Search NASA⌕ Search

SEARCH · Search NASA

Results for “Surface diffusion”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 487 records · Page 27
All sourcesNASA NTRSDOE OSTI
NASA NTRS1979

Laser-stimulated migration of adsorbed atoms on solid surfaces

This paper presents a unified theory of the coherent, multiple-photon excitation and laser-stimulated migration of atoms adsorbed on solid surfaces. We show that under steady-state excitation the migration of the adsorbed atom on the surface is diffusional, with diffusion constant dependent upon field intensity, surface temperature, relaxation constants, dipole moment strength, laser frequency, and the vibrational frequency of the adsorbed atom. In particular, it is shown that the rate of diffusion is proportional to the field intensity. Finally, we discuss the utility of laser-stimulated migration in the enhancement of surface chemical reactions, as well as in the analysis of surface relaxational processes.

Slutsky, M. S.↗
DOE OSTI2020

Tritium species diffusion on and desorption from γ-LiAlO 2 (100) surface: A first-principles investigation

γ-LiAlO 2 enriched in the 6 Li isotope is a good candidate for tritium (T, 3 H) production in nuclear reactor. In this work, to better understand its 3 H production performance, first-principles calculations are performed to study the 3 H-related species diffusion on and desorption from the γ-LiAlO 2 (100) surface. For the diffusion process, we investigate the pathways and energy barriers for the T and OT diffusion on the pristine and defective γ-LiAlO 2 (100) surfaces. Our results reveal that the O and Li/Al atoms of the surface layer play important roles for T and OT diffusion, respectively. By comparing with its diffusion barrier in bulk γ-LiAlO 2 , the order of energy barrier for T diffusion is: bulk < surface < defective surface, which is reversed for OT diffusion. Space is the prime factor for OT diffusion, while diffusion-mediating atom instead of space becomes the key factor for T diffusion. For the desorption process, we investigate the 3 H-related species (T, OT, T 2 , and T 2 O) desorption from the γ-LiAlO 2 (100) surface. The desorption energies we obtained are so high that the desorption behavior of all the 3 H-related species is nearly prohibited. We expect the possible T 2 or T 2 O release from the large accumulation of 3 H atoms on the surface.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
NASA NTRS2022

SKYSURF: Constraints on Zodiacal Light and Extragalactic Background Light through Panchromatic HST All-sky Surface-brightness Measurements: II. First Limits on Diffuse Light at 1.25, 1.4, and 1.6 μm

We present the first results from the HST Archival Legacy project "SKYSURF." As described in Windhorst et al., SKYSURF utilizes the large HST archive to study the diffuse UV, optical, and near-IR backgrounds and foregrounds in detail. Here, we utilize SKYSURF's first sky-surface-brightness measurements to constrain the level of near-IR diffuse Extragalactic Background Light (EBL) in three near-IR filters (F125W, F140W, and F160W). This is done by comparing our preliminary sky measurements of >30,000 images to zodiacal light models, carefully selecting the darkest images to avoid contamination from stray light. Our sky-surface-brightness measurements have been verified to an accuracy of better than 1%, which when combined with systematic errors associated with HST, results in sky-brightness uncertainties of ∼ 2%–4% ≃ 0.005 MJy sr−1 in each image. When compared to the Kelsall et al. zodiacal model, an isotropic diffuse background of ∼30 nW m−2 sr−1 remains, whereas using the Wright zodiacal model results in no discernible diffuse background. Based primarily on uncertainties in the foreground model subtraction, we present limits on the amount of diffuse EBL of 29, 40, and 29 nW m−2 sr−1, for F125W, F140W, and F160W, respectively. While this light is generally isotropic, our modeling at this point does not distinguish between a cosmological origin or a solar system origin (such as a dim, diffuse, spherical cloud of cometary dust).

Timothy Carleton↗
DOE OSTI2025

Effects of Temperature Fluctuations on Surface Mobility of Atomic Steps and Oxidation Dynamics in High-Temperature Alloys

In contrast to the traditional perspective that thermal fluctuations are insignificant in surface dynamics, here we report their influence on surface reaction dynamics. Using real-time low-energy electron microscopy imaging of NiAl(100) under both vacuum and O 2 atmospheres, we demonstrate that transient temperature variations substantially alter the direction of atom diffusion between the surface and bulk, leading to markedly different oxidation outcomes. During heating, substantial outward diffusion of atoms from the bulk to the surface results in step growth. Conversely, cooling induces considerable inward diffusion of adatoms, producing a distinct oxide morphology. In both scenarios, initially formed oxide islands impede local atomic step mobility, thereby increasing step length due to mass transfer between the surface and bulk, with atomic steps acting as adatom sinks during heating and sources during cooling. Furthermore, we show that this pinning effect on atomic step mobility can be mitigated by applying persistent temperature fluctuations. As a result, understanding these nuances is vital for accurately predicting and dynamically manipulating the performance of active materials in various chemical processes under transient thermal conditions.

36 MATERIALS SCIENCE↗
DOE OSTI2023

Energetics of silicon in the bulk and near surfaces of tungsten: a first-principles study

Abstract Siliconization of the tokamak walls is a candidate method to improve plasma confinement in fusion tokamaks containing tungsten plasma facing components (W PFCs). To understand the interactions of silicon (Si) with W, the Si behavior in bulk W, and near three low-index W surfaces ((100), (110) and (111)) has been investigated using first-principles density functional theory. In bulk W, Si interstitial atoms have a low solution ability and high mobility, and Si atoms can be strongly trapped by W vacancies. The interaction between two Si adatoms is responsible for the stability of adatom superstructures on W surfaces, consistent with previous experimental observation (Tsong and Casanova 1981 Phys. Rev. Lett. 47 113). Although the coverage dependence of Si adsorption and diffusion energetics on surfaces is related to surface orientation, the W(110) surface has lower Si adsorption affinity and higher Si diffusivity than either the W(111) or W(100) surfaces. The most stable Si adatom superstructure on W surfaces is: square c(2 × 2) pattern on W(100) covered with 0.5 ML Si; rectangular c(4 × 2) pattern on W(110) with 0.25 ML Si; and rhombus p(1 × 1) pattern on W(111) with 1 ML Si. The coverage dependence of Si mobility on/toward W surfaces is generally related to the stability of the Si superstructures as a function of coverage on each surface. Interestingly, Si adatoms prefer to transport below the surface and into W subsurface by an exchange mechanism with W atoms, indicating the likelihood of epitaxial growth of W silicide layers on W surfaces during the operation of W PFCs.

Yang, L. (ORCID:0000000322166071)↗
DOE OSTI2019

Ultrafast probes at the interfaces of solar energy conversion materials

Ultrafast carrier dynamics at interfaces plays a major role in governing solar energy conversion efficiency in solar conversion systems, especially in solar cells and photoelectrochemical devices. Here, we discuss recent advances in ultrafast spectroscopic probes to understand the dynamics at such interfaces. Transient reflectance (TR) enables monitoring of the surface carriers that are within ~10 nm of the surface or interface of interest. Crucial parameters such as surface recombination velocity and carrier diffusion can be determined. When a strong surface or interfacial field is present the reflectance spectrum will exhibit Franz–Kelydesh oscillations. Monitoring the transient formation or decay of such oscillations informs about the interfacial field and is referred to as transient photoreflectance (TPR). Such fields are helpful in designing systems in order to move carriers away from surfaces where photocorrosion can occur and towards catalytic surfaces. Finally, we discuss transient infrared attenuated total reflection (TATR) to probe the ultrafast reaction intermediates in a photo-driven chemical reaction.

14 SOLAR ENERGY↗
NASA NTRS1995

New upper limits on the local metagalactic ionizing radiation density

We have obtained H-alpha observations with the Maryland-Caltech Fabry-Perot Spectrometer attached to the Cassegrain focus of the 1.5 m telescope at Palomer Observatory in order to set limits on the number of ionizing photons from the local metagalactic radiation field. We have observed the SW component of the Haynes-Giovanelli cloud H I 1225+01, an intergalactic cloud which should be optimum for measuring the metagalactic flux because it is nearly opaque to ionizing photons, it does not appear to be significantly shielded from the metagalactic radiation field, and the limits on embedded or nearby ionizing sources are unusually low. For the area of the cloud with an H I column density greater than 10(exp 19)/sq cm we set a 2 sigma limit of 1.1 x 10(exp -19) ergs/sq cm/s/sq arcsec (20 mR) for the surface brightness of diffuse H-alpha. This implies a 2 sigma upper limit on the incident one-sided ionizing flux of Phi(sub ex) is less than 3 x 10(exp 4)/sq cm/s. For a radiation field of the form J(sub nu) is approximately nu(exp -1.4), this yields a firm 2 sigma upper limit on the local metagalactic photoionization rate of Gamma is less than 2 x 10(exp -13)/s, and an upper limit for the radiation field J(sub nu) at the Lyman limit of J(sub nu0) is less than 8 x 10(exp -23) ergs/sq cm/Hz/sr. We discuss previous efforts to constrain the metagalactic ionizing flux using H-alpha surface brightness observations and also other methods, and conclude that our result places the firmest upper limit on this flux. We also observed the 7 min diameter region centered on 3C 273 in which H-alpha emission at a velocity of approximately 1700 km/s was initially reported by Williams and Schommer. In agreement with T. B. Williams (private communication) we find the initial detection was spurious. We obtain a 2 sigma upper limit of 1.8 x 10(exp -19) ergs/sq cm/s/sq arcsec (32 mR) for the mean surface brightness of diffuse H-alpha, about a factor of 6 below the published value.

Vogel, Stuart N.↗
NASA NTRS1987

Simulation studies for surfaces and materials strength

Three different investigations based on computer simulations were carried out. Simulation calculations were performed using model potentials with two- and three-body interactions which were represented by the Mie and the Axilrod-Teller potentials, respectively. In the first part, to analyze stability criteria for simple crystals, a parametrical investigation was performed and stability regions for five different crystalline structures were determined with respect to potential energy parameters. To simulate some of the basic surface processes such as diffusion and nucleation, in the second and third parts, silicon surfaces were considered as a specific example. In these studies diffusion of adatoms on stepped surfaces were simulated and energetics associated with the formation of kink sites were calculated.

Halicioglu, Timur↗
NASA NTRS1989

A search for X-ray emission associated with the great attractor

A search is reported for X-ray emission associated with the object, dubbed the 'great attractor', which has been postulated as the cause of the coherent deviations from the Hubble flow which are observed in nearby parts of the universe. The hypothesis that a substantial fraction of the dynamical mass of the great attractor exists in the form of rich clusters of galaxies is ruled out. The possibility is considered that a substantial fraction of the mass of the great attractor could exist in a form which would increase the apparently diffuse X-ray surface brightness. The observational upper limit to the diffuse X-ray sky surface brightness enhancement in the general direction of the great attractor allows interesting limits to be set on the fraction of the dynamical mass of the great attractor which can exist in the form of X-ray-luminous material.

Jahoda, Keith↗
NASA NTRS1979

Theoretical study of VTOL tilt-nacelle axisymmetric inlet geometries

A systematic theoretical study of VTOL tilt-nacelle inlet design parameters is reported. The parameters considered are internal-lip contraction ratio, internal-lip major-to-minor axis ratio, diffuser-exit-area to throat-area ratio, maximum diffuser wall angle and shape. Each of the inlets was analyzed at the same given flow condition of free-stream velocity, angle between the free stream and centerline of the inlet, and diffuser-exit Mach number. The effects of these geometric parameters on surface static-pressure distribution, peak surface Mach number, diffusion velocity ratio, and tendency for the inlet flow to separate are presented.

Hawk, J. D.↗
NASA NTRS1979

Development of Surfaces Optically Suitable for Flat Solar Panels

A reflectometer which can separately evaluate the spectral and diffuse reflectivities of surfaces is described. A phase locked detection system for the reflectometer is also described. A selective coating on aluminum potentially useful for flat plate solar collector applications is presented. The coating is composed of strongly bound copper oxide (divalent) and is formed by an etching process performed on an aluminum alloy with high copper content. Fabrication costs are expected to be small due to the one stop fabrication process. A number of conclusions gathered from the literature as to the required optical properties of flat plate solar collectors are discussed.

Source record↗
DOE OSTI2019

Dilute Pd/Au Alloy Nanoparticles Embedded in Colloid-Templated Porous SiO 2 : Stable Au-Based Oxidation Catalysts

Dilute alloy materials hold great promise for enhancing selectivity in catalytic reactions. A major challenge with such catalytic materials is developing supported alloy nanoparticles (NPs) with a catalytically optimal composition that are stable with respect to sintering. Here, we demonstrate that NP Pd/Au catalysts with minor concentrations of Pd prepared by a colloid-templating approach are active for oxygen dissociation and catalytic oxidation, as exemplified by CO oxidation. Using electron microscopic imaging, infrared spectroscopy, and X-ray photoelectron spectroscopy, we demonstrate that Pd is stabilized within the Au nanoparticle in its metallic state with minor amounts of Pd at the surface. The Pd–Au nanoparticles are embedded in the colloidally templated silica and form a thermally stable catalyst at high temperature. Surface analysis by diffuse reflectance infrared spectroscopy indicates that the Pd atomic distribution at the surface varies with the bulk concentration, forming isolated Pd atoms at 2% Pd and a mixture of Pd monomers and small Pd clusters at 9% Pd. X-ray absorption fine structure analysis indicates that Pd is well distributed in the bulk of the nanoparticle. In conclusion, in-depth understanding of this new class of catalytic materials opens the way to a wide array of possibilities for crucial enhancement of activity and selectivity in catalysis.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2024

Significance of Low‐Velocity Zones on Solute Retention in Rough Fractures

Natural fractures are characterized by high internal heterogeneity. This internal variability is the cause of flow channeling, which in turn leads to contaminant transport taking place primarily along the high-velocity channels. Mass exchange between the high-velocity channels and the low-velocity zones has the potential to enhance contaminant retention, due to solute diffusion into the low-velocity zones and subsequent exposure to additional surface area for diffusion into the bordering rock matrix. Here, we derive a random walk particle tracking method for heterogeneous fractures, which includes an additional term to account for the aperture gradient. The method takes into account advection, diffusion in the fracture and matrix diffusion. The developed numerical framework is applied to assess the effect of low-velocity zones in rough self-affine fractures. The results show that diffusion into low-velocity zones has a visible but modest impact on contaminant retention. The magnitude of this impact does not change considerably, regardless of whether diffusion into the rock matrix is considered in the model, and increases for a decreasing average Péclet number of the fracture.

58 GEOSCIENCES↗
DOE OSTI2026

Electropolishing-induced topographic defects in niobium: insights and implications for superconducting radio frequency applications

Electropolishing (EP) is the premier surface preparation method for high-Q, high-gradient superconducting RF cavities made of Nb. This leaves behind an apparently smooth surface, yet the achievable peak magnetic fields fall well below the superheating field of Nb, in most cases. Here, in this work, the ultimate surface finish of EP was investigated by studying its effect on highly polished Nb samples. EP introduces high slope angle sloped-steps at grain boundaries. The magnetic field enhancement and superheating field suppression factors associated with such a geometry are calculated in the London theory. Despite the by-eye smoothness of electropolished Nb, such defects compromise the stability of the low-loss Meissner state, likely limiting the achievable peak accelerating fields in superconducting RF cavities. Finally, the impact of surface roughness on impurity diffusion is investigated which can link surface roughness to the effectiveness of heat treatments like low-temperature baking or nitrogen infusion in the vortex nucleation or hydride hypotheses. Surface roughness tends to decrease the effective dose of impurities as a result of the expansion of impurities into regions with greater internal angle. The effective dose of impurities can be protected by minimizing slope angles and step heights, ensuring uniformity.

Hryhorenko, Oleksandr [Thomas Jefferson National A↗
DOE OSTI2026

Electropolishing-induced topographic defects in niobium: Insights and Implications for SRF

Electropolishing (EP) is the premier surface preparation method for high-Q, high-gradient superconducting RF cavities made of Nb. This leaves behind an apparently smooth surface, yet the achievable peak magnetic fields fall well below the superheating field of Nb, in most cases. In this work, the ultimate surface finish of EP was investigated by studying its effect on highly polished Nb samples. EP introduces high slope angle sloped-steps at grain boundaries. The magnetic field enhancement and superheating field suppression factors associated with such a geometry are calculated in the London theory. Despite the by-eye smoothness of electropolished Nb, such defects compromise the stability of the low-loss Meissner state, likely limiting the achievable peak accelerating fields in superconducting RF cavities. Finally, the impact of surface roughness on impurity diffusion is investigated which can link surface roughness to the effectiveness of heat treatments like low-temperature baking or nitrogen infusion in the vortex nucleation or hydride hypotheses. Surface roughness tends to decrease the effective dose of impurities as a result of the expansion of impurities into regions with greater internal angle. The effective dose of impurities can be protected by minimizing slope angles and step heights, ensuring uniformity.

Lechner, Eric [Thomas Jefferson National Accelerat↗
NASA NTRS1983

Application of modern surface analytical tools in the investigation of surface deterioration processes

Surface profilometry and scanning electron microscopy were utilized to study changes in the surface of polymers when eroded. The X-ray photoelectron spectroscopy (XPS) and depth profile analysis indicate the corrosion of metal and ceramic surfaces and reveal the diffusion of certain species into the surface to produce a change in mechanical properties. Ion implantation, nitriding and plating and their effects on the surface are characterized. Auger spectroscopy analysis identified morphological properties of coatings applied to surfaces by sputter deposition.

Buckley, D. H.↗
NASA NTRS1988

Noncontact true temperature measurement, 2

A laser pyrometer was developed for acquiring the true temperature of a levitated sample. The reflectivity is measured by first expanding the laser beam to cover the entire cross-sectional surface of the diffuse target. The reflectivity calibration of this system is determined from the surface emissivity of a target with a blackbody cavity. The emissivity of the real target can then be calculated. The overall system constant is obtained by passively measuring the radiance of the blackbody cavity (emissivity = 1.0) at a known, arbitrary temperature. Since the photosensor used is highly linear over the entire operating temperature range, the true temperature of the target can then be computed. The latest results available from this on-going research indicate that true temperatures thus obtained are in very good quantitative agreement with thermocouple measured temperatures.

Lee, Mark C.↗