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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 487 records · Page 27
All sourcesNASA NTRSDOE OSTI
DOE OSTI2020

Momentum-exchange current drive by electrostatic waves in an unmagnetized collisionless plasma

For a planar electrostatic wave interacting with a single species in a collisionless plasma, momentum conservation implies current conservation. However, when multiple species interact with the wave, they can exchange momentum, leading to current drive. A simple, general formula for this driven current is derived. As examples, we show how currents can be driven for Langmuir waves in electron–positron–ion plasmas, and for ion-acoustic waves in electron–ion plasmas.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2021

Effect of chemical substituents attached to the zwitterion cation on dielectric constant

Materials with high dielectric constant, ε s , are desirable in a wide range of applications including energy storage and actuators. Recently, zwitterionic liquids have been reported to have the largest ε s of any liquid and, thus, have the potential to replace inorganic fillers to modulate the material ε s . Although the large ε s for zwitterionic liquids is attributed to their large molecular dipole, the role of chemical substituents attached to the zwitterion cation on ε s is not fully understood, which is necessary to enhance the performance of soft energy materials. Here, we report the impact of zwitterionic liquid cation chemical substituents on ε s (50 < ε s < 300 at room temperature). Dielectric relaxation spectroscopy reveals that molecular reorientation is the main contributor to the high ε s . The low Kirkwood factor g calculated for zwitterionic liquids (e.g., 0.1–0.2) suggests the tendency for the antiparallel zwitterion dipole alignment expected from the strong electrostatic intermolecular interactions. With octyl cation substituents, the g is decreased due to the formation of hydrophobic-rich domains that restrict molecular reorientation under applied electric fields. In contrast, when zwitterion cations are functionalized with ethylene oxide (EO) segments, g increases due to the EO segments interacting with the cations, allowing more zwitterion rotation in response to the applied field. The reported results suggest that high ε s zwitterionic liquids require a large molecular dipole, compositionally homogeneous liquids (e.g., no aggregation), a maximized zwitterion number density, and a high g, which is achievable by incorporating polar chemical substituents onto the zwitterion cations.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2021

Enabling particle applications for exascale computing platforms

The Exascale Computing Project (ECP) is invested in co-design to assure that key applications are ready for exascale computing. Within ECP, the Co-design Center for Particle Applications (CoPA) is addressing challenges faced by particle-based applications across four “sub-motifs”: short-range particle–particle interactions (e.g., those which often dominate molecular dynamics (MD) and smoothed particle hydrodynamics (SPH) methods), long-range particle–particle interactions (e.g., electrostatic MD and gravitational N-body), particle-in-cell (PIC) methods, and linear-scaling electronic structure and quantum molecular dynamics (QMD) algorithms. Our crosscutting co-designed technologies fall into two categories: proxy applications (or “apps”) and libraries. Proxy apps are vehicles used to evaluate the viability of incorporating various types of algorithms, data structures, and architecture-specific optimizations and the associated trade-offs; examples include ExaMiniMD, CabanaMD, CabanaPIC, and ExaSP2. Libraries are modular instantiations that multiple applications can utilize or be built upon; CoPA has developed the Cabana particle library, PROGRESS/BML libraries for QMD, and the SWFFT and fftMPI parallel FFT libraries. Success is measured by identifiable “lessons learned” that are translated either directly into parent production application codes or into libraries, with demonstrated performance and/or productivity improvement. The libraries and their use in CoPA’s ECP application partner codes are also addressed.

97 MATHEMATICS AND COMPUTING↗
DOE OSTI2021

Controlled synthesis and ordered assembly of Co 3 O 4 nanowires using genetically engineered bacterial flagella as biotemplates (Final Technical Report)

The major goals of the project are to gain a fundamental understanding on the influence of the displayed peptides and other processing parameters on the flagella assembly and the resulting biomimetic control over the synthesis and assembly of Co 3 O 4 nanoparticles (NPs) and nanowires (NWs). To pursue these goals, we designed two specific aims: Aim 1: Understanding the self-assembly of genetically engineered flagella and its outcome for site-specific nucleation and growth of Co 3 O 4 NPs and NWs. Aim 2: Understanding controllable alignment of 1D Co 3 O 4 -flagella NWs into highly ordered 2D and 3D structures.

59 BASIC BIOLOGICAL SCIENCES↗
DOE OSTI2019

In Situ Loading and Delivery of Short Single- and Double-Stranded DNA by Supramolecular Organic Frameworks

Short DNA represents an important class of biomacromolecules that are widely applied in gene therapy, editing, and modulation. However, the development of simple and reliable methods for their intracellular delivery remains a challenge. Herein, we describe that seven water-soluble, homogeneous supramolecular organic frameworks (SOFs) with a well-defined pore size and high stability in water that can accomplish in situ inclusion of single-stranded (ss) and double-stranded (ds) DNA (21, 23, and 58 nt) and effective intracellular delivery (including two noncancerous and six cancerous cell lines). Fluorescence quenching experiments for single and double end-labeled ss- and ds-DNA support that the DNA sequences can be completely enveloped by the SOFs. Confocal laser scanning microscopy and flow cytometry reveal that five of the SOFs exhibit excellent delivery efficiencies that, in most of the studied cases, outperform the commercial standard Lipo2000, even at low SOF–nucleic acid ratios. In addition to high delivery efficiencies, the water-soluble, self-assembled SOF carriers have a variety of advantages, including convenient preparation, high stability, and in situ DNA inclusion, which are all critical for practical applications in nucleic acid delivery.

59 BASIC BIOLOGICAL SCIENCES↗
NASA NTRS1971

Kubo conductivity of a strongly magnetized two-dimensional plasma.

The Kubo formula is used to evaluate the bulk electrical conductivity of a two-dimensional guiding-center plasma in a strong dc magnetic field. The particles interact only electrostatically. An ?anomalous' electrical conductivity is derived for this system, which parallels a recent result of Taylor and McNamara for the coefficient of spatial diffusion.

Montgomery, D.↗
NASA NTRS1972

Three-dimensional plasma diffusion in a very strong magnetic field.

The thermal equilibrium coefficient of spatial diffusion transverse to a strong uniform dc magnetic field is calculated for a fully ionized plasma. The particles are assumed to move transverse to the field only as a consequence of the E x B drift, but to move freely parallel to it. The particles interact only electrostatically. The calculation is done at large, but fixed and finite, plasma volume. It is shown that, as magnetic field density approaches infinity, the leading term of the coefficient of transverse spatial diffusion falls off in a prescribed manner, but contains a multiplicative factor which goes to zero as the plasma volume becomes infinite. The method of calculation fails for unbounded plasmas.

Montgomery, D.↗
NASA NTRS1982

Light ion mass spectrometer for space-plasma investigations

Direct satellite measurements and ground-based techniques have given a comprehensive view of the density distribution of the cold plasma population in the earth's magnetosphere. There were, however, no direct measurements of the low-energy plasma mass composition, temperature, density, pitch-angle distribution, or plasma flow velocity. A description is presented of the evolution and development of an instrument, the Light Ion Mass Spectrometer (LIMS), designed to make these low-energy plasma measurements. The instrument was developed for flight on the spacecraft SCA-THA, a satellite to study satellite charging at high altitudes. This satellite, whose primary mission was to study spacecraft-plasma interactions and electrostatic charging, was launched into a near-geosynchronous orbit. The design requirements regarding the instrument are discussed, and attention is given to the calibration procedures, the flight configuration, and some examples of flight data.

Reasoner, D. L.↗
NASA NTRS1985

Estimation and comparison of quasilinear electron heating in the shock foot at Jupiter and earth

A simple quasilinear model is developed to estimate the electron heating that occurs in the foot of a supercritical, quasiperpendicular shock through interactions with electrostatic waves generated by reflected ions. At earth the increase in electron thermal energy calculated using the measured wave amplitudes is negligible, while at Jupiter it is comparable with the observed temperature gain across the shock. The anisotropic quasilinear heating should destabilize whistler mode waves in the foot. These have been detected by the plasma wave instrument on Voyager with amplitudes sufficient to isotropize the electron distribution.

Moses, S. L.↗
NASA NTRS1986

Transverse acceleration of oxygen ions by electromagnetic ion cyclotron resonance with broad band left-hand polarized waves

Central plasma sheet (CPS) ion conics are oxygen-dominated, with peak energies ranging from tens to hundreds of eV centered around pitch-angles between 115 and 130 degrees. Because of the lack of correlation between the CPS conics and the observed currents and/or electron beam-like structures, it is not likely that all of these conics are generated by interactions with electrostatic ion cyclotron waves or lower hybrid waves. Instead, it is suggested that the observed intense broad band electric field fluctuations in the frequency range between 0 and 100 Hz can be responsible for the transverse energization of the ions through cyclotron resonance heating with the left-hand polarized electromagnetic waves. This process is much more efficient for heating the oxygen ions than hydrogen ions, thus providing a plausible explanation of the oxygen dominance in CPS conics. Simple algebraic expressions are given from which estimates of conic energy and pitch angle can be easily calculated. This suggested mechanism can also provide some preheating of the oxygen ions in the boundary plasma sheet (BPS) where discrete aurorae form.

Chang, T.↗
NASA NTRS1986

Theoretical studies on rapid fluctuations in solar flares

Rapid fluctuations in the emission of solar bursts may have many different origins e.g., the acceleration process can have a pulsating structure, the propagation of energetic electrons and ions can be interrupted from plasma instabilities and finally the electromagnetic radiation produced by the interaction of electrostatic and electromagnetic waves may have a pulsating behavior in time. In two separate studies the conditions for rapid fluctuations in solar flare driven emission were analyzed.

Vlahos, Loukas↗
NASA NTRS1989

Particle dynamics and gamma-ray emission in the magnetospheres of neutron stars with accretion disks

Whether the existence of cold accretion disks around isolated, magnetized neutron stars might result in a distinct observational signature due to the Compton drag interaction between the electrostatically accelerated changes and the thermal radiation emitted by these disks. The particle dynamics resulting from the combined effects of electrostatic acceleration and the Compton drag interaction are determined. In the course of their deceleration, the charged particles boost the thermal disk radiation to gamma-ray energies, which may result in a significant spectral component. Cold disks are too underluminous to significantly retard the flow, and if such disks are present in pulsars, only a small fraction of the particle energy is transferred to the radiation field. The results also indicate that steady, unidirectional particle acceleration is unlikely to be the mechanism operating in gamma-ray burst sources.

Melia, Fulvio↗
NASA NTRS1990

Theoretical studies of the first- and second-row transition-metal mono- and dicarbonyl positive ions

Ab initio calculations have been carried out on the first- and second-row transition-metal mono- and dicarbonyl positive ions. The bonding in these systems is discussed in detail. Trends in the series of mono- and dicarbonyl ions and between the first- and second-row transition metals are explained in terms of a dominantly electrostatic bonding interaction and differences in metal ion state separations, ionization potentials, and s and d orbital sizes. Dissociation energies are presented and a detailed comparison is made with experimental data. Where reliable experimental data exists, agreement with the theoretical results is generally good.

Barnes, Leslie A.↗
NASA NTRS1999

Interaction of Space Suits with Windblown Soil: Preliminary Mars Wind Tunnel Results

Experiments in the Mars Wind Tunnel at NASA Ames Research Center show that under Mars conditions, spacesuit materials are highly susceptible to dust contamination when exposed to windblown soil. This effect was suspected from knowledge of the interaction of electrostatically adhesive dust with solid surfaces in general. However, it is important to evaluate the respective roles of materials, meteorological and radiation effects, and the character of the soil. The tunnel permits evaluation of dust contamination and sand abrasion of space suits by simulating both pressure and wind conditions on Mars. The long-term function of space suits on Mars will be primarily threatened by dust contamination. Lunar EVA activities caused heavy contamination of space suits, but the problem was never seriously manifest because of the brief utilization of the suits, and the suits were never reused. Electrostatically adhering dust grains have various detrimental effects: (1) penetration and subsequent wear of suit fabrics, (2) viewing obscuration through visors and scratching/pitting of visor surfaces, (3) penetration, wear, and subsequent seizing-up of mechanical suit joints, (4) changes in albedo and therefore of radiation properties of external heat-exchanger systems, (5) changes in electrical conductivity of suit surfaces which may affect tribocharging of suits and create spurious discharge effects detrimental to suit electronics/radio systems. Additional information is contained in the original.

Marshall, J.↗
NASA NTRS1997

Crystalline Colloidal Arrays in Polymer Matrices

Crystalline Colloidal Arrays (CCA, also known as colloidal crystals), composed of aqueous or nonaqueous dispersions of self-assembled nanosized polymer colloidal spheres, are emerging toward the development of advanced optical devices for technological applications. The spontaneous self assembly of polymer spheres in a dielectric medium results from the electrostatic repulsive interaction between particles of uniform size and charge distribution. In a way similar to atomic crystals that diffract X-rays, CCA dispersions in thin quartz cells selectively and efficiently Bragg diffract the incident visible light. The reason for this diffraction is because the lattice (body or face centered cubic) spacing is on the order of the wavelength of visible light. Unlike the atomic crystals that diffract a fixed wavelength, colloidal crystals in principle, depending on the particle size, particle number and charge density, can diffract W, Vis or IR light. Therefore, the CCA dispersions can be used as laser filters. Besides, the diffraction intensity depends on the refractive index mismatch between polymer spheres and dielectric medium; therefore, it is possible to modulate incident light intensities by manipulating the index of either the spheres or the medium. Our interest in CCA is in the fabrication of all-optical devices such as optical switches, limiters, and spatial light modulators for optical signal processing. The two major requirements from a materials standpoint are the incorporation of suitable nonlinear optical materials (NLO) into polymer spheres which will allow us to alter the refractive index of the spheres by intense laser radiation, and preparation of solid CCA filters which can resist laser damage. The fabrication of solid composite filters not only has the advantage that the films are easier to handle, but also the arrays in solid films are more robust than in liquid media. In this paper, we report the photopolymerization process used to trap CCA in polymer matrices, the factors which affect the optical diffraction qualities of resulting polymer films, and methods to improve the efficiencies of solid optical filters. Before this, we also present the experimental demonstration, of controlling the optical diffraction intensities from aqueous CCA dispersions by varying the temperature, which establishes the feasibility of fabricating all-optical switching devices with nonlinear periodic array structures.

Sunkara, Hari B.↗