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At least 469 records · Page 26

Anomalous dips in reflection spectra of optical polymers deposited on plasmonic metals

Abstract We have studied reflection spectra of dye-doped and undoped polymers deposited onto Ag and Au substrates and found anomalous dips in the UV spectral range. On top of Ag substrates, the λ ∼ 375 nm dips were observed in undoped PMMA, PVP, and PS polymers as well as PMMA doped with Rh590 and HITC laser dyes. In silver-based samples, the spectral positions of the observed reflection dips were close to singularities in the refractive indexes of surface plasmon polaritons (SPPs) propagating at the interface between Ag and polymer. The latter singularities can tentatively explain the λ ∼ 375 nm reflection dips, if the scattering of Ag and polymeric films is large enough to launch SPP without any prism or grating. The dips observed in reflection of Rh590:PMMA and HITC:PMMA on top of Au, were more pronounced than those on Ag, broader, shifted to shorter wavelengths, and their spectral positions had large standard deviations. Furthermore, no anomalous dips in gold-based samples were observed in the reflection spectra of undoped PMMA, PVP, and PS polymers, and a modest singularity in the SPP refractive index, predicted theoretically at λ ∼ 500 nm, cannot explain the dips in the UV reflection spectra observed experimentally. It appears likely that the origin of the reflection dips on top of Au substrates is different from that on top of Ag substrates.

36 MATERIALS SCIENCE↗

Light-Toned, Layered Outcrops of Northern Terra Meridiani Mars: Viking, Phobos 2, and Mars Global Surveyor Observations

Locating outcrops of sedimentary rock on Mars is an important step toward deciphering the planet's geologic and climatologic record. Sedimentary rock representing the earliest martian environments, are of particular interest in this context. This is a report about a vast exposure of material proposed to be martian sedimentary rock. The outcrops cover an area (approximately sq 300,000 km) roughly the size of the Colorado Plateau in North America (approximately 260,000 sq km). The materials occur in northern Terra Meridiani, near of one of the four sites being considered for a 2004 NASA Mars Exploration Rover (MER) landing. The landing ellipse, centered at deg S, deg W, lies in a region exhibiting smooth and rough (at meter scale) dark-toned surfaces, with scattered light-toned patches. Stratigraphically, the dark-toned materials at the MER site lie unconformably on top of a previously-eroded, light-toned surface; the light-toned patches in the landing ellipse are geologic windows down to this lower stratigraphic unit. North of the landing ellipse, the light-toned materials are well-exposed because the darker materials have been removed, stranding outlier remnants in a few locations. The light-toned materials are layered, vertically heterogeneous, and exhibit lateral continuity over hundreds of kilometers. Eroded layers produce cliffs; some outcrops are expressed as mesas, buttes, and spires; and impact craters ranging in diameter from a few meters to tens of kilometers are interbedded with the layers. The purpose of this report is to summarize the results of greater than 6 years of photogeologic investigation into the nature of the light-toned outcrops of northern Terra Meridiani. The work is a 'snapshot' of progress made toward eventual geologic mapping and establishment of the stratigraphic sequence for the materials through 30 September 2002, a day prior to the first release of Mars Odyssey Thermal Emission Imaging System (THEMIS) data to the NASA Planetary Data System (PDS). The main body of data examined were Mars Global Surveyor (MGS) Mars Orbiter Camera (MOC) images acquired through 30 September 2002. The data also 2 include Viking orbiter images, a Phobos 2 Termoscan image, MGS Mars Orbiter Laser Altimeter (MOLA) topographic observations, and the products of published Viking Infrared Thermal Mapper (IRTM) and Mars Global Surveyor (MGS) Thermal Emission Spectrometer (TES) analyses. Through September 2002, over 126,000 MOC images had been acquired, and greater than 600 of the MOC narrow angle (1.5-12 m/pixel) images occur within the portions of Terra Meridiani and southwestern Arabia Terra.

Edgett, Kenneth S.↗

Report on Recent Upgrades to the Curved Duct Test Rig at NASA Langley Research Center

The Curved Duct Test Rig (CDTR) is an experimental facility that is designed to assess the acoustic and aerodynamic performance of aircraft engine nacelle liners in close to full scale. The test section is between 25% and 100% of the scale of aft bypass ducts of aircraft engines ranging in size from business jet to large commercial passenger jet. The CDTR has been relocated and now shares space with the Grazing Flow Impedance Tube in the Liner Technology Facility at NASA Langley Research Center. As a result of the relocation, research air is supplied to the CDTR from a 50,000 cfm centrifugal fan. This new air supply enables testing of acoustic liner samples at up to Mach 0.500. This paper documents experiments and analysis on a baseline liner sample, which the authors had analyzed and reported on prior to the move to the new facility. In the present paper, the experimental results are compared to those obtained previously in order to ensure continuity of the experimental capability. Experiments that take advantage of the facility s expanded capabilities are also reported. Data analysis features that enhance understanding of the physical properties of liner performance are introduced. The liner attenuation is shown to depend on the mode that is incident on the liner test section. The relevant parameter is the mode cut-on ratio, which determines the angle at which the sound wave is incident on the liner surface. The scattering of energy from the incident mode into higher order, less attenuated modes is demonstrated. The configuration of the acoustic treatment, in this case lined on one surface and hard wall on the opposite surface, is shown to affect the mode energy redistribution.

Gerhold, Carl H.↗

Prediction of particulate contamination on aperture window

This paper presents an analysis to predict the effects of light scattering by surface particles on the sensor window of a missile during ascent flight. The particulate contaminant distribution on the window is calculated by tallying the number of particles in a set of size ranges. The particulate contamination at the end of the mission is predicted by adding the contributions from the events of ground and flight operations. The surface particle redistributions caused by vibroacoustically induced surface acceleration was found to contribute the most of the particulate surface contamination. The analytical surface obscuration calculation with a set of particle counts was compared to the results of image analyzer measurement. The analytical results, which were calculated with a given function of particle shape depending on the size, were more conservative than the measurement. A scattering calculation using a verified BSDF model showed that the scattering was less than 0.001 at 20 off the direction of the incident light in the mid IR wavelength when the surfaces were at Level 300 initially.

Lee, Aleck L.↗

Radar scattering from a diffuse vegetation layer over a smooth surface

A simple model is presented for the oblique backscatter and bistatic scatter from a smooth surface overlain by a diffuse layer. Only single scattering in the diffuse layer is taken into account. The model analysis shows that the combination of volume scattering and oblique reflection at the surface may increase appreciably the waves scattering. The scattering strongly depends on the properties of the smooth surface. These results support some of the observations made with the Seasat spaceborne imaging radar over flooded regions with heavy vegetation cover.

Engheta, N.↗

Surveyor results.

Surveyor lunar scientific payload and results, discussing TV camera, soil mechanics and surface sampler, alpha scattering instrument, small magnets and surface analysis

Hibbs, A. R.↗

Atmospheric scattering effects on ground-based measurements of thermospheric winds

Convergent or divergent thermospheric wind patterns detected by ground-based Fabry-Perot interferometric measurements of the Doppler shifts of atomic lines are demonstrated to occur in the presence of strong intensity gradients and a scattering atmosphere. Consideration is given to the color shifts observed when sighting to the north or the south, and a numerical model is developed to describe the wind patterns which produce the recorded shifts. An account is taken of the direct and scattered components of the brightness, with the atmosphere treated as a single scattering layer with a reflecting surface underneath. A scattering coefficient is calculated, together with the line shape of the wavelength shifts. The scattered light is demonstrated, both through simulations and measurements taken near Calgary, Alberta, to produce convergence or divergence of the color shifts, depending on the line-of-sight of the viewing.

Abreu, V. J.↗

An investigation of the forward scattering theorem

The calculation of an EM wave's extinction loss during propagation within an inhomogeneous medium, as in active and passive remote sensing modeling, can be undertaken either through the summation of the scattering and absorption losses or through the use of the forward scattering theorem. Attention is presently given to the similarities and differences of these two approaches as a function of dielectric properties of a spherical scatterer and the incident frequency. Scattering loss is obtainable by integrating the magnitude-squared of the scattered field over a spherical surface surrounding the scatterer; the scattered field and the field within the scatterer are computed according to Mie theory.

Karam, M. A.↗

Measurement of sea ice backscatter characteristics at 36 GHz using the surface contour radar

Scattering studies of sea ice off the coast of Greenland were performed in January 1984 using the 36-GHz Surface Contour Radar (SCR) aboard the NASA P-3 aircraft. An oscillating mirror scans an actual half-power width of 0.96 degrees laterally to measure the surface at 51 evenly spaced points. By banking the aircraft, real-time topographical mapping and relative backscattered power are obtained at incidence angles between 0 and 30 degrees off-nadar, achieving at 175 m altitude a 2.9 by 4.4 m spatial resolution at nadir. With an aircraft ground speed of 100 m/s, 5-m successive scan line spacing and 1.8-m cross-track direction spacing is provided. By circling the aircraft in the 15 degree bank, the azimuthal anisotropy of the scattering is investigated along with the incidence angle dependence.

Fedor, L. S.↗

Backscattering from a randomly rough dielectric surface

A backscattering model for scattering from a randomly rough dielectric surface is developed based on an approximate solution of a pair of integral equations for the tangential surface fields. Both like and cross-polarized scattering coefficients are obtained. It is found that the like polarized scattering coefficients contain two types of terms: single scattering terms and multiple scattering terms. The single scattering terms in like polarized scattering are shown to reduce the first-order solutions derived from the small perturbation method when the roughness parameters satisfy the slightly rough conditions. When surface roughnesses are large but the surface slope is small, only a single scattering term corresponding to the standard Kirchhoff model is significant. If the surface slope is large, the multiple scattering term will also be significant. The cross-polarized backscattering coefficients satisfy reciprocity and contain only multiple scattering terms. The difference between vertical and horizontal scattering coefficients is found to increase with the dielectric constant and is generally smaller than that predicted by the first-order small perturbation model. Good agreements are obtained between this model and measurements from statistically known surfaces.

Fung, Adrian K.↗

A theory of microwave apparent temperature over the ocean

In the microwave region combined active (scatterometer) and passive (radiometer) remote sensors over the ocean show promise of providing surface wind speeds and weather information to the oceanographer and meteorologist. This has aroused great interest in the investigation of the scattering of waves from the sea surface. A composite surface scattering theory is investigated. The two-scale scattering theory proposed by Semyonov was specifically extended to compute the emmision and scattering characteristics of ocean surfaces. The effects of clouds and rain on the radiometer and scatterometer observations are also investigated using horizontally stratified model atmospheres with rough sea surfaces underneath. Various cloud and rain models proposed by meteorologist were employed to determine the rise in the microwave temperature when viewing downward through these model atmospheres. For heavy rain-fall rates the effects of scattering on the radiative transfer process are included.

Wu, S. T.↗

Fully quantum calculations of O 2 –N 2 scattering using a new potential energy surface: Collisional perturbations of the oxygen 118 GHz fine structure line

A proper description of the collisional perturbation of the shapes of molecular resonances is important for remote spectroscopic studies of the terrestrial atmosphere. Of particular relevance are the collisions between the $\text{O}_2$ and $\text{N}_2$ molecules—the two most abundant atmospheric species. In this work, we report a new highly accurate $\text{O}_2(\text{X}^3Σ^–_g)–\text{N}_2(\text{X}^1Σ^+_g)$ potential energy surface and use it for performing the first quantum scattering calculations addressing line shapes for this system. We use it to model the shape of the 118 GHz fine structure line in $\text{O}_2$ perturbed by collisions with $\text{N}_2$ molecules, a benchmark system for testing our methodology in the case of an active molecule in a spin triplet state. The calculated collisional broadening of the line agrees well with the available experimental data over a wide temperature range relevant for the terrestrial atmosphere. This work constitutes a step toward populating the spectroscopic databases with ab initio line shape parameters for atmospherically relevant systems.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Energy transfer in volume-reflecting heat shields

An approximate analysis of radiative transfer in highly scattering materials was developed based on the Kubelka-Munk differential equations--a set of two differential equations representing the spatial rate of change of radiative half-fluxes within the scattering media. These approximate solutions of the Kubelka-Munk equations together with analytic solutions for the steady state temperature distribution for two types of boundary conditions are given. These solutions show the influence of back surface reflectance, scattering power, incident radiative flux parameter and boundary conductive flux parameter on overall reflectance and temperature distributions. This radiation field analysis, adapted to spherical geometry, was applied to the evaluation of the thermal performance of teflon and fritted quartz as heat protection materials for entry into the atmosphere of Jupiter.

Weston, K. C.↗

Bidirectional reflectance spectroscopy. I - Theory

An approximate analytic solution is derived for the radiative transfer equation describing particulate surface light scattering, taking into account multiple scattering and mutual shadowing. Analytical expressions for the following quantities are found: bidirectional reflectance, radiance coefficient and factor, the normal, Bond, hemispherical, and physical albedos, integral phase function and phase integral, and limb-darkening profile. Scattering functions for mixtures can be calculated, as well as corrections for comparisons of experimental transmission or reflection spectra with observational planetary spectra. The theory should be useful for the interpretation of reflectance spectroscopy of laboratory surfaces and the photometry of solar system objects.

Hapke, B.↗

Open Rotor Noise Prediction at NASA Langley - Capabilities, Research and Development

The high fuel prices of recent years have caused the operating cost of the airlines to soar. In an effort to bring down the fuel consumption, the major aircraft engine manufacturers are now taking a fresh look at open rotors for the propulsion of future airliners. Open rotors, also known as propfans or unducted fans, can offer up to 30 per cent improvement in efficiency compared to high bypass engines of 1980 vintage currently in use in most civilian aircraft. NASA Langley researchers have contributed significantly to the development of aeroacoustic technology of open rotors. This report discusses the current noise prediction technology at Langley and reviews the input data requirements, strengths and limitations of each method as well as the associated problems in need of attention by the researchers. We present a brief history of research on the aeroacoustics of rotating blade machinery at Langley Research Center. We then discuss the available noise prediction codes for open rotors developed at NASA Langley and their capabilities. In particular, we present the two useful formulations used for the computation of noise from subsonic and supersonic surfaces. Here we discuss the open rotor noise prediction codes ASSPIN and one based on Ffowcs Williams-Hawkings equation with penetrable data surface (FW - Hpds). The scattering of sound from surfaces near the rotor are calculated using the fast scattering code (FSC) which is also discussed in this report. Plans for further improvements of these codes are given.

Farassat, Fereidoun↗

The Dissolution of an Interfween Miscible Liquids

The disappearance of the surface tension of the interface of a binary mixture, measured using the dynamic surface light scattering technique, is slower for a binary mixture of higher density contrast. A comparison with a naive diffusion model, expected to provide a lower limit for the speed of dissolution in the absence of gravity shows that the interfacial surface tension disappears much slower than even by diffusion with the effect becoming much more pronounced when density contrast between the liquid phases is increased. Thus, the factor most likely to be responsible for this anomalously slow dissolution is gravity. A mechanism could be based on the competition between diffusive relaxation and sedimentation at the dissolving interface.

Vlad, D.H.↗

Surface contamination monitoring by the measurement of scattering distribution functions

This paper describes the use of Bidirectional Scattering Distribution Functions (BSDF) to quantify surface degradation, thus providing an effective method for contamination monitoring. This approach to contamination monitoring is based on the use of witness surfaces (mirrors or glass slides) located next to the critical surfaces. Contaminant accretion can be monitored during all phases of spacecraft fabrication, assembly, and testing. The method can be applied in other areas of contamination control such as monitoring of clean room environments. The BSDF can also prove extremely useful in establishing contamination control requirements and acceptability criteria. This paper describes the apparatus adopted to perform BSDF measurements and discusses some practical aspects of data collection. The results obtained in contamination monitoring programs performed at the NASA Goddard Space Flight Center are presented. Some possible new applications of this monitoring technique are also addressed.

Carosso, Paola A.↗