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At least 487 records · Page 27

Geochemical comparison of impact glasses from lunar meteorites ALHA81005 and MAC88105 and Apollo 16 regolith 64001

Parameterizations have been developed for impact glass compositions which makes its possible to acquire geochemical information about pre-impact target materials. The impact glass populations among unrelated highland regoliths including Apollo 16 regolith 64001 and the lunar meteorites ALHA81005 and MAC88105 have been compared. It is concluded that the Apollo 16 impact glasses are compositionally more diverse than those in the lunar meteorites. This diversity reflects the complex geology of the Apollo 16 region, in which extensive exposures of mare basalts occur within 300 km. Apollo 16 regolith 64001 contains a distinctive subset of impact glasses with major element compositions similar to lunar highland meteorite. These impact glasses (less than 100 micrograms) indicate that the lunar highlands are geochemically more diverse than the compositional range currently represented by large (more than 1 gram) samples. Lunar impact glasses provide geochemical constraints on the full range of regolith compositions that occur on the moon.

Delano, John W.↗

Applications of Advanced, Waveform Based AE Techniques for Testing Composite Materials

Advanced, waveform based acoustic emission (AE) techniques have been previously used to evaluate damage progression in laboratory tests of composite coupons. In these tests, broad band, high fidelity acoustic sensors were used to detect signals which were then digitized and stored for analysis. Analysis techniques were based on plate mode wave propagation characteristics. This approach, more recently referred to as Modal AE, provides an enhanced capability to discriminate and eliminate noise signals from those generated by damage mechanisms. This technique also allows much more precise source location than conventional, threshold crossing arrival time determination techniques. To apply Modal AE concepts to the interpretation of AE on larger composite structures, the effects of wave propagation over larger distances and through structural complexities must be well characterized and understood. In this research, measurements were made of the attenuation of the extensional and flexural plate mode components of broad band simulated AE signals in large composite panels. As these materials have applications in a cryogenic environment, the effects of cryogenic insulation on the attenuation of plate mode AE signals were also documented.

Prosser, William H.↗

Crystal-chemistry and partitioning of REE in whitlockite

Partitioning of Rare Earth Elements (REE) in whitlockite is complicated by the fact that two or more charge-balancing substitutions are involved and by the fact that concentrations of REE in natural whitlockites are sufficiently high such that simple partition coefficients are not expected to be constant even if mixing in the system is completely ideal. The present study combines preexisting REE partitioning data in whitlockites with new experiments in the same compositional system and at the same temperature (approximately 1030 C) to place additional constraints on the complex variations of REE partition coefficients and to test theoretical models for how REE partitioning should vary with REE concentration and other compositional variables. With this data set, and by combining crystallographic and thermochemical constraints with a SAS simultaneous-equation best-fitting routine, it is possible to infer answers to the following questions: what is the speciation on the individual sites Ca(B), Mg, and Ca(IIA) (where the ideal structural formula is Ca(B)18 Mg2Ca(IIA)2P14O56); how are REE's charge-balanced in the crystal; and is mixing of REE in whitlockite ideal or non-ideal. This understanding is necessary in order to extrapolate derived partition coefficients to other compositional systems and provides a broadened understanding of the crystal chemistry of whitlockite.

Colson, R. O.↗

Application of composites to helicopter airframe and landing gear structures

A preliminary design study has indicated that advanced composite helicopter airframe structures can provide significant system cost advantages in the 1980's. A seven percent increase in productivity and a five percent reduction in life cycle cost are projected. Due to their complexity, landing gear structures do not substantially benefit from the use of advanced composites. The most successful concept was found to be all-molded composite modular panels, which provide integral skin/stringer and frame subassemblies. These subassemblies significantly reduce the number of parts relative to present construction. The subassemblies are mechanically jointed together for economical, rapid final assembly and permit field replacement in the event of major damage.

Rich, M. J.↗

NASA Composite Materials Development: Lessons Learned and Future Challenges

Composite materials have emerged as the materials of choice for increasing the performance and reducing the weight and cost of military, general aviation, and transport aircraft and space launch vehicles. Major advancements have been made in the ability to design, fabricate, and analyze large complex aerospace structures. The recent efforts by Boeing and Airbus to incorporate composite into primary load carrying structures of large commercial transports and to certify the airworthiness of these structures is evidence of the significant advancements made in understanding and use of these materials in real world aircraft. NASA has been engaged in research on composites since the late 1960 s and has worked to address many development issues with these materials in an effort to ensure safety, improve performance, and improve affordability of air travel for the public good. This research has ranged from synthesis of advanced resin chemistries to development of mathematical analyses tools to reliably predict the response of built-up structures under combined load conditions. The lessons learned from this research are highlighted with specific examples to illustrate the problems encountered and solutions to these problems. Examples include specific technologies related to environmental effects, processing science, fabrication technologies, nondestructive inspection, damage tolerance, micromechanics, structural mechanics, and residual life prediction. The current state of the technology is reviewed and key issues requiring additional research identified. Also, grand challenges to be solved for expanded use of composites in aero structures are identified.

Tenney, Darrel R.↗

Origin of Archean anorthosites - Evidence from the Bad Vermilion Lake anorthosite complex, Ontario

Studies of the petrology and geochemistry of the anorthosite complex at Bad Vermillion Lake, Canada, based on 400 samples collected in summer, 1979, are presented. Petrographic, microprobe, X-ray-fluorescence, and instrumental-neutron-activation analyses were performed. Major and trace-element abundances of the anorthositic rocks and surrounding mafic and felsic rocks are reported in tables, chondrite-normalized rare-earth-element patterns are shown, and the anorthositic, intrusive, and metavolcanic formations are characterized in detail. The anothrositic plagioclases are found to have a coarse porphyritic texture and calcic composition (80 normative mol percent An) similar to those of other Archean anorthosite complexes. Chemical similarities indicate that the gabbro and mafic to felsic metavolcanic formations associated with the anorthosite complex may be comagmatic with it, while the absence of ultramafic material and the bulk composition of the comagmatic basalt (about 20 wt percent Al2O3) suggest that much of the original comagmatic material has been separated.

Ashwal, L. D.↗

Compositional Study of Trans-Neptunian Objects at λ > 2.2 μm

Using data from the Infrared Array Camera on the Spitzer Space Telescope, we present photometric observations of a sample of 100 trans-Neptunian objects (TNOs) beyond 2.2 μm. These observations, collected with two broadband filters centered at 3.6 and 4.5 μm, were done in order to study the surface composition of TNOs, which are too faint to obtain spectroscopic measurements. With this aim, we have developed a method for the identification of different materials that are found on the surfaces of TNOs. In our sample, we detected objects with colors that are consistent with the presence of small amounts of water, and we were able to distinguish between surfaces that are predominantly composed of complex organics and amorphous silicates. We found that 86% of our sample have characteristics that are consistent with a certain amount of water ice, and the most common composition (73% of the objects) is a mixture of water ice, amorphous silicates, and complex organics. Twenty-three percent of our sample may include other ices, such as carbon monoxide, carbon dioxide, methane, or methanol. Additionally, only small objects seem to have surfaces dominated by silicates. This method is a unique tool for the identification of complex organics and to obtain the surface composition of extremely faint objects. Furthermore, this method will be beneficial when using the James Webb Space Telescope for differentiating groups within the trans-Neptunian population.

Trans-Neptunian objects↗

A Scaling Methodology Applied to Buckling of Sandwich Composite Cylindrical Shells

Studying buckling behavior of large shell structures through full-scale test articles can be complex and expensive. Therefore, reduced scale structures are often preferred to investigate the buckling behavior. However, designing reduced scale structures that are representative of the full-scale structure can be difficult. An analytical scaling methodology for compression-loaded sandwich composite cylindrical shells based on the nondimensionalization of the buckling equations is presented herein. The methodology is used to develop scaled configurations that show similar buckling responses to the full-scale baseline configuration. Finite element analysis results showed that both a baseline and a scaled configuration buckled similarly, when the nondimensional stiffness, defined as the ratio between the nondimensional load and nondimensional displacement, is matched between the different scale models. Limitations of the methodology are discussed and are believed to be a result of neglecting the flexural anisotropy and the transverse shear compliance. A preliminary failure assessment for the different scales is also considered.

Ines Uriol Balbin↗

The Bholghati howardite - Petrography and mineral chemistry

A 10 g sample of the Bholghati howardite was disaggregated in order to separate two eucrite clasts, several small carbonaceous clasts, fragments of diogenitic pyroxene, and bulk matrix. The eucrite clasts show evidence of moderately rapid cooling from a melt, followed by prolonged subsolidus annealing. The carbonaceous clasts mostly resemble CM2 carbonaceous chondrites with low-iron silicates and Fe-Ni sulphides in a fine grained dark matrix. One clast, however, is mineralogically, petrographically, and compositionally similar to a CI1 chondrite. Both carbonaceous and eucritic clasts have a complex history prior to incorporation into the howardite matrix with no evidence of significant metamorphism since assembly. Most clasts in the howardite breccia are monomineralic, with pyroxene and plagioclase predominant. Pyroxenes range from 'diogenitic' to 'eucritic' with diogenitic compositions most abundant; a significant number of intermediate compositions are present, consistent with derivation from a series of rocks related by fractionation.

Reid, A. M.↗

Nonlinear analysis of laminated fibrous composites

A computerized analysis of the nonlinear behavior of fibrous composite laminates including axial loading, thermal loading, temperature dependent properties, and edge effects is presented. Ramberg-Osgood approximations are used to represent lamina stress-strain behavior and percent retention curves are employed to model the variation of properties with temperature. Balanced, symmetric laminates comprised of either boron/epoxy, graphite/epoxy, or borsic-aluminum are analyzed using a quasi-three-dimensional finite element analysis. Results are presented for the interlaminar stress distributions in cross-ply, angle-ply, and more complex laminates. Nonlinear stress-strain curves for a variety of composite laminates in tension and compression are obtained and compared to other existing theories and experimental results.

Renieri, G. D.↗

Lunar ferroan anorthosites - Mineralogy, compositional variations, and petrogenesis

Results of a study of 16 samples from the anorthositic ferroan subgroup, or 'typical' ferroan anorthosites, are reported. The presence of heterogeneous, bimodal, and/or trimodal pyroxene compositions suggests that some of the anorthosites are polymict rocks; however, they are composed entirely of ferroan-anorthosite-suite lithologies. It is suggested that complex processes operated during the formation of the ferroan anorthosites. It is argued that original igneous compositional characteristics were altered during and/or after crystallization. Processes operative during anorthosite formation may have included some mixing of different melts, trapping of variable amounts of intercumulus liquid, postcrystallization redistribution of elements, or perturbations both during adcumulus growth and subsequent to crystallization by impact events.

Mcgee, J. J.↗

Mineral compositions of plutonic rocks from the Lewis Hills massif, Bay of Islands ophiolite

Mineral compositions of residual and cumulate rocks from the Lewis Hills massif of the Bay of Islands ophiolite complex are reported and interpreted in the context of magnetic processes involved in the geochemical evolution of spatially associated diabase dikes. The mineral compositions reflect greater degrees of partial melting than most abyssal peridotites do and appear to represent the most depleted end of abyssal peridotite compositions. Subsolidus equilibration between Cr-Al spinal and olivine generally has occurred at temperatures of 700 to 900 C. The spinel variations agree with the overall fractionation of basaltic magmas producing spinels with progressively lower Cr numbers. The compositions of clinopyroxenes suggest that the fractionation of two different magma series produced the various cumulate rocks.

Smith, Susan E.↗

Dielectric Permittivity Measurements of Geologic Samples at Venus Surface Temperatures

Synthetic-aperture radar (SAR) and radar sounding are two powerful remote sensing techniques used to examine the surface and subsurface of planets. Their value is critical in the case of Venus due to this planet’s global and visually opaque cloud layer. The recently selected VERITAS and EnVision orbital missions, slated to study the planet in the early 2030’s, employ radar instruments to image the surface (VERITAS and EnVision) and probe the subsurface (EnVision). For both techniques, the complex dielectric permittivity of the surface and subsurface materials control radar backscatter intensity and penetration depth. Since the 1970’s, many studies have characterized the dielectric permittivity of geologic materials collected both on Earth and on the Moon to constrain the radar reflectivity and transparency at a variety of radar frequencies [e.g., 1]. Two consistent findings from those studies are that complex permittivity depends on both the density (or porosity) and the composition of the material. Denser materials and more metal-rich compositions tend to have higher permittivity values and to incur greater propagation path loss. Water content also elevates permittivity of otherwise dry rocks/soils/regolith [e.g., 2]. However, permittivity is independent of frequency for the 0.5-18 GHz range, within which SAR imaging commonly lies. The one aspect poorly explored thus far is the effect of elevated temperatures on dielectric permittivity. Previous work suggests that increased lattice vibrations and flow of free electrons associated with an increase in temperature elevate both the real (reflectivity) and imaginary (path loss) parts of the complex permittivity. We are currently conducting a 3-year campaign to measure the complex dielectric permittivity of Venusrelevant geologic materials at Venus surface temperatures (380°C - 460°C) and with frequencies relevant to VERITAS, EnVision, and Magellan imaging synthetic aperture radars.

M Barmatz↗

Thermomechanical and Environmental Durability of Environmental Barrier Coated Ceramic Matrix Composites Under Thermal Gradients

This paper presents the developments of thermo-mechanical testing approaches and durability performance of environmental barrier coatings (EBCs) and EBC coated SiCSiC ceramic matrix composites (CMCs). Critical testing aspects of the CMCs will be described, including state of the art instrumentations such as temperature, thermal gradient, and full field strain measurements; materials thermal conductivity evolutions and thermal stress resistance; NDE methods; thermo-mechanical stress and environment interactions associated damage accumulations. Examples are also given for testing ceramic matrix composite sub-elements and small airfoils to help better understand the critical and complex CMC and EBC properties in engine relevant testing environments.]

Enviornmental Barrier Coatings↗

Morphology and types of particles of regolith sample from the Sea of Fertility

A brief description of the morphology of lunar surface material returned by Luna 16 automatic lunar station is given. Adhesiveness of the surface material and its ability to be electrified is noted. Two main genetic groups of regolith particles are differentiated: primary, represented mainly by fragments of magmatic rocks of the basalt and gabbro types, as well as mineralized grains of their constituent minerals, and secondary, particles subjected to appreciable exogenic transformation on the surface of the Moon. The second group, representing more than 70 percent of the material in coarse fractions, includes particles of breccias, sintered aggregates of complex dendritic form, and glass and vitrified particles of varied composition.

Florenskiy, K. P.↗

The new applications of sputtering and ion plating

The potential industrial applications of sputtering and ion plating are strictly governed by the unique features these methods possess. The outstanding features of each method, the resultant coating characteristics and the various sputtering modes and configurations are discussed. New, more complex coatings and deposits can be developed such as graded composition structures (metal-ceramic seals), laminated and dispersion strengthened composites which improve the mechanical properties and high temperature stability. Specific industrial areas where future effort of sputtering and ion plating will concentrate to develop intricate alloy or compound coatings and solve difficult problem areas are discussed.

Spalvins, T.↗

The new applications of sputtering and ion plating

The potential industrial applications of sputtering and ion plating are strictly governed by the unique features these methods possess. The outstanding features of each method, the resultant coating characteristics and the various sputtering modes and configurations are discussed. New, more complex coatings and deposits can be developed such as graded composition structures (metal-ceramic seals), laminated and dispersion strengthened composites which improve the mechanical properties and high temperature stability. Specific industrial areas where future effort of sputtering and ion plating will concentrate to develop intricate alloy or compound coatings and solve difficult problem areas are discussed.

Spalvins, T.↗

Feldspathic granulite 79215 - Limitations on T-fo2 conditions and time of metamorphism

Feldspathic granulite 79215, an annealed polymict breccia which has a bulk composition between anorthositic gabbro and gabbroic anorthosite, contains numerous oxide complexes in the matrix. An Ar-39-Ar-40 stepwise heating experiment gives a well-defined plateau corresponding to an age of 4.03 + or - 0.02 AE. The polmict character of this breccia and the variability of the complexes suggest that they formed as a consequence of reactions between spinel-rich clasts and matrix under the high-T low-P conditions of an ejecta blanket. The duration of annealing is estimated to have been less than 10 million yr; the absence of a KREEP component may indicate an inhomogeneous distribution of this component at the lunar surface at 4.0 AE.

Mcgee, J. J.↗