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NASA NTRS2013

Non-Magnetic, Tough, Corrosion- and Wear-Resistant Knives From Bulk Metallic Glasses and Composites

Quality knives are typically fabricated from high-strength steel alloys. Depending on the application, there are different requirements for mechanical and physical properties that cause problems for steel alloys. For example, diver's knives are generally used in salt water, which causes rust in steel knives. Titanium diver's knives are a popular alternative due to their salt water corrosion resistance, but are too soft to maintain a sharp cutting edge. Steel knives are also magnetic, which is undesirable for military applications where the knives are used as a tactical tool for diffusing magnetic mines. Steel is also significantly denser than titanium (8 g/cu cm vs. 4.5 g/cu cm), which results in heavier knives for the same size. Steel is hard and wear-resistant, compared with titanium, and can keep a sharp edge during service. A major drawback of both steel and titanium knives is that they must be ground or machined into the final knife shape from a billet. Since most knives have a mirrored surface and a complex shape, manufacturing them is complex. It would be more desirable if the knife could be cast into a net or near-net shape in a single step. The solution to the deficiencies of titanium, steel, and ceramic knives is to fabricate them using bulk metallic glasses (or composites). These alloys can be cast into net or near-net shaped knives with a combination of properties that exceed both titanium and steel. A commercially viable BMG (bulk metallic glass) or composite knife is one that exhibits one or all of the following properties: It is based on titanium, has a self-sharpening edge, can retain an edge during service, is hard, is non-magnetic, is corrosion-resistant against a variety of corrosive environments, is tough (to allow for prying), can be cast into a net-shape with a mirror finish and a complex shape, has excellent wear resistance, and is low-density. These properties can be achieved in BMG and composites through alloy chemistry and processing. For each desired property for knife fabrication and performance, there is an alloy development strategy that optimizes behavior. Although BMG knives have been demonstrated as far back as 1995, they never found commercial success because they had to be ground (which presented problems because the alloys contained beryllium), they weren't low cost (because they weren't cast to a net-shape), they were brittle (because they were made with a low-quality commercial material), and they had extremely poor corrosion resistance (because corrosion was not well-understood in these materials). Ultimately, these shortcomings prevented the widespread commercialization. In the current work, the inventors have applied more than a decade of research on BMGs from Caltech and JPL to develop a better understanding of how to make BMG knives that exhibit an optimal combination of properties, processing and cost. Alloys have been developed based in titanium (and other metals), that exhibit high toughness, high hardness, excellent corrosion resistance, no ferromagnetism, edge-retaining selfsharpening, and the ability to be cast like a plastic using commercially available casting techniques (currently used by commercial companies such as Liquidmetal Technologies and Visser Precision Casting). The inventors argue that depending on the application (diving, military, tactical, utility, etc.) there is an optimal combination of design and alloy composition. Moreover, with new casting technologies not available at the inception of these materials, net-shaped knives can be cast into complex shapes that require no aftermarket forming, except for sharpening using water-cooled polishing wheel. These combinations of discoveries seek to make low-cost BMG knives commercially viable products that have no equal among metal or ceramic knives. Current work at JPL focuses on net-shape casting of these alloys and testing their mechanical properties versus commercially available knives to demonstrate their benefits.

Hoffman, Douglas C.↗

NASA NTRS2014

Proteins with Novel Structure, Function and Dynamics

Recently, a small enzyme that ligates two RNA fragments with the rate of 10(exp 6) above background was evolved in vitro (Seelig and Szostak, Nature 448:828‐831, 2007). This enzyme does not resemble any contemporary protein (Chao et al., Nature Chem. Biol. 9:81‐83, 2013). It consists of a dynamic, catalytic loop, a small, rigid core containing two zinc ions coordinated by neighboring amino acids, and two highly flexible tails that might be unimportant for protein function. In contrast to other proteins, this enzyme does not contain ordered secondary structure elements, such as alpha‐helix or beta‐sheet. The loop is kept together by just two interactions of a charged residue and a histidine with a zinc ion, which they coordinate on the opposite side of the loop. Such structure appears to be very fragile. Surprisingly, computer simulations indicate otherwise. As the coordinating, charged residue is mutated to alanine, another, nearby charged residue takes its place, thus keeping the structure nearly intact. If this residue is also substituted by alanine a salt bridge involving two other, charged residues on the opposite sides of the loop keeps the loop in place. These adjustments are facilitated by high flexibility of the protein. Computational predictions have been confirmed experimentally, as both mutants retain full activity and overall structure. These results challenge our notions about what is required for protein activity and about the relationship between protein dynamics, stability and robustness. We hypothesize that small, highly dynamic proteins could be both active and fault tolerant in ways that many other proteins are not, i.e. they can adjust to retain their structure and activity even if subjected to mutations in structurally critical regions. This opens the doors for designing proteins with novel functions, structures and dynamics that have not been yet considered.

Proteins↗

NASA NTRS2015

Development of a Climatology of Vertically Complete Wind Profiles from Doppler Radar Wind Profiler Systems

This paper describes in detail the QC and splicing methodology for KSC's 50- and 915-MHz DRWP measurements that generates an extensive archive of vertically complete profiles from 0.20-18.45 km. The concurrent POR from each archive extends from April 2000 to December 2009. MSFC NE applies separate but similar QC processes to each of the 50- and 915-MHz DRWP archives. DRWP literature and data examination provide the basis for developing and applying the automated and manual QC processes on both archives. Depending on the month, the QC'ed 50- and 915-MHz DRWP archives retain 52-65% and 16-30% of the possible data, respectively. The 50- and 915-MHz DRWP QC archives retain 84-91% and 85-95%, respectively, of all the available data provided that data exist in the non- QC'ed archives. Next, MSFC NE applies an algorithm to splice concurrent measurements from both DRWP sources. Last, MSFC NE generates a composite profile from the (up to) five available spliced profiles to effectively characterize boundary layer winds and to utilize all possible 915-MHz DRWP measurements at each timestamp. During a given month, roughly 23,000-32,000 complete profiles exist from 0.25-18.45 km from the composite profiles' archive, and approximately 5,000- 27,000 complete profiles exist from an archive utilizing an individual 915-MHz DRWP. One can extract a variety of profile combinations (pairs, triplets, etc.) from this sample for a given application. The sample of vertically complete DRWP wind measurements not only gives launch vehicle customers greater confidence in loads and trajectory assessments versus using balloon output, but also provides flexibility to simulate different DOL situations across applicable altitudes. In addition to increasing sample size and providing more flexibility for DOL simulations in the vehicle design phase, the spliced DRWP database provides any upcoming launch vehicle program with the capability to utilize DRWP profiles on DOL to compute vehicle steering commands, provided the program applies the procedures that this report describes to new DRWP data on DOL. Decker et al. (2015) details how SLS is proposing to use DRWP data and splicing techniques on DOL. Although automation could enhance the current DOL 50-MHz DRWP QC process and could streamline any future DOL 915-MHz DRWP QC and splicing process, the DOL community would still require manual intervention to ensure that the vehicle only uses valid profiles. If a program desires to use high spatial resolution profiles, then the algorithm could randomly add high-frequency components to the DRWP profiles. The spliced DRWP database provides lots of flexibility in how one performs DOL simulations, and the algorithms that this report provides will assist the aerospace and atmospheric communities that are interested in utilizing the DRWP.

Barbre, Robert E., Jr.↗

NASA NTRS2015

Combined Pressure and Thermal Window System for Space Vehicles

A window system for a vehicle comprising a pressure and thermal window pane, a seal system, and a retainer system. The pressure and thermal window pane may be configured to provide desired pressure protection and desired thermal protection when exposed to an environment around the vehicle during operation of the vehicle. The pressure and thermal window pane may have a desired ductility. The seal system may be configured to contact the pressure and thermal window pane to seal the pressure and thermal window pane. The retainer system may be configured to hold the seal system and the pressure and thermal window pane.

Svartstrom, Kirk Nils↗

NASA NTRS2015

Mechanical Properties and Real-Time Damage Evaluations of Environmental Barrier Coated SiC/SiC CMCs Subjected to Tensile Loading Under Thermal Gradients

SiC/SiC ceramic matrix composites (CMCs) require new state-of-the art environmental barrier coatings (EBCs) to withstand increased temperature requirements and high velocity combustion corrosive combustion gasses. The present work compares the response of coated and uncoated SiC/SiC CMC substrates subjected to simulated engine environments followed by high temperature mechanical testing to asses retained properties and damage mechanisms. Our focus is to explore the capabilities of electrical resistance (ER) measurements as an NDE technique for testing of retained properties under combined high heat-flux and mechanical loading conditions. Furthermore, Acoustic Emission (AE) measurements and Digital Image Correlation (DIC) were performed to determine material damage onset and accumulation.

Ceramic matrix composites↗

NASA NTRS2012

Recent Simulations of the Late Stages Growth of Jupiter

Presented by Lissauer et al. (2009, Icarus 199, 338) are used to test the model of capture of Jupiter's irregular satellites within proto-Jupiter's distended and thermally-supported envelope. We find such capture highly unlikely, since the envelope shrinks too slowly for a large number of moons to be retained, and many of those that would be retained would orbit closer to the planet than do the observed Jovian irregulars. Our calculations do not address (and therefore do not exclude) the possibility that the irregular satellites were captured as a result of gas drag within a circumjovian disk. Support for this research from NASA Outer Planets Research Program is gratefully acknowledged.

circumjovian disk↗

NASA NTRS2016

Phosphate Stability in Diagenetic Fluids Constrains the Acidic Alteration Model for Lower Mt. Sharp Sedimentary Rocks in Gale Crater, Mars

The Mars rover Curiosity has encountered silica-enriched bedrock (as strata and as veins and associated halos of alteration) in the largely basaltic Murray Fm. of Mt. Sharp in Gale Crater. Alpha Particle X-ray Spectrometer (APXS) investigations of the Murray Fm. revealed decreasing Mg, Ca, Mn, Fe, and Al, and higher S, as silica increased (Fig. 1). A positive correlation between SiO2 and TiO2 (up to 74.4 and 1.7 wt %, respectively) suggests that these two insoluble elements were retained while acidic fluids leached more soluble elements. Other evidence also supports a silica-retaining, acidic alteration model for the Murray Fm., including low trace element abundances consistent with leaching, and the presence of opaline silica and jarosite determined by CheMin. Phosphate stability is a key component of this model because PO4 3- is typically soluble in acidic water and is likely a mobile ion in diagenetic fluids (pH less than 5). However, the Murray rocks are not leached of P; they have variable P2O5 (Fig. 1) ranging from average Mars (0.9 wt%) up to the highest values in Gale Crater (2.5 wt%). Here we evaluate APXS measurements of Murray Fm. bedrock and veins with respect to phosphate stability in acidic fluids as a test of the acidic alteration model for the Lower Mt. Sharp rocks.

Berger, J. A.↗

NASA NTRS2016

California Reservoir Inflow Projections Using a Hybrid EMD-Matalas Method

Inflow projections provide scenarios for future water availability and are integral to operational reservoir management. They can aid water practitioners in decision-making for conservation efforts, multiyear storage retention, managing flood risk, downstream water releases, and regional growth planning. However, conventional methods are often limited in terms of their ability to incorporate non-stationarity, long run persistence, and the cross-correlation of multiple series in a region. This research aims to address these issues with a hybrid approach that integrates Empirical Mode Decomposition (EMD) with the Matalas multisite generation method. Multiple long-run inflows were examined for the Shasta/Trinity Reservoirs and Oroville Reservoir of California. EMD is used to decompose each inflow series into a set of independent intrinsic mode functions (IMFs) that have different timescales and frequencies. These IMFs were grouped into intradecadal (less-than- 10-year average periodicity) and interdecadal (greater-than-10-year average periodicity) series for each site. The IMF projections at each site were then combined to produce replicates of the historical data. This preserves the correlation structure of the intra- and interdecadal components of the series. The hybrid EMD-Matalas method was compared to a traditional autoregressive lag-one model. Both methods were found to retain the statistical characteristics of the historical data. However, the EMD-Matalas method retained the multiyear wet and dry periods to a greater degree. This was examined by comparing the 5-year and 10-year sums from the traditional model with the hybrid EMD-Matalas model. An advantage of the EMD-Matalas method is the ability to explicitly incorporate modes of non-stationary long-run persistence often associated with large-scale climate drivers such as the El Nino Southern Oscillation (ENSO) or the Pacific Decadal Oscillation (PDO). This contributes to scenario planning that may be particularly important for managing multiyear low flow periods.

inflow projections↗

NASA NTRS2017

Combined Pressure and Thermal Window System for Space Vehicles

Svartstrom, Kirk Nils↗

NASA NTRS2017

Data Assimilation to Extract Soil Moisture Information From SMAP Observations

Statistical techniques permit the retrieval of soil moisture estimates in a model climatology while retaining the spatial and temporal signatures of the satellite observations. As a consequence, they can be used to reduce the need for localized bias correction techniques typically implemented in data assimilation (DA) systems that tend to remove some of the independent information provided by satellite observations. Here, we use a statistical neural network (NN) algorithm to retrieve SMAP (Soil Moisture Active Passive) surface soil moisture estimates in the climatology of the NASA Catchment land surface model. Assimilating these estimates without additional bias correction is found to significantly reduce the model error and increase the temporal correlation against SMAP CalVal in situ observations over the contiguous United States. A comparison with assimilation experiments using traditional bias correction techniques shows that the NN approach better retains the independent information provided by the SMAP observations and thus leads to larger model skill improvements during the assimilation. A comparison with the SMAP Level 4 product shows that the NN approach is able to provide comparable skill improvements and thus represents a viable assimilation approach.

D↗

NASA NTRS2018

Relative Sputtering Rates of FeS, MgS, and Mg Silicates: Implications for ISM Gas Phase Depletions of Rock-Forming Elements

Astronomical measurements of S abundances in the diffuse interstellar medium (ISM) indicate ionized S is a dominant species with little (< 5%) S residing in grains (e.g. Jenkins 2009). This is an enigmatic result, given that abundant Fe-sulfide grains are observed in dust around pre- and post-main sequence stars and are also observed as major components of primitive meteoritic and cometary samples. These disparate observations suggest that the lifetime of sulfide grains in the ISM is short because of destruction processes. Our previous work has shown that FeS and MgS retain their crystallinity and do not amorphize during radiation processing, whereas enstatite and forsterite are readily amorphized. We have extended this study to measure the relative sputtering rates of FeS and MgS compared to enstatite and forsterite. Irradiation of FeS with 4 keV He+ results in preferential sputtering of S and the formation of a thin 2-3 nm, compact Fe metal layer that armors the surface. The zone of S loss extends to a depth of ~8-10 nm below the exposed surface. Despite this S loss, the FeS retains its crystallinity and shows no sign of incipient amorphization. Irradiation of FeS with 5kV Ga+ in a focused ion beam (FIB) instrument resulted in preferential sputtering of S and the formation of a 5-8-nm thick surface layer of nanophase Fe metal. X-ray mapping shows that the zone of S sputtering extends to a depth of nearly 20 nm, but there is no evidence for FeS amorphization, consistent with our previous work. The irradiation experiments show that the relative sputtering rate of FeS and MgS are much higher than olivine or enstatite. Sputtering experiments utilizing 30 kV and 5 kV Ga ions in the FIB produced volume loss in troilite that was ~4X greater than in enstatite or forsterite. The sputter yield under these conditions is such that for every Si atom sputtered from enstatite, ~14 S atoms are sputtered from FeS. We have performed similar sputtering experiments on Fe-bearing niningerite (MgS) and co-existing enstatite from the ALH 84170 EH3 chondrite. MgS also sputters much more rapidly than enstatite with a relative Si:S sputter yield of 1:8. For MgS, sulfur is highly depleted at the surface and the S-depletion zone extends to a depth of ~15 nm (using 5 kV Ga+). There is a corresponding zone of Mg and especially Fe enrichment that extends from 5 to ~10 nm below the surface, respectively. The dominant grain destruction mechanism in the ISM is sputtering from passage of supernova-generated shock waves. This process also results in the amorphization of crystalline silicates in the ISM. Our results indicate that FeS and MgS grains produced in evolved stars and injected into the ISM will be destroyed more rapidly than crystalline silicates. This process may account for the lack of significant depletion of S from the gas phase in the ISM. However, rare nanophase FeS grains occur as inclusions in circumstellar amorphous silicate grains found in comet dust particles analyzed in the laboratory. These results show that a finite amount of S in the ISM is sequestered in solid grains.

SPUTTERING RATES↗

NASA NTRS2019

Unmanned Aircraft Systems (UAS) Integration in the National Airspace System (NAS) Project: ACAS Xu HITL Overview

This presentation provides an overview of a recently completed human-in-the-loop simulation, conducted as part of the Unmanned Aircraft Systems (UAS) Integration in the National Airspace System (NAS) Project. This study examined how to present resolution advisories (RAs) issued by Airborne Collision Avoidance System (ACAS) Xu, which can be in the vertical dimension, the horizontal dimension, or both (i.e., "blended"). The study varied the location of the ACAS Xu traffic information - it was either presented within an 'integrated' display or a 'standalone' display, where the traffic information was separated from the vehicle control interfaces and navigational information. The presentation covers the test set-up, scenario design, and facilities utilized in this experiment. The primary dependent variables are listed, but no detailed results are included in this outbrief since data analysis is still underway. Goal: assess ACAS Xu Run 5 in a HITL setting to measure pilot & system performance – RWC alerting and guidance – RA alerting and guidance • Horizontal-only, vertical-only, and blended RAs • Strengthening RAs, reversals and added/removed RAs during blended maneuvers – Incorporate realistic sensor noise into the simulation environment – Compare pilot and DAA system performance back to NASA’s Phase 1 DAA MOPS V&V HITL • We leveraged the findings of an engineering analysis conducted in March to help inform how to implement the Xu logic – Part 1 focused on how to display horizontal-only, vertical-only and blended RAs – Part 2 focused on how to display automated RA responses Xu Engineering Analysis Results Part 1 objectives: – Characterize pilot responses to (canned) ACAS Xu RAs in a variety of display configurations • With vs. Without text accompaniment • Simple vs. ‘Advanced’ aural alerting • Results – Pilots struggled to meet 5 seconds initial response requirement • Particularly against horizontal and blended RAs – Pilots failed to respond more quickly to secondary RAs • Expected response time to subsequent RAs = 2.5 seconds No clear effect of the different alerting conditions on response times – Response times primarily driven by RA type • Pilots demonstrated high level of compliance with RAs and self-reported Xu alerting and guidance as being acceptable – 1/5 reported text as being necessary – 4/5 wanted the aural alert to retain the original RA sequence (i.e., issue a follow-on RA second rather than first) – 4/5 wanted to retain the “Maintain Heading/Vertical Speed” aural alert in the event that the pilot reached their target response at the time of secondary RA Based on these results, we decided on the following for the HITL experimental design: – Incorporated an ‘auto-fill’ feature in Vigilant Spirit that removes the need for pilots to manually enter a heading or altitude for RAs • Pilots only have to click ‘Send’ to upload the RA target heading/altitude – Did not include an RA ‘text box’ • The auto-fill feature largely replaces the purpose of the text box – Using a combination of the ‘Basic’ and ‘Advanced’ aural alerting • In case of blended maneuvers will issue “Maintain Heading/Vertical Rate” if pilot has reached 1st RA target at the time the 2nd RA is issued • Integration and testing with Xu Run 5 also resulted in us adding display logic to modify how horizontal RAs are presented – Target heading was shown to update at approx. 1 Hz making it difficult for pilots to implement – Display logic limited horizontal RA strengthening to once every 5 seconds • Did not impact timing of reversals, new RAs (i.e., blended), or CoC Engineering Analysis Results

human systems integration↗

NASA NTRS2019

Investigating Additively Manufactured 17-4 PH for Structural Applications

17-4 is used regularly to manufacture force transducers particularly for wind tunnel testing. Such applications place demanding structural requirements on the transducers with static safety factors of 1.5 common and the potential for additional dynamic loads. Additive manufacturing (AM) of transducers is very appealing because of significant potential cost and time savings as well as increased design flexibility. This study looks at the processing of 17-4 powder using selective laser melting by two different facilities using their own best practices. Hot isostatic pressing (HIP) is used by both facilities as part of the thermomechanical processing following printing to explore whether it can improve the consistency of mechanical properties. Results revealed that HIP reduced average porosity of 17-4 parts and that the yield strength of parts following solutionization and aging met wrought material property targets. Strain to failure of one of the facilities parts was less than 5% compared to greater than 9% for the other facility. Inspection of failure surfaces revealed this discrepancy could be attributed to pores (2-4% area fraction) on the failure surface of the low ductility parts. Phase content varied between the facilities with one facility producing fully martensitic parts and the other containing some retained austenite. The phase content of the starting powder and a slower than air cooling rate following the final heat treatment above the austenite eutectoid temperature are likely sources of the retained austenite. Taken together these results suggest that the current state of the art in AM 17-4 processing is sufficient for many NASA force measurement applications, but that attention is required at each stage of processing to assure desired mechanical properties.

Burns, Devin E.↗

NASA NTRS2019

Comprehensive Severe Weather Impact Assessment and Monitoring using Synthetic Aperture Radar and Auxiliary Data

Remote sensing datasets, particularly acquired by Synthetic Aperture Radar (SAR) sensors, have become increasingly important in severe weather disaster impact studies given their ability to observe the Earth largely irrespective of weather and sunlight conditions. The reliability of existing SAR change detection products applied on a pair of SAR images is constrained by the limitation of current methods to differentiate and classify disaster specific changes from anthropogenic surface alterations. Moreover, the inherent properties of the sensors, variations in SAR backscatter due to changes in surface conditions, and other factors exacerbate these limitations. We proposed a novel procedure expanding on earlier SAR-based change detection methods to exclude anthropogenic alterations and other sources of ambiguity that might lead to inaccurate mapping of the impacts of severe weather disasters. We applied the proposed procedure that is based on long term interferometric and amplitude-based change detection analyses of Sentinel- 1 SAR imagery to two study sites recently impacted by severe weather disasters (Flooding post severe weather events in urban centers; Hailstorm damage on crops). For the first case study, Sentinel-1 SLC scenes from two flood events in the Houston area (April 2016 flooding event and Hurricane Harvey of August-September 2017) were used to construct a flood map depicting areas repeatedly affected by the flood. Pixels with consistent coherence values in the pre-disaster coherence stack were retained for comparison with the pre- and post-disaster coherence stack and pixels with significant decline (greater than 60%) in coherence values were retained in the final flood map. The findings of the applied technique were calibrated and validated through datasets from NOAA/NWS Service storm reports, aerial imaging (NOAA and Civil Air Patrol), Federal Emergency Management Agency (FEMA) reporting, and targeted collections of NASA’s L-band UAVSAR data. Findings and products derived from the adopted methodology can be useful in disaster response and mitigation activities.

Gebremichael, Esayas↗

NASA NTRS2020

Combining MODIS LAI with ICESat-Based Canopy Heights Improves Spaceborne Estimates of Vegetation Roughness Length for Momentum

Most land-surface models require parameterization of vertical wind profiles within the atmospheric boundary layer. For vegetated surfaces, it is common to assume a logarithmic profile in the surface layer, which includes estimates of vegetation roughness length for momentum (z0) and zero-plane displacement height (d0). This study finds that remotely-sensed forest canopy heights improve estimates of aerodynamic roughness length for momentum using a previously-developed representation of the roughness sublayer (Raupach 1992; Jasinski et al. 2005). Resulting roughness products consist of two datasets: 1) 14 years of 8-day snapshots of the global land surface at a nominal spatial resolution of 500-meters for users who wish to retain full temporal resolution and interannual variability; and 2) multiyear averages of the 8-day snapshots, here referred to as "climatologies" of roughness, which retain underlying seasonality. Both products are suitable for use in data assimilation and reanalyses such as the National Climate Assessment Land Data Assimilation System (NCA-LDAS), for which these products were initially developed.

Borak, Jordan S.↗

NASA NTRS2019

Thermally-Induced Healing of Electrically-Insulating Ethylene-Octene Copolymers

We report on electrical insulating materials that not only have sufficient mechanical toughness to survive use conditions, but also possess the ability to undergo thermally induced self-repair when damaged. By controlling the cross-link density, a modified ethylene-octene copolymer (EOC) is able to retain its self-healing abilities while also being used at temperatures greater than the original, unmodified polymer. Specifically, an EOC cross-linked with 0.25 wt% dicumyl peroxide affords a material ability to recover 61% of its critical fracture energy — a value similar to thermoplastic EOC. Furthermore, as shown by dielectric spectroscopy, the cross-linked EOC retains good electrically-insulating properties.

Self-healing↗

NASA NTRSDate not supplied

Mars 2020's First Sample: The Fractured Rough Rock Unit on the Floor of Jezero Crater

A central goal of the Mars 2020 mission is to select and cache samples for future return to Earth. The first samples targeted for collection are from the crater-retaining, Crater Floor Fractured Rough (CF-Fr) unit of Stack et al., 2020.The CF-Fr unit is a topographically low unit in the current Jezero setting, likely overlain by morphologically discrete units, including possible Jezero delta deposits and eolian features. CF-Fr is an aerially extensive unit with lobate margins. Two distinct morphologies are observed: a locally-exposed lower expression, with flat relatively horizontal light-toned surfaces and polygonal fracturing, and an upper expression consisting of up to ~5vertical meters of massive, sometimes boulder-producing, material. The locally-exposed lower expression appears to represent a local ground level in which the upper material has been removed. Near the Octavia E. Butler landing site, the lower morphology is exposed as polygonally-fractured, light-toned bedrock that appears to grade continuously into higher-standing massive outcrops, often with no clearly exposed contact. Further south, a darker upper expression of the CF-Fr unit is more distinct and the unit exhibits some horizontal layering. The Perseverance rover will initially sample the flat-lying expression of this unit. Hypotheses for the origin of CF-Fr include fluvial, aeolian, or lacustrine sediment likely derived from the Jezero watershed, and/or pyroclastic material resulting from regional volcanism. Geochronology of the returned sample could be used to help constrain the timing of geological events in Jezero. It may also help constrain stratigraphic relationships with crater-retaining units outside of Jezero within the Nili Planum, which could be used to calibrate the cratering chronology of Mars. Paleomagnetic analyses of an oriented sample could establish the history of the martian dynamo and whether it persisted into the Hesperian. Finally, if present, secondary phases within the primary deposit would help constrain diagenetic conditions and inform post-depositional aqueous and potentially habitable environmental conditions.

Justin I Simon↗

NASA NTRS2021

A lingering local exopshere created by a gas plume of a lunar lander

We model the expected local exosphere created by outgassing from a lunar lander plume water deposit located adjacent to a lunar lander. We assume the landing is near dawn within Lacus Mortis at 45oN. We consider a set of water desorption scenarios especially focusing on the water-surface desorption activation energy that can possess a distribution of energy states. Our initial simulation starts with a deposition surface having 1020 water molecules per square meter in a 2 km × 2 km region where 90% of the water is retained by weak water-water sorption interactions and 10% are bound by water-regolith sorption interactions. We find that the loosely bound water molecules in water-water interactions quickly desorb within hours after landing. However, water molecules bound to surface sites having a desorption activation greater than 0.7 eV were found to be retained until the source region rotated to later local times (i.e., surface temperature becomes relatively high). We found such time-delayed desorption leads to a tenuous but lingering exosphere emitted from the lander plume deposit region for many 10's of hours after landing. We also adjusted the initial condition by considering different landing local times and considered a case where 100% of the water is bound by water-regolith interactions (mimicking a porous regolith).

W.M. Farrell↗