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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 487 records · Page 27

Field Testing of the COTS DESI/DART-MS/MS System Against High Explosives Residues

This testing was performed to evaluate the performance of the FLIR systems® portable DESI/DART MS/MS (Direct ElectroSpray Ionization)/Direct Analysis in Real Time-Mass Spectrometer/ Mass Spectrometer) system against high explosives residues under field conditions. The samples collected for analysis do not require sample preparation and are analyzed in less than 20 seconds.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

The Effects on Non-Actinide Impurities from Aging Heat Source Plutonium in Stainless Steel Containers

Replacing the tantalum vials used for 238 PuO 2 sample collection and storage with stainless steel sample vials has several advantages. These advantages include a decreased cost, better material availability, and ease of fabrication. However, it must first be demonstrated that the alloying elements contained in stainless steel are not leached into the 238 PuO 2 such that product specifications are exceeded. In order to determine the suitability of stainless steel for this application, two seperate 238 PuO 2 fuel lots were investigated. These two fuel lots had been stored in stainless steel containers since their first sampling date of March of 2015, and were again sampled in February of 2019.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Software Requirements for a Sample Check-in application in CBRNResponder

In 2021, functional area drills were held that focused on field sample collection and custody transfer at the sample control hotline for the Radiological Assistance Program (RAP) Consequence Management (CM) program. The overarching goal of these drills were to evaluate the current CM processes using the CBRNResponder mobile and web-based applications. There were several needs identified to improve CM processes and to stream/transfer data across multiple devices with and without internet: (1) A sample check-in process is needed to streamline current processes to reduce errors and create efficiencies, (2) the sample check-in application needs to be deployed as a mobile application and on the browser versions when on-line, and (3) the sample check-in process needs to function in an environment with internet connections and also in a standalone mode when internet is not available.

61 RADIATION PROTECTION AND DOSIMETRY↗

Aerosol samples overview from the AEROICESTUDY campaign

Mastersheet of aerosol samples collected by a Microorifice Uniform Deposit Impactor (MOUDI) during the Aerosol-Ice Formation Closure Pilot Study (AEROICESTUDY) at SGP occurring 7 – 28 October 2019. Dates and times of collection and location/storage and types of samples are described. Please read AEROICESTUDY_MOUDI_README.csv file for details.

54 ENVIRONMENTAL SCIENCES↗

Solar-Wind Conditions During the Initial Phase of the Genesis Mission

We describe solar-wind conditions, including relative fractions of the solar-wind regimes (interstream, coronal hole, coronal mass ejections), during initial Genesis solar-wind sample collection, and give implications for eventual sample analysis. Additional information is contained in the original extended abstract.

Wiens, R. C.↗

Orbital Drag Near Small Bodies Due to Lofted Fines from Surface Activity

Recent exploratory missions have revealed that small bodies are more granular and dusty than previously expected. As a result of landings, mining, impacts, or other natural phenomena, bodies with negligible atmospheres such as moons and asteroids may experience an exospheric environment abundant in lofted fines. Significant quantities of these may interfere with the nominal trajectories of spacecraft in low orbits. This paper applies data collected from remote sensor and direct sample collection to approximate the density of atmospheric fines in three environments: high-velocity lunar fines generated during landings, the coma of active comets, and cryovolcanic plumes from the Saturnian moon Enceladus. It also investigates the threshold of activity that would induce concerns about a spacecraft's nominal mission. Coupled motion of spacecraft navigation and control is expressed in SE(3).

Fines↗

Evidence of gas phase nucleation of nanodiamond in microwave plasma assisted chemical vapor deposition

The mechanism of ballas-like nanodiamond formation still remains elusive, and this work attempts to analyze its formation in the framework of activation energy (Ea) of nanodiamond films grown from a H2/CH4 plasma in a 2.45 GHz chemical vapor deposition system. The Ea was calculated from the Arrhenius equation corresponding to the thickness growth rate using substrate temperature (∼1000−1300 K) in all the calculations. While the calculated values matched with the Ea for nanodiamond formation throughout the literature, these values of ∼10 kcal/mol were lower compared to ∼15–25 kcal/mol for standard single crystal diamond (SCD) formation, concluding thus far that the energetics and processes involved were different. Further, the substrate preparation and sample collection method were modified while keeping the growth parameters constant. Unseeded Si substrate was physically separated from the plasma discharge by a molybdenum disk with a pinhole drilled in it. Small quantity of a sample substance was collected on the substrate. The sample was characterized by electron microscopy and Raman spectroscopy, confirming it to be nanodiamond, thus suggesting that nanodiamond self-nucleated in the plasma and flowed to the substrate that acted as a mere collection plate. It is hypothesized then, if nanodiamond nucleates in gas phase, gas temperature has to be used in the Arrhenius analysis. The Ea values for all the nanodiamond films were re-calculated using the simulated gas temperature (∼1500−2000 K) obtained from a simple H2/CH4 plasma model, giving new values within the range characteristic to SCD formation. Based on these findings, a unified growth mechanism for nanodiamond and SCD is proposed, concluding that the rate-limiting reactions for nanodiamond and SCD formation are the same.

Materials Science↗

Rehabilitation of Westbay{sup R} Wells with PCE-Contaminated Tubing Fluid - 19250

In November 2015, tetrachloroethylene, also known as PCE, was discovered in groundwater samples collected from a Westbay{sup R} multi-level groundwater monitoring well at the Idaho National Laboratory (INL).a The result was unexpected due to the remote location of the well. Subsequent investigation determined that PCE was not present in the groundwater. The detected PCE was due to inadvertent contamination of the tubing fluid in the Westbay well-monitoring system. Further investigation showed that three of the 11 Westbay wells at the INL contained PCE-contaminated tubing fluid at concentrations above the U.S. Environmental Protection Agency maximum contamination level (5 μg/L); the three wells were identified for rehabilitation as part of the INL well maintenance program. Well rehabilitation would either remove and replace the PCE-contaminated tubing fluid or remove the PCE from the tubing fluid. The interior of the Westbay well casing is isolated from the surrounding groundwater and filled with tubing fluid (either distilled or potable water). Groundwater samples are collected by opening sealed ports using a specialized sampling device. The unique construction prevents the direct interaction of the groundwater and tubing fluid. The tubing fluid also supports the structural integrity of the Westbay wells. The unique construction of the Westbay wells-i.e., the small diameter (5.08 cm [2 in.]) and the depths of the tubing fluid ranging from 144.8 to 419 m (475 to 1,376 ft) below ground surface-posed unique challenges to the rehabilitation. Because the tubing fluid provides structural integrity to the Westbay well, the fluid cannot be removed and then replaced without damaging the integrity of the Westbay well. Additionally, the small diameter of the systems and the associated depths limit the availability of equipment that can be used for the rehabilitation. After an evaluation of potential methods, it was determined that the use of an in-well, granular-activated-carbon filtration swab deployed via a wire line would provide the safest and most cost-effective method for rehabilitation. Rehabilitation commenced during the summer of 2018 and is ongoing with measurable success. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Post-Flight Microbial Analysis of Samples from the International Space Station Water Recovery System and Oxygen Generation System

The Regenerative, Environmental Control and Life Support System (ECLSS) on the International Space Station (ISS) includes the the Water Recovery System (WRS) and the Oxygen Generation System (OGS). The WRS consists of a Urine Processor Assembly (UPA) and Water Processor Assembly (WPA). This report describes microbial characterization of wastewater and surface samples collected from the WRS and OGS subsystems, returned to KSC, JSC, and MSFC on consecutive shuttle flights (STS-129 and STS-130) in 2009-10. STS-129 returned two filters that contained fluid samples from the WPA Waste Tank Orbital Recovery Unit (ORU), one from the waste tank and the other from the ISS humidity condensate. Direct count by microscopic enumeration revealed 8.38 x 104 cells per mL in the humidity condensate sample, but none of those cells were recoverable on solid agar media. In contrast, 3.32 x lOs cells per mL were measured from a surface swab of the WRS waste tank, including viable bacteria and fungi recovered after S12 days of incubation on solid agar media. Based on rDNA sequencing and phenotypic characterization, a fungus recovered from the filter was determined to be Lecythophora mutabilis. The bacterial isolate was identified by rDNA sequence data to be Methylobacterium radiotolerans. Additional UPA subsystem samples were returned on STS-130 for analysis. Both liquid and solid samples were collected from the Russian urine container (EDV), Distillation Assembly (DA) and Recycle Filter Tank Assembly (RFTA) for post-flight analysis. The bacterium Pseudomonas aeruginosa and fungus Chaetomium brasiliense were isolated from the EDV samples. No viable bacteria or fungi were recovered from RFTA brine samples (N= 6), but multiple samples (N = 11) from the DA and RFTA were found to contain fungal and bacterial cells. Many recovered cells have been identified to genus by rDNA sequencing and carbon source utilization profiling (BiOLOG Gen III). The presence of viable bacteria and fungi from WRS and OGS subsystems demonstrates the need for continued monitoring of ECLSS during future ISS operations and investigation of advanced antimicrobial controls.

Birmele, Michele N.↗

SPRUCE: Shrub-Layer Vegetation Biomass Collection Metadata, Marcell Experimental Forest, Minnesota, August 2025

This data set contains metadata associated with shrub-layer vegetation samples collected from the Spruce and Peatland Responses Under Changing Environments (SPRUCE) experiment in August 2025. This sample metadata contains no analytical results and is a reference for analytical datasets. To ensure accessibility and discoverability, each sample was assigned an International Generic Sample Number (IGSN), a persistent identifier, using System for Earth and Extraterrestrial Sample Registration (SESAR). These samples were used for downstream analysis by multiple teams of researchers the results of which will be reported separately. This dataset contains one data file in comma separate (.csv) format. Additional metadata are provided: one data dictionary and a file-level metadata file in comma separate (.csv) format and a user guide in PDF (*.pdf) format. An aliquot of most samples is stored in the SPRUCE archive and may be available for further analysis by request. See below under 7 Sample Access. Access this collection event on SESAR https://doi.org/10.58052/IEJ9B069L. To inquire about obtaining archived samples for analysis, reach out using the Contact Sample Owner form located on the bottom of the landing page in SESAR.

Birkebak, Joshua [ORNL] (ORCID:0009000955611494)↗

The Genesis Mission Solar Wind Collection: Solar-Wind Statistics over the Period of Collection

The NASA Genesis spacecraft was launched August 8, 2001 on a mission to collect samples of solar wind for 2 years and return them to earth September 8, 2004. Detailed analyses of the solar wind ions implanted into high-purity collection substrates will be carried out using various mass spectrometry techniques. These analyses are expected to determine key isotopic ratios and elemental abundances in the solar wind, and by extension, in the solar photosphere. Further, the photospheric composition is thought to be representative of the solar nebula with a few exceptions, so that the Genesis mission will provide a baseline for the average solar nebula composition with which to compare present-day compositions of planets, meteorites, and asteroids. The collection of solar wind samples is almost complete. Collection began for most substrates in early December, 2001, and is scheduled to be complete on April 2 of this year. It is critical to understand the solar-wind conditions during the collection phase of the mission. For this reason, plasma ion and electron spectrometers are continuously monitoring the solar wind proton density, velocity, temperature, the alpha/proton ratio, and angular distribution of suprathermal electrons. Here we report on the solar-wind conditions as observed by these in-situ instruments during the first half of the collection phase of the mission, from December, 2001 to present.

Barraclough, B. L.↗

Produced Water and Waste Heat-aided Blowdown Water Treatment: Using Chemical and Energy Synergisms for Value Creation

The project objective was to develop a cooling blowdown water (BDW) treatment process utilizing produced water (PW) and low-grade heat to maximize water reuse and saleable by-product generation while reducing chemical and energy footprints of the treatment. The proposed treatment process consists of mixing, softening, organics and suspended solids removal, reverse osmosis (RO), thermal desalination, and brine electrolysis. BDW samples collected from a local coal-fired power plant and PW samples from two shale gas production wells were used in this study. Each treatment unit was first designed and tested to quantify its treatment efficiency, and its chemical and energy requirements. In addition, a process model was developed and model simulations were conducted based on the experimental results and literature data to optimize the treatment process. A techno-economic analysis was conducted to quantify chemical and energy savings as well as production of 10-lb brine as a saleable product. With the field-collected BDW and PW samples, mixing experiments determined a volumetric mixing ratio 10:1 (BDW:PW) resulted in the best performance of multivalent ions removal and largest chemical savings for softening. Softening of the BDW/PW mixtures using alkaline chemicals (Na 2 CO 3 and NaOH) achieved 95%-100% removal of scaling-forming cations (Ca, Mg, Fe, Ba, Sr) and 60% of silicon, and 10% of total organic carbon (TOC). The mixing and softening treatments yielded an effluent with total dissolved solids (TDS) concentration of 23 g/L. Activated carbon (AC) filtration removed TOC to a low level (< 3 mg/L) and further removed remaining scale-forming divalent metals and silica from the softened water. The AC filtration resulted in a slight reduction of TDS from 23 g/L to 20 g/L, leaving behind only mostly monovalent ions (i.e., sodium and chloride) in the filtered water. These pretreatments yielded a feed water that met the criteria of the downstream reverse osmosis (RO) to prevent membrane fouling. A cross-flow RO system was used to further concentrate the TDS of the AC effluent. Various factors including TDS, pH, and applied pressure were examined and optimal conditions were determined for the co-treatment process. An integrated process consisting of mixing, softening, AC filtration and RO was used to treat a continuous flow (0.25 – 1.2 L/min, or 0.07 – 0.32 gpm) and successfully generated RO permeate as product water (TDS < 0.5 g/L) for reuse in cooling operation, and a concentrate (TDS ~ 45 g/L) to be further treated in a thermal desalination unit. These flow rates meet the FOA’s criterion of 0.01 – 1 gpm. Overall, the co-treatment of BDW/PW allowed shorter ramp-up time compared to treatment of BDW alone. It resulted in 40% and 55% savings of Na 2 CO 3(s) and NaOH, respectively, compared to treating the BDW and PW individually for the same level of softening. The co-treatment also resulted in a 29% energy saving compared to treatment of BDW only for the level of TDS concentration. A thermal desalination system was designed using CFD simulations and manufactured in the WVU Innovation Hub for further treatment of the RO concentrate to generate 10-lb brine. The system has a design flow rate of 2 gpm and has been successfully tested. A bench-scale brine electrolysis system was developed for on-site generation of chlorine/hypochlorite (Cl 2 /OCl - ) and caustic soda (NaOH) as useful chemicals for the co-treatment process. Using salt solutions (0.5 M and 1 M), the system achieved faradaic efficiencies of 93%-97% and 70%-77% for caustic soda and chlorine/hypochlorite generation, respectively. An economic analysis showed that the electricity costs for on-site generation of these chemicals were significantly lower than the chemical prices offered by suppliers. An industrial-scale process model consisting of mixing, softening, AC filtration, RO, thermal desalination, and brine electrolysis was developed using the Aspen Plus V9 in conjunction with Aspen Custom Modeler V9. The model serves as a solvable Aspen Plus model and as basis to form the costing infrastructure. In addition, techno-economic analysis considering capital, operating, and transportation costs was conducted. An optimization solution showed that produced water for mixing is still advantageous in low quantities. The optimum solution approaches a leveled cost of water (LCW) of 2 $/m 3 which becomes cost competitive with nominal water treatment prices.

20 FOSSIL-FUELED POWER PLANTS↗

Atomic-oxygen stimulated outgassing (A0034)

The objective of this experiment is to determine if the impingement of atomic oxygen in near-Earth orbit is a major factor in producing optically damaging outgassed products. The expected results will be to obtain samples which have been exposed to atomic oxygen for long durations. Analysis of these samples will determine if the impingement of atomic oxygen on the thermal control surfaces stimulates a significant amount of outgassed products. This experiment will give a clearer picture of the contamination problem and will assist in assuring that future Shuttle payloads, such as the Space Telescope and High-Energy Astronomy Observatory, will not experience Skylab contamination levels. Selected thermal control surfaces will be exposed to the atomic oxygen in near-Earth orbit. Passive collecting samples will collect any induced outgassing resulting from oxygen impingement. The optical condition of the passive samples will be measured using a ground-based integrating sphere reflectometer and a directional reflectometer.

Scott, R. L., Jr.↗

Bioaccessibility of Cd and Pb in tailings from a zinc smelting in Brazil: implications for human health

Soils and wastes enriched with heavy metals may present significant ecological and human health risks. A considerable number of mining/smelting areas exist in Brazil, where high levels of metals have been found, as well as in their surrounding soils and sediments. However, studies of bioaccessibility of metals in soils/tailings from these areas are scarce, despite their potential informational contribution concerning exposure risks for residents near these areas. This study evaluated tailing samples collected from four sites of a smelting area aiming to: (i) evaluate the presence of metals of potential concern; (ii) investigate Cd and Pb bioaccessibility; and, (iii) determine the desorption kinetics of Cd and Pb. Five composite samples were collected from each site, at two depths, from a zinc smelting area located near Três Marias city - MG, Brazil. Availability of Cd and Pb was measured using a bioaccessibility test and a desorption experiment. High concentrations of total Cd and Pb and great variability were found in the tailings (up to 1743 mg Cd kg -1 and 8675 mg Pb kg -1 ), indicating the importance of adequate planning for their final disposal, in order to avoid contamination in the surrounding environment. Cadmium and Pb bioaccessibility percentages in the intestinal phase were less than 47 and 4%, respectively, which represents significant fractions not available for absorption in the intestinal tract. However, this material has to be monitored since its bioaccessibility may increase with eventual physicochemical changes, releasing Cd and Pb. Desorption kinetics experiments revealed that the Pb in the samples remained in less labile fractions whereas Cd was found in more labile fractions, which is in accordance with the bioaccessibility result.

54 ENVIRONMENTAL SCIENCES↗

A Detailed Characterization of the Saharan Dust Collected During the Fennec Campaign in 2011: In Situ Ground-Based and Laboratory Measurements

Millions of tons of mineral dust are lifted by the wind from arid surfaces and transported around the globe every year. The physical and chemical properties of the mineral dust are needed to better constrain remote sensing observations and are of fundamental importance for the understanding of dust atmospheric processes. Ground-based in situ measurements and in situ filter collection of Saharan dust were obtained during the Fennec campaign in the central Sahara in 2011. This paper presents results of the absorption and scattering coefficients, and hence single scattering albedo (SSA), of the Saharan dust measured in real time during the last period of the campaign and subsequent laboratory analysis of the dust samples collected in two supersites, SS1 and SS2, in Algeria and in Mauritania, respectively. The samples were taken to the laboratory, where their size and aspect ratio distributions, mean chemical composition, spectral mass absorption efficiency, and spectral imaginary refractive index were obtained from the ultraviolet (UV) to the near-infrared (NIR) wavelengths. At SS1 in Algeria, the time series of the scattering coefficients during the period of the campaign show dust events exceeding 3500 Mm (exp -1), and a relatively high mean SSA of 0.995 at 670 nm was observed at this site. The laboratory results show for the fine particle size distributions (particles diameter <5μm and mode diameter at2–3 μm) in both sites a spectral dependence of the imaginary part of the refractive index Im(m) with a bow-like shape, with increased absorption in UV as well as in the shortwave infrared. The same signature was not observed, however, in the mixed particle size distribution (particle diameter<10 μm and mode diameter at 4 μm) in Algeria. Im(m) was found to range from 0.011 to 0.001i for dust collected in Algeria and 0.008 to 0.002i for dust collected in Mauritania over the wavelength range of 350-2500 nm. Differences in the mean elemental composition of the dust collected in the supersites in Algeria and in Mauritania and between fine and mixed particle size distributions were observed from EDXRF measurements, although those differences cannot be used to explain the optical properties variability between the samples. Finally, particles with low-density typically larger than 10 μm in diameter were found in some of the samples collected at the supersite in Mauritania, but these low-density particles were not observed in Algeria.

Saharan dust measured in real time↗

Mars Climate Orbiter

The purpose of this mission is to study the climate history and the water distribution of Mars. Beautiful panoramic views of the shuttle on the launch pad, engine ignition, Rocket launch, and the separation and burnout of the Solid Rocket Boosters are shown. The footage also includes an animation of the mission. Detailed views of the path that the Orbiter traversed were shown. Once the Orbiter lands on the surface of Mars, it will dig a six to eight inch hole and collect samples from the planets' surface. The animation also included the prospective return of the Orbiter to Earth over the desert of Utah. The remote sensor on the Orbiter helps in finding the exact location of the Orbiter so that scientists may collect the sample and analyze it.

Source record↗

Introducing “ The Integrator ”: A novel technique to monitor environmental flow systems

Abstract We introduce “ The Integrator ,” a novel technique to quantify transport and reaction metrics commonly used to characterize flow systems. This development consists of two products: (1) The Integrator sampling device and (2) its supporting mathematical framework, which is compatible with semi‐continuous sensor data. The use of The Integrator device simplifies the logistics of sample collection and greatly reduces the number of samples needed, making it ideal to characterize systems that are: (1) difficult to access, (2) large and thus intractable or highly heterogeneous, and (3) highly instrumented otherwise but where a more holistic, mechanistic understanding may be gained by monitoring one or more currently untracked elements. We tested and validated The Integrator technique using experimental data collected from a heart rate monitor (high‐quality, high‐frequency data in response to known excitation events) and solute tracer experiments conducted in two contrasting (fourth and seventh order) rivers. In the Supporting Information , we provide details concerning the design of The Integrator device used in our field case studies and provide insight into potential improvements. Despite our case studies focus on the analysis of conservative and reactive transport of solutes in rivers, the principles behind The Integrator technique can be used to monitor water quality in hyporheic zones, aquifers, wetlands, swamps, karsts, oceans, wastewater treatment plants, pipe networks, and air quality. Furthermore, special arrangements of Integrator devices can be used to gather data at spatial and temporal resolutions that are currently unattainable due to high transportation and/or personnel costs.

54 ENVIRONMENTAL SCIENCES↗

NGEE Arctic Plant Traits: Plant Aboveground Biomass, NPP and Traits, Kougarok Road Mile Marker 64, Seward Peninsula, Alaska, beginning 2016

Aboveground biomass was determined in twelve plots at the Kougarok hillslope site Kougarok Road, Mile Marker 64 (KG_MM64), Seward Peninsula, Alaska, from samples collected in late July of 2016. The sampled plots were located across six ecotypes present at this site (n=2 replicates per ecotype). Methods employed included destructive harvests to sample understory species (Understory Clip plots) and shrub surveys combined with existing allometric relationships to determine the aboveground biomass of tall shrub species (Shrub Clip Plots). Current year leaves and stems were separated to quantify net primary production of leaves and stems. This data package contains two CSV data files, one pdf and one zip file.The October 2020 update (*.v3) now provides of aboveground biomass and net primary production data (NPP) by plant species and tissue type. The initial release (*.v2) reported just aboveground biomass by plant functional type. Both versions are provided.Foliar specific leaf area, %C, %N, %P, d15N and d13C were measured on an array of vascular plant leaves collected at the Kougarok hillslope site starting in 2016. Leaves were collected during various plant harvests, including understory clip plots, shrub clip plots, nodule biomass plots, N fixation rate measurements and alder point-center-quarter transects. Paired observations from these harvests are also available through the NGEE Arctic data catalogue (see supplemental files).This October 2020 update (*v3) only removed the Ecotype column. No data were changed from initial release (*v2). Both versions are provided.The Next-Generation Ecosystem Experiments: Arctic (NGEE Arctic), was a 10-year research effort (2012-2022) to reduce uncertainty in Earth System Models by developing a predictive understanding of carbon-rich Arctic ecosystems and feedbacks to climate. NGEE Arctic was supported by the Department of Energy's Office of Biological and Environmental Research.The NGEE Arctic project had two field research sites: 1) located within the Arctic polygonal tundra coastal region on the Barrow Environmental Observatory (BEO) and the North Slope near Utqiagvik (Barrow), Alaska and 2) multiple areas on the discontinuous permafrost region of the Seward Peninsula north of Nome, Alaska.Through observations, experiments, and synthesis with existing datasets, NGEE Arctic provided an enhanced knowledge base for multi-scale modeling and contributed to improved process representation at global pan-Arctic scales within the Department of Energy's Earth system Model (the Energy Exascale Earth System Model, or E3SM), and specifically within the E3SM Land Model component (ELM).

54 ENVIRONMENTAL SCIENCES↗