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At least 487 records · Page 27

Calculation of low frequency vibrational resonances of submerged structures

Numerical techniques for calculating the low frequency vibrational resonances of submerged structures are reviewed. Both finite element and boundary element approaches for calculating fully-coupled added mass matrices for use in NASTRAN analysis are described and illustrated. The finite element approach is implemented using existing capability in NASTRAN. The boundary element approach uses the NASHUA structural-acoustics program to compute the added mass matrix. The two procedures are compared to each other for the case of a submerged cylindrical shell with flat end closures. It is concluded that both procedures are capable of computing accurate submerged resonances and that the more elegant boundary element procedure is easier to use but may be more expensive computationally.

Everstine, Gordon C.↗

Chemical Preparation, Crystal Structure Reinvestigation and Vibrational Study of CoNa 3 P 3 O 10 ·12H 2 O and X-ray Characterization of the New Anhydrous Triphosphate CoNa 3 P 3 O 10

The triphosphate dodecahydrate of cobalt and sodium CoNa 3 P 3 O 10 ·12H 2 O was prepared by the ion exchange resin process. Its structure was studied by X-ray diffraction and determined in the monoclinic space group P12 1 /c1 with the unit-cell parameters a = 14.6650(5) Å, b=9.1916(3) Å, c = 15.0239(5) Å,β =90.2210(10)°, Z = 4 and V = 2025.13(12) Å 3 . The thermal dehydration of this compound was performed, leading to an anhydrous new form, CoNa 3 P 3 O 10 , which was characterized by X-ray diffraction. The obtained CoNa 3 P 3 O 10 crystallized in monoclinic space group P21/n with the unit-cell parameters a=15,3774 Å, b=7,6988 A°, c=14,2832A°, β=92,9115°. The characteristic IR wavenumbers of the P 3 O 10 5- ions observed in the vibrational spectra were calculated using isotopic substitutions, which confirms the existence of these groups in the studied compound. A comparison between the IR and Raman wavenumbers of CoNa 3 P 3 O 10 ·12H 2 O, CoNa 3 P 3 O 10 and Na 5 P 3 O 10 ·12H 2 was performed. A kinetic study was also made for CoNa 3 P 3 O 10 ·12H 2 O.

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Active and passive vibration suppression for space structures

The relative benefits of passive and active vibration suppression for large space structures (LSS) are discussed. The intent is to sketch the true ranges of applicability of these approaches using previously published technical results. It was found that the distinction between active and passive vibration suppression approaches is not as sharp as might be thought at first. The relative simplicity, reliability, and cost effectiveness touted for passive measures are vitiated by 'hidden costs' bound up with detailed engineering implementation issues and inherent performance limitations. At the same time, reliability and robustness issues are often cited against active control. It is argued that a continuum of vibration suppression measures offering mutually supporting capabilities is needed. The challenge is to properly orchestrate a spectrum of methods to reap the synergistic benefits of combined advanced materials, passive damping, and active control.

Hyland, David C.↗

Novel Multidisciplinary Models Assess the Capabilities of Smart Structures to Manage Vibration, Sound, and Thermal Distortion in Aeropropulsion Components

The development of aeropropulsion components that incorporate "smart" composite laminates with embedded piezoelectric actuators and sensors is expected to ameliorate critical problems in advanced aircraft engines related to vibration, noise emission, and thermal stability. To facilitate the analytical needs of this effort, the NASA Lewis Research Center has developed mechanics and multidisciplinary computational models to analyze the complicated electromechanical behavior of realistic smart-structure configurations operating in combined mechanical, thermal, and acoustic environments. The models have been developed to accommodate the particular geometries, environments, and technical challenges encountered in advanced aircraft engines, yet their unique analytical features are expected to facilitate application of this new technology in a variety of commercial applications.

Saravanos, Dimitris A.↗

Aircraft noise induced building vibration and effects on human response

The acoustic loads resulting from aircraft noise and sonic booms which can induce vibration in the structure and result in radiation of noise into its interior, rattling of items in contact with the structure, and the perception of the inhabitants that the structure is vibrating, are investigated. In particular, the response of buildings, particularly residential structures, to aircraft noise and the resulting effects on human response have been the subjects of considerable research at the NASA Langley Research Center. These studies are reviewed with particular emphasis on the response of houses to aircraft overflight noise and any increase in noise annoyance caused by the perception of vibration and rattling.

Powell, Clemans A.↗

Vibration of prestressed periodic lattice structures

Equations are developed for vibration of general lattice structures that have repetitive geometry. The method of solution is an extension of a previous paper for buckling of similar structures. The theory is based on representing each member of the structure with the exact dynamic stiffness matrix and taking advantage of the repetitive geometry to obtain an eigenvalue problem involving the degrees-of-freedom at a single node in the lattice. Results are given for shell-and beam-like lattice structures and for rings stiffened with tension cables and a central mast. The variation of frequency with external loading and the effect of local member vibration on overall modes is shown.

Anderson, M. S.↗

Quantum Choreography of the Nucleus: Rotations, Vibrations, and Emergent Structure

Abstract Nuclei are complex many-body quantum systems where interactions of the neutrons and protons via the strong, the weak, and the electromagnetic forces lead to the emergence of simple patterns of energy states that have been described by various theoretical approaches. One of the goals of all the theoretical models is the development of a universal theory that can be applied across the entire chart of nuclides. Significant progress has been made by experiments as well as the increasing sophistication of models, but a universal theory has yet to be established. A recent review of nuclei in the Z = 50–82 region of the chart of nuclides has analyzed all the available compiled data from several decades of studies towards a clarification of the low-lying structure of nuclei. Other reviews have reported and explained the emergence of multiple different shapes in nuclei at somewhat higher excitation energies than the ground state. Some have challenged the interpretation of the first excited K π = 0 + band as a vibration of ground state. This work attempts to provide a guide to determining the nature of the first excited K π = 0 + band in nuclei by the combined use of nuclear lifetimes, energy level evolutions, dynamic moments of inertia, and intrinsic quadrupole moments extracted from transition probabilities. The result is that for a subset of the nuclei in this region, the K π = 0 + band is consistent with the traditional 𝛽-vibration description of an oscillation built on the ground state.

CHFB+5DCH↗

Vibrational spectra and structure of biphosphine and biphosphine-d4

Infrared and Raman spectra have been obtained for biphosphine and biphosphine-d4 in both solid and vapor phases. From the spectral data, it is concluded that only one conformer exists in both solid and fluid phases and that this is the gauche conformer. A normal-coordinate analysis has also been performed, in which the 24 vibrational frequencies of the two isotopes have been fitted by 10 force constants to an overall average error of 1.0%. The PED indicates that there is practically no mixing of the normal modes in the P2H4 molecule but the P-P stretch and the PD2 wagging modes are extensively mixed for the P2D4 molecule.

Odom, J. D.↗

Vibrational spectra and structure of dimethylaminodichlorophosphine.

Evaluation of the infrared spectra of dimethylaminodichlorophosphine and dimethylaminodichlorophosphine-d sub 6 recorded from 4000 to 33 per cm in the gas and solid phases. The Raman spectra of the liquid and solid phases for both compounds were also recorded. The spectra were consistent with the presence of only one isomer over the range of phases and temperatures studied. Available experimental data were discussed in connection with the spectra, and it is concluded that the molecule exists in the gauche conformer with the PNC2 portion of the molecule planar. A vibrational assignment is proposed for the molecule.

Durig, J. R.↗

A new approach for vibration control in large space structures

An approach for augmenting vibration damping characteristics in space structures with large panels is presented. It is based on generation of bending moments rather than forces. The moments are generated using bimetallic strips, suitably mounted at selected stations on both sides of the large panels, under the influence of differential solar heating, giving rise to thermal gradients and stresses. The collocated angular velocity sensors are utilized in conjunction with mini-servos to regulate the control moments by flipping the bimetallic strips. A simple computation of the rate of dissipation of vibrational energy is undertaken to assess the effectiveness of the proposed approach.

Kumar, K.↗

Structural Heat Intercept, Insulation and Vibration Evaluation Rig (SHIIVER)

The Structural Heat Intercept, Insulation, and Vibration Evaluation Rig (SHIIVER) is a large scale cryogenic fluid management (CFM) test bed designed to scale CFM technologies for inclusion on large, in-space stages. A part of the evolvable Cryogenics (eCryo) project, SHIIVER is a technology development task that is supportive of future exploration propulsion needs. Technologies developed under the eCryo Project will play a critical role in enabling increasingly longer duration in-space missions beyond Low Earth Orbit (LEO).

Vapor cooling↗

Effect of Solvent on the Local Structure, Dynamics, and Vibrational Density of States in Sn-BEA Zeolite

Lewis acid zeolites are attractive catalysts for epoxidation and biomass valorization, as they are highly active and selective in the liquid phase and can operate at or near ambient conditions. While a rich experimental literature exists on liquid-phase Lewis acid zeolite catalysis, our understanding of the molecular organization and solvent dynamics in the vicinity of Lewis acid sites with differing metal site speciation remains limited. In this work, we investigate the molecular coordination and diffusion of two common solvents (methanol and water) around the closed and open Sn-BEA zeolite active sites using molecular dynamics simulations with a machine-learned interatomic potential trained on ab initio molecular dynamics trajectories. Molecular dynamics simulations reveal that introducing active sites significantly enhances local order in the first and second solvation shells compared to the pure silica case. For methanol, both closed and open active sites are singly coordinated, while more than two water molecules coordinate the open site. In contrast to methanol, we observed that water molecules dissociate, leading to the formation of additional Sn-OH and silanol groups away from the active site. The diffusion coefficients of water and methanol are functions of the solvent population in the pore. Here, our work provides insights into how active site speciation in Lewis acid zeolites affects solvent coordination, diffusion, and vibrational signature. This information is foundational for catalyst design and optimization of liquid-phase catalytic processes in zeolites. It also demonstrates the suitability of machine-learned interatomic potentials for modeling reactive systems, enabling sufficiently long trajectories for appropriate statistical averaging.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗