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Sister Rod Destructive Test Results (FY19)

This report documents work performed under the Spent Fuel and Waste Disposition, Spent Fuel and Waste Science and Technology program for the US Department of Energy (DOE) Office of Nuclear Energy (NE). This work was performed to fulfill Level 2 Milestone M2SF-19ORO010201026 within work package SF-19OR01020102 and is an update to the work reported in M2SF-19OR010201028 and M3SF-19OR010201027. The document incorporates comments received with respect to the previous reports and incorporates additional test results. As a part of the US Department of Energy (DOE) Office of Nuclear Energy (NE) High Burnup Spent Fuel Data Project, Oak Ridge National Laboratory (ORNL) is performing destructive examinations (DEs) of high burnup (HBU) (>45 gigawatt days per metric ton uranium) spent nuclear fuel (SNF) rods from the North Anna Nuclear Power Station operated by Dominion Energy. The SNF rods, called the “sister rods,” are all HBU and include four different kinds of fuel rod cladding: standard Zircaloy-4 (Zirc-4), low-tin Zircaloy-4 (LT Zirc-4), ZIRLO ® , and M5 ® . The DEs are being conducted to obtain a baseline of the HBU rod’s condition prior to dry storage and are focused on understanding overall SNF rod strength and durability. Both composite fuel and empty cladding will be tested to derive material properties. While the data generated can be used for multiple purposes, a primary goal for obtaining the post-irradiation examination data and the associated measured mechanical properties is to support SNF dry storage licensing and relicensing activities by (1) addressing identified knowledge gaps and (2) enhancing the technical basis for post-storage transportation, handling, and consolidation activities. This report documents the status of the ORNL Phase I DEs of 8 sister rods and outlines the DE tasks performed and the data collected to date, as guided by the sister rod test plans. The DEs are performed using a phased approach, and the Phase 1 DEs being performed at ORNL include: • full-length rod heat treatments (FHT) of 3 selected sister rods to examine the effects of temperatures reached during dry storage preparation, • rod internal pressure and void volume measurements of the 3 FHT rods and 3 corresponding baseline rods, as well as 2 additional rods selected for depressurization/gas transmission tests and fatigue lifetime tests, • fission gas sampling and analysis, • depressurization and gas transmission tests, • rough segmentation of the selected rods for mechanical tests and rod characterization, • fuel sampling and burnup analysis, • metallography, • cladding total hydrogen measurements, • mechanical testing, including fatigue lifetime (CIRFT), four-point bend, axial tension, microhardness, ring compression, and burst tests. Table S-1 provides a summary of the DE status. The mechanical testing will be performed using fueled segments and is expected to complement previous and current mechanical test results using defueled cladding segments.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Update on 17 O evaluation and fast neutron evaluation for 181 Ta [Slides]

Reliable fast-neutron evaluation can be entirely encapsulated in the reaction model and related input. Ta181 is a particularly relevant case due to extraordinary coverage of various observables by differential experiments that offer much help and relatively little headache. Differences from the similar ENDF/B-VIII evaluation are as follows: more advanced modeling (CC OMP, MSD, MSC, decay schemes), more careful selection of models and parameters, new experimental data, and isomers. Overall, there is improved agreement with differential data and hints of better performance in integral testing.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Impact of Changes in ENDF/B-VII.1 and ENDF/B-VIII.0 235U Nuclear Data Indicated by NDSE Studies on LLNL Pulsed Sphere Simulations

A recent journal article by J.A. Gomez et al. measured gamma-ray die-off curves of three subcritical static highly-enriched uranium (HEU) assemblies driven by an external neutron source with a new detector system. This new detector system was developed for being used in dynamically driven subcritical assemblies as part of the Neutron Diagnosed Subcritical Experiments (NDSE) program. Simulations of these die-off curves with various nuclear data and comparison to experimental data indicated that a decrease of the ENDF/B-VII.1 235 U(n,inl) cross section by a factor 0.8 and 0.85 for ENDF/B-VIII.0 would lead to better predictions of experimental data. Here, we test the proposed changes with another type of measurement response, namely neutron-leakage spectra emitted in LLNL pulsed sphere measurements. These spheres were pulsed by 14-MeV neutrons produced via the D+T reaction in their center. The proposed changes in nuclear data have a distinctly smaller impact on predicting pulsed-sphere neutron-leakage spectra than for the die-off curves; they lead to a worsened prediction of the inelastic valley of LLNL pulsed-sphere neutron spectra indicating that the proposed change could constitute a compensating error. Changes in the inelastic angular distributions along with the cross section might be worthwhile to study

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Machine learning framework for predicting uranium enrichments from M400 CZT gamma spectra

A machine learning framework was developed for predicting uranium enrichments from M400 CZT gamma spectra. This framework leverages the availability of a large amount of measured M400 gamma spectra and uses a recently updated version of Gamma Detector Response and Analysis Software (GADRAS) for gamma spectrum analysis and generation. It also leverages the existing machine learning modules in Python for gamma spectrum data processing, curation, model training, benchmarking, and optimization of the deep machine learning models. The framework is used to develop a deep learning model to analyze gamma spectra from a set of U 3 O 8 samples with enrichments ranging from 0.31 to 93.17% and UF 6 cylinders with enrichments ranging from 0.2 to 4.95%, and the model performance is tested using a set of measured spectra and the respective declared enrichment values. Results show that the model can correctly classify 99.35% of the U 3 O 8 sample enrichments, and can predict the samples’ enrichments within an average absolute error of 0.099% (in percentage points of enrichment). For the UF 6 cylinders, the average absolute error was approximately 0.03%, with an accuracy of 98% in classifying discrete enrichment values of UF 6 samples. Finally, the results also show that the model has performed significantly better in terms of predicting enrichments in UF 6 cylinders based on measured gamma spectra than the GEM code, with a standard deviation (of the relative errors) of 2.23% (compared with the 11.51% value for the GEM code) based on results from a set of test data.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Improving robustness for model discerning synthesis process of uranium oxide with unsupervised domain adaptation

The quantitative characterization of surface structures captured in scanning electron microscopy (SEM) images has proven to be effective for discerning provenance of an unknown nuclear material. Recently, many works have taken advantage of the powerful performance of convolutional neural networks (CNNs) to provide faster and more consistent characterization of surface structures. However, one inherent limitation of CNNs is their degradation in performance when encountering discrepancy between training and test datasets, which limits their use widely. The common discrepancy in an SEM image dataset occurs at low-level image information due to user-bias in selecting acquisition parameters and microscopes from different manufacturers. Therefore, in this study, we present a domain adaptation framework to improve robustness of CNNs against the discrepancy in low-level image information. Furthermore, our proposed approach makes use of only unlabeled test samples to adapt a pretrained model, which is more suitable for nuclear forensics application for which obtaining both training and test datasets simultaneously is a challenge due to data sensitivity. Through extensive experiments, we demonstrate that our proposed approach effectively improves the performance of a model by at least 18% when encountering domain discrepancy, and can be deployed in many CNN architectures.

scanning electron microscopy↗

AGC-5 Graphite Pre-irradiation Data Analysis Report

This report documents all preirradiation examination material property measurement data for the graphite specimens which were to be used within the fifth Advanced Graphite Capsule (AGC-5) irradiation capsule. The AGC-5 capsule was to be the fifth in six planned irradiation capsules comprising the AGC test series that was designed to irradiate graphite specimens in a temperature range of 600 – 1100°C and medium dose levels to 7 dpa. This would provide quantitative data necessary for predicting the irradiation behavior and operating performance of new nuclear graphite grades for use within very high temperature reactor designs (VHTR). However, due to the lack of commercial interest in building a VHTR design within the USA, the graphite irradiation program was redirected by DOE Advanced Reactor Technology (ART) to re-irradiate the existing specimens from AGC-1 through AGC-4 in the remaining AGC capsules to achieve higher dose levels (15 dpa) at a lower irradiation temperature range (600-800°C). These new irradiation capsules have been designated as the High Dose Graphite (HDG) capsules. This new low temperature, high dose irradiation program favors the current high temperature reactor (HTR) design of interest to the US commercial nuclear community. This report summarizes the measurements from material property tests on the designated AGC-5 specimens. Similar to past AGC runs the specimens were categorized as major graphite grades (IG-110, NBG-17, NBG-18, PCEA and 2114), smaller experimental samples (thermal diffusivity sized specimens of major grades). It is anticipated that some AGC-5 specimens may be required for use within the new HDG-1 capsule. Any specimens from this pre-irradiation testing campaign will be identified in the future HDG-1 Pre-Irradiation Data Report. AGC-5 specimen testing was conducted at Idaho National Laboratory (INL) from December 2015 to February 2018.

(AGC)↗

NEA HTTR LOFC Project Test#3 Benchmark Results

In the second half of FY23, the High Temperature Engineering Test Reactor (HTTR) Loss Of Forced Cooling (LOFC)#3 data for the 9 MW test case with Vessel Cooling System (VCS) off were made available through the Nuclear Energy Agency (NEA) LOFC project framework; the neutronic model developed for the initial test (LOFC#1) achieved a satisfactory level of maturity, demonstrating its accuracy in predicting power evolution and core re-criticality, but LOFC#3 should be used primarily to investigate thermal hydraulic phenomena, as the reactor was shut down prematurely due to overheating in the upper reactor components, which prevented re-criticality; this report focuses on advancing the HTTR thermal hydraulic model to accurately simulate the LOFC#3 scenario, including simulating the LOFC#3 benchmark and generating the corresponding benchmark specifications, aiming to ensure consistency across participant models and provide essential data for future participants, including private industry stakeholders seeking to validate their computational tools.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

FAUST - Benchmark and Validation Framework [Slides]

This presentation discusses Python packages for nuclear data applications and for benchmarking. It also discusses the goals and objectives for FAUST which include providing input and output processing for different calculation codes, allowing for exchanging results between different applications and codes, running benchmarks and processing the results, automating and simplify plot and report generation, and providing a basis for developing applications useful for nuclear data evaluators. The presentation also discusses how the packages can be used both inside and outside LANL.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Development of Data Acquisition System for nuclear thermal hydraulic out-of-pile facility using the graphical programming methods

This paper describes the design of data acquisition system (DAQ) that is connected to a PC and development of a feedback control system that maintains the coolant temperature of the process at a desired set point using a digital controller system based on the graphical programming language. The paper will provide details about the data acquisition unit, shows the implementation of the controller, and present test results. (authors)

42 ENGINEERING↗

Weapon Physicist Declassifies Rescued Nuclear Test Films

The U.S. conducted 210 atmospheric nuclear tests between 1945 and 1962, with multiple cameras capturing each event at around 2,400 frames per second. But in the decades since, around 10,000 of these films sat idle, scattered across the country in high-security vaults. Not only were they gathering dust, the film material itself was slowly decomposing, bringing the data they contained to the brink of being lost forever. For the past five years, Lawrence Livermore National Laboratory (LLNL) weapon physicist Greg Spriggs and a crack team of film experts, archivists and software developers have been on a mission to hunt down, scan, reanalyze and declassify these decomposing films. The goals are to preserve the films’ content before it’s lost forever, and provide better data to the post-testing-era scientists who use computer codes to help certify that the aging U.S. nuclear deterrent remains safe, secure and effective.

98 NUCLEAR DISARMAMENT, SAFEGUARDS, AND PHYSICAL P↗

Development of autonomous gamma dose logger for environmental monitoring

Continuous monitoring and archiving of background radiation levels in and around the nuclear installation is essential and the data would be of immense use during analysis of any untoward incidents. A portable Geiger Muller detector based autonomous gamma dose logger (AGDL) for environmental monitoring is indigenously designed and developed. The system operations are controlled by microcontroller (AT89S52) and the main features of the system are software data acquisition, real time LCD display of radiation level, data archiving at removable compact flash card. The complete system operates on 12 V battery backed up by solar panel and hence the system is totally portable and ideal for field use. The system has been calibrated with Co-60 source (8.1 MBq) at various source-detector distances. The system is field tested and performance evaluation is carried out. This paper covers the design considerations of the hardware, software architecture of the system along with details of the front-end operation of the autonomous gamma dose logger and the data file formats. The data gathered during field testing and inter comparison with GammaTRACER are also presented in the paper. AGDL has shown excellent correlation with energy fluence monitor tuned to identify {sup 41}Ar, proving its utility for real-time plume tracking and source term estimation.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Sister Rod Destructive Examinations (FY22) Appendix E: Mechanical Testing

As a part of the DOE NE High Burnup Spent Fuel Data Project, Oak Ridge National Laboratory (ORNL) is performing destructive examinations (DEs) of high burnup (HBU) (>45 GWd/MTU) spent nuclear fuel (SNF) rods from the North Anna Nuclear Power Station operated by Dominion Energy. The SNF rods, called sister rods or sibling rods, are all HBU and include four different kinds of fuel rod cladding: standard Zircaloy-4 (Zirc-4), low-tin Zirc-4, ZIRLO, and M5. The DEs are being conducted to obtain a baseline of the HBU rod’s condition before dry storage and are focused on understanding overall SNF rod strength and durability. Composite fuel and defueled cladding will be tested to derive material properties. Although the data generated can be used for multiple purposes, one primary goal for obtaining the post-irradiation examination data and the associated measured mechanical properties is to support SNF dry storage licensing and relicensing activities by (1) addressing identified knowledge gaps and (2) enhancing the technical basis for post-storage transportation, handling, and subsequent disposition.This appendix documents the status of the ORNL Phase 1 DE activities related to the mechanical testing of selected sister rods in Phase 1 of the sister rod test program.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Radiation effects in concrete for nuclear power plants, Part II: Perspective from micromechanical modeling

The need to understand and characterize the effects of neutron irradiation on concrete has become urgent because of the possible extension of service life of many nuclear power generating stations. Current knowledge is primarily based on a collection of data obtained in test reactors. These results are inherently difficult to interpret because materials and testing conditions are inconsistent. A micromechanical approach based on the Hashin composite sphere model is presented to derive a first-order separation of the effects of radiation on cement paste and aggregate, and, also, on their interaction. Although the scarcity of available data limits the validation of the model, it appears that, without negating a possible gamma-ray induced effect, the neutron-induced damage and swelling of aggregate plays a predominant role on the overall concrete expansion and the damage of the cement paste. Finally, the radiation-induced volumetric expansion (RIVE) effects can also be aided by temperature elevation and shrinkage in the cement paste.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

AGR-2 Final Data Qualification Report for U.S. Capsules - ATR Cycles 147A Through 154B

This report provides the data qualification status of AGR-2 fuel irradiation experimental data in four U.S. capsules from all 15 Advanced Test Reactor (ATR) Cycles 147A, 148A, 148B, 149A, 149B, 150A, 150B, 151A, 151B, 152A, 152B, 153A, 153B, 154A, and 154B, as recorded in the Nuclear Data Management and Analysis System (NDMAS). Thus, this report covers data qualification status for the entire AGR-2 irradiation and will replace four previously issued AGR-2 data qualification reports (e.g., INL/EXT-11-22798, INL/EXT-12-26184, INL/EXT-13-29701, and INL/EXT-13-30750). During AGR-2 irradiation, two cycles, 152A and 153A, occurred when the ATR core was briefly at low power, so AGR-2 irradiation data are not used for physics and thermal calculations. Also, two cycles, 150A and 153B, are Power Axial Locator Mechanism (PALM) cycles when the ATR power is higher than during normal cycles. During the first PALM cycle, 150A, the experiment was temporarily moved from the B-12 location to the ATR water canal and during the second PALM cycle, 153B, the experiment was temporarily moved from the B-12 location to the I-24 location to avoid being overheated. During the “Outage” cycle, 153A, seven flow meters were installed downstream from seven Fission Product Monitoring System (FPMS) monitors to measure flows from the monitors and these data are included in the NDMAS database.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Corrosion Testing of Refractory inContact with Molten Glasses Designed for Waste Vitrification - VSL Touchpoint Matrix Glasses

It is known that the predictive life of the refractory ceramic liner of nuclear waste glass melters is conservative, as demonstrated by performance of these materials such as in the Defense Waste Processing Facility (DWPF). The motivation for this task is to maximize the useful life of the melters that will be operated at the Waste Treatment and Immobilization Plant (WTP), which will in turn minimize procurement and disposal costs and melter outage times, as well as to identify maximum loadings in the waste glass of those species that corrode melter components. This task was initiated jointly with Pacific Northwest National Laboratory (PNNL) with the objective to develop a methodology and model to enable more accurate prediction of refractory service life under prototypic conditions from laboratory-scale material corrosion tests. Refractory corrosion is generally reported as physical material loss, measured in units of distance (e.g., inch) or as physical material loss rate, measured in units of distance per time (e.g., inch/day). In post-operational melters, the refractory corrosion is measured directly, sometimes reported as corrosion depth. Crucible tests are used in the laboratory to accelerate the refractory corrosion to facilitate a meaningful measurement in a commensurate amount of time. Crucible tests are particularly useful in understanding refractory corrosion across a large glass composition space, where operational testing would be prohibitive. Some of the critical parameters that are known to influence refractory corrosion by molten glass in a crucible test are temperature, system redox, molten salt phases, glass chemistry, and test duration. The majority of data collected for Monofrax® K-3 (hereafter referred to as K-3) corrosion is from crucible tests, but a small amount comes directly from scaled and production melters. Crucible test data has been collected under varying conditions, whereas data collected from operational melters is relatively fewer and represents conditions specific to the melter campaign. The result is that the published data can be grouped and analyzed in multiple ways, not all of which are readily comparable. The Standard Test Method for Isothermal Corrosion Resistance of Refractories to Molten Glass (ASTM C621) outlines the general guidelines used across industry. That method describes a sealed, static test in which the surface area of the refractory coupon and the volume of glass are fixed. A significant portion of the crucible data pertaining to nuclear waste glasses has been collected in a modified configuration; the most notable differences being the surface area of the refractory coupon to volume of the glass and use of a method for bubbling the melt. To our knowledge, the influence of those parameters on the refractory corrosion has not been quantified. In this work, it was determined that static tests and bubbled tests would be performed. Savannah River National Laboratory (SRNL) was tasked with setting up and performing static testing while PNNL was tasked with setting up and performing bubbled testing. Initial activities were performed to establish laboratory methods that reproduce data comparable to existing data sets of K-3 refractory corrosion by low activity waste (LAW) and high-level waste (HLW) glass compositions. Later activities were focused on refining the test parameters to establish a standard test practice to be used between Laboratories and collecting additional data to be used in the enhanced waste glass model development. This document serves primarily to convey the refractory loss measurement results from corrosion testing of K-3 refractory with waste glass compositions developed for use in the WTP melters. The data will be used in the enhanced property/composition models being developed for waste glass vitrification and melter operations.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Brine Transport Experiments in Granular Salt

To gain confidence in the predictive capability of numerical models, experimental validation must be performed to ensure that parameters and processes are correctly simulated. The laboratory investigations presented herein aim to address knowledge gaps for heat-generating nuclear waste (HGNW) disposal in bedded salt that remain after examination of prior field and laboratory test data. Primarily, we are interested in better constraining the thermal, hydrological, and physicochemical behavior of brine, water vapor, and salt when moist salt is heated. The target of this work is to use run-of-mine (RoM) salt; however during FY2015 progress was made using high-purity, granular sodium chloride.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Reproducible Data Processing Research for the CABRI R.I.A. experiments Acoustic Emission signal analysis

The CABRI facility is an experimental nuclear reactor of the French Atomic Energy Commission (CEA) designed to study the behaviour of fuel rods at high burnup under Reactivity Initiated Accident (R.I.A.) conditions such as the scenario of a control rod ejection. During the experimental phase, the behaviour of the fuel element generates acoustic waves which can be detected by two microphones placed upstream and downstream from the test device. Studies carried out on the last fourteen tests showed the interest in carrying out temporal and spectral analyses on these signals by showing the existence of signatures which can be correlated with physical phenomena. We want presently to return to this rich data in order to have a new point of view by applying modern signal processing methods. Such an antecedent works resumption leads to some difficulties. Although all the raw data are accessible in the form of text files, analyses and graphics representations were not clear in reproducing from the former studies since the people who were in charge of the original work have left the laboratory and it is not easy when time passes, even with our own work, to be able to remember the steps of data manipulations and the exact setup. Thus we decided to consolidate the availability of the data and its manipulation in order to provide a robust data processing workflow to the experimentalists before doing any further investigations. To tackle this issue of strong links between data, treatments and the generation of documents, we adopted a Reproducible Research paradigm. We shall first present the tools chosen in our laboratory to implement this workflow and, then we shall describe the global perception carried out to continue the study of the Acoustic Emission signals recorded by the two microphones during the last fourteen CABRI R.I.A. tests. (authors)

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

Preliminary Results of a Multi-Sensor Data Science System for Monitoring a Solvent Extraction Process

Idaho National Laboratory is building a test bed to allow researchers the opportunity to study nuclear fuel processing operations. This includes studying the solvent extraction process and the use of centrifugal contactors. The goal of this project is to develop a system that utilizes non-traditional measurement sources such as vibration, acoustics, current, color, flow, and temperature in conjunction with data-based, machine learning techniques that will allow for signal discovery. This multi-sensor data supports the development of safeguards by design, provides operator process awareness, and aids in the discovery of process anomalies. This paper highlights some of the preliminary results from initial data collection campaigns and shares some of the lessons learned.

98 NUCLEAR DISARMAMENT, SAFEGUARDS, AND PHYSICAL P↗