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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 487 records · Page 27

Solar Activity Modeling: From Subgranular Dynamical Scales to the Solar Cycles

The dynamical effects of solar magnetoconvection span a wide range spatial and temporal scales that extend from the interior to the corona and from fast turbulent motions to global magnetic activity. To study the solar activity on short temporal scales (from minutes to hours), we use 3D radiative MHD simulations that allow us to investigate complex turbulent interactions that drive various phenomena, such as plasma eruptions, spontaneous formation of magnetic structures, funnel-like structures and magnetic loops in the corona, and others. In particular, we focus on multi-scale processes of energy exchange across layers of the solar interior and atmosphere, which contribute to coronal heating and eruptive dynamics. For modeling global-scale activity, we use a data assimilation approach that has demonstrated great potential for building reliable long-term forecasts of solar activity. In particular, it has been shown that the Ensemble Kalman Filter (EnKF) method applied to the Parker-Kleeorin-Ruzmakin dynamo model is capable of predicting solar activity up to one sunspot cycle ahead in time, as well as estimating the properties of the next cycle a few years before it begins. In this presentation, using the available magnetogram data, we discuss development of the methodology and forecast quality criteria (including forecast uncertainties and sources of errors). We demonstrate the influence of observational limitations on prediction accuracy, and we present the EnKF predictions of the upcoming Solar Cycle (25) based on both the sunspot number series and observed magnetic fields and discuss the uncertainties and potential of the data assimilation approach for modeling and forecasting solar activity.

Kitiashvili, I. N.↗

On the surface energy balance closure at different temporal scales

Measurements of the surface energy fluxes (turbulent and radiative) and other ancillary atmospheric/soil parameters made in the Columbia River Basin (Oregon) in an area of complex terrain during a 10-month long portion of the second Wind Forecast Improvement Project (WFIP 2) field campaign are used to study the surface energy budget (SEB) and surface fluxes over different temporal scales. This study analyzes and discusses SEB closure based on half-hourly, daily, monthly, seasonal, and sub-annual (~10-month) temporal averages. The data were collected over all four seasons for different states of the underlying ground surface (dry, wet, and frozen). Our half-hourly direct measurements of energy balance show that the sum of the turbulent sensible and latent heat fluxes systematically underestimate positive net radiation by around 20–30% during daytime and overestimate negative net radiation at night. This imbalance of the surface energy budget is comparable to other terrestrial sites. However, on average, the residual energy imbalance is significantly reduced at daily, weekly, and monthly averaging timescales, and moreover, the SEB can be closed for this site within reasonable limits on seasonal and sub-annual timescales (311-day averaging for the entire field campaign dataset). Increasing the averaging time to daily and longer time intervals substantially reduces the ground heat flux and storage terms, because energy locally entering the soil, air column, and vegetation in the morning is released in the afternoon and evening. Averaging on daily to sub-annual timescales also reduces random instrumental measurement errors and other uncertainties as well as smooths out a hysteresis effect (phase lag) in the SEB relationship between different components. This study shows that SEB closure is better for dry soils compared to wet soils and the statistical dependence of the turbulent fluxes and net radiation for freezing soil surfaces appears weak, if not non-existent, apparently due to lack of the latent heat of fusion term in the traditional SEB equation.

54 ENVIRONMENTAL SCIENCES↗

Monitoring water quality by remote sensing

The author has identified the following significant results. A limited study was conducted to determine the applicability of remote sensing for evaluating water quality conditions in the San Francisco Bay and delta. Considerable supporting data were available for the study area from other than overflight sources, but short-term temporal and spatial variability precluded their use. The study results were not sufficient to shed much light on the subject, but it did appear that, with the present state of the art in image analysis and the large amount of ground truth needed, remote sensing has only limited application in monitoring water quality.

Brown, R. L.↗

Convective organization in the Pacific ITCZ: Merging OLR, TOVS, and SSM/I information

One of the most striking features of the planet's long-time average cloudiness is the zonal band of concentrated convection lying near the equator. Large-scale variability of the Intertropical Convergence Zone (ITCZ) has been well documented in studies of the planetary spatial scales and seasonal/annual/interannual temporal cycles of convection. Smaller-scale variability is difficult to study over the tropical oceans for several reasons. Conventional surface and upper-air data are virtually non-existent in some regions; diurnal and annual signals overwhelm fluctuations on other time scales; and analyses of variables such as geopotential and moisture are generally less reliable in the tropics. These problems make the use of satellite data an attractive alternative and the preferred means to study variability of tropical weather systems.

Hayes, Patrick M.↗

Evaluation of Time-Averaged CERES TOA SW Product Using CAGEX Data

A major component in the analysis of the Earth's radiation budget is the recovery of daily and monthly averaged radiative parameters using noncontinuous spatial and temporal measurements from polar orbiting satellites. In this study, the accuracy of the top of atmosphere (TOA) shortwave (SW) temporal interpolation model for the Clouds and the Earth's Radiant Energy System (CERES) is investigated using temporally intensive half-hourly TOA fluxes from the CERES/ARM/GEWEX Experiment (CAGEX) over Oklahoma (Charlock et al., 1996).

Carlson, Ann B.↗

Elevation Grid for top Columbia River Basalt (CRBG) in the Portland Basin used in DDU Feasibility Study

The Portland Basin is a prime location to assess the feasibility of DDU-TES because natural geologic conditions provide thermal and hydraulic separation from overlying aquifers that would otherwise sweep away stored heat. Under the Portland Basin, the lower Columbia River Basalt Group (CRBG) aquifers contain brackish water (1,000-10,000 mg/L TDS), indicating low groundwater flow rates and poor connection with the overlying regional aquifer. Further, CRBG lavas tend to have comparatively low thermal conductivity, indicating that the 400-1,000 ft thick CRBG may be an effective thermal barrier to the overlying aquifer. A temporally and spatially limited previous study of a Portland Basin CRBG aquifer demonstrated that the injection of waste heat resulted in an increase in temperature by more than a factor of two, indicating a high potential for storing heat. This data submission includes ASCII grid surfaces for the Portland and Tualatin Basins including a DEM of modern topography, the top of Columbia River Basalt (CRB), the base of CRB, and basement. It also includes three isochore (thickness) maps between these intervals. In addition, there is an ArcGIS attribute table for associated data points, a map of data types used to constrain the top of CRB, and cross-sections, all made using IHS Kingdom Suite, Petrosys PRO, ESRI ArcGIS, and Adobe Illustrator software.

15 GEOTHERMAL ENERGY↗

Split-pulse X-ray photon correlation spectroscopy with seeded X-rays from X-ray laser to study atomic-level dynamics

Abstract With their brilliance and temporal structure, X-ray free-electron laser can unveil atomic-scale details of ultrafast phenomena. Recent progress in split-and-delay optics (SDO), which produces two X-ray pulses with time-delays, offers bright prospects for observing dynamics at the atomic-scale. However, their insufficient pulse energy has limited its application either to phenomena with longer correlation length or to measurement with a fixed delay-time. Here we show that the combination of the SDO and self-seeding of X-rays increases the pulse energy and makes it possible to observe the atomic-scale dynamics in a timescale of picoseconds. We show that the speckle contrast in scattering from water depends on the delay-time as expected. Our results demonstrate the capability of measurement using the SDO with seeded X-rays for resolving the dynamics in temporal and spatial scales that are not accessible by other techniques, opening opportunities for studying the atomic-level dynamics.

36 MATERIALS SCIENCE↗

On Neural Architectures for Astronomical Time-series Classification with Application to Variable Stars

Despite the utility of neural networks (NNs) for astronomical time-series classification, the proliferation of learning architectures applied to diverse data sets has thus far hampered a direct intercomparison of different approaches. Here we perform the first comprehensive study of variants of NN-based learning and inference for astronomical time series, aiming to provide the community with an overview on relative performance and, hopefully, a set of best-in-class choices for practical implementations. In both supervised and self-supervised contexts, we study the effects of different time-series-compatible layer choices, namely the dilated temporal convolutional neural network (dTCNs), long-short term memory NNs, gated recurrent units and temporal convolutional NNs (tCNNs). Additionally, we also study the efficacy and performance of encoder-decoder (i.e., autoencoder) networks compared to direct classification networks, different pathways to include auxiliary (non-time-series) metadata, and different approaches to incorporate multi-passband data (i.e., multiple time series per source). Performance—applied to a sample of 17,604 variable stars (VSs) from the MAssive Compact Halo Objects (MACHO) survey across 10 imbalanced classes—is measured in training convergence time, classification accuracy, reconstruction error, and generated latent variables. We find that networks with recurrent NNs generally outperform dTCNs and, in many scenarios, yield to similar accuracy as tCNNs. In learning time and memory requirements, convolution-based layers perform better. We conclude by discussing the advantages and limitations of deep architectures for VS classification, with a particular eye toward next-generation surveys such as the Legacy Survey of Space and Time, the Roman Space Telescope, and Zwicky Transient Facility.

79 ASTRONOMY AND ASTROPHYSICS↗

Directly Fused Porphyrin‐Tetracyanopentacenequinone Conjugates: Role of the Cross‐Conjugated, Powerful Electron Acceptor in Promoting Highly Efficient Charge Separation

Tetracyanopentacenequinone, a powerful electron acceptor, is fused directly to the porphyrin π-system to create a new class of donor-acceptor conjugates. Owing to the direct fusion and electron-deficient property of tetracyanopentacenequinone, strong intramolecular charge transfer both in the ground and excited states was witnessed. As a control, porphyrin fused with pentacenequinone was also investigated. Upon complete spectral and electrochemical characterization, the excited state properties were initially probed by time-dependent DFT studies, and the occurrence of electron transfer from different excited states was established. Free-energy calculations revealed higher exothermic electron transfer (>600 mV) than the control pentacenequinone-porphyrin systems. Pump-probe studies covering broad spatial and temporal regions revealed efficient excited state charge separation. This was unlike the control pentacenequinone-porphyrin system, where slow charge separation was witnessed only in the case of the zinc derivatives but not the free-base ones, followed by the populating of the triplet excited state. The lifetimes of the charge-separated states ranged between 30–500 ps depending on the solvent and metal ion in the porphyrin cavity. Nanosecond transient absorption studies established the charge recombination path to populate the triplet state of porphyrin or directly to the ground state as a function of solvent polarity and the nature of the conjugate. Furthermore, the significance of cross-conjugated tetracyanopentacenequinone fused directly to the porphyrin π system in promoting highly exothermic and efficient charge separation, irrespective of its cross conjugation, is borne out from this study.

Cross conjugation↗

Examining Runner’s Outdoor Heat Exposure Using Urban Microclimate Modeling and GPS Trajectory Mining

It is important to quantify human heat exposure in order to evaluate and mitigate the negative impacts of heat on human well-being in the context of global warming. This study proposed a human-centric framework to examine human personal heat exposure based on anonymous GPS trajectories data mining and urban microclimate modeling. The mean radiant temperature (Tmrt) that represents the human body’s energy balance was used to indicate human heat exposure. The meteorological data and high-resolution 3D urban model generated from multispectral remotely sensed images and LiDAR data were used as inputs in urban microclimate modeling to map the spatio-temporal distribution of the Tmrt in the Boston metropolitan area. The anonymous human GPS trajectory data collected from fitness Apps was used to map the spatiotemporal distribution of human outdoor activities. By overlaying the anonymous GPS trajectories on the generated spatio-temporal maps of Tmrt, this study further examined the heat exposure of runners in different age-gender groups in the Boston area. Results show that there is no significant difference in terms of heat exposure for female and male runners. The female runners in the age of 45-54 are exposed to more heat than female runners of 18-24 and 25-34, while there is no significant difference among male runners. This study proposed a novel method to estimate human heat exposure, which would shed new light on mitigating the negative impacts of heat on human health.

Personal heat exposure↗

Illumination Conditions of the Lunar Polar Regions Using LOLA Topography

We use high-resolution altimetry data obtained by the Lunar Orbiter Laser Altimeter instrument onboard the Lunar Reconnaissance Orbiter to characterize present illumination conditions in the polar regions of the Moon. Compared to previous studies, both the spatial and temporal extent of the simulations are increased significantly, as well as the coverage (fill ratio) of the topographic maps used, thanks to the 28 Hz firing rate of the five-beam instrument. We determine the horizon elevation in a number of directions based on 240 m-resolution polar digital elevation models reaching down to 75 latitude. The illumination of both polar regions extending to 80 can be calculated for any geometry from those horizon longitudinal profiles. We validated our modeling with recent Lunar Reconnaissance Orbiter Wide-Angle Camera images. We assessed the extent of permanently shadowed regions (PSRs, defined as areas that never receive direct solar illumination), and obtained total areas generally larger than previous studies (12,866 and 16,055 sq. km, in the north and south respectively). We extended our direct illumination model to account for singly-scattered light, and found that every PSR does receive some amount of scattered light during the year. We conducted simulations over long periods (several 18.6-years lunar precession cycles) with a high temporal resolution (6 h), and identified the most illuminated locations in the vicinity of both poles. Because of the importance of those sites for exploration and engineering considerations, we characterized their illumination more precisely over the near future. Every year, a location near the Shackleton crater rim in the south polar region is sunlit continuously for 240 days, and its longest continuous period in total darkness is about 1.5 days. For some locations small height gains ( 10 m) can dramatically improve their average illumination and reduce the night duration, rendering some of those particularly attractive energy-wise as possible sites for near-continuous sources of solar power.

E. Mazarico↗

Receptivity in parallel flows: An adjoint approach

Linear receptivity studies in parallel flows are aimed at understanding how external forcing couples to the natural unstable motions which a flow can support. The vibrating ribbon problem models the original Schubauer and Skramstad boundary layer experiment and represents the classic boundary layer receptivity problem. The process by which disturbances are initiated in convectively-unstable jets and shear layers has also received attention. Gaster was the first to handle the boundary layer analysis with the recognition that spatial modes, rather than temporal modes, were relevant when studying convectively-unstable flows that are driven by a time-harmonic source. The amplitude of the least stable spatial mode, far downstream of the source, is related to the source strength by a coupling coefficient. The determination of this coefficient is at the heart of this type of linear receptivity study. The first objective of the present study was to determine whether the various wave number derivative factors, appearing in the coupling coefficients for linear receptivity problems, could be reexpressed in a simpler form involving adjoint eigensolutions. Secondly, it was hoped that the general nature of this simplification could be shown; indeed, a rather elegant characterization of the receptivity properties of spatial instabilities does emerge. The analysis is quite distinct from the usual Fourier-inversion procedures, although a detailed knowledge of the spectrum of the Orr-Sommerfeld equation is still required. Since the cylinder wake analysis proved very useful in addressing control considerations, the final objective was to provide a foundation upon which boundary layer control theory may be developed.

Hill, D. Christopher↗

Interactions of Microhabitat and Time Control Grassland Bacterial and Fungal Composition

Dryland grasslands are vast and globally important and, as in all terrestrial ecosystems, soil microbial communities play fundamental roles in regulating dryland ecosystem function. A typical characteristic of drylands is the spatial mosaic of vascular plant cover surrounded by interspace soils, where biological soil crusts (biocrusts)—a complex community of organisms including bacteria, fungi, algae, mosses, and lichens—are common. The implications of this heterogeneity, where plants and biocrust cover co-occur, are often explored in the context of soil fertility and hydrology, but rarely has the impact of these multiple microhabitat types been simultaneously explored to determine the influence on bacterial and fungal communities, key biological players in these ecosystems. Further, our understanding of the temporal dynamics of bacterial and fungal communities in grasslands, and of how these dynamics depend on the microhabitat within the ecosystem, is notably poor. Here we used a temporally and spatially explicit approach to assess bacterial and fungal communities in a grassland on the Colorado Plateau, and to link variation in these communities to edaphic characteristics. We found that microhabitat (e.g., vascular plant rhizosphere, biocrust, and below biocrust) was the strongest driver of differences in bacterial and fungal community richness, diversity, and composition. Microhabitat type also significantly mediated the impact of temporal change in shaping community composition. Taken together, 29% of the variation in bacterial community composition could be explained by microhabitat, date, and microhabitat-by-date interactions, while only 11% of the variation in fungal community composition could be explained by the same factors, suggesting important differences in community assembly processes. Soil microbial communities dictate myriad critical ecosystem functions, thus understanding the factors that control their compostition is crucial to considering and forecasting how terrestrial ecosystems work. Overall, this case study provides insights for future studies on the spatial and temporal dynamics of bacterial and fungal communities in dryland grasslands.

59 BASIC BIOLOGICAL SCIENCES↗

Climate-Driven Legacies in Simulated Microbial Communities Alter Litter Decomposition Rates

The mechanisms underlying diversity-functioning relationships have been a consistent area of inquiry in biogeochemistry since the 1950s. Though these mechanisms remain unresolved in soil microbiomes, many approaches at varying scales have pointed to the same notion—composition matters. Confronting the methodological challenge arising from the complexity of microbiomes, this study used the model DEMENTpy, a trait-based modeling framework, to explore trait-based drivers of microbiome-dependent litter decomposition. We parameterized DEMENTpy for five sites along a climate gradient in Southern California, United States, and conducted reciprocal transplant simulations analogous to a prior empirical study. The simulations demonstrated climate-dependent legacy effects of microbial communities on plant litter decomposition across the gradient. This result is consistent with the previous empirical study across the same gradient. An analysis of community-level traits further suggests that a 3-way tradeoff among resource acquisition, stress tolerance, and yield strategies influences community assembly. Simulated litter decomposition was predictable with two community traits (indicative of two of the three strategies) plus local environment, regardless of the system state (transient vs. equilibrium). Although more empirical confirmation is still needed, community traits plus local environmental factors (e.g., environment and litter chemistry) may robustly predict litter decomposition across spatial-temporal scales. In conclusion, this study offers a potential trait-based explanation for climate-dependent community effects on litter decomposition with implications for improved understanding of whole-ecosystem functioning across scales.

54 ENVIRONMENTAL SCIENCES↗

Spatial and temporal baseline of perfluorooctanesulfonic acid retained in sediment core samples from Puget Sound, Washington, USA

Per- and poly-fluorinated alkyl substances (PFAS) are a group of highly persistent synthetic chemicals utilized in many industrial and consumer products, and — most significantly toward introduction to the marine environment — in fire-fighting foams. Recently, PFAS have been linked to adverse health effects, prompting the need to understand transport and fate. Puget Sound’s main basin, hosting densely populated urban and industrial areas, is known to be contaminated with various persistent organic pollutants and provides a central focus for ecosystem monitoring. Perfluorooctanesulfonic acid, a manufactured PFAS and biodegradation product, partitions to marine sediments and thus can be used as a primary indicator toward regulatory efforts. The current study offers a spatial and temporal analysis of the Puget Sound from cores collected adjacent, Tacoma and Seattle, WA, as well as cores from central Hood Canal and Carr Inlet.

Per- and poly-fluorinated alkyl substances (PFAS),↗

Simulation and analysis of a geopotential research mission

Methods for the determination of the initial conditions for the two satellites that will satisfy Geopotential Research Mission (GRM) requirements are investigated. For certain gravitational recovery techniques, the satellites must remain close to a specified separation distance and their groundtracks must repeat after a specified interval of time. Since the objective of the GRM mission is to improve the gravity model, any pre-mission orbit predicted using existing gravity models will be in error. A technique has been developed to eliminate the drift between the two satellites caused by gravitational modeling errors and return them to repeating groundtracks. The concept of frozen orbits, which minimize altitude variations over given latitudes, was investigated. Finally, the effects of temporal perturbations on the relative range-rate signal were studied. At the proposed altitude of 160 km, the range-rate signal produced by perturbations other than the static geopotential field are dominated by the luni-solar effect. This study demonstrates that the combined effects of all the temporal perturbations does not prevent the orbit from being frozen or the satellites from obtaining a repeating groundtrack to within a specified closure distance.

White, Lisa K.↗

Reviews and syntheses: Opportunities for robust use of peak intensities from high-resolution mass spectrometry in organic matter studies

Abstract. Earth's biogeochemical cycles are intimately tied to the biotic and abiotic processing of organic matter (OM). Spatial and temporal variations in OM chemistry are often studied using direct infusion, high-resolution Fourier transform mass spectrometry (FTMS). An increasingly common approach is to use ecological metrics (e.g., within-sample diversity) to summarize high-dimensional FTMS data, notably Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR MS). However, problems can arise when FTMS peak-intensity data are used in a way that is analogous to abundances in ecological analyses (e.g., species abundance distributions). Using peak-intensity data in this way requires the assumption that intensities act as direct proxies for concentrations. Here, we show that comparisons of the same peak across samples (within-peak) may carry information regarding variations in relative concentration, but comparing different peaks (between-peak) within or between samples does not. We further developed a simulation model to study the quantitative implications of using peak intensities to compute ecological metrics (e.g., intensity-weighted mean properties and diversity) that rely on information about both within-peak and between-peak shifts in relative abundance. We found that, despite analytical limitations in linking concentration to intensity, ecological metrics often perform well in terms of providing robust qualitative inferences and sometimes quantitatively accurate estimates of diversity and mean molecular characteristics. We conclude with recommendations for the robust use of peak intensities for natural organic matter studies. A primary recommendation is the use and extension of the simulation model to provide objective guidance on the degree to which conceptual and quantitative inferences can be made for a given analysis of a given dataset. Broad use of this approach can help ensure rigorous scientific outcomes from the use of FTMS peak intensities in environmental applications.

54 ENVIRONMENTAL SCIENCES↗

The Impact of Clean Grid Transition on Wastewater Sector Greenhouse Gas Emissions

This study examines the spatial and temporal impacts of the U.S. clean energy grid transition on related greenhouse gas (GHG) emissions from the wastewater treatment industry. By analyzing data from 17,156 water resource recovery facilities (WRRFs) and state-specific grid decarbonization scenarios, the results project a 60% reduction in Scope 2 emissions by 2050, driven by the national shift to renewable energy. However, regional disparities are prominent, with northeastern and western states achieving the most significant reductions, while the Ohio Valley and Rockies are likely to experience higher emissions due to the reliance on fossil fuels. This study offers the first assessment of clean grid impacts on the WRRFs and highlights the need for targeted, region-specific strategies across different emission scopes. This research provides insights for policymakers and stakeholders in the wastewater sector, emphasizing the critical role of grid decarbonization in achieving GHG reduction goals.

Li, Xiatong↗