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At least 487 records · Page 27

40 Years of Processing Pieces of Space

This year marks the 40th year anniversary for the Antarctic Search for Meteorite (ANSMET) program. In 1976, the ANSMET program led the first expedition to Antarctica. The ANSMET program is a US-led field-based science project that recovers meteorite samples from Antarctica. Once a year from late November to late January, a field team consisting of 8 to 12 people, spends 6-8 weeks camping on the ice and collecting meteorites. Since 1976, more than 22,000 meteorite samples have been recovered. These meteorites come from asteroids, planets and other bodies of the solar system. Once collected, the Antarctic meteorites are shipped to NASA/Johnson Space Center (JSC) Houston, TX. in a refrigerated truck and are kept frozen to minimize oxidation until they are ready for initial processing. In Antarctica each meteorite is given a field tag which consists of numbers, once in the lab, this is replaced by an official tag, consisting of the Antarctic field location and year collected. The types and numbers of meteorites that have been classified include 849 carbonaceous chondrites, 135 enstatites, 512 achondrites, 64 stony, 115 irons, 48 others (27 R chondrites, 7 ungrouped), 6,161 H chondrites, 7,668 L chondrites, and 4,589 LL chondrites. Although 80-85 percent of the collected meteorites fall in the ordinary chondrite group, the other approximately 15 percent represent rare types of achondrites and carbonaceous chondrites. These rare meteorites include 25 lunar meteorites, 15 Martian meteorites, scores of various types of carbonaceous chondrites, and unique achondrites. The Antarctic meteorites that have been collected are processed in the Meteorite Processing Lab at JSC in Houston, TX. Initial processing of the meteorites begins with thawing/drying the meteorites in a nitrogen glove box for 24 to 48 hours. The meteorites are then photographed, measured, weighed and a description of the interior and exterior of each meteorite is written. The meteorite is broken and a representative sample, either a 1-3 gram chip or thin section is sent to the Smithsonian Institution for classification. After Antarctic meteorites have been classified and approved by the Nomenclature Committee of the Meteoritical Society, they are announced in the Antarctic Meteorite Newsletter, which is published twice per year (fall and spring) so that scientists may review which meteorites are available to study. Requests for Antarctic Meteorite samples are welcomed from research scientists, regardless of their current state of funding for meteorite studies. Since its inception over 3,300 requests have been made for pieces of these meteorites and over 400 investigators worldwide are active in the study of meteorites.. Research on these samples has been published in more than1500 peer reviewed articles; a listing of papers for any meteorite sample can be generated by accessing http://curator.jsc.nasa.gov/antmet/referencesearch.cfm. Antarctic meteorite samples requested by scientists are prepared several different ways. Most samples are prepared as chips, either using a rock splitter or using a chisel and chipping bowl. In special situations, a researcher may request a meteorite slab in which case the samples are cut using a diamond-bladed bandsaw inside of a dry nitrogen glove box. The meteorites are always cut in a 100 percent liquid-free environment. Additionally, thin/thick sections of Antarctic meteorites are also prepared at JSC. The meteorite thin section lab at JSC can prepare standard 30-micron thin sections, thick sections of variable thickness (100 to 200 microns), or demountable sections using superglue, all section are prepared without using water. Although many of the techniques used back in the '70's are still used today, advances in computers, software, databases, available tools and instrumentation have helped to streamline and shorten the duration of the classification process. In conjunction with present day missions to asteroids and other planets, meteorite studies have not only led to a better understanding of the complex histories of these bodies but have also tied certain meteorite groups to particular asteroid bodies. New meteorite discoveries by the ANSMET program provide a cost effective method for obtaining samples of previously unsampled bodies, allowing scientists to learn more about the origin, composition, and evolution of the solar system. Preservation in our cleanrooms at NASA allows material to be archived for future generations and advances in instrumentation and analysis.

Satterwhite, C. E.↗

Insights into the Reactivity of Brookite TiO 2 Nanorods in Liquid Water from Ab Initio Molecular Dynamics Simulations

Brookite TiO 2 , a rare natural polymorph of TiO 2 , has been reported to be an excellent photocatalyst for the production of hydrogen from water and aqueous alcohol solutions, especially when it is reduced and synthesized in the form of nanorods. Here, we investigate the reactivity of stoichiometric and reduced brookite nanorods in liquid water using ab initio molecular dynamics and hybrid density functional theory calculations. Our simulations show a much higher water dissociation fraction on reduced nanorods than on stoichiometric ones, with an accumulation of the resulting bridging hydroxyls (O br H) and terminal hydroxyls (Ti –OH) on different facets of the nanorod. ObrH groups accumulate preferentially on low-energy (210) facets, where they are stabilized by adjacent reduced Ti (Ti 3+ ) sites, while Ti –OH groups prefer to form at the four-fold coordinated Ti atoms on high-energy (010) facets. This hydroxylation pattern also favors the spatial localization of excited holes on the (010) facets. This coupling between water-induced surface chemistry and charge separation underpins the enhanced photocatalytic activity of brookite nanorods, providing useful information for the design of more efficient TiO2-based nanostructures for solar-driven hydrogen evolution.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Watching Polarons Dance: Coherent Carrier–Phonon Coupling in Hematite Revealed by Transient Absorption Spectroscopy

Hematite remains a prominent photoanode candidate for the oxygen evolution reaction in solar water splitting, despite efficiency limitations from rapid trapping of photoexcited electrons and holes. While the formation of polarons, quasiparticles formed by electron–hole interactions with lattice vibrations, is a proposed trapping mechanism, direct evidence of such states has been elusive. Here, we use potential-dependent transient absorption spectroscopy to identify the coherent phonon mode and strong exciton–phonon coupling responsible for exciton–polaron formation after band gap excitation in α-hematite and identify the three underlying d–d transitions that are strongly modulated by this phonon. The equilibrium geometry of exciton–polarons in α-hematite is displaced from the ground state geometry along the vibrational coordinate of an A 1g symmetric Fe–O stretching motion at 225 ± 7 cm –1 , resulting in vibrational coherence with a lifetime of 1.9 ± 0.1 ps. Our comparative ex situ and in situ experiments reveal that the energy and dephasing time of the A 1g mode are remarkably resilient to applied potential and the addition of an Al 2 O 3 overlayer; however, the dephasing time is sensitive to substrate identity. Furthermore, this potential-dependent transient absorption approach establishes a powerful platform for directly probing polaron dynamics in photoelectrochemical systems, opening new pathways to rationally design modified hematite and other transition metal oxide electrodes with enhanced charge transport properties for more efficient solar water splitting.

Hematite↗

The possibility of hydrogen-water demixing in Uranus, Neptune, K2-18 b and TOI-270 d

Context. The internal structures of Uranus and Neptune remain unknown. In addition, sub-Neptunes are now thought to be the most common type of exoplanets. Improving our understanding of the physical processes that govern the interiors of such planets is therefore essential. Phase separation between planetary constituents may occur, in particular, hydrogen-water immiscibility in cold, water-rich intermediate-mass planets. Aims. We assess whether hydrogen-water demixing could occur in Uranus, Neptune, K2-18 b and TOI-270 d, and investigate its effect on the planetary evolution and inferred internal structure. Methods. We couple planetary evolution models with recent ab initio calculations of the hydrogen-water phase diagram, allowing for temperature shifts to account for uncertainties in miscibility gaps. Results. We find that demixing may occur and could lead to a complete depletion of water in the outermost regions of Uranus and Neptune. Temperature offsets of up to 1100 K lead to a depleted region comprising as much as 16% of the planet’s mass, and an increase in planetary radius by nearly 20%. For K2-18 b, our models suggest that hydrogen-water demixing is ongoing and may explain the absence of water features in its JWST spectrum. A temperature offset of 500 K is required to get a complete depletion of water in the atmosphere of K2-18b. TOI-270d may also have experienced hydrogen-water demixing. When applying a similar temperature offset on the phase diagram as for K2-18 b, we find a partial depletion of water in the atmosphere of TOI-270 d, consistent with JWST’s detection of water. Conclusions. Hydrogen-water immiscibility may play a key role in shaping the structure and evolution of both Solar System giant planets like Uranus and Neptune, and cold/temperate exoplanets such as K2-18 b and TOI-270 d. Accounting for such internal processes is crucial to accurately interpret atmospheric observations from current (e.g., JWST) and upcoming (e.g., ARIEL) missions.

planets and satellites: composition↗

Mariner Mars 1971 project. Volume 3: Mission operations system implementation and standard mission flight operations

The Mariner Mars 1971 mission which was another step in the continuing program of planetary exploration in search of evidence of exobiological activity, information on the origin and evolution of the solar system, and basic science data related to the study of planetary physics, geology, planetology, and cosmology is reported. The mission plan was designed for two spacecraft, each performing a separate but complementary mission. However, a single mission plan was actually used for Mariner 9 because of failure of the launch vehicle for the first spacecraft. The implementation is described, of the Mission Operations System, including organization, training, and data processing development and operations, and Mariner 9 spacecraft cruise and orbital operations through completion of the standard mission from launch to solar occultation in April 1972 are discussed.

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Accumulation processes in the primitive solar nebula.

Particle accumulation processes are discussed for a variety of physical environments, ranging from the collapse phase of an interstellar cloud to the different parts of the models of the primitive solar nebula constructed by Cameron and Pine (1973). The interstellar collapse phase, the settling of particles to the control plane, processes in the convective zone, the accumulation of planetary bodies, and gas accretion are discussed. Attention is given to the formation of satellites, angular momentum aspects of star formation, the formation of comets, the formation of Mercury, the T Tauri solar wind, the evolution of the terrestrial planets, the radial distances of the planets, and the dissipation of excess solids.

Cameron, A. G. W.↗

On the primordial condensation and accretion environment and the remanent magnetization of meteorites

In the context of various models for the early evolution of a solar nebula, the possible roles assigned to ambient magnetic fields and the paleointensities required to establish the stable natural remanent magnetization observed in meteorites, are discussed. It is suggested that the record of paleofields present during condensation, growth, and accumulation of grains is likely to have been preserved as chemical or thermochemical remanence in unaltered meteoritic material. Fine particle theories appear adequate for treating meteoritic remanence, if models based on corresponding types of permanent magnet materials, e.g., powder ferrites for chondrites and diffusion hardened alloys for iron meteorites, are adopted.

Brecher, A.↗

Lunar interactions: Abstracts of papers presented at the Conference on Interactions of the Interplanetary Plasma with the Modern and Ancient Moon

Reviewed are the active mechanisms relating the moon to its environment and the linkage between these mechanisms and their records in the lunar sample and geophysical data. Topics: (1) large scale plasma interactions with the moon and non-magnetic planets; (2) ancient and present day lunar surface magnetic and electric fields; (3) dynamics and evolution of the lunar atmosphere; (4) evolution of the solar plasma; (5) lunar record of solar radiations; (6) non-meteoritic and meteoritic disturbance and transport of lunar surface materials; and (7) future lunar exploration.

Criswell, D. R.↗

Exploring Jupiter and its satellites with an orbiter

Review of the initial studies that define a challenging Mariner Jupiter Orbiter mission. Elegant and precise astrodynamics are shown to make possible a bravura examination of the entire Jovian system with two Mariner-class spacecraft to be launched in 1981. This mission is expected to advance considerably our understanding of the origin and evolution of the solar system.

Beckman, J. C.↗

A primer in lunar geology

Primary topics in lunar geology range from the evolution of the solar system to lunar photointerpretation, impact crater formation, and sampling to analyses on various Apollo lunar landing site geomorphologies.

Greeley, R.↗

Morphological evolution of X-ray flare structures from the rise through the decay phase

The morphological evolution of 12 solar X-ray subflares from onset through the decay phase has been studied using photographic X-ray images obtained from Skylab. The spatial configurations are found to vary widely from flare to flare, but they appear to be composed of two basic kinds of structures. The first, termed 'X-ray kernels', are brightest during the rise phase; the second, looplike structures, appear during the maximum and decay phases of the event. The X-ray kernels are small pointlike structures which may be related to the nonthermal phases of flares.

Kahler, S. W.↗

New horizons

The contribution of space exploration and space related research to the future of man and the accomplishments of the space program are assessed. Topics discussed include: the role of applications satellites in crop surveillance, land use surveys, weather forecasting, education, communications, and pollution monitoring; planetary studies which examine the origin and evolution of the solar system, including dynamic processes that bear directly on earth's environment; and fuel conservation and development of new energy sources.

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Preliminary design and performance of an advanced gamma ray spectrometer for future orbiter missions

A knowledge of the composition of planets, satellites, and asteroids is of primary importance in understanding the formation and evolution of the solar system. Gamma-ray spectroscopy is capable of measuring the composition of meter-depth surface material from orbit around any body possessing little or no atmosphere. Measurement sensitivity is determined by detector efficiency and resolution, counting time, and the background flux while the effective spatial resolution depends upon the field-of-view and counting time together with the regional contrast in composition. The advantages of using germanium as a detector of gamma rays in space are illustrated experimentally and a compact instrument cooled by passive thermal radiation is described. Calculations of the expected sensitivity of this instrument at the Moon and Mars show that at least a dozen elements will be detected, twice the number which have been isolated in the Apollo gamma-ray data.

Metzger, A. E.↗

Voyager: Journey to the outer planets

The mission plan of the Voyager Spacecraft to Jupiter, Saturn, and their satellites is briefly discussed. Emphasis is placed on the study of the origin and evolution of the solar system.

Source record↗

Chemical abundances in the atmospheres of the giant planets and their satellites

Recent results on the composition and structure of the atmospheres of Jupiter, Saturn, Uranus, Neptune, Pluto, and their satellites are summarized with an orientation toward topics of particular interest to the subject of exobiology. The need for an accurate Jovian temperature profile is noted, and current values are given for the known H2, NH3, and CH4 abundances of each planet as well as Titan and Triton. Trace constituents and chromophores in the Jovian atmosphere are discussed, the role of comets as a link between chemical evolution in the solar system and the chemistry of the interstellar medium is examined, and some features in the IR spectrum of Titan are interpreted. The hope is expressed that Titan will remain a useful proving ground for theories of low-temperature abiogenic organic-compound production

Owen, T.↗