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At least 487 records · Page 27

A green degumming approach for lignocellulosic kenaf bast using ethanolamine deep eutectic solvent

Traditional chemical degumming methods for lignocellulosic bast fibers pose substantial challenges, especially when dealing with kenaf bast, which has a high lignin content. Here, these challenges include severe pollution and low efficiency, etc. Therefore, this study developed a novel, green, and efficient degumming approach for lignocellulosic kenaf bast, leveraging choline chloride-ethanolamine (ChCl-ETA) alkaline deep eutectic solvent (DES). The efficacy of the ChCl-ETA DES based degumming method was validated through comprehensive chemical composition analysis, scanning electron microscopy (SEM), Fourier transform infrared (FT-IR) spectroscopy, X-ray diffraction (XRD), thermogravimetric analysis (TG), and two-dimensional (2D) nuclear magnetic resonance (NMR) spectroscopy. Subsequently, the optimal degumming conditions, with a choline chloride to ethanolamine ratio of 1:6 and a degumming temperature of 120 °C, were determined based on the results of the residual gum content. Significantly, the recycled ChCl-ETA DES mixtures could maintain a degumming capacity (revealed by the residual gum content of degummed fibers) comparable to that of the conventional double-boiling method for at least five degumming cycles without purification. Given its low-pollution process and high efficiency, this developed method holds great potential for industrial-scale applications of lignocellulosic bast fibers.

Choline chloride↗

Constraining axion properties with radio telescopes

Axion dark matter or any ultralight bosonic dark matter can go through Bose-Einstein condensation due to the large phase density, leading to the formation of axion stars or solitons in dark matter halo centers. The formation rate is enhanced in the presence of the substructures expected in the postinflationary scenario for the QCD axion or axionlike particles. An axion star will continue to grow until a critical mass is reached, after which it collapses and then explodes, with the emission of relativistic axions, in a process called an “axinovae.” There can also be accompanying photon emission due to the stimulated decay of axions in the coherent compact axion star. In axion models with a modest enhancement (𝜅 ∼𝒪⁡(10)) of the axion-photon coupling 𝑔 𝑎⁢𝛾 = 𝜅⁢𝛼/(2⁢𝜋⁢𝑓 𝑎 ) axinovae will contain a significant flux of radio photons. We determine the range of parameters over which axinovae can be detectable with radio transient searches.

Fox, Patrick J. [Fermi National Accelerator Labora↗

On particle track detectors

Aqueous sodium hydroxide is widely used to develop charged particle tracks in polycarbonate film, particularly Lexan. The chemical nature of the etching process for this system has been determined. A method employing ultra-violet absorbance was developed for monitoring the concentration of the etch products in solution. Using this method it was possible to study the formation of the etching solution saturated in etch products. It was found that the system super-saturates to a significant extent before precipitation occurs. It was also learned that the system approaches its equilibrium state rather slowly. It is felt that both these phenomena may be due to the presence of surfactant in the solution. In light of these findings, suggestions are given regarding the preparation and maintenance of the saturated etch solution. Two additional research projects, involving automated techniques for particle track analysis and particle identification using AgCl crystals, are briefly summarized.

Benton, E. V.↗

A methodology for small scale rural land use mapping in semi-arid developing countries using orbital imagery. Part 5: Experimental and operational techniques of mapping land use

The author has identified the following significant results. Scope of the preprocessing techniques was restricted to standard material from the EROS Data Center accompanied by some enlarging procedures and the use of the diazo process. Investigation has shown that the most appropriate sampling strategy for this study is the stratified random technique. A viable sampling procedure, together with a method for determining minimum number of sample points in order to test results of any interpretation are presented.

Vangenderen, J. L.↗

Models of an early lunar dynamo

The hypothesis that a dynamo once existed in the moon, and hence was the source of lunar paleomagnetism, is tested using a model for the global thermoremanent magnetization of spherical lithospheres. Various models of an ancient lunar dipole field are used which incorporate intensity variations and reversals, and which are consistent with lunar sample paleointensities. It is found that non-reversing lunar dynamos which have simple exponential decay histories beginning at 4.6 b.y. ago are inconsistent with this limit, unless the moon has been thoroughly demagnetized to a depth of tens of kilometers by impacts or other processes. An early lunar dynamo cannot be excluded by global scalar measurements unless the permanent lunar dipole moment is shown to be significantly less than 10 to the 13th power G/cu cm by future spacecraft measurements, which may be technologically impossible; vector measurements of lunar magnetic anomalies over the whole moon offer a possibility of determining the source of the field which magnetized the lunar crust.

Srnka, L. J.↗

The injection of energy into the Io plasma torus

Voyager EUV observations of the Io plasma torus indicate the presence of an intensity modulation in the corotating reference frame of significant magnitude on a 10-hour time scale. The phenomenon has a persistence which suggests it is a permanent feature, and the magnitude is such that a substantial amount of energy is injected into the torus at a 10-hour periodic rate. An investigation is conducted regarding the nature of the energy enjection process as determined by the plasma parameters and the observed characteristics. Attention is given to excitation-relaxation relations, aspects of ion-electron relaxation, and electron-electron relaxation and energy transfer rates. The radial distribution of temperature at the eastern and western elongations is found to indicate that the energy input to the electrons is distributed over the width of the torus. The dominant mechanism of energy transport to the plasma appears to be electron-electron heating.

Shemansky, D. E.↗

GSFC optical ozonesonde results during the Gap, France, intercomparisons, June 1981

O3 soundings made with balloon-borne optical sensors during the French Intercomparison Ozone Campaign in June, 1981, are reported. The GSFC four-channel UV-filter-photometer ozonesonde designed for the Super Loki rocket was attached to the gondola roof for redundant O3-density measurements at altitudes of 22-32 km, using the 300 and 303-nm filters. Sensor calibration, data processing, input constants, and vertical O3-distribution calculations are discussed. The density profiles for three legs of the flight, calculated using Bass or Vigroux cross sections, agreed within a standard error of 1.4 percent for each channel, but showed a consistent 4-5 percent (significant) difference between channels. Total average O3-column amounts determined by combining the GSFC data with ECC measurements for altitudes below 21 km were in good agreement with bias-corrected TOMS data from Nimbus-VII and with ground-based data from the Observatoire de Haute-Provence at Mt. Chiran, when the latter were computed using the pre-campaign calibration. A 9-percent discrepancy arose when the Chiran data were corrected for a post-campaign recalibration of the Dobson spectrophotometer.

Krueger, A. J.↗

Laser measurements of the effects of vibrational energy on the reactions of CN

Pulsed laser photolysis of C2N2 at 193 nm has been used as a source of CN radicals in both the v-double-prime = 0 and v-double-prime = 1 levels. Individual rovibronic levels of these radicals were measured as a function of time with a tunable dye laser. From these measurements the rate constants for the reaction of each of these vibrational levels with H2, O2, CO, CO2, N2, HCN, C2N2, and CH4 have been determined. Some enhancement in the rate constant with vibrational energy which could not be ascribed to quenching was observed for O2, CH4, and H2. Only vibrational quenching was observed for HCN, N2, CO2, CO and C2N2. In the CO case the vibrational quenching rate appears to be significantly enhanced by complex formation during the quenching process.

Sayah, N.↗

Evaluation of results of cell electrophoresis experiments on space shuttle STS-3 including pre-flight and post-flight laboratory experiments

The objectives of the red blood cell experiments were to provide a visual check on the electrophoretic process and especially electroosmotic flow in space as well as to provide test separations of non-degradable standard particles for comparison with the separations of the three viable cell types studied on the Apollo-Soyuz Test Project. Determination of the maximum concentrations of cells that can be separated in column electrophore was a significant goal. Two of the eight columns were available for red cell experiments, so two concentrations of human and rabbit RBC mixtures were used. The objectives of another experiment were to evaluate the reproducibility of microgravity electrophoretic separation of living kidney cells, to separate cells with highly viability despite two freeze-thaw cycles, and to optimize the physical conditions of cell separation. Owing to the uncertain heterogeneity of the starting material, the experimental design does not assess resolution in microgravity, but improved separability was sought in comparison to density-gradient electrophoresis or continuous-flow electrophoresis. Efforts were made to increase cell yield and cell viability and to assess reproducibility directly.

Todd, P. W.↗

Shielding of CO from dissociating radiation in interstellar clouds

The paper investigates the photodissociation of CO in interstellar clouds in the light of recent laboratory studies which suggest that line rather than continuum processes dominate its dissociation by ultraviolet radiation. Using a simple radiative transfer model, the shielding of representative dissociating bands is estimated, including self-shielding, mutual shielding between different isotopes, and near coincidences with strong lines of H2. Each of these processes materially affects the photodestruction rates of the various isotopic species in the transition regions of molecular clouds. These results are combined with an appropriate gas phase chemical model to determine how the abundances of the CO isotopes vary with depth into the cloud. It is found that self-shielding and mutual shielding cause significant variations in isotopic ratios. In addition, fractionation enhances species containing C-13. The relationship between the column densities of CO and H2 is found to vary for the different isotopes and to be sensitive to local conditions.

Glassgold, A. E.↗

Application of digital pulse shaping by least squares method to ultrasonic signals in composites

For ultrasonic testing in composites, a signal processing tool is identified that can significantly enhance the sharpness of ultrasonic waveforms and provide clearer pictures of the nature of the material flaw. The technique artificially improves the resolution of the system to discrete events by pulse shaping the measured waveform based on the signal from a reference. The optimum pulse shape operator is determined from a least-squares method in the z-domain.

Kishoni, D.↗

On the Wiener-Masani algorithm for finding the generating function of multivariate stochastic processes

The algorithms developed by Wiener and Masani (1957 and 1958) and Masani (1960) for the characterization of a class of multivariate stationary stochastic processes are investigated analytically. The algorithms permit the determination of (1) the generating function, (2) the prediction-error matrix, and (3) an autoregressive representation of the linear least-squares predictor. A number of theorems and lemmas are proved, and it is shown that the range of validity of the algorithms can be extended significantly beyond that given by Wiener and Masani.

Miamee, A. G.↗

Determining The Degree Of Graphitization In Carbon Composites

Method for determining degree of graphitization of carbon/carbon composite material combines infrared spectral experimental technique with thermodynamical theoretical model of solubility. By interrupting manufacturing process at almost any time and applying method, one can judge quality of composite and monitor chemical transformations taking place during process. Also computes effective solubility parameter for composite considered as unitary material. Parameter significant for subsequent fabrication steps involving chemical treatments; e.g., coating or joining with adhesives.

Lawson, Daniel D.↗

Sensitivity of acoustic predictions to variation of input parameters

Rotor noise prediction codes predict the thickness and loading noise produced by a helicopter rotor, given the blade motion, rotor operating conditions, and fluctuating force distribution over the blade surface. However, the criticality of these various inputs, and their respective effects on the predicted acoustic field, have never been fully addressed. This paper examines the importance of these inputs, and the sensitivity of the acoustic predicitions to a variation of each parameter. The effects of collective and cyclic pitch, as well as coning and cyclic flapping, are presented. Blade loading inputs are examined to determine the necessary spatial and temporal resolution, as well as the importance of the chordwise distribution. The acoustic predictions show regions in the acoustic field where significant errors occur when simplified blade motions or blade loadings are used. An assessment of the variation in the predicted acoustic field is balanced by a consideration of Central Processing Unit (CPU) time necessary for the various approximations.

Brentner, Kenneth S.↗

The East and Southeast Asia Initiatives: Aerosol Column Measurements

Airborne dusts from northern China contribute a significant part of the air quality problem and, to some extent, regional climatic impact in Asia during spring- time. However, with the economical growth in China, increases in the emission of air pollutants generated from industrial and vehicular sources will not only impact the radiation balance, but adverse health effects to humans all year round. In addition, both of these dust and air pollution clouds can transport swiftly across the Pacific reaching North America within a few days, possessing an even larger scale effect. The Asian dust and air pollution aerosols can be detected by its colored appearance on current Earth observing satellites (e.g., MODIS, SeaWiFS, TOMS, etc.) and its evolution monitored by satellites and surface network. Biomass burning has been a regular practice for land clearing and land conversion in many countries, especially those in Africa, South America, and Southeast Asia. However, the unique climatology of Southeast Asia is very different than that of Africa and South America, such that large-scale biomass burning causes smoke to interact extensively with clouds during the peak-burning season of March to April. Significant global sources of greenhouse gases (e.g., CO2, CH4), chemically active gases (e.g., NO, CO, HC, CH3,Br), and atmospheric aerosols are produced by biomass burning processes. These gases influence the Earth- atmosphere system, impacting both global climate and tropospheric chemistry. Some aerosols can serve as cloud condensation nuclei, which play an important role in determining cloud lifetime and precipitation, hence, altering the earth's radiation and water budget. Biomass burning also affects the biogeochemical cycling of nitrogen and carbon compounds from the soil to the atmosphere; the hydrological cycle (i.e., run off and evaporation); land surface reflectivity and emissivity; as well as ecosystem biodiversity and stability. Two new initiatives, EAST-AIRE (East Asian Study of Tropospheric Aerosols: an International Regional Experiment) and BASE-ASIA (Biomass-burning Aerosols in South East-Asia: Smoke Impact Assessment) will be presented and discussed their contribution to better understand the impacts of aerosols on regional-to- global climate, hydrological and carbon cycles, and tropospheric chemistry.

Tsay, Si-Chee↗

Dust, Pollution, and Biomass Burning Aerosols in Asian Pacific: A Column Satellite-Surface Perspective

Airborne dusts from northern China contribute a significant part of the air quality problem and, to some extent, regional climatic impact in Asia during spring-time. However, with the economical growth in China, increases in the emission of air pollutants generated from industrial and vehicular sources will not only impact the radiation balance, but adverse health effects to humans all year round. In addition, both of these dust and air pollution clouds can transport swiftly across the Pacific reaching North America within a few days, possessing an even larger scale effect. The Asian dust and air pollution aerosols can be detected by its colored appearance on current Earth observing satellites (e.g., MODIS, SeaWiFS, TOMS, etc.) and its evolution monitored by satellites and surface network. Biomass burning has been a regular practice for land clearing and land conversion in many countries, especially those in Africa, South America, and Southeast Asia. However, the unique climatology of Southeast Asia is very different than that of Africa and South America, such that large-scale biomass burning causes smoke to interact extensively with clouds during the peak-burning season of March to April. Significant global sources of greenhouse gases (e.g., CO2, CH4), chemically active gases (e.g., NO, CO, HC, CH3Br), and atmospheric aerosols are produced by biomass burning processes. These gases influence the Earth-atmosphere system, impacting both global climate and tropospheric chemistry. Some aerosols can serve as cloud condensation nuclei, which play an important role in determining cloud lifetime and precipitation, hence, altering the earth's radiation and water budget. Biomass burning also affects the biogeochemical cycling of nitrogen and carbon compounds from the soil to the atmosphere; the hydrological cycle (i.e., run off and evaporation); land surface reflectivity and emissivity; as well as ecosystem biodiversity and stability. Two new initiatives, EAST-AIRE (East Asian Study of Tropospheric Aerosols: an International Regional Experiment) and BASE-ASIA (Biomass-burning Aerosols in South East-Asia: Smoke Impact Assessment) will be presented and discussed their contribution to better understand the impacts of aerosols on regional-to-global climate, hydrological and carbon cycles, and tropospheric chemistry.

Tsay, Si-Chee↗

Single-Nucleon Transfer on Unstable 59 Cu Probes the NiCu Cycle in Astrophysical X-Ray Bursts

Recent models of the rapid proton (𝑟⁢𝑝) capture process indicate that a competition between the 59 Cu⁢(𝑝,𝛾) ⁢60 Zn and 59 Cu⁢(𝑝,𝛼) ⁢56 Ni reactions may result in the formation of a nickel-copper (NiCu) cycle that traps the flux of material between 56 Ni and 60 Zn . Here, in this work, we report the identification of 15 proton-unbound levels in 60 Zn , populated via 59 Cu⁢(𝑑,𝑛) transfer, which govern the rate of the 59 Cu⁢(𝑝,𝛾)⁢ 60 Zn reaction in XRBs. Precise excitation energies for levels in 60 Zn were obtained from observed 𝛾 decays, and spectroscopic factors were determined from angle-integrated cross sections. Incorporating these results into stellar-model calculations, we find that with experimentally constrained uncertainties a NiCu cycle in XRBs is indeed possible, though we limit its branching strength to less than 38%. While modest, such a branching has significant impact on the light curve, motivating further studies of the relevant rates. Our calculations also indicate that a significant NiCu cycle leads to an increase in the amount of odd-𝐴 nuclei in the burst ashes, which may affect Urca cooling processes in neutron star crusts.

direct reactions↗

NASA's Lunar Atmosphere and Dust Environment Explorer (LADEE)

Nearly 40 years have passed since the last Apollo missions investigated the mysteries of the lunar atmosphere and the question of levitated lunar dust. The most important questions remain: what is the composition, structure and variability of the tenuous lunar exosphere? What are its origins, transport mechanisms, and loss processes? Is lofted lunar dust the cause of the horizon glow observed by the Surveyor missions and Apollo astronauts? How does such levitated dust arise and move, what is its density, and what is its ultimate fate? The US National Academy of Sciences/National Research Council decadal surveys and the recent "Scientific Context for Exploration of the Moon" (SCEM) reports have identified studies of the pristine state of the lunar atmosphere and dust environment as among the leading priorities for future lunar science missions. These measurements have become particularly important since recent observations by the Lunar Crater Observation and Sensing Satellite (LCROSS) mission point to significant amounts of water and other volatiles sequestered within polar lunar cold traps. Moreover Chandrayaan/M3, EPOXI and Cassini/VIMS have identified molecular water and hydroxyl on lunar surface regolith grains. Variability in concentration suggests these species are likely to be present in the exosphere, and thus constitute a source for the cold traps. NASA s Lunar Atmosphere and Dust Environment Explorer (LADEE) is currently under development to address these goals. LADEE will determine the composition of the lunar atmosphere and investigate the processes that control its distribution and variability, including sources, sinks, and surface interactions. LADEE will also determine whether dust is present in the lunar exosphere, and reveal its sources and variability. LADEE s results are relevant to surface boundary exospheres and dust processes throughout the solar system, will address questions regarding the origin and evolution of lunar volatiles, and will have implications for future exploration activities. LADEE will be the first mission based on the Ames Common Bus design. LADEE employs a high heritage instrument payload: a Neutral Mass Spectrometer (NMS), an Ultraviolet/Visible Spectrometer (UVS), and the Lunar Dust Experiment (LDEX). It will also carry a space terminal as part of the Lunar Laser Communication Demonstration (LLCD), which is a technology demonstration. LLCD will also supply a ground terminal. LLCD is funded by the Space Operations Mission Directorate (SOMD), managed by GSFC, and built by MIT Lincoln Lab. NMS was directed to the Goddard Space Flight Center (GSFC) and UVS to Ames Research Center (ARC). LDEX was selected through the Stand Alone Missions of Opportunity Notice (SALMON) Acquisition Process, and is provided by the University of Colorado at Boulder. The LADEE NMS covers a m/z range of 2-150 and draws its design from mass spectrometers developed at GSFC for the MSL/SAM, Cassini Orbiter, CONTOUR, and MAVEN missions. The UVS instrument is a next-generation, high-reliability version of the LCROSS UV-Vis spectrometer, spanning 250-800 nm wavelength, with high (<1 nm) spectral resolution. UVS will also perform dust occultation measurements via a solar viewer optic. LDEX senses dust impacts in situ, at LADEE orbital altitudes of 50 km and below, with a particle size range of between 100 nm and 5 micron. Dust particle impacts on a large hemispherical target create electron and ion pairs. The latter are focused and accelerated in an electric field and detected at a microchannel plate. LADEE is an important part of NASA s portfolio of near-term lunar missions; launch is planned for May, 2013. The lunar atmosphere is the most accessible example of a surface boundary exosphere, and may reveal the sources and cycling of volatiles. Dynamic dust activity must be accounted for in the design and operation of lunar surface operations.

Elphic, Richard↗