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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 487 records · Page 27
All sourcesNASA NTRSDOE OSTI
DOE OSTI2018

Refractory Solar Selective Coatings

This three-year project worked towards developing high-performance selective receiver coatings for concentrated solar power (CSP) to meet the DOE SunShot 2020 goal of levelized cost of energy (LCOE) ≤6 ¢/kWhe. We exploited recent advances in photonic crystal fabrication and nanocomposite materials synthesis to manufacture coatings designed to withstand high operating temperatures in air (>800 °C) while maintaining a high solar absorptivity (≥95%) and low IR emissivity (≤10%). We engineered the selective receiver coatings at multiple length scales. In the 0.1-1 μm regime, the coating has a photonic crystal structure comprised of a periodic mesoporous array. This structure alters the photonic density of states to improve spectral selectivity while also mitigating thermal stress for improved lifetime. At the 1-10 nm scale, the coatings are composed of optically absorbing nanoparticles in a transparent matrix where the size, spacing, and composition of the nanoparticles are tailored to tune the optical properties for high visible absorption and low IR emittance - similar to a cermet, but with dramatically enhanced thermal stability. The photonic structure was fabricated by self-assembly from a nanoparticle suspension followed by infiltration using atomic layer deposition (ALD). The nanophase composite results by combining the ALD processes for a metal and a metal oxide.

14 SOLAR ENERGY↗
DOE OSTI2021

Outdoor performance of a tandem InGaP/Si photovoltaic luminescent solar concentrator

Here, we report the design, fabrication and outdoor characterization of a tandem luminescent solar concentrator/Si multi-junction photovoltaic module. Our tandem LSC/Si device consists of an InGaP LSC functioning as a top cell and a passivated contact Si bottom cell. The LSC comprises of an InGaP microcell array coupled to a polymer waveguide, loaded with CdSe/CdS core-shell quantum dot luminophores. The light trapping efficiency of the LSC waveguide is enhanced by encapsulation with photoluminescence trapping mirrors consisting of dielectric multilayer thin films. We demonstrate the performance of the LSC/Si device through a series of outdoor tests under various irradiance conditions conducted at the National Renewable Energy Laboratory. We report the first outdoor testing data of an LSC/Si tandem module, displaying maintained performance across varied diffusivity conditions for the LSC component. Finally, we model the tandem module performance using a ray optic simulation-based multiphysics model and forecast a pathway for high efficiency tandem LSC/Si module performance.

14 SOLAR ENERGY↗
DOE OSTI2016

MEASURING HIGH-PRECISION ASTROMETRY WITH THE INFRARED ARRAY CAMERA ON THE SPITZER SPACE TELESCOPE

The Infrared Array Camera (IRAC) on the Spitzer Space Telescope currently offers the greatest potential for high-precision astrometry of faint mid-IR sources across arcminute-scale fields, which would be especially valuable for measuring parallaxes of cold brown dwarfs in the solar neighborhood and proper motions of obscured members of nearby star-forming regions. To more fully realize IRAC's astrometric capabilities, we have sought to minimize the largest sources of uncertainty in astrometry with its 3.6 and 4.5 μm bands. By comparing different routines that estimate stellar positions, we have found that Point Response Function (PRF) fitting with the Spitzer Science Center's Astronomical Point Source Extractor produces both the smallest systematic errors from varying intra-pixel sensitivity and the greatest precision in measurements of positions. In addition, self-calibration has been used to derive new 7th and 8th order distortion corrections for the 3.6 and 4.5 μm arrays of IRAC, respectively. These corrections are suitable for data throughout the mission of Spitzer when a time-dependent scale factor is applied to the corrections. To illustrate the astrometric accuracy that can be achieved by combining PRF fitting with our new distortion corrections, we have applied them to archival data for a nearby star-forming region, arriving at total astrometric errors of ∼20 and 70 mas at signal to noise ratios of 100 and 10, respectively.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2021

High-Fidelity Models and Fast EMT Simulation Algorithms for Isolated Multi-port Autonomous Reconfigurable Solar power plant (MARS)

The integration of hybrid photovoltaic (PV) and energy storage system (ESS) based plants has become a promising way of solving the intermittency of PV plants and providing frequency support to the power grid. The multi-port autonomous reconfigurable solar power plant (MARS) can integrate the PV systems and ESSs to an ac grid and dc lines. The proposed isolated MARS incorporates an isolated converter that connects to the PV arrays and is based on the dual active bridge (DAB) converter. The high frequency switching in the DAB and the means to control the DAB converter using delays between switching signals lead to the need for a small timestep in simulations. Moreover, several hundreds of modules that include a DAB converter are present in the MARS. The small timestep and the presence of several hundreds of modules lead to a significant rise in the overall simulation time. To address this issue, simulation algorithms like numerical stiffness-based hybrid discretization and the hysteresis relaxation technique are applied to the switched system model of isolated MARS. Additionally, an event-driven interpolating method is introduced to help increase the minimum timestep to simulate the conventional DAB converter model while maintaining high accuracy in the simulation results. The developed model is validated by comparison with its reference model built in the PSCAD/EMTDC and MATLAB software environments using library components.

Xia, Qian↗
DOE OSTI2022

Altering apparent optical properties with an array of semitransparent mesoscale structures

The ability to control and optimize interactions between light and matter has much utility in engineering design. A well-researched way to achieve optical property modulation is via the use of optical metamaterials, which feature sub-wavelength scale surface structures. In this work, an alternative approach for modulating optical properties is presented using a composite surface modified with a periodic array of semitransparent hemispherical shell mesoscale structures which are larger than the incident light wavelength. A ray-tracing simulation approach is used to predict the optical behavior for an arrayed surface. At oblique angles of incidence, significant increases and decreases in apparent absorptance are achieved via the use of optically thick and thin shells, respectively. Additionally, a potential application to solar cells is described with optimal spectral behavior achieved via the use of semitransparent external structures.

Kucuktas, Onur A.↗
DOE OSTI2015

Advanced Research Projects Agency - Energy Annual Report for FY 2014

This report presents a summary of the activities of the Advanced Research Projects Agency-Energy (ARPA-E) during Fiscal Year 2014 (FY2014). In FY2014, ARPA-E issued funding solicitations and selected projects for three new programs covering a broad array of energy technologies, including: 27 million dollars to develop next-generation power switching devices that improve energy efficiency in a wide range of applications; 30 million dollars for hybrid solar energy beyond current photovoltaic (PV) and concentrated solar power (CSP) technologies; and 33 million dollars for electrochemical technologies to enable low-cost distributed power generation. ARPA-E released three additional funding opportunities in FY2014 with project selections that were ultimately announced in FY2015. These programs include: 30 million dollars for localized heating and cooling devices to expand temperature ranges within buildings reducing energy consumption; 30 million dollars for low-cost, high-sensitivity systems to detect and measure methane emissions; and 30 million dollars for low-cost tools to aid in the future development of fusion power. ARPA-E also continued the use of a rolling open solicitation to quickly support innovative applied energy research that has the potential to lead to new focused programs. In addition to these new programs, ARPA-E hosted the fifth annual Energy Innovation Summit from February 24-26, 2014. The Summit brought together leaders from academia, government, and business to discuss the foremost energy issues, showcase the latest technology innovations, and cultivate relationships to help advance cutting-edge technologies to market. The event drew over 2,100 attendees and featured over 120 speakers and keynote addresses. At the Summit, ARPA-E announced at least 24 ARPA-E project teams that have formed new companies and more than 16 ARPA-E projects, which have partnered with other government agencies for further development. Additionally, 22 ARPA-E projects have attracted more than 625 million dollars in private-sector follow-on funding after ARPA-E’s investment of approximately 95 million dollars. Lastly, ARPA-E continued to focus on providing awardees with practical training and critical business information as part of the Agency’s Technology-to-Market program. This support equips projects with a clear understanding of market needs to guide technical development and help projects succeed the marketplace.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗
DOE OSTI2022

ARPA-E PERFORM datasets

Time-coincident load, wind, and solar data including actual and probabilistic forecast datasets at 5-min resolution for ERCOT, MISO, NYISO, and SPP. Wind and solar profiles are supplied for existing sites as well as planned sites based on interconnection queue projects as of 2021. For ERCOT actuals are provided for 2017 and 2018 and forecasts for 2018, and for the remaining ISOs actuals are provided for 2018 and 2019 and forecasts for 2019. There datasets were produced by NREL as part of the ARPA-E PERFORM project, an ARPA-E funded program that aim to use time-coincident power and load seeks to develop innovative management systems that represent the relative delivery risk of each asset and balance the collective risk of all assets across the grid. For more information on the datasets and methods used to generate them see https://github.com/PERFORM-Forecasts/documentation.

5-min data↗
DOE OSTI2016

SCINTILLATION ARCS IN LOW-FREQUENCY OBSERVATIONS OF THE TIMING-ARRAY MILLISECOND PULSAR PSR J0437–4715

Low-frequency observations of pulsars provide a powerful means for probing the microstructure in the turbulent interstellar medium (ISM). Here we report on high-resolution dynamic spectral analysis of our observations of the timing-array millisecond pulsar PSR J0437–4715 with the Murchison Widefield Array (MWA), enabled by our recently commissioned tied-array beam processing pipeline for voltage data recorded from the high time resolution mode of the MWA. A secondary spectral analysis reveals faint parabolic arcs akin to those seen in high-frequency observations of pulsars with the Green Bank and Arecibo telescopes. Data from Parkes observations at a higher frequency of 732 MHz reveal a similar parabolic feature with a curvature that scales approximately as the square of the observing wavelength (λ{sup 2}) to the MWA's frequency of 192 MHz. Our analysis suggests that scattering toward PSR J0437–4715 predominantly arises from a compact region about 115 pc from the Earth, which matches well with the expected location of the edge of the Local Bubble that envelopes the local Solar neighborhood. As well as demonstrating new and improved pulsar science capabilities of the MWA, our analysis underscores the potential of low-frequency pulsar observations for gaining valuable insights into the local ISM and for characterizing the ISM toward timing-array pulsars.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2023

Utility-Scale Solar, 2023 Edition: Analysis of Empirical Plant-level Data from U.S. Ground-mounted PV, PV+battery, and CSP Plants (exceeding 5 MWAC)

Berkeley Labs "Utility-Scale Solar", 2023 Edition presents analysis of empirical plant-level data from the U.S. fleet of ground-mounted photovoltaic (PV), PV+battery, and concentrating solar-thermal power (CSP) plants with capacities exceeding 5 MWAC. While focused on key developments in 2022, this report explores trends in deployment, technology, capital and operating costs, capacity factors, the levelized cost of solar energy (LCOE), power purchase agreement (PPA) prices, wholesale market value, and interconnection queue data.

analysis↗
DOE OSTI2021

Photovoltaic Data Acquisition (PVDAQ) Public Datasets

The NREL PVDAQ is a large-scale time-series database containing system metadata and performance data from a variety of experimental PV sites and commercial public PV sites. The datasets are used to perform on-going performance and degradation analysis. Some of the sets can exhibit common elements that effect PV performance (e.g. soiling). The dataset consists of a series of files devoted to each of the systems and an associated set of metadata information that explains details about the system hardware and the site geo-location. Some system datasets also include environmental sensors that cover irradiance, temperatures, wind speeds, and precipitation at the site.

Array↗
DOE OSTI2015

Diverging polygon-based modeling (DPBM) of concentrated solar flux distributions

This paper presents an efficient and robust methodology for modeling concentrated solar flux distributions. Compared to ray tracing methods, which provide high accuracy but can be computationally intensive, this approach makes a number of simplifying assumptions in order to reduce complexity by modeling incident and reflected flux as a series of simple geometric diverging polygons, then applying shading and blocking effects. A reduction in processing time (as compared to ray tracing) allows for evaluating and visualizing numerous combinations of engineering and operational variables (easily exceeding 106 unique iterations) to ascertain instantaneous, transient, and annual system performance. The method is demonstrated on a linear Fresnel reflector array and a number of variable iteration examples presented. While some precision is sacrificed for computational speed, flux distributions were compared to ray tracing (SolTrace) and average concentration ratio generally found to agree within ~3%. Furthermore, this method presents a quick and very flexible coarse adjust method for concentrated solar power (CSP) field design, and can be used to both rapidly gain an understanding of system performance as well as to narrow variable constraint windows for follow-on high accuracy system optimization.

14 SOLAR ENERGY↗
DOE OSTI2015

Robust Technique for Measuring and Simulating Silicon Wafer Quality Characteristics that Enable the Prediction of Solar Cell Electrical Performance of MEMC Silicon Wafer. Cooperative Research and Development Final Report, CRADA Number CRD-11-438

NREL and MEMC Electronic Materials are interested in developing a robust technique for monitoring material quality of mc-Si and mono-Si wafers -- a technique that can provide relevant data to accurately predict the performance of solar cells fabricated on them. Previous work, performed under two TSAs between NREL and MEMC, has established that dislocation clusters are the dominant performance-limiting factor in MEMC mc-Si solar cells. The work under this CRADA will go further in verifying these results on a larger data set, evaluate possibilities of faster method(s) for mapping dislocations in wafers/ingots, understanding dislocation generation during ingot casting, and helping MEMC to have an internal capability for basic characterization that will provide feedback needed for more accurate crystallization simulations. NREL has already developed dislocation mapping technique and developed a basic electronic model (called Network Model) that uses spatial distribution of dislocations to predict the cell performance. In this CRADA work, we will use these techniques to: (i) establish dislocation, grain size, and grain orientation distributions of the entire ingots (through appropriate DOE) and compare these with theoretical models developed by MEMC, (ii) determine concentrations of some relevant impurities in selected wafers, (iii) evaluate potential of using photoluminescence for dislocation mapping and identification of recombination centers, (iv) evaluate use of diode array analysis as a detailed characterization tool, and (v) establish dislocation mapping as a wafer-quality monitoring tool for commercial mc-Si production.

14 SOLAR ENERGY↗
DOE OSTI2025

Sequential Infiltration Synthesis of Cadmium Sulfide Discrete Atom Clusters

Abstract Exposure of soft material templates to alternating volatile chemical precursors can produce inorganic deposition within the permeable template (e.g. a polymer thin film) in a process akin to atomic layer deposition (ALD). While such sequential infiltration synthesis (SIS) processes have now been demonstrated for many metal oxides, we report an SIS process for a transition metal sulfide – CdS. Gas phase dimethyl cadmium and hydrogen sulfide precursors infiltrated into poly(4‐vinylpyridine) thin films result in the 3D‐nucleation of clusters consistent with a cubane‐type Cd 4 S 4 core that are variably terminated with methyl, thiol and hydroxy capping ligands. First principles models and simulation of few‐atom Cd‐based clusters are consistent with electronic and vibrational spectroscopy and grazing‐incidence total X‐ray scattering measurements of 3D‐cluster‐arrays synthesized at 80 °C. The direct synthesis of few‐atom transition metal sulfide clusters within polymer thin films will provide a versatile new route to precision architectures for light‐absorbing materials including solar energy harvesting and conversion applications.

Jayaweera, Nuwanthaka P. [Material Science Divisio↗
DOE OSTI2021

Monolithic Photoelectrochemical CO 2 Reduction Producing Syngas at 10% Efficiency

We report increasing anthropogenic carbon dioxide emissions have prompted the search for photoelectrochemical (PEC) methods of converting CO 2 to useful commodity products, including fuels. Ideally, such PEC approaches will be sustained using only sunlight, water, and CO 2 as energetic and reactant inputs. However, low peak conversion efficiencies (< 5%) have made commercialization of fully-integrated PEC devices prohibitive. Here, a 4 cm 2 monolithic PEC device exceeding 10% solar-to-fuel efficiency with principal fuel products of carbon monoxide and hydrogen is reported. The corresponding solar-to-CO and solar-to-H 2 efficiencies are 7% and 3.5%, respectively. Screening of a range of operating conditions reveals a tunable product mixture of H 2 and CO using a gold electrocatalyst. Accordingly, it is shown that device optimization yields a H 2 -to-CO ratio of 1:2 commonly present in synthesis gas (syngas). Notably, the modularity and facile fabrication of this device permit the incorporation of a broad array of materials for various applications. For example, the electrocatalyst may easily be swapped to target a different set of products.

36 MATERIALS SCIENCE↗
DOE OSTI2018

Surface Passivation and Carrier Collection in {110}, {100} and Circular Si Microwire Solar Cells

Surface recombination is a major bottleneck for realizing highly efficient micro/nanostructure solar cells. Parametric studies of the influence of Si microwire (SiMW) surface-facet orientation (rectangular with flat-facets, {110}, {100} and circular), with a fixed height of 10 µm, diameter (D = 1.5–9.5 µm), and sidewall spacing (S = 2.5–8.5 µm), and mesh-grid density (1–16 mm -2 ) on recombination and carrier collection in SiMW solar cells with radial p-n junctions are reported. An effective surface passivation layer composed of thin thermally grown silicon dioxide (SiO 2 ) and silicon nitride (SiN x ) layers is employed. For a fixed D of 1.5 µm, tight SiMW spacing results in improved short-circuit current density (J sc = 30.1 mA cm -2 ) and sparse arrays result in open-circuit voltages (V oc = 0.552 V) that are similar to those of control Si planar cells. For a fixed S, smaller D results in better light trapping at shorter wavelengths and higher J sc while larger D exhibits better light trapping at larger wavelengths and a higher V oc . With a mesh-grid electrode the power conversion efficiency increases to 15.3%. Finally, these results provide insights on the recombination mechanisms in SiMW solar cells and provide general design principles for optimizing their performance.

14 SOLAR ENERGY↗