Atomic spectroscopy with the shock tube.
Shock tube application to transition probability measurements with emphasis on thermodynamic state of radiating gas, noting temperature dependence of level population
Bengtson, R.↗
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Diatomic gasdynamic lasers
Predictions from a numerical model of the vibrational relaxation of anharmonic diatomic oscillators in supersonic expansions are used to show the extent to which the small anharmonicity of gases like CO can cause significant overpopulations of upper vibrational states. When mixtures of CO and N2 are considered, radiative gain on many of the vibration-rotation transitions of CO is predicted. Experiments are described that qualitatively verify the predictions by demonstrating laser oscillation in CO-N2 expansions. The resulting CO-N2 gasdynamic laser displays performance characteristics that equal or exceed those of similar CO2 lasers.
Mckenzie, R. L.↗
Atomic processes in astrophysics.
Studies of particle excitation processes in the solar corona are reviewed, covering electron affinities, negative ion experiments using two-photon laser and drift tube techniques, geometrical hindrance in molecular ion formation, negative ion-molecule reactions, and negative ions in the ionosphere and astrophysics. Aspects of forbidden atomic transitions are also discussed, including the calculation of transition probabilities, the Fe II problem, and magnetic quadrupole radiation in a relativistic approximation.
Garstang, R. H.↗
Diatomic gasdynamic lasers.
Predictions from a numerical model of the vibrational relaxation of anharmonic diatomic oscillators in supersonic expansions are used to show the extent to which the small anharmonicity of gases like CO can cause significant overpopulations of upper vibrational states. When mixtures of CO and N2 are considered, radiative gain on many of the vibration-rotation transitions of CO is predicted. Experiments are described that qualitatively verify the predictions by demonstrating laser oscillation in CO-N2 expansions. The resulting CO-N2 gasdynamic laser displays performance characteristics that equal or exceed those of similar CO2 lasers.
Mckenzie, R. L.↗
The solar XUV spectrum of He II
OSO-7 observations of the first five Lyman lines and the Lyman continuum of He II are given for the quiet sun, a coronal hole, prominences, filaments, and the flare of August 7, 1972. These data are calibrated and given in specific intensity units together with color and brightness temperatures for the He II continuum. It is found that He II is overionized in all features except the flare and that the continuum is formed at temperatures near 14,000 K. The He II-He III ionization equilibrium appears to be dominated by photoionizations and radiative recombinations. Schematic calculations for realistic chromosphere and transition-region models can account for the observed intensities of Ly-beta through Ly-epsilon, the Lyman continuum, and its color temperature. To account for the intensity of Ly-alpha, either an implausible 100-km plateau at temperatures near 80,000 K is needed or, more likely, the diffusion-enhanced collisional excitation should be incorporated into the models.
Linsky, J. L.↗
Quantum mechanical theory of collisional ionization in the presence of intense laser radiation
The paper presents a quantum mechanical formalism for treating ionizing collisions occurring in the presence of an intense laser field. Both the intense laser radiation and the internal electronic continuum states associated with the emitted electrons are rigorously taken into account by combining discretization techniques with expansions in terms of electronic-field representations for the quasi-molecule-plus-photon system. The procedure leads to a coupled-channel description of the heavy-particle dynamics which involves effective electronic-field potential surfaces and continua. It is suggested that laser-influenced ionizing collisions can be studied to verify the effects of intense laser radiation on inelastic collisional processes. Calculation procedures for electronic transition dipole matrix elements between discrete and continuum electronic states are outlined.
Bellum, J. C.↗
Radiation absorption by the C2 band systems for Jupiter entry conditions
Revised values of the absorption cross sections for seven electronic band systems of C2 have been calculated using recently published experimental data for the electronic transition moments. Using these revised C2 cross section values, computations were made for the radiating flow field over a Jupiter entry probe with coupled ablation injection from a carbon-phenolic heat shield. Results are presented which show that radiation absorption within the ablation layer for the spectral range of 4 to 6 eV is less than that predicted using previous C2 absorption cross section values. The effect of the reduced radiation absorption by the C2 molecule is an increase in the radiative heating rates and ablation mass loss rates for the Jupiter entry conditions considered in the study.
Sutton, K.↗
The spectrum of the Becklin-Neugebauer source in Orion from 3.3 to 5.5 microns
Spectra of the Becklin-Neugebauer source in Orion and the associated nebula are presented covering the complete range from 3.3-5.5 microns with a resolution of 1.2 kaysers. The data were taken in December 1976 and February 1978. Atomic hydrogen emission lines of Brackett-alpha and Pfund-beta are seen, as well as molecular CO absorptions. No other features intrinsic to BN were detected. The December 1976 data show an anomalously high intensity for Pfund-beta line. Theoretical considerations are presented which suggest that Pfund-beta radiation arises in a small dense region, with the transition possibly lasing.
Smith, H. A.↗
X-ray lasers. Citations from the International Aerospace Abstracts data base
Various aspects of X-ray lasers are discussed in approximately 122 citations. Included are laser plasmas and outputs, plasma radiation, far ultraviolet radiation, gamma rays, optical pumping, optical resonators, and electron transitions. Laser applications, laser materials, and laser fusion are also included.
Mauk, S. C.↗
The sun at 1.4 GHz - Intensity and polarization
1.4 GHz radio pictures of the sun are presented which were made on 1981 September 26 using the VLA with a resolution of 40 arcsec. Features observed include active regions, limb brightening, coronal holes and filament channels; all correspond well with features seen in H-alpha or He 10830 A, and can be explained as relative enhancements or depressions of free-free brmsstrahlung from the corona and upper transition region. The degree of circular polarization of the radiation from active regions ranges up to 0.2 and the sense corresponds, with a few exceptions, with the polarity of the photospheric magnetograms, even though the 1.4 GHz radiation arises from the corona at a height of 10 to 50 Mm. The polarization is in the sense of the x-mode and is highest near the edges of active regions, whereas the brightness is highest (maximum of 2.2 x 10 to the 6th K) near the line of zero polarization.
Dulk, G. A.↗
A static model of chromospheric heating in solar flares
The response of the solar chromosphere to flare processes, namely nonthermal electrons, thermal conduction, and coronal pressure, is modeled. Finite difference methods employing linearization and iteration are used in obtaining simultaneous solutions to the equations of steady-state energy balance, hydrostatic equilibrium, radiative transfer, and atomic statistical equilibrium. The atmospheric response is assumed to be confined to one dimension by a strong vertical magnetic field. A solution is obtained to the radiative transfer equation for the most important optically thick transitions of hydrogen, magnesium, and calcium. The theoretical atmospheres discussed here are seen as elucidating the role of various physical processes in establishing the structure of flare chromospheres. At low coronal pressures, conduction is found to be more important than nonthermal electrons in establishing the position of the transition region. Only thermal conduction can adequately account for the chromospheric evaporation in compact flares. Of the mechanisms considered, only nonthermal electrons bring about significant heating below the flare transition region.
Ricchiazzi, P. J.↗
Toxicological safeguards in the manned Mars missions
Safeguards against toxic chemical exposures during manned Mars missions (MMMs) will be important for the maintenance of crew health and the accomplishment of mission objectives. Potential sources include offgassing, thermodegradation or combustion of materials, metabolic products of crew members, and escape of chemical from containment. Spacecraft maximum allowable concentration (SMAC) limits will have to be established for potential contaminants during the MMMs. The following factors will be used in establishing these limits: duration of mission, simultaneous exposure to other contaminants, deconditioning of crew members after long periods of reduced gravity, and simultaneous exposure to ionizing radiation. Atmospheric contaminant levels in all compartments of the transit spacecraft and Manned Mars Station (MMS) will be monitored at frequent intervals with a real time analyzer. This analyzer will be highly automated, requiring minimal crew time and expertise. The atmospheric analyzer will find other usages during the MMMs such as analyzing Martian atmospheres and soils, exhaled breath and body fluids of crew members, and reaction products in chemical processing facilities.
Coleman, Martin E.↗
Measurement of solar magnetic fields from radio observations
Measurements of magnetic fields in the sun's atmosphere using radio observations are discussed. Radio measurements of magnetic fields in the chromosphere and the corona are indirect. In the chromosphere, these are based upon the measurement of polarization of active regions at millimeter wavelengths. In the transition region and the corona, the properties of gyroresonance radiation of active regions at centimeter wavelengths are used. Total intensity and polarization maps and modeling are used to determine which harmonic (second or third) is predominant in the active region emission. A direct method of measuring coronal magnetic fields using cyclotron line emission is discussed, and the relevant data as presently available are presented.
Kundu, M. R.↗
Stationary Plasma Thruster Plume Emissions
The emission spectrum from a xenon plasma produced by a Stationary Plasma Thruster provided by the Ballistic Missile Defense Organization (BMDO) was measured. Approximately 270 individual Xe I, Xe II, and XE III transitions were identified. A total of 250 mW of radiated optical emission was estimated from measurements taken at the thruster exit plane. There was no evidence of erosion products in the emission signature. Ingestion and ionization of background gas at elevated background pressure was detected. The distribution of excited states could be described by temperatures ranging from fractions of 1 eV to 4 eV with a high degree of uncertainty due to the nonequilibrium nature of this plasma. The plasma was over 95 percent ionized at the thruster exit plane. Between 10 and 20 percent of the ions were doubly charged. Two modes of operation were identified. The intensity of plasma emission increased by a factor of two during operation in an oscillatory mode. The transfer between the two modes of operation was likely related to unidentified phenomena occurring on a time scale of minutes.
Manzella, David H.↗
Observations of the Rotational Transitions of OH from the Orion Molecular Cold
The goal of the observations carried out under this grant was to use several transitions of OH to infer conditions within a 1-arcminute region centered on Orion-KL. OH was selected as a diagnostic because: (1) it was predicted to be sufficiently abundant to be detectable by the KAO spectrometers; (2) there exist a number of transitions in the far- infrared free from atmospheric interference at airplane altitudes; and (3) these transitions are sensitive to a range of collisional and radiative excitation conditions believed to apply toward Orion-KL These observations were carried out as a Guest Investigator in collaboration with the Townes and Houck spectrometer groups. Though not every flight series resulted in usable data -due to technical difficulties with instrumentation - sufficient data was obtained to yield a clear picture of the source of the OH emission in Orion-KL.
Melnick, Gray J.↗
The Positronium Radiative Combination Spectrum: Calculation in the Limit of Thermal Positrons and Low Densities
We calculate the intensities of the positronium de-excitation lines for two processes: (1) the radiative combination of free thermal electrons and positrons for transitions with principal quantum number n less than 20, and (2) charge exchange between free positrons and hydrogen and helium atoms, restricting our evaluation to the Lyman-alpha line. We consider a low-density medium modeled by the case A assumption of Baker & Menzel and use the "nL method" of Pengelly to calculate the absolute intensities. We also evaluate the positronium fine and hyperfine intensities and show that these transitions are in all cases much weaker than positronium de-excitation lines in the same wavelength range. We also extrapolate our positronium de-excitation intensities to the submillimeter, millimeter, and centimeter wavelengths. Our results favor the search of infrared transitions of positronium lines for point sources when the visual extinction A, is greater than approx. 5.
Wallyn, P.↗
The Wardle Instability in Interstellar Shocks: Gas Temperture and Line Emission - 2
We have modeled the gas temperature structure in unstable C-type shocks and obtained predictions for the resultant CO and H2 rotational line emissions, using numerical simulations of the Wardle instability. Our model for the thermal balance of the gas includes ion-neutral frictional heating; compressional heating; radiative cooling due to rotational and ro-vibrational transitions of the molecules CO, H2O, and H2; and gas-grain collisional cooling. We obtained results for the gas temperature distribution in-and H2 and CO line emission from-shocks of neutral Alfvenic Mach number 10 and velocity 20 or 40 km/ s in which the Wardle instability has saturated. Both two- and three-dimensional simulations were carried out for shocks in which the preshock magnetic field is perpendicular to the shock propagation direction, and a two-dimensional simulation was carried out for the case in which the magnetic field is obliquely oriented with respect to the shock propagation direction. Although the Wardle instability profoundly affects the density structure behind C-type shocks, most of the shock-excited molecular line emission is generated upstream of the region where the strongest effects of the instability are felt. Thus the Wardle instability has a relatively small effect on the overall gas temperature distribution in-and the emission-line spectrum from-C-type shocks, at least for the cases that we have considered. In none of the cases that we have considered thus far did any of the predicted emission-line luminosities change by more than a factor of 2.5, and in most cases the effects of instability were significantly smaller than that. Slightly larger changes in the line luminosities seem likely for three-dimensional simulations of oblique shocks, although such simulations have yet to be carried out and lie beyond the scope of this study. Given the typical uncertainties that are always present when model predictions are compared with real astronomical data, we conclude that Wardle instability does not imprint any clear observational signature on the shock-excited CO and H2 line strengths. This result justifies the use of one-dimensional steady shock models in the interpretation of observations of shock-excited line emission in regions of star formation. Our three-dimensional simulations of perpendicular shocks revealed the presence of warm filamentary structures that are aligned along the magnetic field, a result that is of possible relevance to models of water maser emission from C-type shocks.
Neufeld, David A.↗
Liquid Space Lubricants Examined by Vibrational Micro-Spectroscopy
Considerable effort has been expended to develop liquid lubricants for satellites and space exploration vehicles. These lubricants must often perform under a range of harsh conditions such as vacuum, radiation, and temperature extremes while in orbit or in transit and in extremely dusty environments at destinations such as the Moon and Mars. Historically, oil development was guided by terrestrial application, which did not provide adequate space lubricants. Novel fluids such as the perfluorinated polyethers provided some relief but are far from ideal. With each new fluid proposed to solve one problem, other problems have arisen. Much of the work performed at the National Aeronautics and Space Administration (NASA) Glenn Research Center (GRC) in elucidating the mechanisms by which chemical degradation of space oils occur has been done by vibrational micro-spectroscopic techniques such as infrared and Raman, which this review details. Presented are fundamental lubrication studies as well as actual case studies in which vibrational spectroscopy has led to millions of dollars in savings and potentially prevented loss of mission.
Street, Kenneth W., Jr.↗