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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 487 records · Page 27

Fuel Retention Improvement at High Temperatures in Tungsten-Uranium Dioxide Dispersion Fuel Elements by Plasma-Spray Cladding

An investigation was undertaken to determine the feasibility of depositing integrally bonded plasma-sprayed tungsten coatings onto 80-volume-percent tungsten - 20-volume-percent uranium dioxide composites. These composites were face clad with thin tungsten foil to inhibit uranium dioxide loss at elevated temperatures, but loss at the unclad edges was still significant. By preheating the composite substrates to approximately 3700 degrees F in a nitrogen environment, metallurgically bonded tungsten coatings could be obtained directly by plasma spraying. Furthermore, even though these coatings were thin and somewhat porous, they greatly inhibited the loss of uranium dioxide. For example, a specimen that was face clad but had no edge cladding lost 5.8 percent uranium dioxide after 2 hours at 4750 dgrees F in flowing hydrogen. A similar specimen with plasma-spray-coated edges, however, lost only 0.75 percent uranium dioxide under the same testing conditions.

Grisaffe, Salvatore J.↗

Multivariate Methods for Prediction of Geologic Sample Composition with Laser-Induced Breakdown Spectroscopy

Laser-induced breakdown spectroscopy (LIBS) uses pulses of laser light to ablate a material from the surface of a sample and produce an expanding plasma. The optical emission from the plasma produces a spectrum which can be used to classify target materials and estimate their composition. The ChemCam instrument on the Mars Science Laboratory (MSL) mission will use LIBS to rapidly analyze targets remotely, allowing more resource- and time-intensive in-situ analyses to be reserved for targets of particular interest. ChemCam will also be used to analyze samples that are not reachable by the rover's in-situ instruments. Due to these tactical and scientific roles, it is important that ChemCam-derived sample compositions are as accurate as possible. We have compared the results of partial least squares (PLS), multilayer perceptron (MLP) artificial neural networks (ANNs), and cascade correlation (CC) ANNs to determine which technique yields better estimates of quantitative element abundances in rock and mineral samples. The number of hidden nodes in the MLP ANNs was optimized using a genetic algorithm. The influence of two data preprocessing techniques were also investigated: genetic algorithm feature selection and averaging the spectra for each training sample prior to training the PLS and ANN algorithms. We used a ChemCam-like laboratory stand-off LIBS system to collect spectra of 30 pressed powder geostandards and a diverse suite of 196 geologic slab samples of known bulk composition. We tested the performance of PLS and ANNs on a subset of these samples, choosing to focus on silicate rocks and minerals with a loss on ignition of less than 2 percent. This resulted in a set of 22 pressed powder geostandards and 80 geologic samples. Four of the geostandards were used as a validation set and 18 were used as the training set for the algorithms. We found that PLS typically resulted in the lowest average absolute error in its predictions, but that the optimized MLP ANN and the CC ANN often gave results comparable to PLS. Averaging the spectra for each training sample and/or using feature selection to choose a small subset of wavelengths to use for predictions gave mixed results, with degraded performance in some cases and similar or slightly improved performance in other cases. However, training time was significantly reduced for both PLS and ANN methods by implementing feature selection, making this a potentially appealing method for initial, rapid-turn-around analyses necessary for Chemcam's tactical role on MSL. Choice of training samples has a strong influence on the accuracy of predictions. We are currently investigating the use of clustering algorithms (e.g. k-means, neural gas, etc.) to identify training sets that are spectrally similar to the unknown samples that are being predicted, and therefore result in improved predictions

Morris, Richard↗

Iodine Capture with Copper-Electroplated Nickel Foams

This work explores the use of Ni0 foam scaffolds for Cu0 coatings for use as sorbents for iodine. The Cu0 electroplating was performed from aqueous copper(II) sulfate (CuSO4) solutions under different conditions to achieve a range of Cu0-layer thicknesses (4.89 ± 1.05 μm–57.32 ± 3.95 μm) with 900 A·m–2 current densities and coating times of 15–180 min. The thickest coatings resulted in Cu0-plated Ni0 foams with >89 mass % Cu0 in the final product. Iodine capture experiments showed very high Cu0 utilizations of 91.9–97.3 mass % at iodine loadings of 839–1774 mg·g–1 through the formation of CuI (marshite; space group F-43m). No evidence was found of iodine reactions taking place with the Ni0 scaffold, so it remained in iodine-loaded Cu-electroplated Ni foams as structural support to provide mechanical rigidity to the foams during the iodine loading process. Hot pressing of these materials can be used to create a CuI/Ni ceramic-metal composite waste form for disposal as demonstrated with spark plasma sintering.

Riley, Brian [Pacific Northwest National Laborator↗

Experimental Setup to Investigate Hydrogen Isotope Retention on Powder Samples as Slag/Dust Proxies for Advanced Fusion Reactors

Slag/dust formation is one of the critical issues regarding tritium retention in advanced fusion reactors. We upgraded an ultrahigh vacuum device, the sample exposure station (SES), to perform temperature-programmed desorption (TPD), also known as thermal desorption spectroscopy, to investigate deuterium (D) retention in powder samples that are utilized as proxies for slag/dust particles formed in fusion reactors. TPD analysis, calibrated for the desorption rate, was successfully performed on commercially available crystalline/amorphous boron (B) powder after D 2 neutral gas or D + ion exposure. We calibrated the B powder temperature measurement for TPD analysis utilizing a D 2 desorption peak from B-D bonding known for its desorption temperature ~700 K. We introduce a separation procedure of observed D TPD signals, convoluted for corresponding D retention pathways, that was necessary for TPD analysis. This is the first report on the retention of D 2 neutral gas to B, and this observation was enabled by utilizing the B powder sample, which has a larger surface area than films commonly used in laboratory experiments. In conclusion, the upgraded SES system will enable us to investigate hydrogen isotope behaviors for powder/dust samples of various elemental compositions, including metals.

Plasma-facing component debris↗

Research investigation of the physical interactions and phenomena associated with hypervelocity sub-micron particles

Signals from impact ionization plasmas were studied as a means of performing microparticle composition analysis. Impact ionization signal response was measured in a time-of-flight (TOF) system for lanthanum hexaboride, carbonyl iron, and aluminum microparticle impacts on a tantalum target, primarily in the 1 - 8 km/s velocity range. Oscilloscope photographs of representative ion TOF signal response are given for each material studied. Graphs and histograms are presented of the total charge collected as well as the charge collected in each observed ion mass group. Data show that ion signals consist primarily of the lower ionization potential elements over the 1 - 8 km/s range.

Roy, N. L.↗

In Situ Data

In-situ planetary data include all measurements made by a wide variety of instruments whose sensors are exposed directly to the planetry environment. Typical measurements include those of magnetic fields, energetic particle densities and energy distributions, plasma wave characteristics, ionospheric and neutral gas densities, temperatures, composition and motions. A large body of scientists in the United States, and the world, are involved in research using in-situ data. Many of these scientists are associated with Mission investigations groups which provide specific types of in-situ data. These groups, in the course of data analysis, use data provided by similar groups. The interdisciplinary nature of these investigations fosters exchange and reliance upon one another for data is heavy. To a lesser extent, correlative data sets are obtained from the National Space Science Data Center (NSSDC). However, the data entries often have limited temporal and spatial resolution, are of uncertain quality, and are usually available only for measurements that are several years old.

Source record↗

Comparative magnetospheric/ionospheric studies using Dynamics Explorer spacecraft and ground-based radars

Coincident observations between the Dynamics Explorer 1 and 2 spacecraft with Chatanika and Arecibo ground-based radar are briefly reviewed. Ionospheric-magnetospheric coupling processes in the plasmasphere, main trough, auroral zone, and polar cap are inferred from the density, temperature, composition, and angular distributions of the low-energy plasma observed from the E-region ionosphere out into the magnetosphere to an altitude of 2.5 earth radii (Re). From the polar cap to the inner plasmasphere, parallel and perpendicular electric fields, polar wind flow, and equilibrium diffusion appear to be involved in the ionospheric-magnetospheric coupling of the low energy plasma.

Green, J. L.↗

Observations of ionospheric magnetospheric coupling - DE and Chatanika coincidences

Observations from several experiments on board the Dynamics Explorer 1 and 2 (DE 1 and 2) spacecraft and ground-based radar measurements from the Chatanika radar are combined in order to examine the details of ionospheric/magnetospheric coupling in the local evening sector. DE 1 and DE 2 were in coplanar polar orbits that provided measurements almost simultaneously in time and magnetically coincident with the Chatanika radar from L = 3 to L = 17. The coupling processes are inferred from the density, temperature, composition, and angular distributions of the low-energy plasma observed from the E region of the ionosphere to magnetospheric altitudes of 2.5 earth radii. Plasma characteristics of the plasmasphere, main trough, auroral zone, and polar cap can be studied in this data set. The observations imply that as L increases, the dominant coupling mechanism between the ionosphere and magnetosphere in the measured energy range changes from equilibrium diffusion to perpendicular acceleration and finally to parallel acceleration.

Green, J. L.↗

Comparative magnetospheric/ionospheric studies using Dynamics Explorer spacecraft and ground-based radars

Coincident magnetosphere-ionosphere observations between the Dynamics Explorer 1 and 2 spacecraft with ground-based radar are reviewed. Ionospheric-magnetospheric coupling processes in the plasmasphere, main trough, auroral zone, and polar cap are inferred from the density, temperature, composition, and angular distributions of the low-energy plasma observed from the E-region ionosphere out into the magnetosphere to an altitude of 2.5 Re. From the polar cap to the inner plasmasphere, parallel and perpendicular electric fields, polar wind flow, and equilibrium diffusion appear to be involved in the ionospheric-magnetospheric coupling of the low energy plasma.

Green, J. L.↗

Radial profiles of quiet time magnetospheric parameters

The quiet time magnetosphere is studied using ion measurements covering energies from about 1 keV to about 4 MeV from selected passes of the Charge Composition Explorer during low geomagnetic activity. The quiet time plasma pressure in the midnight sector was found to be comparable to that deduced by Spence et al. (1989) and Kan et al. (1992) from inverting the magnetic field models of Tsyganenko and Usmanov (1982) and Tsyganenko (1987). The radial profile of the total plasma pressure exhibited a peak at L = 3-4 and decreased monotonically from L = 4 and L = 9. Contrary to theoretical expectations for the magnetospheric closure of the region 2 field-aligned current system, no large-scale earthward decrease in plasma pressure was found to occur in these outer L shells.

Lui, A. T. Y.↗

Ultraviolet spectra of quenched carbonaceous composite derivatives: Comparison to the '217 nanometer' interstellar absorption feature

QCCs (quenched carbonaceous composite) are amorphus carbonaceous material formed from a hydrocarbon plasma. We present the UV-visible spectra of 'filmy QCC; (obtained outside of the beam ejected from the hydrocarbon plasma) and 'dark QCC' (obtained very near to the beam) for comparison to the stellar extinction curve. When filmy QCC is heated to 500-700 C (thermally altered), the wavelength of the absorption maximum increases form 204 nm to 220-222 nm. The dark QCC has an absorption maximum at 217-222 nm. In addition, the thermally altered filmy QCC has a slope change at about 500 nm which resmbles that in the interstellar extinction curve. The resemblance of the extinction curve of the QCCs to that of the interstellar medium suggests that QCC derivatives may be representative of the type of interstellar material that produces the 217 nm interstellar medium feature. The peak extinction of the dark QCC is higher than the average interstellar extinction curve while that of the thermally altered filmy QCC is lower, so that a mixture of dark and thermally altered filmy QCC can match the peak extinction observed in the interstellar medium. It is shown from electron micrographs that most of the thermally altered flimy QCC is in the form of small grainy structure less than 4 nm in diameter. This shows that the structure unit causing the 217-222 nm feature in QCC is very small.

Sakata, Akira↗

The Dipper Satellite: A Medium-Class Explorer Mission to the Threshold of Space

The Dipper satellite will carry out an unprecedented, systematic, and focused in-situ exploration of the Earth's lower ionosphere and thermosphere below 200 km that will produce a pivotal base of knowledge that will significantly advance our understanding of knowledge that will significantly advance our understanding of how our near-space environment works. The satellite will carry comprehensive in-situ probes to measure vector electric and magnetic fields, plasma density and temperature, ion velocities, ion and neutral composition and winds, energetic particles including suprathermal electrons, gravity waves, and lightning bursts. The satellite will include a propulsion system and tapered body that will provide over 10,000 excursions to altitudes below 200 km with over 3000 dips to altitudes below 150 km. With this instrument complement, spacecraft, and orbit, the Dipper mission will gather the necessary combined electrodynamics and neutral dynamics measurements to provide an understanding of the Earth's critical boundary region where the ionized gases of space and the neutral gases of the atmosphere are coupled, and where impinging forces and momentum are deposited from the magnetosphere above and from the troposphere, stratosphere, and mesosphere below. In exploring those physical processes in the lower ionosphere which can only be measured in-situ, the Dipper mission addresses four main science objectives. The Dipper will: 1) reveal how ion-neutral coupling creates a global system of dynamo electric fields and currents; 2) provide first-hand understanding of how magnetospheric currents close in the ionosphere and reveal the effects on the upper atmosphere of magnetospheric energy and momentum deposition; 3) discover the degree of upwards coupling and energy deposition due to thunderstorm electric fields and determine their significance; 4) determine the dynamics and composition of the Earth's lower thermosphere, including its response to gravity, tidal, and planetary waves on a range of spatial scales. A proposal to design, build, operate, and analyze data from instruments on the Dipper spacecraft within the schedule and budget constraints of NASA's MIDEX program was submitted to NASA in 1998. This presentation summarizes the main features of the mission.

Pfaff, R. F., Jr.↗

Pickup Ion Phase Space Distributions at Titan in a Three Dimensional Exosphere

The composition and structure of neutral exospheres imbedded in moving plasmas can be determined by measurements of the velocity distributions of their pickup ion progeny. In turn, the velocity distributions are dependent on the spatial structure of the neutral source gases. Since Titan's neutral exosphere extends into the Saturn's magnetosphere (or solar wind) and well above its ionopause, it serves as a good place to analyze such characteristics. They are analyzed using pickup ion measurements made by the Cassini Plasma Spectrometer (CAPS) at Titan [e.g., Hartle et al., 2006] and an ion kinetic model. An early version of the model [Hartle and Sittler, 2007] is an expression describing the phase space density of pickup ions, which is derived from the Vlasov equation with an ion source that explicitly accounts for the velocity and spatial variation of the exosphere source gases. The current version used here includes exosphere source gases in three dimensions. A fundamental parameter of the phase space densities is the ratio of the gyroradius to the neutral scale height alpha, = r(sub g)/H. Titan's exosphere structure yields pickup ions whose phase space distributions are beam-like when alpha >> 1 and fluid-like when alpha << 1. Downstream from the source peak, the light pickup ions, with alpha << 1, are easily observed because their phase space densities are almost uniform over the orbit phases. On the other hand, the phase space distributions of the heavier ions, with alpha >> 1, peak over narrow velocity and spatial ranges. This beam-like nature makes it considerably more difficult to observe heavy ions because their downstream positions and viewing directions are narrowly constrained. Examples of these extremes will be discussed.

Hartle, Richard↗

Mercury's Atmosphere and Magnetosphere: MESSENGER Third Flyby Observations

MESSENGER's third flyby of Mercury en route to orbit insertion about the innermost planet took place on 29 September 2009. The earlier 14 January and 6 October 2008 encounters revealed that Mercury's magnetic field is highly dipolar and stable over the 35 years since its discovery by Mariner 10; that a structured, temporally variable exosphere extends to great altitudes on the dayside and forms a long tail in the anti-sunward direction; a cloud of planetary ions encompasses the magnetosphere from the dayside bow shock to the downstream magnetosheath and magnetotail; and that the magnetosphere undergoes extremely intense magnetic reconnect ion in response to variations in the interplanetary magnetic field. Here we report on new results derived from observations from MESSENGER's Mercury Atmospheric and Surface Composition Spectrometer (MASCS), Magnetometer (MAG), and Energetic Particle and Plasma Spectrometer (EPPS) taken during the third flyby.

Slavin, James A.↗

Understanding plasma turbulence through exact coherent structures

Plasma turbulence is a key challenge in understanding transport phenomena in magnetically confined plasmas. This work presents a generalized framework to analyze plasma turbulence that utilizes periodic orbit theory. In periodic orbit theory, doubly periodic solutions (coherent structures) of the governing equation(s) serve as building blocks of the considered turbulent dynamics. To illustrate the concept and method, the particularly simple Kuramoto–Sivashinsky (referred to here as LMRT for the original authors: LaQuey, Mahajan, Rutherford, and Tang) trapped-ion mode toy model is used. By applying numerical optimization techniques to the LMRT equation, we extract coherent spacetime patterns that represent the library of allowable fundamental structures of the equation. These structures provide a framework to systematically describe turbulence as a composition of recurrent solutions, revealing an underlying order within chaotic plasma motion. Although illustrated here using the simplified LMRT model for clarity, this framework provides a general strategy that can be extended to more complex and realistic models of plasma turbulence, including gyrokinetic systems. This offers a new method for predicting and potentially controlling transport processes in fusion plasmas by providing a bridge between nonlinear dynamical systems theory and plasma physics in the form of a generalized framework with which to analyze and understand spatially extended nonlinear partial differential equations.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Molecular beam epitaxy growth of IrO 2 using plasma-only oxidation

Growth of IrO 2 films via molecular beam epitaxy (MBE) using an oxygen plasma as the sole oxidant is demonstrated for the first time. We investigate the oxidizing conditions required for IrO 2 by characterizing the species present in the plasma using optical emission spectroscopy and comparing the thermodynamic equilibrium between Ir/IrO 2 under atomic and molecular oxygen. Across the pressure range accessible, monatomic oxygen was the primary reactive species present in the plasma. IrO 2 films were grown under varying Ir flux, oxygen pressure, and substrate temperature to understand growth thermodynamics and kinetics. Structural characterization assessed film phase and composition, crystallinity, strain, and surface morphology. The optimized films from this study validate plasma-only reactive growth by MBE as a successful method for growing IrO 2 .

36 MATERIALS SCIENCE↗

Discharge Chamber Performance of the NEXIS Ion Thruster

The Nuclear-Electric Xenon Ion System (NEXIS) thruster was designed to produce greater than or equal to 70% efficiency at ISPs in excess of 6500 sec and total power levels in excess of 15 kW. In order to achieve this performance, the thruster requires a large area plasma generator capable of high propellant utilimtion efficiency and low discharge loss while producing a very flat, uniform beam profile. Fortunately, larger thrusters can be made more uniform and efficient due to the higher volume to surface ratio, provided that the magnetic cusp confinement is designed properly and the thruster length to diameter ratio is adequate. This paper describes the discharge chamber performance of the NEXIS Laboratory Model (LM) thruster. The LM discharge chamber is 65 cm in diameter at the grid plane and uses 6 ring-cusps to provide magnetic confinement of the plasma. The thruster was tested with flat carbon-carbon composite grids with the hole pattern masked to 57 cm in diameter and a conventional Type-B "1/2" diameter hollow cathode. During the preliminary "discharge only" tests, the LM thruster demonstrated profile factors of 0.84 and a discharge loss of about 160 eV/ion at 25 V discharge voltage and over 90% propellant utilization efficiency in simulated beam extraction experiments at 3.9 A of beam current. Analysis of the data from these tests used the discharge-only model developed by Brophy. Subsequent beam extraction experiments validated the key variables used in the model to predict the performance from the discharge-only data, and demonstrated 3.9 A of beam current at over 90% propellant utilization efficiency with a flatness parameter of better than 0.8 and a discharge loss of about 185 eV/ion. The slightly higher discharge loss measured during beam extractions was found to be due to a lower screen transparency in the as-manufactured LM grid set. Plasma measurements with a scanning probe internal to the thruster near the screen grid showed plasma densities over l x 10(exp 11) per cubic centimeter and electron temperatures of 3.5 to 5.5 eV depending on the operation parameters. The performance of the NEXIS discharge chamber contributed to the over 78% thruster efficiency measured during beam extraction at 7500 sec ISP and 25 kW of power, and over 81% thruster efficiency measured at 8500 sec ISP.

plasma generation↗

Structure and Variability of the Martian Ion Composition Boundary Layer

A complex boundary layer with a variety of charged particle and electromagnetic field signatures, including a transition between plasma predominantly of solar wind origin and plasma of planetary origin, lies between the Martian bow shock and the ionosphere. In this paper, we develop and utilize algorithms to autonomously identify and characterize this ion composition boundary (ICB), using data from the Mars Atmosphere and Volatile EvolutioN (MAVEN) mission. We find an asymmetric ICB with a larger average thickness, lower altitude, and lower velocity shear in the hemisphere where the solar wind motional electric field points outward, as a result of the asymmetry of the mass loading process. The ICB thickness scales with the magnetosheath proton gyroradius at the top of the boundary layer but does not clearly vary with external drivers. The ICB location varies with solar wind ram pressure and crustal magnetic field strength, but does not clearly respond to solar wind Mach number or extreme ultraviolet irradiance. The ICB represents a distinct boundary for ion density and flow speed, but the magnetic field strength and direction typically do not vary significantly across the ICB. The plasma density and flow speed at the ICB vary seasonally, likely in response to variations in the neutral exosphere and/or atmosphere. However, the ICB on average remains at or below the altitude where pressure balance is achieved between the piled up magnetic field (MPB) and the solar wind ram pressure, regardless of season or crustal magnetic field strength.

Electromagnetic↗