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Results for “PAIRING INTERACTIONS”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 487 records · Page 27
All sourcesNASA NTRSDOE OSTI
NASA NTRS1987

Thermal and dynamical effects of pair production on two-temperature accretion flows

The two-temperature criterion for quasi-spherical (ion-pressure supported) accretion onto a black hole, including the effects of electron-positron pair production is studied. For an interesting range of accretion rates, Coulomb interactions between protons and pairs can cool the innermost regions of the accretion flow. The cooled plasma, assumed to possess some angular momentum, will collapse onto the equatorial plane, forming an optically thick annulus. Hysteresis effects involved in the cooling criterion are expected to lead to bistability or time dependence, which may be associated with variability in certain classes of active galactic nuclei (AGNs). Radiation from the annulus may be responsible for the EUV/soft X-ray excess observed in some AGNs.

Begelman, Mitchell C.↗
NASA NTRS1987

Mixed Cu-simple metal dimers and trimers - CuLi, CuLi2, CuNa, CuK, CuBe, CuBe2, Cu2Be, CuAl, and CuAl2

Theoretical studies of selected diatomic and triatomic molecules containing copper and the simple metals Li, Na, K, Be, and Al are presented, with emphasis on elucidating the nature of the bonding in mixed transition metal-simple metal systems. Large Gaussian basis sets are used in the diatomic calculations, and are used to calibrate the triatomic calculations, in which somewhat smaller Gaussian basis sets are employed. Electron correlation is incorporated using both the single-reference singles plus doubles configuration interaction and coupled pair functional methods. It is found that alkali atoms form very polar sigma bonds with copper, and that the ionicity increases with the inclusion of higher excitations because they improve the electron affinity of copper, which in turn allows a larger negative charge on copper. Aluminum is found to form stronger bonds than beryllium, since it does not have to undergo sp hybridization. Some of the trimers bond by forming three-center three-electron bonds. These multicenter bonds are quite strong even when compared to the two-electron bonds in the dimers or to other bonding mechanisms in the trimers.

Bauschlicher, Charles W., Jr.↗
NASA NTRS1988

Nonaxisymmetric viscous lower branch modes in axisymmetric supersonic flows

In a previous paper, the weakly nonlinear interaction of a pair of axisymmetric lower branch Tollmien-Schlichting instabilities in cylindrical supersonic flows was considered. Here the possibility that nonaxisymmetric modes might also exist is investigated. In fact, it is found that such modes do exist and, on the basis of linear theory, it appears that these modes are the most important. The nonaxisymmetric modes are found to exist for flows around cylinders with nondimensional radius alpha less than some critical value alpha sub c. This critical value alpha sub c is found to increase monotonically with the azimuthal wavenumber nu of the disturbance and it is found that unstable modes always occur in pairs. It is also shown that, in general, instability in the form of lower branch Tollmien-Schlichting waves will occur first for nonaxisymmetric modes and that in the unstable regime the largest growth rates correspond to the latter modes.

Duck, Peter W.↗
NASA NTRS1989

Electrodynamics of the Getaway Tether Experiment

An electrodynamic circuit model of the interaction of a pair of small tethered satellites and the ionosphere is developed and analyzed. The system under study, the Getaway Tether Experiment (GATE), is composed of two small satellites and 1 km of insulated conducting tether. The nonlinear model has elements representing the emission, collection, and resistive flow of charge through an electrically conductive tether, plasma contactors, and the ionosphere. The circuit model is incorporated into a dynamic orbital simulation to predict mission performance. Simulation results show the feasibility to bilaterally transfer energy between stored electrical energy and orbital momentum. A transient model is also developed using the circuit model and a string of N lumped-parameter modules, each consisting of resistance, capacitance, and induced potential for the tether. Transients are shown via simulation to occur over millisecond intervals.

Greene, Michael↗
NASA NTRS1990

Non-axisymmetric viscous lower-branch modes in axisymmetric supersonic flows

A previous paper by Duck and Hall (1989) considered the weakly nonlinear interaction of a pair of axisymmetric lower-branch Tollmien-Schlichting instabilities in cylindrical supersonic flows. Here, the possibility that nonaxisymmetric modes might also exist is investigated. In fact, it is found that such modes do exist and, on the basis of linear theory, it appears that these modes are the most important. The nonaxisymmetric modes are found to exist for flows around cylinders with nondimensional radius a less than some critical value a(c). This critical value a(c) is found to increase monotonically with the azimuthal wavenumber n of the disturbance, and it is found that unstable modes always occur in pairs. It is shown that, in general, instability in the form of lower-branch Tollmien-Schlichting waves will occur first for nonaxisymmetric modes and that, in the unstable regime, the largest growth rates correspond to the latter modes.

Duck, Peter W.↗
NASA NTRS1991

Peculiar morphologies of four IRAS galaxies

Optical and radio data that reveal the peculiar morphologies of four IRAS galaxies are discussed. NGC 1620 is shown to have an off-center arclike structure of 3 kpc radius that may be the largest supernova-blown bubble known. UGC 2982 is an ongoing merger of two gas-rich galaxies. It is shown that the UGC 3004/3005 pair is not interacting despite the proximity of its components. UGC 3004 is a regular barred spiral galaxy. A second nucleus in the edge-on system UGC 3005 suggests a recent merger. Finally, IRAS 23385 + 0300 is one of the most infrared-luminous galaxies known.

Chaboyer, Brian↗
NASA NTRS1992

The nature of triad interactions in homogeneous turbulence

A decomposition of the velocity field in terms of helical modes is used to investigate nonlinear interactions in homogeneous turbulence. In a single-triad interaction, the large-scale helical mode is unstable when the small-scale modes have helicities of opposite signs (class 'F', for 'forward'), and the medium scale is otherwise unstable (class 'R', for 'reverse'). It is proposed that, on average, the triple correlations in a turbulent flow correspond to these unstable states. In the limit of nonlocal triads, where one leg is much smaller than the other two, the triadic interscale energy transfer is largest for interactions of class 'R'. The physical processes associated with both classes of interactions are discussed. It is shown that the large local transfers due to nonlocal 'R' interactions appear in pairs of opposite signs that nearly cancel each other and the net effect corresponds to an advection in wave space.

Waleffe, Fabian↗
NASA NTRS1992

The modeling of piezoceramic patch interactions with shells, plates and beams

General models describing the interactions between a pair of piezoceramic patches and elastic substructures consisting of a cylindrical shell, plate and beam are presented. In each case, the manner in which the patch loads enter both the strong and weak forms of the time-dependent structural equations of motion is described. Through force and moment balancing, these loads are then determined in terms of material properties of the patch and substructure (thickness, elastic properties, Poisson ratios), the geometry of the patch placement, and the voltages into the patches. In the case of the shell, the coupling between banding and inplane deformations, which is due to the curvature, is retained. These models are sufficiently general to allow for potentially different patch voltages which implies that they can be suitably employed when using piezoceramic patches for controlling system dynamics when both extensional and bending vibrations are present.

Banks, H. T.↗
NASA NTRS1993

Starbursts triggered by central overpressure in interacting galaxies

A triggering mechanism for the origin of enhanced, massive-star formation in the central regions of interacting spiral galaxy pairs is proposed. Our mechanism is based on the detailed evolution of a realistic interstellar medium in a galaxy following an encounter. As a disk giant molecular cloud (GMC) tumbles into the central region following a galaxy encounter, it undergoes a radiative shock compression via the pre-existing high pressure of the central intercloud medium. The shocked outer shell of a GMC becomes gravitationally unstable and begins to fragment thus resulting in a burst of star formation, when the growth time for the gravitational instabilities in the shell becomes smaller than the crossing time of the shock. The resulting values of typical infrared luminosity agree with observations.

Jog, Chanda J.↗
NASA NTRS1993

The 'Taffy' galaxies UGC 12914/5

The interacting spiral galaxy pair UGC 12914/5 was mapped with the 'VLA' for a 1.49 GHz atlas of the IRAS Bright Galaxy Sample. Half of the flux from UGC 12914/5 arises from the gap between UGC 12914 and UGC 12915, across which the radio contours are drawn like filaments of taffy. The bright radio continuum connecting UGC 12914 with UGC 12915 is a synchrotron source which therefore probably contains both cosmic rays and magnetic fields. It is suggested that the filaments were stripped from UGC 12914 and UGC 12915 as their stellar disks interpenetrated during a recent encounter; this implies that the radio bridge is a relic whose properties contain information about direct collisions of galaxies with gaseous disks. New maps have been made of the radio continuum and H I line emission from UGC 12914/5 in order to verify the stripping hypothesis.

Condon, J. J.↗
NASA NTRS1993

The high-energy diffuse cosmic gamma-ray background radiation from blazars

We predict the spectrum and flux of the high-energy diffuse cosmic gamma-ray background radiation produced by blazars. Our calculations are based on the Compton Observatory EGRET observations of high-energy gamma-rays from these objects, the Whipple observation of TeV gamma-rays from Mrk 421, and radio population studies of flat-spectrum radio sources. Our statistical analysis gives a result consistent with a linear correlation. We then use the radio luminosity function and redshift evolution to calculate the gamma-ray background. We find that blazars cannot account for the flux level or steep spectrum of the background observed by SAS 2 in the sub-GeV range, but could likely provide the dominant background component in the multi-GeV energy range and above. We predict a differential photon spectral index for this component of about 2 up to about 10 GeV. Above that energy, the spectrum should gradually steepen owing to pair production by interactions of the gamma-rays with intergalactic infrared photons. Using the calculations of this effect by Stecker et al. (1992), we estimate a spectral index of about 3.5 for energies above a TeV.

Stecker, F. W.↗
NASA NTRS1993

Flow field measurements in a crossing shockwave turbulent boundary layer interaction at Mach 3

An experimental study has been conducted to examine the flow field of the 3D crossing shock wave/turbulent boundary layer interaction. A symmetric pair of 9-deg fins were used to generate the crossing shocks. The incoming boundary layer was developed on the tunnel sidewall and thus was relatively thick, 0.49 arcsec, and suited for pitot probe surveys. The test conditions were a nominal Mach number of 3 and unit Reynolds number of 1.2 x 10 exp 7/ft. The measurements obtained included surface oil flow visualizations, surface static pressures, and boundary layer pitot pressure profiles. The results showed that downstream of the crossing shock intersection, the stagnation pressure losses were significant and the stagnation pressure profiles were highly nonuniform. Despite the severe shock disturbances, the law of the wall and the law of the wake were found to give relatively good agreement with the experimental data.

Lachowicz, Jason T.↗
NASA NTRS1993

Magnetospheric response to solar wind dynamic pressure variations: Interaction of interplanetary tangential discontinuities with the bow shock

Some magnetic impulse events observed in the polar region are related to vortices associated with plasma convection in the ionosphere. Recent analyses of satellite and ground data suggest that the interaction of solar wind dynamic pressure pulses and the magnetosphere may lead to the formation of velocity vortices in the magnetopause boundary layer region. This can in turn lead to the presence of vortices in the polar ionosphere. However, before reaching the Earth's magnetopause, these interplanetary pressure pulses must interact with and pass through the bow shock. A variation of the solar wind dynamic pressure may be associated with shocks, magnetic holes, or tangential discontinuities (TDs) in the interplanetary medium. We study the interaction of interplanetary TDs with the Earth's bow shock (BS) using both theoretical analysis and MHD computer simulations. It is found that as a result of the collision between a TD and the BS, the jump in the solar wind dynamic pressure associated with the TD is significantly modified, the bow shock moves, and a new fast shock or fast rarefaction wave, which propagates in the downstream direction, is excited. Our theoretical analysis shows that the change in the plasma density across the interplanetary TD plays the most important role in the collision process. In the case with an enhanced dynamic pressure behind the interplanetary TD, the bow shock is intensified in strength and moves in the earthward direction. The dynamic pressure jump associated with the transmitted TD is generally reduced from the value before the interaction. A fast compressional shock is excited ahead of the transmitted TD and propagates toward the Earth's magnetosphere. For the case in which the dynamic pressure is reduced behind the interplanetary TD, the pressure jump across the transmitted TD is substantially weakened, the bow shock moves in the sunward direction, and a rarefaction wave which propagates downstream is excited. We also simulate and discuss the interaction of a pair of tangential discontinuities, which may correspond to a magnetic hole, with the BS.

Wu, Bor-Han↗
NASA NTRS1999

Simulation of Acoustic Scattering from a Trailing Edge

Three model problems were examined to assess the difficulties involved in using a hybrid scheme coupling flow computation with the the Ffowcs Williams and Hawkings equation to predict noise generated by vortices passing over a sharp edge. The results indicate that the Ffowcs Williams and Hawkings equation correctly propagates the acoustic signals when provided with accurate flow information on the integration surface. The most difficult of the model problems investigated inviscid flow over a two-dimensional thin NACA airfoil with a blunt-body vortex generator positioned at 98 percent chord. Vortices rolled up downstream of the blunt body. The shed vortices possessed similarities to large coherent eddies in boundary layers. They interacted and occasionally paired as they convected past the sharp trailing edge of the airfoil. The calculations showed acoustic waves emanating from the airfoil trailing edge. Acoustic directivity and Mach number scaling are shown.

Singer, Bart A.↗
NASA NTRS1977

Passive chevron replicator

There is described a passive replicator device to be used in magnetic bubble domain systems. The replicator is passive, i.e., does not require an active element such as a current source or the like, and both propagates and replicates bubble domains. In a preferred embodiment, the replicator uses chevron type elements arranged in an appropriate pattern so as to interact with a pair of propagation paths wherein bubble domains are propagated. A bubble in one propagation path is routinely transferred therealong and, concurrently, replicated by the instant device into another propagation path. A plurality of elements arranged in juxtaposition to the chevrons assists in controlling the propagation of the bubbles through the respective propagation paths and, at the appropriate time, provides a cutting action wherein a bubble which is elongated between the chevrons of the two propagation paths is split into two separate bubbles.

Oeffinger, Thomas R.↗
NASA NTRS2008

Gamma-Ray Imaging for Explosives Detection

We describe a gamma-ray imaging camera (GIC) for active interrogation of explosives being developed by NASA/GSFC and NSWCICarderock. The GIC is based on the Three-dimensional Track Imager (3-DTI) technology developed at GSFC for gamma-ray astrophysics. The 3-DTI, a large volume time-projection chamber, provides accurate, approx.0.4 mm resolution, 3-D tracking of charged particles. The incident direction of gamma rays, E, > 6 MeV, are reconstructed from the momenta and energies of the electron-positron pair resulting from interactions in the 3-DTI volume. The optimization of the 3-DTI technology for this specific application and the performance of the GIC from laboratory tests is presented.

deNolfo, G. A.↗
DOE OSTI2017

Electrostatic Control of Regioselectivity in Au(I)-Catalyzed Hydroarylation

Competing pathways in catalytic reactions often involve transition states with very different charge distributions, but this difference is rarely exploited to control selectivity. The proximity of a counterion to a charged catalyst in an ion paired complex gives rise to strong electrostatic interactions that could be used to energetically differentiate transition states. We investigate the effects of ion pairing on the regioselectivity of the hydroarylation of 3-substituted phenyl propargyl ethers catalyzed by cationic Au(I) complexes, which forms a mixture of 5- and 7-substituted 2H-chromenes. We show that changing the solvent dielectric to enforce ion pairing to a SbF 6 – counterion changes the regioselectivity by up to a factor of 12 depending on the substrate structure. Density functional theory (DFT) is used to calculate the energy difference between the putative product-determining isomeric transition states (ΔΔE ‡ ) in both the presence and absence of the counterion. The change in ΔΔE ‡ upon switching from the unpaired transition states in high solvent dielectric to ion paired transition states in low solvent dielectric (Δ(ΔΔE ‡ )) was found to be in good agreement with the experimentally observed selectivity changes across several substrates. Our calculations indicate that the origin of Δ(ΔΔE ‡ ) lies in the preferential electrostatic stabilization of the transition state with greater charge separation by the counterion in the ion paired case. By performing calculations at multiple different values of the solvent dielectric, we show that the role of the solvent in changing selectivity is not solely to enforce ion pairing, but rather that interactions between the ion paired complex and the solvent also contribute to Δ(ΔΔE ‡ ). Our results provide a foundation for exploiting electrostatic control of selectivity in other ion paired systems.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗