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At least 487 records · Page 27

Internal Standards for Quantitative Analysis of Chemical Warfare Agents by the GC/MS Method: Nerve Agents

General conditions and requirements for an internal standard useful in the determination of chemical warfare agents (CWAs) by the method of gas chromatography coupled with mass detection (GC/MS) were defined. The determination is based on a GC/MS analysis of a mixture of a CWA with an internal standard, conversion of the TIC chromatogram to a chromatogram extracted at a particular m / z ratio, and calculation of the CWA concentration from the internal standard concentration, response factor, and chromatographic peak areas. Available internal standards were identified, and they were verified for seven organophosphorus nerve-paralysing agents. Corresponding response factors were determined as a ratio of gradients of the linear functions of the peak area and compound concentration. Linearity, repeatability, and accuracy of the measurements were evaluated. The determination can be performed on all GC/MS systems of the Fire Rescue Service of the Czech Republic (FRS), where no CWA standards are available.

Capoun, Tomas↗

BSDF Data generation for daylight applications: A call for international standardization

Standardized methods for generating angle-dependent, bidirectional, solar-optical properties for complex fenestration systems do not exist, which means that energy and daylight evaluations in building performance simulations often suffer from major inaccuracies. This position paper provides an overview of state-of-the-art data-driven methods for characterizing light scattering properties of fenestration materials and blind systems (e.g. fabrics, metal slats, patterned glazing), validation via laboratory, simulation and field tests, and salient issues in support of standardization of such methods via the International Standardization Organization (ISO). The ISO standard is intended to provide the fundamental underpinnings for recently mandated daylight standards that rely on bidirectional scattering distribution function data for climate-based daylight modelling and building performance simulations.

Geisler-Moroder, D.↗

Review of footnotes and annotations to the 1949–2013 tables of standard atomic weights and tables of isotopic compositions of the elements (IUPAC Technical Report)

Abstract The Commission on Isotopic Abundances and Atomic Weights uses annotations given in footnotes that are an integral part of the Tables of Standard Atomic Weights to alert users to the possibilities of quite extraordinary occurrences, as well as sources with abnormal atomic-weight values outside an otherwise acceptable range. The basic need for footnotes to the Standard Atomic Weights Table and equivalent annotations to the Table of Isotopic Compositions of the Elements arises from the necessity to provide users with information that is relevant to one or more elements, but that cannot be provided using numerical data in columns. Any desire to increase additional information conveyed by annotations to these Tables is tempered by the need to preserve a compact format and a style that can alert users, who would not be inclined to consult either the last full element-by-element review or the full text of a current Standard Atomic Weights of the Elements report. Since 1989, the footnotes of the Tables of Standard Atomic Weights and the annotations in column 5 of the Table of Isotopic Compositions of the Elements have been harmonized by use of three lowercase footnotes, “g”, “m”, and “r”, that signify geologically exceptionally specimens (“g”), modified isotopic compositions in material subjected to undisclosed or inadvertent isotopic fractionation (“m”), and the range in isotopic composition of normal terrestrial material prevents more precise atomic-weight value being given (“r”). As some elements are assigned intervals for their standard atomic-weight values (applies to 12 elements since 2009), footnotes “g” and “r” are no longer needed for these elements.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Standard atomic weights of the elements 2021 (IUPAC Technical Report)

Following the reviews of atomic-weight determinations and other cognate data in 2015, 2017, 2019 and 2021, the IUPAC (International Union of Pure and Applied Chemistry) Commission on Isotopic Abundances and Atomic Weights (CIAAW) reports changes of standard atomic weights. The symbol A r°(E) was selected for standard atomic weight of an element to distinguish it from the atomic weight of an element E in a specific substance P, designated A r(E, P). The CIAAW has changed the values of the standard atomic weights of five elements based on recent determinations of terrestrial isotopic abundances. The standard atomic weight of argon and lead have changed to an interval to reflect that the natural variation in isotopic composition exceeds the measurement uncertainty of A r(Ar) and A r(Pb) in a specific substance. The standard atomic weights and/or the uncertainties of fourteen elements have been changed based on the Atomic Mass Evaluations 2016 and 2020 accomplished under the auspices of the International Union of Pure and Applied Physics (IUPAP). A r° of Ho, Tb, Tm and Y were changed in 2017 and again updated in 2021.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Controlling for Survey Effort Is Worth the Effort: Comparing Bottlenose Dolphin ( Tursiops truncatus ) Habitat Use Between Standardized and Opportunistic Photographic-Identification Surveys

Although opportunistic data collected from wildlife ecotours can provide useful information on marine mammal distribution and behavior, concerns exist about whether resultant analyses have diminished accuracy due to spatial bias. To address these concerns, this study compared common bottlenose dolphin ( Tursiops truncatus ) habitat use results derived from standardized boat-based photographic-identification surveys and opportunistic photographic-identification surveys conducted during wildlife ecotours in Roanoke Sound, North Carolina. The main objectives of this study were to (1) identify areas of importance to dolphins, (2) identify activities (feed, mill, social, and travel) most often observed in these areas, and (3) determine the consistency of habitat use results between standardized and opportunistic surveys. Standardized survey hot spots for feeding and travel were located in southern Roanoke Sound according to the hot spot (Getis-Ord Gi*) spatial statistic. Conversely, opportunistic survey hot spots for feeding and travel were detected in central Roanoke Sound near the wildlife ecotour launch site. Opportunistic survey effort was concentrated around the ecotour launch site which introduced spatial bias by overestimating dolphin density in this area. These hot spot location differences between survey methods indicate that opportunistic survey results are affected by spatial bias which can lead to inaccurate conclusions about dolphin habitat use. Hot spot results of standardized data without survey effort supported the conclusion that spatial bias affected opportunistic habitat use results. Furthermore this study provides a direct comparison of standardized and opportunistic datasets and demonstrates the importance of controlling for survey effort when examining marine mammal distribution and habitat use.

59 BASIC BIOLOGICAL SCIENCES↗

Vehicle to Grid Communication Standards Development, Testing and Validation - Status Report

In the US, more than 10,000 electric vehicles (EV) have been delivered to consumers during the first three quarters of 2011. A large majority of these vehicles are battery electric, often requiring 220 volt charging. Though the vehicle manufacturers and charging station manufacturers have provided consumers options for charging preferences, there are no existing communications between consumers and the utilities to manage the charging demand. There is also wide variation between manufacturers in their approach to support vehicle charging. There are in-vehicle networks, charging station networks, utility networks each using either cellular, Wi-Fi, ZigBee or other proprietary communication technology with no standards currently available for interoperability. The current situation of ad-hoc solutions is a major barrier to the wide adoption of electric vehicles. SAE, the International Standards Organization/International Electrotechnical Commission (ISO/IEC), ANSI, National Institute of Standards and Technology (NIST) and several industrial organizations are working towards the development of interoperability standards. PNNL has participated in the development and testing of these standards in an effort to accelerate the adoption and development of communication modules.

33 ADVANCED PROPULSION SYSTEMS↗

ASSESSMENT OF THE ABILITY OF STANDARD SLURRY PUMPS TO MIX SOLIDS WITH LIQUIDS IN TANK 50H

Tank 50H is the feed tank for the Saltstone Production Facility (SPF). In the summer of 2011, Tank 50H contained two standard slurry pumps and two quad volute slurry pumps. Current requirements for mixing operation is to run three pumps for one hour prior to initiating a feed transfer to SPF. Savannah River Site (SRS) Liquid Waste moved both of the Quad Volute pumps from Tank 50H to Tank 51H to replace pumps in Tank 51H that were failing. In addition, one of the standard pumps in Tank 50H exhibits high seal leakage and vibration. SRS Liquid Waste requested Savannah River National Laboratory (SRNL) to conduct a study to evaluate the feasibility of mixing the contents of Tank 50H with one to three standard slurry pumps. To determine the pump requirements to mix solids with liquids in Tank 50H, the author reviewed the pilot-scale blending work performed for the Small Column Ion Exchange Process (SCIX), SRNL computational fluid dynamics (CFD) modeling, Tank 50H operating experience, and the technical literature, and applied the results to Tank 50H to determine the number, size, and operating parameters of pumps needed to mix the solid particles with the liquid in Tank 50H. The analysis determined pump requirements to suspend the solids with no 'dead zones', but did not determine the pump requirements to produce a homogeneous suspension. In addition, the analysis determined the pump requirements to prevent the accumulation of a large amount of solid particles under the telescoping transfer pump. The conclusions from this analysis follow: (1) The analysis shows that three Quad Volute pumps should be able to suspend the solid particles expected ({approx}0.6 g/L insoluble solids, {approx}5 micron) in Tank 50H. (2) Three standard slurry pumps may not be able to suspend the solid particles in Tank 50H; (3) The ability of two Quad Volute pumps to fully suspend all of the solid particles in Tank 50H is marginal; and (4) One standard slurry pump should be able to achieve a cleaning radius larger than 43.5 feet, which will prevent large amounts of solid particles from settling under the telescoping transfer pump (TTP). The report recommends a pump operating approach to maximize the achieved cleaning radius.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Analysis of Daylighting Requirements within ASHRAE Standard 90.1

Pacific Northwest National Laboratory (PNNL), under the Building Energy Codes Program (BECP) funded by U.S. Department of Energy (DOE), provides support to the ASHRAE/IES/IESNA Standard 90.1(Standard 90.1) Standing Standards Project Committee (SSPC 90.1) and its subcommittees. In an effort to provide the ASHRAE SSPC 90.1 with data that will improve the daylighting and fenestration requirements in the Standard, PNNL collaborated with Heschong Mahone Group (HMG), now part of TRC Solutions. Combining EnergyPlus, a whole-building energy simulation software developed by DOE, with Radiance, a highly accurate illumination modeling software (Ward 1994), the daylighting requirements within Standard 90.1 were analyzed in greater detail. The initial scope of the study was to evaluate the impact of the fraction of window area compared to exterior wall area (window-to-wall ratio (WWR)) on energy consumption when daylighting controls are implemented. This scope was expanded to study the impact of fenestration visible transmittance (VT), electric lighting controls and daylighted area on building energy consumption.

90.1↗

Electric Vehicle Communication Standards Testing and Validation Phase I: SAE J2847/1

Executive Summary Vehicle to grid communication standards are critical to the charge management and interoperability among vehicles, charging stations and utility providers. Several standards initiatives by the Society of Automobile Engineers (SAE), International Standards Organization and International Electrotechnical Commission (ISO/IEC), and ZigBee / HomePlug Alliance are developing requirements for communication messages and protocols. While the standard development is in progress for more than two years, no definitive guidelines are available for the automobile manufacturers, charging station manufacturers and utility backhaul network systems. At present, there is a wide range of proprietary communication options developed and supported in the industry. Recent work by the Electric Power Research Institute (EPRI) in collaboration with SAE and automobile manufacturers has identified performance requirements and test plan based on possible communication pathways using power line communication over the control pilot and mains. Though the communication pathways and power line communication technology options are identified, much work needs to be done in developing application software and testing of communication modules before these can be deployed in production vehicles. This report presents a test plan and results from initial testing of two power line communication modules developed to meet the requirements of SAE J2847/1 standard.

33 ADVANCED PROPULSION SYSTEMS↗

Search for the standard model Higgs boson in association with a W boson at D0.

I present a search for the standard model Higgs boson, H, produced in association with a W boson in data events containing a charged lepton (electron or muon), missing energy, and two or three jets. The data analysed correspond to 9.7 fb -1 of integrated luminosity collected at a center-of-momentum energy of √s = 1.96 TeV with the D0 detector at the Fermilab Tevatron p$\bar{p}$ collider. This search uses algorithms to identify the signature of bottom quark production and multivariate techniques to improve the purity of H → b$\bar{b}$ production. We validate our methodology by measuring WZ and ZZ production with Z → b$\bar{b}$ and find production rates consistent with the standard model prediction. For a Higgs boson mass of 125 GeV, we determine a 95% C.L. upper limit on the production of a standard model Higgs boson of 4.8 times the standard model Higgs boson production cross section, while the expected limit is 4.7 times the standard model production cross section. I also present a novel method for improving the energy resolution for charged particles within hadronic signatures. This is achieved by replacing the calorimeter energy measurement for charged particles within a hadronic signature with the tracking momentum measurement. This technique leads to a ~ 20% improvement in the jet energy resolution, which yields a ~ 7% improvement in the reconstructed dijet mass width for H → b$\bar{b}$ events. The improved energy calculation leads to a ~ 5% improvement in our expected 95% C.L. upper limit on the Higgs boson production cross section.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

ANSI/ASHRAE/IES Standard 90.1-2013 Determination of Energy Savings: Qualitative Analysis

This report provides a final qualitative analysis of all addenda to ANSI/ASHRAE/IES Standard 90.1-2010 (referred to as Standard 90.1-2010 or 2010 edition) that were included in ANSI/ASHRAE/IES Standard 90.1-2013 (referred to as Standard 90.1-2013 or 2013 edition). All addenda in creating Standard 90.1-2013 were evaluated for their projected impact on energy efficiency. Each addendum was characterized as having a positive, neutral, or negative impact on overall building energy efficiency.

Halverson, Mark A.↗

ANSI/ASHRAE/IES Standard 90.1-2013 Determination of Energy Savings: Quantitative Analysis

This report provides a final quantitative analysis to assess whether buildings constructed according to the requirements of ANSI/ASHRAE/IES Standard 90.1-2013 would result in improved energy efficiency in commercial buildings. The final analysis considered each of the 110 addenda to Standard 90.1-2010 that were included in Standard 90.1-2013. PNNL reviewed all addenda included by ASHRAE in creating Standard 90.1-2013 from Standard 90.1-2010, and considered their combined impact on a suite of prototype building models across all U.S. climate zones. Most addenda were deemed to have little quantifiable impact on building efficiency for the purpose of DOE’s final determination. However, out of the 110 total addenda, 30 were identified as having a measureable and quantifiable impact.

Halverson, Mark A.↗

Developing Performance Cost Index Targets for ASHRAE Standard 90.1 Appendix G – Performance Rating Method

Appendix G, the Performance Rating Method in ASHRAE Standard 90.1 has been updated to make two significant changes for the 2016 edition, to be published in October of 2016. First, it allows Appendix G to be used as a third path for compliance with the standard in addition to rating beyond code building performance. This prevents modelers from having to develop separate building models for code compliance and beyond code programs. Using this new version of Appendix G to show compliance with the 2016 edition of the standard, the proposed building design needs to have a performance cost index (PCI) less than targets shown in a new table based on building type and climate zone. The second change is that the baseline design is now fixed at a stable level of performance set approximately equal to the 2004 code. Rather than changing the stringency of the baseline with each subsequent edition of the standard, compliance with new editions will simply require a reduced PCI (a PCI of zero is a net-zero building). Using this approach, buildings of any era can be rated using the same method. The intent is that any building energy code or beyond code program can use this methodology and merely set the appropriate PCI target for their needs. This report discusses the process used to set performance criteria for compliance with ASHRAE Standard 90.1-2016 and suggests a method for demonstrating compliance with other codes and beyond code programs.

99 GENERAL AND MISCELLANEOUS↗

Developing Performance Cost Index Targets for ASHRAE Standard 90.1 Appendix G – Performance Rating Method - Rev.1

Appendix G, the Performance Rating Method in ASHRAE Standard 90.1 has been updated to make two significant changes for the 2016 edition, to be published in October of 2016. First, it allows Appendix G to be used as a third path for compliance with the standard in addition to rating beyond code building performance. This prevents modelers from having to develop separate building models for code compliance and beyond code programs. Using this new version of Appendix G to show compliance with the 2016 edition of the standard, the proposed building design needs to have a performance cost index (PCI) less than targets shown in a new table based on building type and climate zone. The second change is that the baseline design is now fixed at a stable level of performance set approximately equal to the 2004 code. Rather than changing the stringency of the baseline with each subsequent edition of the standard, compliance with new editions will simply require a reduced PCI (a PCI of zero is a net-zero building). Using this approach, buildings of any era can be rated using the same method. The intent is that any building energy code or beyond code program can use this methodology and merely set the appropriate PCI target for their needs. This report discusses the process used to set performance criteria for compliance with ASHRAE Standard 90.1-2016 and suggests a method for demonstrating compliance with other codes and beyond code programs.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Prospective Evaluation of the Energy and CO 2 Emissions Impact of China’s 2010 – 2013 Efficiency Standards for Products

Since China introduced its first mandatory minimum energy performance standards (MEPS) for eight major household products in 1989, its MEPS program has expanded significantly to cover nearly 60 residential, industrial and commercial products. In June of 2012, the pace of standards development for new and revised standards was further accelerated with the launch of the national “100 Energy Efficiency Standards.” Initiatives. An unprecedented 21 MEPS were adopted by China from 2012 to 2013, compared to only 7 MEPS adopted from 2010 to 2011. The Chinese MEPS program now covers 15 products in the residential sector, 15 types of commercial and office equipment, 14 types of industrial equipment and 13 lighting products, making it one of the most comprehensive MEPS program in the world. This study provides an updated prospective evaluation of the potential energy and CO 2 impact of 23 of the 28 MEPS adopted by China from 2010 to 2013. This study updates a previous analysis (Zhou et al. 2011) by quantifying the additional potential energy and CO 2 reductions from the newest standards that have been adopted since 2010. The most recent actual and projected sales, usage, and efficiency data were collected for 14 product categories covered under 23 MEPS adopted between 2010 and 2013. Three scenarios are then used to quantify the energy and CO 2 reduction potential of the one-time implementation of these 23 MEPS, including a baseline counterfactual scenario, the actual MEPS scenario and a best available technologies efficiency scenario. The setting of the baseline efficiency is crucial to determining the savings potential of the new and revised MEPS and international best available technology efficiency levels, as it reflects the market average in the absence of MEPS. For this study, the average baseline is based on either the reported 2010 market-average efficiency if sales-weighted efficiency data is available for new product MEPS and selected products with revised MEPS, or the minimum efficiency requirement of the previous MEPS for products with revised MEPS from 2010 to 2013 that do not have sales-weighted efficiency data. Using sales-weighted efficiency data for the baseline help capture market transformation that has already occurred prior to the implementation of the MEPS, and can better differentiate the savings that are attributable to MEPS. The efficiency levels of best available technologies are taken from recent reviews of international commercially available best available technologies.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Measurement of Top Quark Properties and Search for the Standard Model Higgs Boson in Proton Anti-Proton Collisions at $\sqrt{s}$ = 1.96 TeV

We present a measurement of the top quark mass and of the top-antitop ( tf) pair production cross section and a search for the Standard Model Higgs boson with CDF II Detector in pp collisions at $\sqrt{s}$ = 1.96 TeV. The integrated luminosity of 2.9 $fb^{-1}$ is used for top-antitop pair production cross section and top quark mass measurement. We adopt a neural-network algorithm to select candidate events from six or more jets. At least one of these jets should be required to be b jet, as identified by the reconstruction of a secondary vertex inside the jet. The mass measurement is based on a likelihood fit incorporating reconstructed mass distributions representative of signal and background, where the absolute jet energy scale (JES) is measured simultaneously with the top quark mass. The measurement yields a value of 174.8 ± 2.4 (stat + JES) $^{+1.2}_{-1.0}$ (syst) GeV/$c^2$ , where the uncertainty from the absolute jet energy scale is evaluated together with the statistical uncertainty. The procedure also measures the amount of signal from which we derive a cross section, $\sigma_{t\bar{t}}$ = 7.2 ± 0.5 (stat) ±1.0 (syst) ± 0.4 (lum) $pb$, for the measured values of top quark mass and JES. Top quark mass and W boson mass constrain the mass of the Standard Model Higgs boson, indirectly. This prediction implies MH = 89 $^{+35}_{-26}$GeV/$c^2$ (68% confidence level) as of July 2010. Therefore, we concentrate on the Standard Model Higgs mass search region with $\le$ 135 GeV / $c^2$ . Then, we search for the Standard Model Higgs boson associated with vector boson using the decay modes consisting of leptons only: Signal processes are $WH \to \ell \nu + \tau\tau$ and $ZH \to l l + \tau \tau$. We simply select 3 or 4 lepton including hadronic T to pick candidate events out. To improve search sensitivity, we adopt Support Vector Machine to discriminate signals from backgrounds. Using about 6.2 $fb^{-1}$ data, there was no clear discrepancy between data and our background estimation. Therefore, we extract cross section upper limit of the Standard Model Higgs production at 95 % confidence level. The observed upper limit on assumption of $M_H$ = 115 GeV/$c^2$ is 25.1 x $\sigma^{SM}$ at 95% confidence level while the expectation is 17.3 x $\sigma ^{SM}$ at 95%.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

ANSI/ASHRAE/IES Standard 90.1-2016 Performance Rating Method Reference Manual

This document is intended to be a reference manual for the Appendix G Performance Rating Method (PRM) of ANSI/ASHRAE/IES Standard 90.1-2016 (Standard 90.1-2016). The PRM can be used to demonstrate compliance with the standard and to rate the energy efficiency of commercial and high-rise residential buildings with designs that exceed the requirements of Standard 90.1. Use of the PRM for demonstrating compliance with Standard 90.1 is a new feature of the 2016 edition. The procedures and processes described in this manual are designed to provide consistency and accuracy by filling in gaps and providing additional details needed by users of the PRM.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Lattice Gauge Theories Within and Beyond the Standard Model

The Standard Model of particle physics has been very successful in describing fundamental interactions up to the highest energies currently probed in particle accelerator experiments. However, the Standard Model is incomplete and currently exhibits tension with experimental data for interactions involving $B$~mesons. Consequently, $B$-meson physics is of great interest to both experimentalists and theorists. Experimentalists worldwide are studying the decay and mixing processes of $B$~mesons in particle accelerators. Theorists are working to understand the data by employing lattice gauge theories within and beyond the Standard Model. This work addresses the theoretical effort and is divided into two main parts. In the first part, I present a lattice-QCD calculation of form factors for exclusive semileptonic decays of $B$~mesons that are mediated by both charged currents ($B \to \pi \ell \nu$, $B_s \to K \ell \nu$) and neutral currents ($B \to \pi \ell^+ \ell^-$, $B \to K \ell ^+ \ell^-$). The results are important for constraining or revealing physics beyond the Standard Model. This work uses MILC's (2+1+1)-flavor ensembles, with the HISQ action for the up, down, strange, and charm sea and valence quarks, and the clover action in the Fermilab interpretation for the $b$~quark. Simulations are carried out on five ensembles at three lattice spacings down to $\approx 0.088$~fm, with both physical and unphysical sea-quark masses. I present results for correlation-function fits and describe the chiral-continuum extrapolation and $z$~expansion of the form factors. In the second part, I present the status of an ongoing lattice calculation of $SU(3)$ gauge theory with eight and 12 fundamental fermions, in which I search for the endpoint of the line of first-order phase transitions in the mass--coupling plane. The results are important for understanding the phase diagram of these models, with possible applications to physics beyond the Standard Model. This work uses the staggered action and the nHYP-improved stagge! red action for the fermions, as well as the Wilson action in the fundamental and fundamental--adjoint representations for the gauge bosons. With the unimproved actions, I present results for a small lattice and describe the ongoing effort on larger lattices. I also discuss the shift symmetry on lattices with and without improved actions.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗