Search NASA⌕ Search

SEARCH · Search NASA

Results for “compositional reasoning”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 487 records · Page 27

Scattering by ensembles of small particles experiment, theory and application

A hypothetical self consistent picture of evolution of prestellar intertellar dust through a comet phase leads to predictions about the composition of the circum-solar dust cloud. Scattering properties of thus resulting conglomerates with a bird's-nest type of structure are investigated using a micro-wave analogue technique. Approximate theoretical methods of general interest are developed which compared favorably with the experimental results. The principal features of scattering of visible radiation by zodiacal light particles are reasonably reproduced. A component which is suggestive of (ALPHA)-meteoroids is also predicted.

Gustafson, B. A. S.↗

Delaminations in composite plates caused by non-penetrating impact

A model is presented for estimating the dimensions of delaminations in continuous fiber reinforced composite plates subjected to non-penetrating (low velocity) impact of a solid object. The model is based on dimensional analysis, and results in two simple, closed form expressions, one providing the delamination length, the other the delamination width. Comparisons of delamination lengths and widths calculated by these expressions with experimental data suggest that the model predicts these dimensions with reasonable accuracy.

Finn, Scott R.↗

LET spectra of trapped anomalous cosmic rays in low-Earth orbit

Observations aboard Cosmos satelites discovered trapped anomalous cosmic rays (ACRs), tracked the variation in their intensity in 1986-1988, and measured their fluence, spectrum, and composition at solar minimum in the previous solar cycle. The MAST instrument aboard the SAMPEX satellite has observed trapped anomalous cosmic rays in the present solar cycle, confirmed the general features of the Cosmos data, and provided the first detailed observations of trapped ACRs. In this paper we apply theoretical modeling of trapped ACRs, which is shown to provide a reasonably good description of both the Cosmos and SAMPEX data, to calculate the integral linear-energy-transfer (LET) spectra due to trapped ACRs in typical low-Earth orbits. We compare these calculations with the LET spectra produced by galactic cosmic rays (GCRs) and non-trapped ACRs in order to assess the relative radiation hazard posed by trapped ACRs.

Tylka, A. J.↗

Properties of the Hermean Regolith: New Optical Reflectance Spectra, Comparison with Lunar Anorthosites and Mineralogical Modelling - 5

We present new optical (0.4-0.65 micron) spectra of Mercury and lunar pure anorthosite locations, obtained quasi-simultaneously with the Nordic Optical Telescope (NOT) in 2002. A comparative study is performed with the model of Lucey et al. between iron-poor, mature, pure anorthosite (less than 90% plagioclase feldspar) Clementine spectra from the lunar farside and a combined 0.4-1.0 micron mercurian spectrum, obtained with the NOT, calculated for standard photometric geometry. Mercury is located at more extreme locations in the Lucey ratio-reflectance diagrams than any known lunar soil, specifically with respect to the extremely iron-poor mature anorthosites. Though quantitative prediction of FeO and TiO2 abundances cannot be made without a more generally applicable model, we find qualitatively that the abundances of both these oxides must be near zero for Mercury. We utilize the theory of Hapke, with realistic photometric parameters, to model laboratory spectra of matured mineral powders and lunar soils, and remotely sensed spectra of lunar anorthosites and Mercury. An important difference between fabricated and natural powders is the high value for the internal scattering parameter necessary to interpret the spectra for the former, and the requirement of rough and non-isotropically scattering surfaces in the modelling of the latter. The mature lunar anorthosite spectra were well modelled with binary mixtures of calcic feldspars and olivines, grain sizes of 25-30 micron and a concentration of submicroscopic metallic iron (SMFe) of 0.12-0.15% in grain coatings. The mercurian spectrum is not possible to interpret from terrestrial mineral powder spectra without introducing an average particle scattering function for the bulk soil that increases in backscattering efficiency with wavelength. The observed spectrum is somewhat better predicted with binary mixture models of feldspars and pyroxenes, that single-component regoliths consisting of either albite or diopside. Correct spectral reflectance values were predicted with a concentration of 0.1 wt% SMFe in coatings of 15-30 micron sized grains. Since reasonable cosmogonical formation scenarios for Mercury, or meteoritic infall, predict iron concentrations at least this high, we draw the conclusion that the average grain size of Mercury is about a factor of two smaller than for average returned lunar soil samples. The 0.6-2.5 micron spectrum of McCord and Clark is used to further limit the possible range of mineralogical composition of Mercury. It is found that an intimately mixed and matured 3 : 1 labradorite-to-enstatite regolith composition best matches both the optical and near-infrared spectra, yielding an abundance of approx. 1.2 wt% FeO and -approx. 0 wt% TiO2.

Warell, J.↗

Studies of convection in a solidifying binary mixture at reduced gravity

A great deal of interest was generated recently in the possibility of producing new materials in the reduced gravity environment provided during the forthcoming missions of Spacelab. The range of possibilities extend from producing large crystals of uniform properties to manufacturing materials with unique properties. Most of these processes involve the solidification of materials from the liquid state. Convective motions within the liquid during solidification can influence the local material composite and the shape of the solid-liquid interface which may result in solids with non-uniform properties and crystal defects. The microgravity environment of Spacelab is being viewed as one in which the buoyancy forces are eliminated so that convection driven by thermal gradients does occur, resulting in an improved solidification process. However, convection may occur for other reasons and whether convection is negligible or not during solidification constitutes processing in low-gravity environment. Little information exists presently on convection during solidification under such circumstances. A continuation of an analytical investigation into the nature of convective motion in a binary liquid layer due to surface tension forces during its solidification is reported. The onset of convection will be determined through a stability analysis which is described.

Antar, B. N.↗

Carbon/graphite composite material study, appendix A and appendix B

A comprehensive assessment of the possible damage to electrical and electronic equipment caused by accidental release of carbon fibers from burning civil aircraft with carbon composite parts was completed. The study concluded that the amount of fiber likely to be released is much lower than initially predicted. Carbon fiber released from an aircraft crash fire was found (from atmospheric dissemination models) to disperse over a much larger area than originally estimated, with correspondingly lower fiber concentrations. Long term redissemination of fiber was shown to be insignificant if reasonable care is exercised in accident cleanup. The vulnerability of electrical equipment to structural fibers in current use was low. Consumer appliances, industrial electronics, and avionics were essentially invulnerable to carbon fibers. Shock hazards (and thus potential injury or death) were found to be extremely unlikely.

Source record↗

Statistical Models of Fracture Relevant to Nuclear-Grade Graphite: Review and Recommendations

The nuclear-grade (low-impurity) graphite needed for the fuel element and moderator material for next-generation (Gen IV) reactors displays large scatter in strength and a nonlinear stress-strain response from damage accumulation. This response can be characterized as quasi-brittle. In this expanded review, relevant statistical failure models for various brittle and quasi-brittle material systems are discussed with regard to strength distribution, size effect, multiaxial strength, and damage accumulation. This includes descriptions of the Weibull, Batdorf, and Burchell models as well as models that describe the strength response of composite materials, which involves distributed damage. Results from lattice simulations are included for a physics-based description of material breakdown. Consideration is given to the predicted transition between brittle and quasi-brittle damage behavior versus the density of damage (level of disorder) within the material system. The literature indicates that weakest-link-based failure modeling approaches appear to be reasonably robust in that they can be applied to materials that display distributed damage, provided that the level of disorder in the material is not too large. The Weibull distribution is argued to be the most appropriate statistical distribution to model the stochastic-strength response of graphite.

Nemeth, Noel N.↗

Development of Challenge Aerosols for Testing Filters in Spacecraft Air Revitalization Systems

The common means for reducing particle concentrations in air in enclosed spaces, including in space habitats, are source prevention and particle removal by air filters. While air filtration and testing is a well-established discipline and industry, testing and classifying filters according to commonly used standards rely on a test aerosol that is often arbitrary and chosen for the convenience of the test method. In space habitats, the particle size distributions are expected to be quite different than the particle size distributions prescribed in test standards, due to the partial or low gravity environment affecting sedimentation of large particulates like hair or cloth fibers, or the introduction of planetary dust to the pressurized volume. This means that the efficacy of the filter will be quite different in the space habitat than specified according to a prevailing standard. This paper will present a means to specify and generate a “composite” test aerosol that is similar to the measured and reported particle sizes utilizing the International Space Station (ISS) as an example. Application of this test aerosol is expected to yield filter efficiencies and loading effects closer to what one can expect on the ISS and to be useful in determining filter lifetime and replacement cycles. The method can be tuned, within reason, to match other particle size distributions one may encounter, such as the intrusion of Lunar dust for a Lunar lander or habitat.

Filtration↗

On the applicability of the Redlich-Kister framework for viscosity estimation of molten halide salt mixtures

For molten halide salt mixtures already being utilized or under consideration for carbon-free energy production systems, it is crucial that their viscosity is well understood so that system thermal hydraulics can be reliably assessed. Because of the difficulty in accurately measuring molten halide viscosity and the sheer size of the matrix of possible higher order salt mixtures that may be of interest to the energy industry, there are several gaps in the quantified understanding of molten halide viscosity across this matrix. As such, both first-principles and semi-empirical modeling techniques may be crucial for rapidly assessing this broad, complex compositional domain. Herein, the Redlich-Kister framework is applied to assess the feasibility of broadly interpolating and estimating the viscosity of several pseudobinary and pseudoternary molten halide salt systems that may be of key interest to the energy industry. The framework is based on the assumption that an ideal component and a nonideal component collectively describe the viscosity as a function of composition and temperature for a given molten halide system. Three different ideal models were considered for the ideal component, including Grunburg-Nissan, Katti-Chaudhri, and Gambill methods. Regarding the pseudobinary interpolations, the Redlich-Kister models with either the Grunburg-Nissan or Katti-Chaudhri models as the ideal component resulted in either highly (average error less than 5%) or reasonably (average error less than 15%) accurate interpolations of pseudobinary halide viscosity; BeF 2 - or UF 4 -bearing salts tended to result in reasonably accurate interpolations, whereas other pseudobinary mixtures tended to show high accuracy. Regarding the pseudoternary extrapolations, the Redlich-Kister framework shows reasonable success at estimating the extent to which a pseudoternary system may indicate deviations from ideal Grunburg-Nissan mixing, where discrepancies with comparative experimental data generally stay within 30%. Finally, the primary reasons identified for such discrepancies are (1) inaccuracy in the underlying experimental data, (2) different complexation behavior in the higher order systems compared to the pseudobinary subsystems, and (3) extrapolation into temperatures too far out of the domain, which is valid for the underlying experimental data feeding the Redlich-Kister model.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Studies of liquid metal surfaces using Auger spectroscopy

The surface composition of liquid gallium-tin alloys is studied in an Auger electron spectrometer as a function of bulk composition and temperature. The sessile drop samples are cleaned by argon ion bombardment sputtering of the liquid. This technique produces surfaces that are entirely free of impurities within the sensitivity of the spectrometer and remain so for many days. Tin is found to be strongly adsorbed at the liquid-vacuum interface. Surface concentrations based on Auger measurements are found to be in reasonably good agreement with values calculated from surface tension measurements interpreted in terms of a monolayer depth distribution model for the adsorbed tin.

Hardy, S.↗

Composite interstellar grains

The possibility that interstellar grains are composite collections of very small particles, loosely attached to one another, is investigated. The grains are assumed to include a substantial proportion of vacuum along with solid particles. The optical properties of the composite grains are calculated with the approximate 'Bruggeman mixing rule', and the extinction of the grain is calculated wih standard Mie theory. The derived cross sections are close to those of hollow spheres in which the constituents occupy the proper volume fractions, and the derived optical constants of the mixture also obey the Kramers-Kroenig relations. The calculated interstellar extinction law shows reasonable agreement with observations of the diffuse ISM over the 1500-0.12 micron wavelength range. The predicted albedo is 0.5-0.6. It is predicted that the visual extinction per H nucleus should increase slightly with R(V).

Mathis, John S.↗

Estimating Marine Aerosol Particle Volume and Number from Maritime Aerosol Network Data

As well as spectral aerosol optical depth (AOD), aerosol composition and concentration (number, volume, or mass) are of interest for a variety of applications. However, remote sensing of these quantities is more difficult than for AOD, as it is more sensitive to assumptions relating to aerosol composition. This study uses spectral AOD measured on Maritime Aerosol Network (MAN) cruises, with the additional constraint of a microphysical model for unpolluted maritime aerosol based on analysis of Aerosol Robotic Network (AERONET) inversions, to estimate these quantities over open ocean. When the MAN data are subset to those likely to be comprised of maritime aerosol, number and volume concentrations obtained are physically reasonable. Attempts to estimate surface concentration from columnar abundance, however, are shown to be limited by uncertainties in vertical distribution. Columnar AOD at 550 nm and aerosol number for unpolluted maritime cases are also compared with Moderate Resolution Imaging Spectroradiometer (MODIS) data, for both the present Collection 5.1 and forthcoming Collection 6. MODIS provides a best-fitting retrieval solution, as well as the average for several different solutions, with different aerosol microphysical models. The average solution MODIS dataset agrees more closely with MAN than the best solution dataset. Terra tends to retrieve lower aerosol number than MAN, and Aqua higher, linked with differences in the aerosol models commonly chosen. Collection 6 AOD is likely to agree more closely with MAN over open ocean than Collection 5.1. In situations where spectral AOD is measured accurately, and aerosol microphysical properties are reasonably well-constrained, estimates of aerosol number and volume using MAN or similar data would provide for a greater variety of potential comparisons with aerosol properties derived from satellite or chemistry transport model data.

Sayer, A. M.↗

Model Evaluation and Intercomparison Using Data Collected by the Langley Mobile Ozone Lidar in Hampton, Virginia

Throughout the year 2022, the Langley Mobile Ozone Lidar (LMOL) has been frequently collecting ozone and aerosol measurements in the lower troposphere. The lidar is located in the parking lot behind the Atmospheric Sciences building at NASA Langley in Hampton, Virginia, approximately 37.095 N, -76.389 W. The data was collected during a range of several distinct atmospheric conditions, including stratospheric intrusions, surface frontal passages, and long-range transported wildfire smoke plumes. We use this data to evaluate and intercompare the forecast accuracy of two atmospheric chemistry models: the GEOS Composition Forecasting model (GEOS-CF) and the Weather Research and Forecasting model with Chemistry (WRF-Chem). Both models make daily three-dimensional forecasts of many trace gases and species for the contiguous United States. Over a range of ten distinct collection events, each spanning 36 hours to nearly seven days, the forecast models predict tropospheric ozone at NASA Langley with reasonable accuracy. The models best predict the timing and shape of the observed stratospheric intrusions in the middle troposphere but often vary in the magnitude of the ozone mixing ratios. For other atmospheric conditions, there is more variability in the model accuracy. Here, we summarize the accuracy of the models for all events and investigate reasons for differences between the models and the lidar.

Daniel B. Phoenix↗

Verification of thermal analysis codes for modeling solid rocket nozzles

One of the objectives of the Solid Propulsion Integrity Program (SPIP) at Marshall Space Flight Center (MSFC) is development of thermal analysis codes capable of accurately predicting the temperature field, pore pressure field and the surface recession experienced by decomposing polymers which are used as thermal barriers in solid rocket nozzles. The objective of this study is to provide means for verifications of thermal analysis codes developed for modeling of flow and heat transfer in solid rocket nozzles. In order to meet the stated objective, a test facility was designed and constructed for measurement of the transient temperature field in a sample composite subjected to a constant heat flux boundary condition. The heating was provided via a steel thin-foil with a thickness of 0.025 mm. The designed electrical circuit can provide a heating rate of 1800 W. The heater was sandwiched between two identical samples, and thus ensure equal power distribution between them. The samples were fitted with Type K thermocouples, and the exact location of the thermocouples were determined via X-rays. The experiments were modeled via a one-dimensional code (UT1D) as a conduction and phase change heat transfer process. Since the pyrolysis gas flow was in the direction normal to the heat flow, the numerical model could not account for the convection cooling effect of the pyrolysis gas flow. Therefore, the predicted values in the decomposition zone are considered to be an upper estimate of the temperature. From the analysis of the experimental and the numerical results the following are concluded: (1) The virgin and char specific heat data for FM 5055 as reported by SoRI can not be used to obtain any reasonable agreement between the measured temperatures and the predictions. However, use of virgin and char specific heat data given in Acurex report produced good agreement for most of the measured temperatures. (2) Constant heat flux heating process can produce a much higher heating rate than the radiative heating process. The results show that heating rates of 125 C/s (225 F/s) can be achieved. (3) The electrical resistance of the FM 5055 samples were about 150 Omega in the virgin state, and decreased to about 35 Omega when charred. A reliable scheme must be developed to electrically insulate the composite from the heater foil in order to prevent any current leakage into the sample which can result in volumetric heating of the char zone of the composite.

Keyhani, M.↗

Solar modulation and a galactic origin for the anomalous component observed in low-energy cosmic rays

The current theory of solar modulation can be used to argue that the cosmic-ray component at low energies, which is observed to have an anomalous composition, is not of galactic origin, i.e., it is not a component of the galactic cosmic-ray flux. The current theory predicts, from quite general considerations, that an unreasonably large intensity of cosmic rays, by many orders of magnitude, would be required in the interstellar medium to account for the observed fluxes. Conceivably, the current modulation theory could be modified so that only reasonable interstellar fluxes are predicted. One such modification involves an unusual scheme for particle diffusion in the interplanetary medium. Particles are assumed to diffuse not as a result of their own motion among small-scale irregularities in the magnetic field, but rather in a process in which they are trapped between time-varying constrictions in the large-scale field.

Fisk, L. A.↗

Mars and earth - Origin and abundance of volatiles

An investigation is conducted concerning the factors which are responsible for the tenuous nature of the Martian atmosphere in comparison to the terrestrial atmosphere, taking into account new data obtained in connection with the Viking missions. It is found that Mars was poor in volatiles from the start and fell further behind earth by less complete outgassing, by extensive retrapping, and by the partial loss of lighter gases. Attention is given to noble gases on earth and Mars, the condensation of noble gases and other volatiles, the sources of earth's volatiles, the bulk composition of earth, the release of volatiles from earth, clues to the volatile endowment of Mars, an abundance table for Mars, a comparison of terrestrial and Martian conditions, isotopic data on noble gases, xenon-129 on Mars and earth, possibilities concerning the loss of an early Martian atmosphere, the evolution of the atmosphere of Mars, conditions in the case of planet Venus, and the reasons for the poorness of small planets in volatiles.

Anders, E.↗

Isotopic signatures of black tektites from the K-T boundary on Haiti - Implications for the age and type of source material

An isotopic study was carried out to characterize the type of black tektites from the Cretaceous-Tertiary (K-T) boundary on Haiti (the first reasonably well-preserved impact-derived material recovered from the K-T boundary), in order to help characterize the tektite source material (i.e., the type of rocks that were melted and ejected during the impact event(s) at around 64.5 Ma). Results show that the isotopic data and all of the element concentration data obtained are consistent with an andesitic-dacitic composition for the tektites and their source material. The Nd isotopic data suggest that the source rocks were not older than Silurian (T(chur) = 400 Ma) in age, and were composed largely of young (less than 1080 Ma) crustal material. Of the suspected K-T boundary impact sites, both the Manson (Iowa) and Chicxulub (Yucatan) structures occur in suitable lithologies to yield the Haitian black tektites.

Premo, W. R.↗

Morphometric comparison of Icelandic lava shield volcanoes versus selected Venusian edifices

Shield volcanoes are common landforms on the silicate planets of the inner Solar System, and a wide variety have recently been documented on Venus by means of Magellan observations. In this report, we emphasize our recently completed morphometric analysis of three representative Icelandic lava shields: the classic Skjaldbreidur edifice, the low-reflief Lambahraun feature, and the monogenetic Sandfellshaed shield, as the basis for comparison with representative venusian edifices (greater than 60 km in diameter). Our detailed morphometric measurements of a representative and well-studied set of Icelandic volcanoes permits us to make comparisons with our measurements of a reasonable subset of shield-like edifices on Venus on the basis of Magellan global radar altimetry. Our study has been restricted to venusian features larger than approximately 60 km in basal diameter, on the basis of the minimum intrinsic spatial resolution (8 km) of the Magellan radar altimetry data. Finally, in order to examine the implications of landform scaling from terrestrial simple and composite shields to larger venusian varieties, we have considered the morphometry of the subaerial component of Mauna Loa, a type-locality for a composite shield edifice on Earth.

Garvin, James B.↗