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At least 487 records · Page 27

Thermal remote sensing of surface soil water content with partial vegetation cover for incorporation into climate models

This study outlines a method for the estimation of regional patterns of surface moisture availability (M(sub 0)) and fractional vegetation (Fr) in the presence of spatially variable vegetation cover. The method requires relating variations in satellite-derived (NOAA, Advanced Very High Resolution Radiometer (AVHRR)) surface radiant temperature to a vegetation index (computed from satellite visible and near-infrared data) while coupling this association to an inverse modeling scheme. More than merely furnishing surface soil moisture values, the method constitues a new conceptual and practical approach for combining thermal infrared and vegetation index measurements for incorporating the derived values of M(sub 0) into hydrologic and atmospheric prediction models. Application of the technique is demonstrated for a region in and around the city of Newcastle upon Tyne situated in the northeast of England. A regional estimate of M(sub 0) is derived and is probabbly good for fractional vegetation cover up to 80% before errors in the estimated soil water content become unacceptably large. Moreover, a normalization scheme is suggested from which a nomogram, `universal triangle,' is constructed and is seen to fit the observed data well. The universal triangle also simplifies the inclusion of remotely derived M(sub 0) in hydrology and meteorological models and is perhaps a practicable step toward integrating derived data from satellite measurements in weather forecasting.

Gillies, Robert R.↗

Landsat - What is operational in water resources

Applications of Landsat data in hydrology and water quality measurement were examined to determine which applications are operational. In hydrology, the principal applications have been surface water inventory, and land cover analysis for (1) runoff modeling and (2) abatement planning for non-point pollution and erosion. In water quality measurement, the principal applications have been: (1) trophic state assessment, and (2) measurement of turbidity and suspended sediment. The following applications were found to be operational: mapping of surface water, snow cover, and land cover (USGS Level 1) for watershed applications; measurement of turbidity, Secchi disk depth, suspended sediment concentration, and water depth.

Middleton, E. M.↗

Lower Illinois River Valley Ecological Forecasting: Inundation Mapping of the Lower Illinois River Valley Using Synthetic Aperture Radar and Optical Satellite Imagery for Wetland Conservation and Restoration Prioritization Efforts

The Lower Illinois River Valley (LIRV) is home to some of the richest agricultural lands in the United States and its wetlands provide key ecosystem services like clean water and flood reduction. It has also experienced extensive degradation due to development and urban pollution. The Great Rivers Land Trust (GRLT), the National Great Rivers Research & Education Center, Principia College, and the American Geophysical Union’s (AGU) Thriving Earth Exchange sought to incorporate inundation and surface water extent layers into their geodatabases to more accurately identify priority areas for wetland restoration. This project aimed to determine the feasibility of detecting inundation extent and duration along the valley using remotely sensed data. The team used Sentinel-1 C-band Synthetic Aperture Radar (SAR) data to classify open water and inundated vegetation within the study site. The open water classification was compared to Dynamic Surface Water Extent (DSWE) derived from Landsat 8 Operational Land Imager. The team successfully created layers of inundation minimum and maximum extent, as well as inundation duration across the study area for 2019 and 2020. The open water classification resulted in an overall accuracy of 86% when validated against DSWE classifications. These analyses will help end users to identify high priority areas along the LIRV best suited for land conversion projects in the future.

Vanessa Machuca↗

Lower Illinois River Valley Ecological Forecasting: Inundation Mapping of the Lower Illinois River Valley Using Synthetic Aperture Radar and Optical Satellite Imagery for Wetland Conservation and Restoration Prioritization Efforts

The Lower Illinois River Valley (LIRV) is home to some of the richest agricultural lands in the United States and its wetlands provide key ecosystem services like clean water and flood reduction. It has also experienced extensive degradation due to development and urban pollution. The Great Rivers Land Trust (GRLT), the National Great Rivers Research & Education Center, Principia College, and the American Geophysical Union’s (AGU) Thriving Earth Exchange sought to incorporate inundation and surface water extent layers into their geodatabases to more accurately identify priority areas for wetland restoration. This project aimed to determine the feasibility of detecting inundation extent and duration along the valley using remotely sensed data. We used Sentinel-1 C-band Synthetic Aperture Radar (SAR) data to classify open water and inundated vegetation within the study site. The open water classification was compared to Dynamic Surface Water Extent(DSWE) derived from Landsat 8 Operational Land Imager. We successfully created layers of inundation minimum and maximum extent, as well as inundation duration across the study area for 2019 and 2020. The open water classification resulted in an overall accuracy of 86% when validated against DSWE classifications. These analyses will help end users to identify high priority areas along the LIRV best suited for land conversion projects in the future.

Vanessa Machuca↗

Correcting airborne scanning infrared radiometer measurements for atmospheric effects

Two techniques were developed for determining atmospheric corrections from observations made by a scanning radiometer. Both techniques depend on knowing the radiometer's limb function. The limb function for an RS-18 scanning radiometer is derived from calculations made with a radiation model and used to demonstrate the techniques. One technique requires observations made over an isothermal water surface within the area being remotely sensed. The other technique does not depend on an isothermal water surface but requires a boat measurement of radiometric sea surface temperature within the area being remotely sensed. The radiation model used to derive the limb function does not account for the effects of atmospheric particulates on the correction. It is hypothesized that the effect of particulates on the limb function derived in this study is negligible, and therefore the technique essentially obtains the total correction. The techniques developed can be used over land provided that a section of isothermal land exists within the experiment area or that a radiometric measurement of surface temperature is made at the surface.

Boudreau, R. D.↗

ResORR: A Globally Scalable and Satellite Data-Driven Algorithm for River Flow Regulation Due to Reservoir Operations

We propose a globally scalable algorithm, ResORR (Reservoir Operations driven River Regulation), to predict regulated river flow and tested it over the heavily regulated basin of the Cumberland River in the US. ResORR was found able to model regulated river flow due to upstream reservoir operations of the Cumberland River. Over a mountainous basin dominated by high rainfall, ResORR was effective in capturing extreme flooding modified by upstream hydropower dam operations. On average, ResORR improved regulated river flow simulation by more than 50% across all performance metrics when compared to a hydrologic model without a regulation module. ResORR is a timely software algorithm for understanding human regulation of surface water as satellite-estimated reservoir state is expected to improve globally with the recently launched Surface Water and Ocean Topography (SWOT) mission.

River Regulation↗

A Cold Wet Mars: A Testable Hypothesis for Ancient Mars Ocean Freezing Point Depression Via Low Molecular Weight Organics

Mars exhibits widespread evidence of surface water in the distant past, but global modeling has had difficulty producing climatological conditions conducive to a wet surface. The hypothesis discussed here examines a different way of approaching the problem rather than focusing on climate, instead an examination of the nature of the surface liquid itself. Previous work has largely assumed that martian surface water was a brine analogous to terrestrial ocean water, but recent discoveries suggest that significant amounts of light organic compounds may have been present via abiogenic native production of light organics on Mars [1]. Light organics such as methanol and formaldehyde have an approximate order-of-magnitude greater freezing point depression than brine, potentially lowering the freezing point of martian surface fluids sufficiently to remain liquid even if the mean surface temperature is below zero Centigrade. As Mars evolved and the surface transitioned to the strongly oxidized conditions seen today, the light organics would have oxidized to carbon dioxide and may be a constituent of the atmosphere today. Considerable work must be done to constrain the freezing points of Mars-relevant organic/water and organic/salt/water mixtures, but this investigation might explain the presence of surface fluid on a cold early Mars – a cold, wet Mars as opposed to a warm, wet Mars. Additionally, this approach may work in conjunction with climatological modeling to better describe early conditions conducive which adequately explain observations. This hypothesis can be tested by examination of ancient fluid inclusions (either in situ or via Mars Sample Return) such as those commonly found in halite, preserving samples of ancient martian surface fluid.

M D Fries↗

Optical technique for measurement of random water wave surfaces

An optical system using the refraction of a vertical light ray has been developed for measuring the slope of random wind-generated water waves. The basic elements of the system are photovoltaic cells which are connected to individual amplifiers so that when the refracted light beam is incident on a cell, the output of the cell is amplified and then supplied as input to a comparator. The comparator then provides a specified voltage output, independent of the incident light intensity, as long as it is above a designated background value. The comparators are designed to give output voltages comparable with standard TTL. This arrangement provides a high signal from the cell when it experiences incident light, and a low signal when there is only background light, with the high and low signals at TTL voltage levels.

Sorrell, F. Y.↗

SWOT Applications for WRF-Hydro Modeling in Alaska

The Surface Water Ocean Topography (SWOT) mission, launching next year, will provide high-spatial resolution measurements of terrestrial surface water, including global rivers with widths greater than 50-100 m. SWOT measurements are naturally suited for stream hydrology, and many previous studies have worked to quantify the impact of SWOT observations on the modeling of channel flow. This work highlights the application of SWOT for WRF-Hydro modeling in Alaska for data assimilation and model calibration to support ongoing National Oceanic and Atmospheric Administration (NOAA) National Water Model development. Results demonstrate the effectiveness of using SWOT discharge estimates to calibrate WRF-Hydro in ungauged basins, and quantifies the impact of SWOT data assimilation on WRF-Hydro performance.

Nicholas Elmer↗

Organizational Principles of Hyporheic Exchange Flow and Biogeochemical Cycling in River Networks Across Scales

Hyporheic zones increase freshwater ecosystem resilience to hydrological extremes and global environmental change. However, current conceptualizations of hyporheic exchange, residence time distributions, and the associated biogeochemical cycling in streambed sediments do not always accurately explain the hydrological and biogeochemical complexity observed in streams and rivers. Specifically, existing conceptual models insufficiently represent the coupled transport and reactivity along groundwater and surface water flow paths, the role of autochthonous organic matter in streambed biogeochemical functioning, and the feedbacks between surface-subsurface ecological processes, both within and across spatial and temporal scales. While simplified approaches to these issues are justifiable and necessary for transferability, the exclusion of important hyporheic processes from our conceptualizations can lead to erroneous conclusions and inadequate understanding and management of interconnected surface water and groundwater environments. This is particularly true at the landscape scale, where the organizational principles of spatio-temporal dynamics of hyporheic exchange flow (HEF) and biogeochemical processes remain largely uncharacterized. This article seeks to identify the most important drivers and controls of HEF and biogeochemical cycling based on a comprehensive synthesis of findings from a wide range of river systems. We use these observations to test current paradigms and conceptual models, discussing the interactions of local-to-regional hydrological, geomorphological, and ecological controls of hyporheic zone functioning. This improved conceptualization of the landscape organizational principles of drivers of HEF and biogeochemical processes from reach to catchment scales will inform future river research directions and watershed management strategies.

54 ENVIRONMENTAL SCIENCES↗

Central America Disasters: Using Earth Observations to Map Flooding for Disaster Monitoring, Inform Potential Risk, and Prepare for Possible Response

In November 2020, Hurricanes Eta and Iota hit Central America within weeks of each other, causing severe flooding, landslides, and widespread damage. NASA DEVELOP partnered with Comité Regional de Recursos Hidráulicos (CRRH), Centro de Coordinación para la Prevención de los Desastres en América Central y República Dominicana (CEPREDENAC), and Sistema de la Integración Centroamericana (SICA) to better understand how flooding throughout Central America has impacted and will continue to affect communities, focusing on sites in Guatemala, Honduras, El Salvador, Belize, Nicaragua, western Panama, and eastern Costa Rica from January 2015 to October 2021. The team utilized surface reflectance data from Landsat 7 Enhanced Thematic Mapper Plus (ETM+), Landsat 8 Operational Land Imager (OLI), Sentinel-2 MultiSpectral Instrument (MSI), Suomi National Polar-orbiting Partnership (NPP) Visible Infrared Imaging Radiometer Suite (VIIRS), and Terra Moderate Resolution Imaging Spectroradiometer (MODIS). This project also utilized backscatter data from Sentinel-1 C-band Synthetic Aperture Radar (C-SAR) and elevation data from the Shuttle Radar Topography Mission (SRTM). Incorporating these Earth observations in NASA SERVIR’s Hydrologic Remote Sensing Analysis for Floods (HYDRAFloods) tool run on Google Earth Engine (GEE), the team produced historical surface water maps, a case study analysis of the two hurricanes, and a code tutorial. These results indicated that surface water increased in priority sites from 2015 to 2021, optical and SAR imagery detected similar flood patterns and extent after the hurricanes, and rainfall was concentrated on the east coast of the region. These products allow partners to make informed decisions around flooding preparation and disaster mitigation.

Caroline Williams↗

Former SLF Fire and Rescue Building SWMU #120 Per- and Polyfluoroalkyl Substances (PFAS) Site Assessment Work Plan

This Work Plan documents the proposed field sampling activities for a per- and polyfluoroalkyl substances (PFAS) Site Assessment at the Former Space Shuttle Landing Facility (SLF) Fire and Rescue Building (FRB) at Kennedy Space Center (KSC). The Work Plan provides a background of the historical activities that occurred at the SLF FRB, and the limited environmental investigations performed at the SLF FRB. The proposed Site Assessment activities at SLF FRB includes the collection of soil samples from eight locations, the advancement of a soil lithologic boring to 60 feet below ground surface, the installation of a staff gauge in site surface water, the installation of four monitoring wells, perform direct push groundwater sampling at seven locations, and collect one surface water sample. Sampling details, depths, and locations are presented in the Work Plan. The Work Plan was presented to the KSC Remediation Team in the form of an Advance Data Package in February 2023. Following STRIVES approval, the SLF FRB PFAS Site Assessment Work Plan will be formally submitted to the Florida Department of Environmental Protection.

Howard Franklin Fowler↗

Morpheus Test Area SWMU #119 Per- and Polyfluoroalkyl Substances (PFAS) Site Assessment Work Plan

This Work Plan documents the proposed field sampling activities for a per- and polyfluoroalkyl substances (PFAS) Site Assessment at the Morpheus Test Area (MTA) at Kennedy Space Center (KSC). The Work Plan provides a background of the historical activities that occurred at the MTA, and the limited environmental investigations performed at the MTA. The proposed Site Assessment activities at MTA includes the collection of soil samples from seven locations, the installation of a staff gauge in site surface water, the installation of four monitoring wells, perform direct push groundwater sampling at ten locations, and collect one surface water sample. Sampling details, depths, and locations are presented in the Work Plan. The Work Plan was presented to the KSC Remediation Team in the form of an Advance Data Package in February 2023. Following STRIVES approval, the SLF FRB PFAS Site Assessment Work Plan will be formally submitted to the Florida Department of Environmental Protection.

Howard Franklin Fowler↗

Application of aerial photography to water-related programs in Michigan

Aerial photography and information system technology were used to generate information required for the effective operation of three water-related programs in Michigan. Potential mosquito breeding sites were identified from specially acquired low altitude 70 mm color photography for the city of Lansing; the inventory identified 35% more surface water areas than indicated on existing field maps. A comprehensive inventory of surface water sources and potential access sites was prepared to assist fire departments in Antrim County with fire truck water-recharge operations. Remotely-sensed land cover/use data for Windsor Township, Eaton County, were integrated with other resource data into a computer-based information system for regional water quality studies. Eleven thematic maps focusing on landscape features affecting non-point water pollution and waste disposal were generated from analyses of a four-hectare grid-based data file containing land cover/use, soils, topographic and geologic (well-log) data.

Enslin, W. R.↗

Structure and energetics of model amphiphilic molecules at the water liquid-vapor interface - A molecular dynamics study

A molecular dynamics study of adsorption of p-n-pentylphenol at infinite dilution at the water liquid-vapor interface is reported. The calculated free energy of adsorption is -8.8 +/- 0.7 kcal/mol, in good agreement with the experimental value of -7.3 kcal/mol. The transition between the interfacial region and the bulk solution is sharp and well-defined by energetic, conformational, and orientational criteria. At the water surface, the phenol head group is mostly immersed in aqueous solvent. The most frequent orientation of the hydrocarbon tail is parallel to the interface, due to dispersion interactions with the water surface. This arrangement of the phenol ring and the alkyl chain requires that the chain exhibits a kink. As the polar head group is being moved into the solvent, the chain length increases and the tail becomes increasingly aligned toward the surface normal, such that the nonpolar part of the molecule exposed to water is minimized. The same effect was achieved when phenol was replaced by a more polar head group, phenolate.

Pohorille, Andrew↗

Promotion of oxygen reduction reaction on a double perovskite electrode by a water-induced surface modification

Highly efficient air electrodes are a key component of reversible fuel cells for energy storage and conversion; however, the development of efficient electrodes that are stable against water vapor remains a grand challenge. Here we report an air–electrode, composed of double perovskite material PrBa 0.8 Ca 0.2 Co 2 O 5+δ (PBCC) backbone coated with nanoparticles (NPs) of BaCoO 3-δ (BCO), that exhibits remarkable electrocatalytic activity for oxygen reduction reaction (ORR) while maintaining excellent tolerance to water vapor. When tested in a symmetrical cell exposed to wet air with 3 vol% H 2 O at 750 °C, the electrode shows an area specific resistance of ~0.03 Ω cm 2 in an extended period of time. The performance enhancement is attributed mainly to the electrocatalytic activity of the BCO NPs dispersed on the surface of the porous PBCC electrode. Moreover, in situ Raman spectroscopy is used to probe reaction intermediates (e.g., oxygen species) on electrode surfaces, as the electrochemical properties of the electrodes are characterized under the same conditions. The direct correlation between surface chemistry and electrochemical behavior of an electrode is vital to gaining insight into the mechanisms of the electrocatalytic processes in fuel cells and electrolysers.

25 ENERGY STORAGE↗

Conserving Land–Atmosphere Synthesis Suite (CLASS)

Accurate estimates of terrestrial water and energy cycle components are needed to better understand climate processes and improve models’ ability to simulate future change. Various observational estimates are available for the individual budget terms; however, these typically show inconsistencies when combined in a budget. In this work, a Conserving Land–Atmosphere Synthesis Suite (CLASS) of estimates of simultaneously balanced surface water and energy budget components is developed. Individual CLASS variable datasets, where possible, 1) combine a range of existing variable product estimates, and hence overcome the limitations of estimates from a single source; 2) are observationally constrained with in situ measurements; 3) have uncertainty estimates that are consistent with their agreement with in situ observations; and 4) are consistent with each other by being able to solve the water and energy budgets simultaneously. First, available datasets of a budget variable are merged by implementing a weighting method that accounts both for the ability of datasets to match in situ measurements and the error covariance between datasets. Then, the budget terms are adjusted by applying an objective variational data assimilation technique (DAT) that enforces the simultaneous closure of the surface water and energy budgets linked through the equivalence of evapotranspiration and latent heat. Comparing component estimates before and after applying the DAT against in situ measurements of energy fluxes and streamflow showed that modified estimates agree better with in situ observations across various metrics, but also revealed some inconsistencies between water budget terms in June over the higher latitudes.

54 ENVIRONMENTAL SCIENCES↗