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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 487 records · Page 27
All sourcesNASA NTRSDOE OSTI
DOE OSTI2023

Direct analysis of cotton swipes for uranium and plutonium isotopic determination by microextraction-ICP-MS

The determination of uranium and plutonium isotopic abundance on environmental samples collected by International Atomic Energy Agency (IAEA) inspectors is vital for the detection of undeclared nuclear activities and material under the international nuclear safeguards regime. Current analytical protocols require time-consuming sample preparation steps prior to subsequent measurement by inorganic mass spectrometry (MS). Recent efforts from this laboratory have focused on developing sample preparation methods for faster analysis, potentially allowing higher sample throughput[1]. Alternative methods including microextraction sampling in conjunction with inductively coupled plasma-mass spectrometry (ICP-MS) have been recently explored. This methodology, microextraction-ICP-MS, was developed such that uranium and plutonium could be extracted from the swipe surface and directed into the ICP-MS for an in-situ measurement, eliminating the need for swipe ashing and digestion. A commercial off-the-shelf microextraction system was customized with an automated movable XY stage that can be programmed to save sampling locations, allowing for automated rapid sampling of swipe surfaces. Additional efforts have focused on the utilization of collision cell technology to the microextraction ICP-MS method. This would eliminate the need for lengthy column chemistry procedures to purify separated uranium and plutonium fractions before analysis. Here, the extracted U/Pu analyte is measured by reacting the uranium ions with CO2 in the collision cell of an ICP-MS, shifting the uranium to UO+, which will not interfere with the plutonium isotopic determination. The developed method utilizing collision cell – ICP-MS technology has demonstrated the ability to measure plutonium isotope ratios in the presence of high uranium concentration on the transient signal from the microextraction system utilizing certified reference materials from JRC-Geel and the New Brunswick Laboratory Program Office.

Bradley, Veronica↗
NASA NTRS2017

Influence of Mid-Latitude Cyclones on European Background Surface Ozone Investigated in Observations, MACC and MERRA-2 Reanalyses

The relationship between springtime mid-latitude cyclones and background ozone at two rural monitoring sites on the west coast of Europe -- Mace Head, Ireland and Monte Velho, Portugal -- is explored using a combination of observations and three reanalyses: 1) the European Centre for Medium-Range Weather Forecasts' (ECMWF) ERA-Interim reanalysis, 2) the Monitoring Atmospheric Composition and Climate (MACC) reanalysis and 3) NASA's Modern-Era Retrospective Analysis for Research and Applications Version-2 (MERRA-2) reanalysis. The ERA-Interim cyclone tracks are used here to establish the long-term relationship between cyclones and ozone observations (since 1988). The MACC reanalysis data set, which covers the period 2003-2012, is produced with the ECMWF integrated forecast system (IFS) model two-way coupled to a chemistry transport model (CTM). Since the MACC reanalysis uses a similar atmospheric model to ERA-Interim, MACC is used to explore the mechanisms within the case study cyclones that can influence surface ozone concentrations at Mace Head and Monte Velho. The MERRA-2 reanalysis also provides 3D distributions of ozone, although less ideal for analysis of surface ozone concentrations since MERRA-2 ozone under represents ozone variability outside the stratosphere as it does not have a detailed chemistry scheme or emission sources for the troposphere. The MERRA-2 reanalysis, which has the potential to identify more features within the cyclones as the resolution is higher than the MACC reanalysis, is used in conjunction with the MACC reanalysis to provide a measure of uncertainty to the case study analysis. We found the main source of high ozone to these two sites is from the stratosphere, which is well represented in both the MERRA-2 and the MACC reanalyses, either from direct injection into the cyclone or associated with aged airstreams from decaying downstream cyclones that can become entrained and descend toward the surface within new cyclones over the NA region.

MERRA-2↗
NASA NTRS1976

On a finite dynamic element method for free vibration analysis of structures

This paper explores the concept of finite dynamic elements involving higher order dynamic correction terms in the associated stiffness and mass matrices. Such matrices are then developed for a rectangular prestressed membrane element. Next, efficient analysis techniques for the eigenproblem solution of the resulting quadratic matrix equations are described in detail. These are followed by suitable numerical examples which indicate that employment of such dynamic elements in conjunction with an efficient quadratic matric solution technique will result in a most significant economy in the free vibration analysis of structures.

Gupta, K. K.↗
DOE OSTI2023

Minimizing Interfacial Recombination in 1.8 eV Triple‐Halide Perovskites for 27.5% Efficient All‐Perovskite Tandems

Abstract All‐perovskite tandem solar cells show great potential to enable the highest performance at reasonable costs for a viable market entry in the near future. In particular, wide‐bandgap (WBG) perovskites with higher open‐circuit voltage ( V OC ) are essential to further improve the tandem solar cells’ performance. Here, a new 1.8 eV bandgap triple‐halide perovskite composition in conjunction with a piperazinium iodide (PI) surface treatment is developed. With structural analysis, it is found that the PI modifies the surface through a reduction of excess lead iodide in the perovskite and additionally penetrates the bulk. Constant light‐induced magneto‐transport measurements are applied to separately resolve charge carrier properties of electrons and holes. These measurements reveal a reduced deep trap state density, and improved steady‐state carrier lifetime (factor 2.6) and diffusion lengths (factor 1.6). As a result, WBG PSCs achieve 1.36 V V OC , reaching 90% of the radiative limit. Combined with a 1.26 eV narrow bandgap (NBG) perovskite with a rubidium iodide additive, this enables a tandem cell with a certified scan efficiency of 27.5%.

14 SOLAR ENERGY↗
DOE OSTI2025

Dynamic Strength and Equation of State of Epon 828 and Diethanolamine (DEA) Polymer Epoxy Under Shock Loading

Polymers are increasingly utilized in engineering applications that can experience high loading rates, necessitating increased understanding of their response under such conditions. The tamped Richtmyer-Meshkov Instability (RMI) method was used to characterize the equation of state and dynamic strength of the polymer Epon 828 cured with Diethanolamine (DEA). Plate impact experiments that drove a uniaxial shock compression wave across a sinusoidally corrugated metal-polymer interface were performed to generate shock stresses from 4-12 GPa and strain rates of approximately 1/s in the polymer. X-ray phase contrast imaging recorded the shock motion in the polymer and subsequent interface evolution. Analysis of this data yielded the polymer equation of state and, in conjunction with numerical modeling, the dynamic strength. The equation of state was validated against one-dimensional plate impact experiments from existing literature. The dynamic strength was compared to prior data for Epon 828 and related polymers at lower strain rates and found to exhibit significant strain rate and pressure-hardening effects. The strength of the Epon 828 polymer at 10 6 1/s was found to be approximately 1.5 GPa, suggesting that it is comparable to the strength of high strength metals at these dynamic conditions.

Equation of state↗
DOE OSTI2020

Exact restoration of Galilei invariance in density functional calculations with quantum Monte Carlo

We investigate some aspects of the connection between mean-field and ab-initio calculations for any-nucleon systems employing the Gogny effective interaction. In particular, we present variational Monte Carlo calculations of 4 He and 16 O, for which we extended the formalism of the linear method to the case of a density-dependent Hamiltonian. Monte Carlo calculations using an uncorrelated basis reduce to Hartree-Fock ones, but Galilean invariance can be preserved, contrary to the usual treatment. An analysis of the results obtained with the Gogny force when used in conjunction with correlated wave functions has also been performed. Here, the calculations show the collapse of the deuteron, leading to a set of unphysical predictions for the structure of heavier nuclei. This behavior remarks the different role of the Gogny effective interaction as compared to bare interactions typically used in fully microscopic calculations.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗
DOE OSTI2024

Solar Energy Innovation Network 2017-2024: Abbreviated Final Technical Report

This material is based upon work supported by the U.S. Department of Energy's (DOE) Office of Energy Efficiency and Renewable Energy (EERE) Solar Energy Technologies Office under the Agreement/Award Number 32954 for Solar Energy Innovation Network (SEIN) Project, 2017-2024. SEIN is a dynamic program that assembles diverse teams of stakeholders to research solutions to real-world challenges associated with solar energy adoption. In conjunction with its partner organizations, NREL implemented the program by providing research, analysis, and technical expertise directly to project teams and groups of teams (cohorts), by facilitating networked learning through cohorts and peer exchange, and by facilitating dissemination and replication of solutions and lessons learned among stakeholders across the U.S. with similar challenges.

14 SOLAR ENERGY↗
NASA NTRS1979

Supercritical wing design using numerical optimization and comparisons with experiment

A numerical minimization scheme is used in conjunction with two-dimensional and three-dimensional inviscid transonic flow analysis codes to provide procedures for wing leading edge aerodynamic design. The procedures are demonstrated in the design of a new leading edge to improve C-141 cruise performance. For the high aspect ratio moderately swept C-141 wing, the 2-D procedure is shown to yield results which are in close agreement with those obtained using the 3-D technique. Although the 2-D approach uses much less computation time than the 3-D technique, the latter requires fewer manhours than the former. Comparisons of predicted and wind tunnel measured performance improvements are presented which verify the design procedures.

Lores, M. E.↗
NASA NTRS1979

Analysis of SRB reentry acoustic environments

Space shuttle solid rocket booster reentry aeroacoustic environments were estimated. Particular emphasis was given to the aft skirt/exit plane region for the Mach number regime 0.6 = or greater than M infinity = or less than 3.5. The analysis is based on the evaluation of wind tunnel model results in conjunction with Monte Carlo simulation of trajectory parameters. The experimental approach is described as well as the evaluation process utilized. Predicted environments are presented in terms of one-third octave band spectra representing space averaged values for critical regions on the solid rocket booster.

Coffin, T.↗
NASA NTRS1980

Prediction and measurement of turbulent aerodynamic trailing edge flows

A viscous-inviscid interaction algorithm is developed for prediction of two-dimensional mean and fluctuating velocity distributions in the wake immediately downstream of an airfoil trailing edge. A composite pressure field is defined, and a Poisson equation solved for transverse pressure variations. A parabolized form of the time-averaged steady Navier-Stokes equations are solved in conjunction with a viscous-augmented two-dimensional inviscid potential flow analysis. A tensor constitutive equation is employed to predict Reynolds stress distributions from solutions of a turbulence kinetic energy two equation closure model. Numerical predictions compared favorably with detailed experimental data for mean and fluctuating velocities, and Reynolds shear stress distributions, in the trailing edge region of a NACA 63-012 airfoil.

Baker, A. J.↗
NASA NTRS1980

The operational use of Landsat for lake quality assessment

A cooperative program between the Wisconsin Department of Natural Resources and the University of Wisconsin for the assessment, with Landsat data, of the trophic status of all the significant inland lakes in Wisconsin is described. The analysis technique is a semiautomatic data acquisition and handling system which, in conjunction with an analytical categorization scheme, can be used for classifying inland lakes into one of seven categories of eutrophication and one of four problem types.

Scarpace, F. L.↗
NASA NTRS1987

Regional and seasonal variations of surface reflectance from satellite observations at 0.6 micron

A global series of seasonal visible surface reflectance maps derived from NOAA-5 Scanning Radiometer observations is presented. Methods for isolating clear-sky observations from satellite data are evaluated and the magnitude of atmospheric effects (Rayleigh scattering and ozone absorption) are presented. A preliminary analysis of digital vegetation and soils data bases, which were analyzed in conjunction with the satellite observations, is discussed. Regional and global reflectance homogeneity of land-cover types, and snow brightening for types, are presented. Results demonstrate that the statistical approach for isolating clear-sky radiances used in this study obtains accurate enough values for each location to allow meaningful measurements of seasonal, spatial and ecosystem variations in surface reflectance.

Matthews, Elaine↗
NASA NTRS1993

Device For Perception Of Polarization

Polarized image viewed through rotating polarizing filter appears to pulsate. Optical device enables human observer to perceive polarization of light. Used alone for viewing in real time and/or in conjunction with video or movie camera to record for subsequent detailed quantitative analysis of polarization in scene. Device used in remote sensing to classify portions of scenes according to polarization characteristics, to enhance viewing through atmosphere and oceans and to enhance contrasts. Used to monitor oilspill from air and detect changes in soil moisture and to map wetlands, among many other possible civilian and military applications.

Whitehead, Victor S.↗
NASA NTRS1993

Expert system-based mineral mapping in northern Death Valley, California/Nevada, using the Airborne Visible/Infrared Imaging Spectrometer (AVIRIS)

Integrated analysis of imaging spectrometer data and field spectral measurements were used in conjunction with conventional geologic field mapping to characterize bedrock and surficial geology at the northern end of Death Valley, California and Nevada. A knowledge-based expert system was used to automatically produce image maps showing the principal surface mineralogy from Airborne Visible/Infrared Imaging Spectrometer (AVIRIS) data. Linear spectral unmixing of the AVIRIS data allowed further determination of relative mineral, abundances and identification of mineral assemblages and mixtures. The imaging spectrometer data show the spatial distribution of spectrally distinct minerals occurring both as primary rockforming minerals and as alteration and weathering products. Field spectral measurements were used to verify the mineral maps and field mapping was used to extend the remote sensing results. Geographically referenced image maps produced from these data form new base maps from which to develop improved understanding of the processes of deposition and erosion affecting the present land surface.

Kruse, F. A.↗
NASA NTRS1992

Expert system-based mineral mapping using AVIRIS

Integrated analysis of imaging spectrometer data and field spectral measurements were used in conjunction with conventional geologic field mapping to characterize bedrock and surficial geology at the northern end of Death Valley, California and Nevada. A knowledge-based expert system was used to automatically produce image maps from Airborne Visible/Infrared Imaging Spectrometer (AVIRIS) data showing the principal surface mineralogy. The imaging spectrometer data show the spatial distribution of spectrally distinct minerals occurring both as primary rock-forming minerals and as alteration and weathering products. Field spectral measurements were used to verify the mineral maps and field mapping was used to extend the remote sensing results. Geographically referenced image-maps produced from these data form new base maps from which to develop improved understanding of the processes of deposition and erosion affecting the present land surface. The 'northern Grapevine Mountains' (NGM) study area was reported on in numerous papers. This area is an unnamed northwestward extension of the range. Most of the research here has concentrated on mapping of Jurassic-age plutons and associated hydrothermal alteration, however, the nature and scope of these studies is much broader, pertaining to the geologic history and development of the entire Death Valley region. AVIRIS data for the NGM site were obtained during May 1989. Additional AVIRIS data were acquired during September 1989 as part of the Geologic Remote Sensing Field Experiment (GRSFE). The area covered by these data overlaps slightly with the May 1989 data. Three and one-half AVIRIS scenes total were analyzed.

Kruse, Fred A.↗
NASA NTRS1994

Simplified Aerodynamic and Structural Modeling for Oblique All-Wing Aircraft. Phase 2: Structures

Any aircraft preliminary design study requires a structural model of the proposed configuration. The model must be capable of estimating the structural weight of a given configuration, and of predicting the deflections which will result from foreseen flight and ground loads. The present work develops such a model for the proposed Oblique All Wing airplane. The model is based on preliminary structural work done by Jack Williams and Peter Rudolph at Mdng, and is encoded in a FORTRAN program. As a stand-alone application, the program can calculate the weight CG location, and several types of structural deflections; used in conjunction with an aerodynamics model, the program can be used for mission analysis or sizing studies.

Kroo, Ilan↗
NASA NTRS2010

The International Space Weather Initiative

The International Space Weather Initiative (ISWI) is a program of international cooperation aimed at understanding the external drivers of space weather. The ISWI program has its roots in the successful International Heliophysical Year (IHY) program that ran during 2007 - 2009 and will continue with those aspects that directly affect life on Earth. The primary objective of the ISWI program is to advance the space weather science by a combination of instrument deployment, analysis and interpretation of space weather data from the deployed instruments in conjunction with space data, and communicate the results to the public and students. Like the IHY, the ISWI will be a grass roots organization with key participation from national coordinators in cooperation with an international steering committee. This presentation outlines the ISWI program including its organizational aspects and proposed activities. The ISWI observatory deployment and outreach activities are highly complementary to the CAWSES II activities of SCOSTEP.

Nat, Gopalswamy↗