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At least 487 records · Page 27

Confronting the water potential information gap

Water potential directly controls the function of leaves, roots and microbes, and gradients in water potential drive water flows throughout the soil–plant–atmosphere continuum. Notwithstanding its clear relevance for many ecosystem processes, soil water potential is rarely measured in situ, and plant water potential observations are generally discrete, sparse, and not yet aggregated into accessible databases. These gaps limit our conceptual understanding of biophysical responses to moisture stress and inject large uncertainty into hydrologic and land-surface models. Here, we outline the conceptual and predictive gains that could be made with more continuous and discoverable observations of water potential in soils and plants. We discuss improvements to sensor technologies that facilitate in situ characterization of water potential, as well as strategies for building new networks that aggregate water potential data across sites. Here, we end by highlighting novel opportunities for linking more representative site-level observations of water potential to remotely sensed proxies. Together, these considerations offer a road map for clearer links between ecohydrological processes and the water potential gradients that have the ‘potential’ to substantially reduce conceptual and modelling uncertainties.

58 GEOSCIENCES↗

Magneto-ionic control of magnetism using a solid-state proton pump

Voltage-gated ion transport as a means of manipulating magnetism electrically could enable ultralow-power memory, logic and sensor technologies. Earlier work made use of electric-field-driven O 2– displacement to modulate magnetism in thin films by controlling interfacial or bulk oxidation states. However, elevated temperatures are required and chemical and structural changes lead to irreversibility and device degradation. Here we show reversible and non-destructive toggling of magnetic anisotropy at room temperature using a small gate voltage through H + pumping in all-solid-state heterostructures. We achieve 90° magnetization switching by H + insertion at a Co/GdO x interface, with no degradation in magnetic properties after >2,000 cycles. We then demonstrate reversible anisotropy gating by hydrogen loading in Pd/Co/Pd heterostructures, making metal–metal interfaces susceptible to voltage control. The hydrogen storage metals Pd and Pt are high spin–orbit coupling materials commonly used to generate perpendicular magnetic anisotropy, Dzyaloshinskii–Moriya interaction, and spin–orbit torques in ferromagnet/heavy-metal heterostructures. Furthermore, our work provides a platform for voltage-controlled spin–orbitronics.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Deep compressed seismic learning for fast location and moment tensor inferences with natural and induced seismicity

Fast detection and characterization of seismic sources is crucial for decision-making and warning systems that monitor natural and induced seismicity. However, besides the laying out of ever denser monitoring networks of seismic instruments, the incorporation of new sensor technologies such as Distributed Acoustic Sensing (DAS) further challenges our processing capabilities to deliver short turnaround answers from seismic monitoring. In response, this work describes a methodology for the learning of the seismological parameters: location and moment tensor from compressed seismic records. In this method, data dimensionality is reduced by applying a general encoding protocol derived from the principles of compressive sensing. The data in compressed form is then fed directly to a convolutional neural network that outputs fast predictions of the seismic source parameters. Thus, the proposed methodology can not only expedite data transmission from the field to the processing center, but also remove the decompression overhead that would be required for the application of traditional processing methods. An autoencoder is also explored as an equivalent alternative to perform the same job. We observe that the CS-based compression requires only a fraction of the computing power, time, data and expertise required to design and train an autoencoder to perform the same task. Implementation of the CS-method with a continuous flow of data together with generalization of the principles to other applications such as classification are also discussed.

54 ENVIRONMENTAL SCIENCES↗

Combined Plasmonic Au-nanoparticle and Conducting Metal Oxide High-temperature Optical Sensing with LSTO

<span style="color: rgba(0, 0, 0, 0.79); font-family: &quot;Source Sans Pro&quot;, source-sans-pro, museo_sans300, museo-sans, Arial, sans-serif; font-size: 16px; background-color: rgb(255, 255, 255);">Fiber optic sensor technology offers several advantages for harsh-environment applications. However, the development of optical gas sensing layers that are stable under harsh environmental conditions is an ongoing research challenge. In this work, electronically conducting metal oxide lanthanum-doped strontium titanate (LSTO) films embedded with gold nanoparticles are examined as a sensing layer for application in reducing gas flows at high temperature (600–800 °C). A strong localized surface plasmon resonance (LSPR) based response to hydrogen is demonstrated in the visible region of the spectrum, while a Drude free electron-based response is observed in the near-IR. Characteristics of these responses are studied both on planar glass substrates and on silica fibers. Charge transfer between the oxide film and the gold nanoparticles is explored as a possible mechanism governing the Au LSPR response and is considered in terms of the corresponding properties of the conducting metal oxide-based matrix phase. Principal component analysis is applied to the combined plasmonic and free-carrier based response over a range of temperatures and hydrogen concentrations. It is demonstrated that the combined visible and near-IR response of these films provides improved versatility for multiwavelength interrogation, as well as improved discrimination of important process parameters (concentration and temperature) through application of multivariate analysis techniques.</span>

Wuenschell, Jeffrey K.↗

Intrinsic and extrinsic conduction contributions at nominally neutral domain walls in hexagonal manganites

Conductive and electrostatic atomic force microscopy (cAFM and EFM) are used to investigate the electric conduction at nominally neutral domain walls in hexagonal manganites. The EFM measurements reveal a propensity of mobile charge carriers to accumulate at the nominally neutral domain walls in ErMnO3, which is corroborated by cAFM scans showing locally enhanced direct current conductance. Our findings are explained based on the established segregation enthalpy profiles for oxygen vacancies and interstitials, providing a microscopic model for previous, seemingly disconnected observations ranging from insulating to conducting behavior. In addition, we observe variations in conductance between different nominally neutral walls that we attribute to deviations from the ideal charge-neutral structure within the bulk, leading to a superposition of extrinsic and intrinsic contributions. Our study clarifies the complex transport properties at nominally neutral domain walls in hexagonal manganites and establishes the possibility to tune their electronic response based on oxidation conditions, opening the door for domain-wall-based sensor technology.

Schultheiß, J. (ORCID:0000000173891295)↗

Acoustic Radiation From a Superconducting Qubit: From Spontaneous Emission to Rabi Oscillations

Hybrid quantum systems that utilize controllable coupling between phonons and superconducting qubits could pave the way for a new generation of compact quantum memories and sensor technologies. However, the same electromechanical interaction mechanisms that enable coherent qubit-phonon coupling can also lead to decoherence due to the spontaneous phonon emission. In this paper we study the dynamics of a qubit coupled to an acoustic resonator by a piezoelectric film. By varying the surface topography of the resonator from rough to flat to shaped, we explore the crossover from fast decay of an excited qubit to quantum-coherent coupling between the qubit and an isolated phonon mode. The developed theoretical model allows us to establish and check quantitative links between the results obtained for the rough and shaped topographies. Discrepancy between the theory and the data for the flat resonator points to the imperfections of the studied device. Our experimental approach may be used for precision measurements of crystalline vibrations, the design of quantum memories, and the study of electromechanical contributions to dielectric loss.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Applying Infrared Thermography as a Method for Online Monitoring of Turbine Blade Coolant Flow

As gas turbine engine manufacturers strive to implement condition-based operation and maintenance, there is a need for blade monitoring strategies capable of early fault detection and root-cause determination. Given the importance of blade cooling flows to turbine blade health and longevity, there is a distinct lack of methodologies for coolant flowrate monitoring. The present study addresses this identified opportunity by applying an infrared thermography system on an engine-representative research turbine to generate data-driven models for prediction of blade coolant flowrate. Thermal images were used as inputs to a linear regression and regularization algorithm to relate blade surface temperature distribution with blade coolant flowrate. Additionally, this study investigates how coolant flowrate prediction accuracy is influenced by the number and breadth of diagnostic measurements. Here, the results of this study indicate that a source of high-fidelity training data can be used to predict blade coolant flowrate within about six percent error. Furthermore, identification of prioritized sensor placement supports application of this technique across multiple sensor technologies capable of measuring blade surface temperature in operating gas turbine engines, including spatially resolved and point-based measurement techniques.

42 ENGINEERING↗

Multi-scale theory-assisted nano-engineering of plasmonic-organic hybrid electro-optic device performance

Multi-scale (correlated quantum and statistical mechanics) modeling methods have been advanced and employed to guide the improvement of organic electro-optic (OEO) materials, including by analyzing electric field poling induced electro-optic activity in nanoscopic plasmonic-organic hybrid (POH) waveguide devices. The analysis of in-device electro-optic activity emphasizes the importance of considering both the details of intermolecular interactions within organic electro-optic materials and interactions at interfaces between OEO materials and device architectures. Dramatic improvement in electro-optic device performance--including voltage-length performance, bandwidth, energy efficiency, and lower optical losses have been realized. These improvements are critical to applications in telecommunications, computing, sensor technology, and metrology. Multi-scale modeling methods illustrate the complexity of improving the electro-optic activity of organic materials, including the necessity of considering the trade-off between improving poling-induced acentric order through chromophore modification and the reduction of chromophore number density associated with such modification. Computational simulations also emphasize the importance of developing chromophore modifications that serve multiple purposes including matrix hardening for enhanced thermal and photochemical stability, control of matrix dimensionality, influence on material viscoelasticity, improvement of chromophore molecular hyperpolarizability, control of material dielectric permittivity and index of refraction properties, and control of material conductance. Consideration of new device architectures is critical to the implementation of chipscale integration of electronics and photonics and achieving the high bandwidths for applications such as next generation (e.g., 5G) telecommunications.

Engineering↗

Origin and mitigation of wind noise on balloon-borne infrasound microbarometers

High-altitude monitoring of low-frequency acoustic waves (infrasound) on Earth has regained prominence in recent years, primarily driven by improvements in light-weight sensor technology and advances in scientific ballooning techniques. Balloon-borne infrasound monitoring is also being proposed as a remote sensing technique for planetary exploration. Contrary to ground-based infrasound monitoring, the infrasound noise background in the stratosphere as measured by a balloon remains uncharacterized and the efficacy of wind noise mitigation filters has not been investigated. In this study, an analysis of pressure data collected using infrasound microbarometers during the flight of a long-duration zero pressure balloon is presented. Here, a dramatic reduction of background noise in the stratosphere is demonstrated and it is shown that wind noise mitigation filters are not effective at reducing wind noise under these conditions. Results from this study demonstrate stratospheric balloons as a low-noise platform for infrasound monitoring and motivate the development of improved noise mitigation tools.

47 OTHER INSTRUMENTATION↗

Correlation-driven attosecond photoemission delay in the plasmonic excitation of C60 fullerene

Extreme light confinement in plasmonic nanosystems enables novel applications in photonics, sensor technology, energy harvesting, biology, and quantum information processing. Fullerenes represent an extreme case for nanoplasmonics: they are sub-nanometer carbon- based molecules showing high-energy and ultrabroad plasmon resonances, however the fundamental mechanisms driving the plasmonic response and the corresponding collective electron dynamics are still elusive. Here, we uncover the dominant role of electron correlations in the dynamics of the giant plasmon resonance (GPR) of the sub-nanometer system C60 by employing attosecond photoemission chronoscopy. We find a characteristic photoemission delay of up to about 300 attoseconds that is purely induced by coherent large-scale electron correlations in the plasmonic potential. These results provide novel insights into the nature of the plasmon resonances in sub-nanometer systems and open new perspectives for advancing nanoplasmonic applications.

Biswas, Shubhadeep [SLAC National Accelerator Labo↗

ARIC 2019 workshop report: The 2nd ACM SIGSPATIAL International Workshop on Advances in Resilient and Intelligent Cities: Chicago, IL, USA November 5, 2019

The advancements in sensor technology and ubiquity of connected devices has enabled the generation of large volume of disparate, dynamic and geographically distributed data both by scientific communities and citizens. With astonishing technological innovations and convergence, there have been major changes in peoples daily activities and social interaction. The socio-technological innovations motivate the concept of smart and connected cities. A smart city, however, is subjected to the same challenges as a conventional city, such as environmental damages, hazard impacts, access to services and resources, due to continuous population and economic growth. Therefore, it is imperative to improve our understanding of Resilient and Intelligent Cities in order to leverage technologies and artificial intelligence to tackle the challenges cities face, which range from climate change, public health, traffic congestion, economic growth, to digital divide, social equity, political movements, and cultural conflicts, among others.

Kar, Bandana↗

Truck Platooning Performance with ADAS and Onboard Camera Data Describing Traffic Interactions

This project was part of the Characterizing Behaviors and Capabilities for Emerging Connected and Automated Vehicle Technologies, Sensors, and Connectivity project. The National Laboratory of the Rockies partnered with Cummins Inc. to collect data from Class 8 tractor trailer combinations in platoon (cooperative adaptive cruise control) operations on public roads in southern Indiana. Data collected include J1939 CAN bus, radar, intervehicle position, and video data. The video data could not be shared in the raw form, so they were processed to extract information on the other vehicles on the road, their relative positions, and intrusion events. This information was then columnized for modeling use and further enhanced by appending road information including road type, speed limit, altitude, and grade. The test route included free-flowing traffic, highway interchanges, and construction zones, as well as low-, medium-, and high-grade sections. Individual test conditions varied by day, with advanced driver-assistance system (ADAS) features engaged or disengaged and different combined vehicle masses tested in addition to uncontrolled variables such as weather and traffic interactions.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Novel Compact Ceilometer (Final Scientific-Technical Report)

Fibertek is developing a novel ceilometer system that provides a new measurement capability not currently available to weather stations such as those in the Department of Energy's AmeriFlux network. Commercially available instruments do not have the sensitivity to see atmospheric aerosols. If the atmospheric aerosols can be measured, then the altitude of the boundary layer can be determined from a discontinuity in the aerosol concentration. The altitude of the boundary layer is a critical parameter in climate and weather models, and adding this piece of information will greatly improve the accuracy of these models. Fibertek's design provides this capability in an inexpensive robust fieldable instrument by applying a new sensor technology: the Silicon Photomultiplier (SiPM). SiPMs are called "photomultipliers" in that they provide very similar performance as a traditional photomultiplier including single photon sensitivity and linear response. However, they are a completely different technology which offers several advantages. They are small, inexpensive, solid-state, and extremely robust. They do not require cooling. They operate at much lower voltages. They cannot be damaged by inadvertent reflections, and when saturated they recover in less than a microsecond, so they don't need to be shielded from the outgoing laser pulse. In short, they make single photon sensitivity accessible for an inexpensive, simple, rugged, fieldable system. In this Phase 1 effort Fibertek developed a breadboard version of the ceilometer to demonstrate the feasibility of our approach. Our partner, Penn State, conducted atmospheric measurements to validate the lidar’s performance and determine algorithms for automatically identifying the height of the boundary layer. The lidar shows sufficient sensitivity to fully characterize the boundary layer in clear air daytime and nighttime conditions.

47 OTHER INSTRUMENTATION↗

Novel, Low-Cost, Light-Weight High Efficiency (H*10 Capable) Neutron Detector-Dosimeter

The goal of this project was to design, develop and validate a novel, spectroscopy enabled H*(10) neutron dosimetry system based on the tensioned metastable fluid detector (TMFD) sensor technology. The project team consisted of staff from Oak Ridge National Laboratory (ORNL), Purdue University (PU) and Sagamore Adams Laboratories, LLC (SAL). PU-SAL staff were tasked with the design, development, construction and testing of the H*TMFD hardware and software, along with developing the control and data acquisition software for comparison of predictions from H*TMFD against a commonly accepted and widely used industry standard system; for this project, the Li-I detector coupled to bonner spheres (LiI-BSS) system manufactured by Ludlum, Inc. was utilized as the reference (“gold”) standard – similar in terms of neutron spectroscopy enablement to another industry recognized, albeit, significantly higher cost (est. $300K) system referred to as “ROSPEC” (from BTI, Inc., which was not available for this project). ORNL staff were tasked with providing field-relevant guidance, apparatus and facilities for acquiring data against calibrated neutron sources, and comparing results of H*TMFD against LiI-BSS system predictions in a series of blind-tests conducted at ORNL. Over the course of 12 months, the PU-SAL-ORNL staff successfully accomplished the proposed technical and administrative tasks, inclusive of engaging in outreach to potential users of this technology in the DOE-wide infrastructure. The proposed tasks were successfully accomplished in timely manner; the follow-up type tasks pertaining to SBIR type Phases 2-3 were discussed and are initiated, inclusive of filing for intellectual property (IP) disclosures and possible patent filings by PU’s Office of Technology Commercialization (OTC). Two H*TMFD system architectures (see Exhibits 1 & 2 in the report) were developed and constructed for hand-portability by health-physicists (HPs) – the HP-H*TMFD, and the H*TMFD system which consists of a side-by-side mounted array of 4 TMFDs of 3 different sizes in sensitive volume (including one with borated fluid) that now simultaneously enables neutron energy spectroscopy: single bin for < 0.1 MeV, and 152 energy bins in the 0.1-15.2 MeV range; H*(10) dosimetry from ~5 μRem/h towards 10 R/h ranges. Several experiments were conducted using neutron sources in various configurations (shielded and unshielded). In direct comparison against the LiI-BSS industry standard (acquiring data for 26h each source), the H*TMFD system (acquiring data for ~6h for each source) offered H*(10) dose predictions for the most part accurate to within +/-10% for dose rates in the 100-300 μRem/h range. The LiI-BSS was impractical to use under ultra-low (~10 μRem/h) dose rate space, as also another metering device used at ORNL (Ludlum 4241L non-spectroscopy enabled) for which the lower limit is set by the manufacturer at 100 μRem/h. The enablement for efficient use in timely manner at the 10 μRem/h levels is deemed to be a strong enabling factor for H*TMFD for use in the DOE-nuclear laboratory arena. In terms of weight, the HP-H*TMFD weighs under ~5-7 lb.; the H*TMFD system weighs ~35-lb. As such, it is ~1/4 the weight of an LiI-BSS system weighing ~120 lb (LiI detector with 6 bonner spheres) and, ~1/2 the weight of ROSPEC. As a result of this activity, two involved post-doctoral student staff have now transitioned their knowledge and experiences to DOE’s Pacific Northwest National Laboratory (PNNL). A PU graduate student has also benefited from this project work which formed a principal basis for his Ph.D. dissertation work (in progress).

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Compact Thermoelastic Cooling System

Maryland Energy & Sensor Technologies, LLC (MEST) demonstrated novel compression-based compact thermoelastic coolers which can be operated in a continuous (non-reciprocating) manner. Roller-based systems were developed which use NiTi (Nickel titanium alloy or Nitinol) wire coils as the refrigerants continuously fed into the rollers for rejecting heat and delivering cooling. Additive manufacturing was used to print heat-exchange subsystems of different shapes and dimensions. Direct cooling of water as the medium was clearly demonstrated, and a clear path toward achieving delivered cooling of up to 400 W per a roller was demonstrated. Some of the innovations developed here included affixing wound coils of NiTi wires around rollers, engineering the shape of the heat-exchanger to enhance the heat exchange coefficient, and introducing a heat rejection mechanism.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Next Generation Logistics Systems for Delivering Optimal Biomass Feedstocks to Biorefining Industries in the Southeastern U.S.

The diverse portfolio of biomass sources that is available in the Southeastern U.S., including a significant supply of pine “residue”, represents a valuable strategic position for the region. Through blends formulated based on critical properties, this project will take full advantage of the range in biomass properties afforded by the portfolio to produce a consistent, high-performance feedstock for the industry, while lowering cost. Key developments being targeted to enable this potential include whole-tree transport to a state-of-the-art merchandising depot that will further access biomass from ongoing, forest industry operations. The approach will more effectively utilize the tree and distribute cost, while minimizing in-woods contamination of the woody biomass component. To implement this vision, information on the chemical composition and changes that are induced during multiple preprocessing steps (size reduction, moisture removal, densification, etc.) is needed. New NIR sensor technology will be developed for online monitoring of important biomass properties. The data will be incorporated into a statistical process control platform to improve process efficiency and meet required specifications. Advanced process models are being developed to inform the techno-economic and life-cycle assessment of the program’s impact. The new system will ultimately reduce operational risks from supply chain disruptions, and allow operation of larger-scale biorefineries.

09 BIOMASS FUELS↗