Investigation into the mechanism of degradation of solar cells with silver- titanium contacts Progress report, 1 Jul. - 30 Nov. 1969
Electrochemical behavior of titanium in presence of halogens at various values of pH
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Electrochemical behavior of titanium in presence of halogens at various values of pH
Design and fabrication of halogen leak detector based on gradient sensing concept
Interatomic potentials and dissociation energies of diatomic hydrogen and halogen molecules studied with spectroscopy and potential curves
Modification of polyurethanes with alkyl halide resins, inorganic salts, and encapsulated volatile and reactive halogen for fuel fire control
Stress corrosion cracking of titanium alloys, velocity of cracking in aqueous and methanol solutions and halogenated organic solvents, concentration of TiCl3 in cracks
Emission line spectra of halogens Cl I, Br I and I I in 4-micron region
NASA program fire safety goals, discussing development of nonflammable materials covering fibrous asbestos, glass, polymides, Teflon, metallics and halogenated materials
A photographic system was designed to visualize the moisture flow in a steam turbine. Good performance of the system was verified using dry turbine mockups in which an aerosol spray simulated, in a rough way, the moisture flow in the turbine. Borescopes and fiber-optic light tubes were selected as the general instrumentation approach. High speed motion-picture photographs of the liquid flow over the stator blade surfaces were taken using stroboscopic lighting. Good visualization of the liquid flow was obtained. Still photographs of drops in flight were made using short duration flash sources. Drops with diameters as small as 30 micrometers (0.0012 in.) could be resolved. In addition, motion pictures of a spray of water simulating the spray off the rotor blades and shrouds were taken at normal framing rates. Specially constructed light tubes containing small tungsten-halogen lamps were used. Sixteen millimeter photography was used in all cases. Two potential problems resulting from the two-phase turbine flow (attenuation and scattering of light by the fog present and liquid accumulation on the borescope mirrors) were taken into account in the photographic system design but not evaluated experimentally.
Tungsten halogen projection lamps have integral ellipsoidal reflector, and hexagonal shaped plastic Fresnel lenses. Reflector is dichroic coated to reduce infrared content of reflected radiation. Array of lamps and lenses produces uniform collimated beam having near AM2 spectrum and intensity that can be used for testing flat plate solar collectors.
Compositions exhibit elastomeric properties and possess various degrees of flame resistance. First material polyurethane, incorporates halogen containing polyol and is flame resistant in air; second contains spandex elastomer with flame retardant additives; and third material is prepared from fluorelastomer composition of copolymer of vinylidene fluoride and hexafluoropropylene.
The process of core formation in the earth is subject to the constraints that it be nearly simultaneous with accretion and yet occur in a manner that the mantle retains radiogenic Xe-129 produced from the extinct radioactivity of I-129 with a half life of 17.6 million y. From these constraints, it appears that the only feasible mechanism is the segregation of an Fe-FeS melt. Trace element abundances in major classes of meteorites and the silicate fractions of the earth show that not only there is a high depletion of sulphur in the crust and the mantle, but that it is even more highly depleted than the rare gases, water and the halogens. From the nature of this depletion pattern and the fact that any model of accretion of the earth will necessarily produce an Fe-FeS melt, it is concluded that the light element in the core is largely sulphur with minor amounts of carbon. A consequence of this mode of core formation is found to be the availability of K-40 radioactive heat production in the liquid core, estimated at about 10 to the 19th power erg/s at the present time.
A low cost air mass 2 solar simulator for testing flat-plate solar collectors was developed and operated at Lewis. Total cost was less than $10,800/sq m ($1000/sq ft). It consists of an array of 143 tungsten-halogen 300-watt lamps, each having integral dichroic coated reflectors. A second array of 143 respective hexagonal-shaped plastic Fresnel lenses are located approximately 1 focal length from the lamps. The simulator will produce a uniform collimated beam covering an area of 1.2 by 1.2m(4 by 4 ft). Design features, construction details, and component costs are given, as well as measured results on a 12-lamp prototype.
Modifications and improvements on a low cost air mass 2 solar simulator are discussed. The performance characteristics of total irradiance, uniformity of irradiance, spectral distribution, and beam subtense angle are presented. The simulator consists of an array of tungsten halogen lamps hexagonally spaced in a plane. A corresponding array of plastic Fresnel lenses shapes the output beam such that the simulator irradiates a 1.2 m by 1.2 m area with uniform collimated irradiance. Details are given concerning individual lamp output measurements and placement of the lamps. Originally, only the direct component of solar irradiance was simulated. Since the diffuse component may affect the performance of some collectors, the capability to simulate it is being added. An approach to this diffuse addition is discussed.
The surface properties of lunar fines were investigated. Results indicate that, for the most part, these properties are independent of the chemical composition and location of the samples on the lunar surface. The leaching of channels and pores by adsorbed water vapor is a distinguishing feature of their surface chemistry. The elements of air, if adsorbed in conjunction with water vapor or liquid water, severely impedes the leaching process. In the absence of air, liquid water is more effective than water vapor in attacking the grains. The characteristics of Apollo 17 orange fines were evaluated and compared with those of other samples. The interconnecting channels produced by water vapor adsorption were found to be wider than usual for other types of fines. Damage tracks caused by heavy cosmic ray nuclei and an unusually high halogen content might provide for stronger etching conditions upon exposure to water vapor.
The present work describes briefly the design, construction, and operation of a low cost air mass 2 solar simulator, and then presents the performance characteristics of a modified version in terms of total irradiance, uniformity of irradiance, spectral distribution, and beam subtense angle. The simulator consists of an array of 143 tungsten halogen lamps and a corresponding array of 143 Fresnel lenses parallel and in front of the lenses, so that a 1.2 m by 1.2 m area is irradiated with uniform collimated irradiance. The performance of this 143-lamp version is compared with that of the 12-lamp prototype. It was found that the larger design required a lower lamp voltage for an equivalent average total irradiance in the test plane. However, distribution of total irradiance was not as good for the large simulator.
Volatile and nonvolatile trace element contents in a suite of Apollo 17 soils and rocks are studied. It is found that the halogens exhibit a remarkable degree of coherence because of their apparent diverse geochemistry, that the F-Cl-P2O5 coherence previously noted persists among Apollo 17 samples, that both U and Ru-Os support lateral mixing of regolith on a local scale, and that the meteoritic Ru/Os ratios found in a few samples are attributed to primitive lunar material that has not been extensively recycled.
A secondary battery is described utilizing hydrogen and halogen as primary reactants. It comprises inert anode and cathode initially contacting an aqueous solution of an acid and an alkali metal bromide. The hydrogen generated during charging of the cell is stored as gas, while the bromine becomes dissolved predominantly in the lower layers of the acid electrolyte. Preferred components are phosphoric acid and lithium bromide.
A preliminary analysis was made on the solar simulator lamp array. It is an array of 405 tungsten halogen lamps with Fresnel lenses to achieve the required spectral distribution and collimation. A computer program was developed to analyze lamp array performance at the test plane. Measurements were made on individual lamp lens combinations to obtain data for the computer analysis. The analysis indicated that the performance of the lamp array was about as expected, except for a need to position the test plane within 2.7 m of the lamp array to achieve the desired 7 percent uniformity of illumination tolerance.