinusoidally in the vertical plane extends the frequency response from 5 Hz to 100 Hz at pressures up to 140 kPa, peak-to-peak. The sinusoidal pressure fluctuations can be generated by both methods in the presence of high pressures (bias) up to 55 MPa. Calibration procedures are given in detail for the use of both sources. The dynamic performance of selected transducers was evaluated using these procedures; the results of these calibrations are presented. Calibrations made with the two sources near 5 Hz agree to within 3% of each other.

Hilten, J. S.↗
DOE OSTI2024

Magnetic Nanoparticle Extraction of Lithium from Produced Waters - CRADA 483 (Final Report)

The demand for lithium in the energy production industry is expected to increase sharply, development of simple and cost-effective techniques for lithium production and recovery from various lithium sources is essential. In this project, core/shell magnetic nanoparticles were successfully designed to selectively extract lithium from aqueous lithium sources as an extension of Pacific Northwest National Laboratory’s magnetic nanofluid extraction technology. The core/shell magnetic nanoparticles are composed of manganese oxide-based lithium ion sieve shells, which allow selective lithium uptake from brines with multiple coexisting ions, over iron oxide cores, which can respond to external magnetic fields for effective recovery and reuse of adsorbents from a liquid. The synthesized lithium ion-sieves and core/shell magnetic nanoparticles were characterized using several techniques to reveal their crystallinity and morphology. The lithium uptake properties of the lithium ion-sieves and core/shell magnetic nanoparticles were evaluated in terms of lithium adsorption capacity, removal percentage, selectivity, and cycling performance in simulated and natural brines. Magnetic properties of the core/shell magnetic nanoparticles were tested by measuring magnetic saturation, and magnetic response of colloidal solutions containing the core/shell magnetic nanoparticles was tested with permanent magnets.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2015

Highly Selective Condensation of Biomass-Derived Methyl Ketones as a Source of Aviation Fuel

Aviation fuel (i.e., jet fuel) requires a mixture of C 9 -C 16 hydrocarbons having both a high energy density and a low freezing point. While jet fuel is currently produced from petroleum, increasing concern with the release of CO 2 into the atmosphere from the combustion of petroleum-based fuels has led to policy changes mandating the inclusion of biomass-based fuels into the fuel pool. Here we report a novel way to produce a mixture of branched cyclohexane derivatives in very high yield (>94 %) that match or exceed many required properties of jet fuel. As starting materials, we use a mixture of n -alkyl methyl ketones and their derivatives obtained from biomass. Here, these synthons are condensed into trimers via base-catalyzed aldol condensation and Michael addition. Hydrodeoxygenation of these products yields mixtures of C 12 -C 21 branched, cyclic alkanes. Using models for predicting the carbon number distribution obtained from a mixture of n-alkyl methyl ketones and for predicting the boiling point distribution of the final mixture of cyclic alkanes, we show that it is possible to define the mixture of synthons that will closely reproduce the distillation curve of traditional jet fuel.

biofuels↗